Magnetic field-temperature phase diagram of multiferroic
Abstract
We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $$[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Dept. of Chemistry
- Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Nanoscale Science and Technology
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab)
- North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry. Dept. of Physics and Astronomy
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Tennessee, Knoxville, TN (United States); Florida State Univ., Tallahassee, FL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1514966
- Report Number(s):
- LA-UR-17-27392
Journal ID: ISSN 2469-9950
- Grant/Contract Number:
- 89233218CNA000001; DMR-1707846; CHE 1464955; DMR-1157490
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 96; Journal Issue: 10; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; antiferromagnetism; magnetic phase transitions; molecular magnetism; phase diagrams
Citation Formats
Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3. United States: N. p., 2017.
Web. doi:10.1103/PhysRevB.96.104424.
Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., & Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3. United States. doi:https://doi.org/10.1103/PhysRevB.96.104424
Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Mon .
"Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3". United States. doi:https://doi.org/10.1103/PhysRevB.96.104424. https://www.osti.gov/servlets/purl/1514966.
@article{osti_1514966,
title = {Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3},
author = {Clune, A. J. and Hughey, K. D. and Lee, C. and Abhyankar, N. and Ding, X. and Dalal, N. S. and Whangbo, M. -H. and Singleton, J. and Musfeldt, J. L.},
abstractNote = {We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.},
doi = {10.1103/PhysRevB.96.104424},
journal = {Physical Review B},
number = 10,
volume = 96,
place = {United States},
year = {2017},
month = {9}
}
Web of Science
Figures / Tables:

Works referenced in this record:
Strong spin-phonon coupling in infrared and Raman spectra of
journal, February 2014
- Kamba, S.; Goian, V.; Skoromets, V.
- Physical Review B, Vol. 89, Issue 6
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Magnetic nanopantograph in the SrCu 2 (BO 3 ) 2 Shastry–Sutherland lattice
journal, February 2015
- Radtke, Guillaume; Saúl, Andrés; Dabkowska, Hanna A.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 7
Magnetic-field-induced color change in -Fe O single crystals
journal, May 2012
- Chen, P.; Lee, N.; McGill, S.
- Physical Review B, Vol. 85, Issue 17
Electron-Phonon and Magnetoelastic Interactions in Ferromagnetic
journal, July 2013
- Brinzari, T. V.; Haraldsen, J. T.; Chen, P.
- Physical Review Letters, Vol. 111, Issue 4
Order–Disorder Transition and Weak Ferromagnetism in the Perovskite Metal Formate Frameworks of [(CH 3 ) 2 NH 2 ][M(HCOO) 3 ] and [(CH 3 ) 2 ND 2 ][M(HCOO) 3 ] (M = Ni, Mn)
journal, December 2013
- Mączka, Mirosław; Gągor, Anna; Macalik, Bogusław
- Inorganic Chemistry, Vol. 53, Issue 1
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
journal, August 2008
- Goddard, P. A.; Singleton, J.; Sengupta, P.
- New Journal of Physics, Vol. 10, Issue 8
Computer graphics and graphical user interfaces as tools in simulations of matter at the atomic scale
journal, October 2003
- Kokalj, Anton
- Computational Materials Science, Vol. 28, Issue 2
A 3D Porous Cobalt−Organic Framework Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition
journal, November 2007
- Huang, You-Gui; Yuan, Da-Qiang; Pan, Long
- Inorganic Chemistry, Vol. 46, Issue 23
Magnetic Susceptibility of and with Added Titanium
journal, June 1950
- Morin, F. J.
- Physical Review, Vol. 78, Issue 6
Multiferroics of spin origin
journal, July 2014
- Tokura, Yoshinori; Seki, Shinichiro; Nagaosa, Naoto
- Reports on Progress in Physics, Vol. 77, Issue 7
Magnetic Structure and Exchange Interactions in Quasi-One-Dimensional MnCl 2 (urea) 2
journal, December 2015
- Manson, Jamie L.; Huang, Qing-zhen; Brown, Craig M.
- Inorganic Chemistry, Vol. 54, Issue 24
Spin-Flopping in MnF2 by High Magnetic Fields
journal, March 1961
- Jacobs, I. S.
- Journal of Applied Physics, Vol. 32, Issue 3
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Understanding Ferroelectricity in the Pb-Free Perovskite-Like Metal–Organic Framework [(CH 3 ) 2 NH 2 ]Zn(HCOO) 3 : Dielectric, 2D NMR, and Theoretical Studies
journal, March 2017
- Abhyankar, Nandita; Kweon, Jin Jung; Orio, Maylis
- The Journal of Physical Chemistry C, Vol. 121, Issue 11
Magnetoelectric coupling in the paramagnetic state of a metal-organic framework
journal, June 2013
- Wang, W.; Yan, L. -Q.; Cong, J. -Z.
- Scientific Reports, Vol. 3, Issue 1
Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework
journal, August 2014
- Tian, Ying; Stroppa, Alessandro; Chai, Yisheng
- Scientific Reports, Vol. 4, Issue 1
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998
- Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
- Physical Review B, Vol. 57, Issue 3, p. 1505-1509
Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an quantum antiferromagnet
journal, April 2017
- Brambleby, Jamie; Manson, Jamie L.; Goddard, Paul A.
- Physical Review B, Vol. 95, Issue 13
Magnetochromic effect in multiferroic ( , Dy)
journal, May 2015
- Chen, P.; Holinsworth, B. S.; O'Neal, K. R.
- Physical Review B, Vol. 91, Issue 20
Quantum Critical Transition Amplifies Magnetoelastic Coupling in
journal, June 2013
- Brinzari, T. V.; Chen, P.; Sun, Q. -C.
- Physical Review Letters, Vol. 110, Issue 23
Efficient synthesis and tailoring of magnetic and dielectric properties of Pb-free perovskite-like ABX 3 metal-organic frameworks
journal, July 2016
- Abhyankar, Nandita; Lee, Minseong; Foley, Megan
- physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8
Quantum criticality
journal, January 2005
- Coleman, Piers; Schofield, Andrew J.
- Nature, Vol. 433, Issue 7023
Quantum Tunneling of Magnetization in a Metal-Organic Framework
journal, January 2014
- Tian, Ying; Wang, Wei; Chai, Yisheng
- Physical Review Letters, Vol. 112, Issue 1
Magnetoelastic Coupling through the Antiferromagnet-to-Ferromagnet Transition of Quasi-Two-Dimensional Using Infrared Spectroscopy
journal, October 2009
- Musfeldt, J. L.; Vergara, L. I.; Brinzari, T. V.
- Physical Review Letters, Vol. 103, Issue 15
Magnetic field induced quantum phase transition of the antiferromagnet
journal, February 2010
- Nellutla, S.; Pati, M.; Jo, Y. -J.
- Physical Review B, Vol. 81, Issue 6
Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal-Organic Framework
journal, May 2011
- Stroppa, Alessandro; Jain, Prashant; Barone, Paolo
- Angewandte Chemie International Edition, Vol. 50, Issue 26
Successive Magnetic-Field-Induced Transitions and Colossal Magnetoelectric Effect in
journal, September 2015
- Kim, Jae Wook; Artyukhin, S.; Mun, E. D.
- Physical Review Letters, Vol. 115, Issue 13
Growth of centimeter-sized [(CH 3 ) 2 NH 2 ][Mn(HCOO) 3 ] hybrid formate perovskite single crystals and Raman evidence of pressure-induced phase transitions
journal, January 2017
- Xin, Lipeng; Fan, Zhen; Li, Guanghui
- New Journal of Chemistry, Vol. 41, Issue 1
Muon spin relaxation investigation of magnetic ordering in the hybrid organic-inorganic perovskites
journal, July 2010
- Baker, P. J.; Lancaster, T.; Franke, I.
- Physical Review B, Vol. 82, Issue 1
Strong spin-lattice coupling in CrSiTe 3
journal, April 2015
- Casto, L. D.; Clune, A. J.; Yokosuk, M. O.
- APL Materials, Vol. 3, Issue 4
Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX 3 Architecture
journal, September 2009
- Jain, Prashant; Ramachandran, Vasanth; Clark, Ronald J.
- Journal of the American Chemical Society, Vol. 131, Issue 38
Evolution of magnetic interactions in a pressure-induced Jahn-Teller driven magnetic dimensionality switch
journal, June 2013
- Ghannadzadeh, S.; Möller, J. S.; Goddard, P. A.
- Physical Review B, Vol. 87, Issue 24
Antiferromagnetic Spin Seebeck Effect
journal, March 2016
- Wu, Stephen M.; Zhang, Wei; Kc, Amit
- Physical Review Letters, Vol. 116, Issue 9
Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials
journal, July 2004
- Wang, Xin-Yi; Gan, Lin; Zhang, Shi-Wei
- Inorganic Chemistry, Vol. 43, Issue 15
Magnetic behavior of the metal organic framework [(CH 3 ) 2 NH 2 ]Co(HCOO) 3
journal, January 2015
- Vinod, K.; Deepak, C. S.; Sharma, Shilpam
- RSC Advances, Vol. 5, Issue 47
Magnetoelectric Coupling through the Spin Flop Transition in
journal, September 2016
- Yokosuk, M. O.; al-Wahish, Amal; Artyukhin, Sergey
- Physical Review Letters, Vol. 117, Issue 14
Local structure of the metal–organic perovskite dimethylammonium manganese( ii ) formate
journal, January 2016
- Duncan, Helen D.; Dove, Martin T.; Keen, David A.
- Dalton Transactions, Vol. 45, Issue 10
Switchable electric polarization and ferroelectric domains in a metal-organic-framework
journal, September 2016
- Jain, Prashant; Stroppa, Alessandro; Nabok, Dmitrii
- npj Quantum Materials, Vol. 1, Issue 1
Works referencing / citing this record:
On the origin of ferroelectric structural phases in perovskite-like metal–organic formate
journal, January 2018
- Sieradzki, Adam; Mączka, Mirosław; Simenas, Mantas
- Journal of Materials Chemistry C, Vol. 6, Issue 35
On the origin of ferroelectric structural phases in perovskite-like metal–organic formate
journal, January 2018
- Sieradzki, Adam; Mączka, Mirosław; Simenas, Mantas
- Journal of Materials Chemistry C, Vol. 6, Issue 35
Strain Coupling and Dynamic Relaxation in a Molecular Perovskite-Like Multiferroic Metal-Organic Framework
journal, November 2018
- Xin, Lipeng; Zhang, Zhiying; Carpenter, Michael A.
- Advanced Functional Materials, Vol. 28, Issue 52
Magnetic field-temperature phase diagram of multiferroic (NH4)2FeCl5·H2O
journal, August 2019
- Clune, Amanda J.; Nam, Jisoo; Lee, Minseong
- npj Quantum Materials, Vol. 4, Issue 1
Electron paramagnetic resonance of a copper doped [(CH 3 ) 2 NH 2 ][Zn(HCOO) 3 ] hybrid perovskite framework
journal, January 2018
- Šimėnas, Mantas; Ciupa, Aneta; Usevičius, Gediminas
- Physical Chemistry Chemical Physics, Vol. 20, Issue 17
Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields
journal, January 2018
- Hu, Lin; Wang, Zhe; Wang, Hui
- RSC Advances, Vol. 8, Issue 25
Elucidation of dipolar dynamics and the nature of structural phases in the [(CH 3 ) 2 NH 2 ][Zn(HCOO) 3 ] hybrid perovskite framework
journal, January 2019
- Šimėnas, Mantas; Balčiūnas, Sergejus; Ciupa, Aneta
- Journal of Materials Chemistry C, Vol. 7, Issue 22
First-principles study of the structural, electronic, magnetic, and ferroelectric properties of a charge-ordered iron( ii )-iron( iii ) formate framework
journal, September 2019
- Tang, Gang; Ren, Wei; Hong, Jiawang
- The Journal of Chemical Physics, Vol. 151, Issue 12
Phonon mode links ferroicities in multiferroic
journal, November 2017
- Hughey, Kendall D.; Clune, Amanda J.; Yokosuk, Michael O.
- Physical Review B, Vol. 96, Issue 18
Figures / Tables found in this record: