Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3

doi:10.1103/PhysRevB.96.104424

Title: Magnetic field-temperature phase diagram of multiferroic $[{({CH}_{3})}_{2} {NH}_{2}] Mn {(HCOO)}_{3}$

Abstract

We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $$[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.

Authors:

Clune, A. J. ^[1]; Hughey, K. D. ^[1]; Lee, C. ^[2]; Abhyankar, N. ^[3]; Ding, X. ^[4]; Dalal, N. S. ^[5]; Whangbo, M. -H. ^[6]; Singleton, J. ^[4]; Musfeldt, J. L. ^[7]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Dept. of Chemistry
Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Nanoscale Science and Technology
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab)
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry. Dept. of Physics and Astronomy

Publication Date:: 2017-09-18

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Tennessee, Knoxville, TN (United States); Florida State Univ., Tallahassee, FL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)

OSTI Identifier:: 1514966

Report Number(s):: [LA-UR-17-27392]
[Journal ID: ISSN 2469-9950]

Grant/Contract Number:: [89233218CNA000001; DMR-1707846; CHE 1464955; DMR-1157490]

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: [ Journal Volume: 96; Journal Issue: 10]; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; antiferromagnetism; magnetic phase transitions; molecular magnetism; phase diagrams

Citation Formats


                    Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3.  United States: N. p., 2017. 
        Web.  doi:10.1103/PhysRevB.96.104424.

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                    Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., & Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3.  United States.  doi:10.1103/PhysRevB.96.104424.

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                    Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Mon .  
        "Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3".  United States.  doi:10.1103/PhysRevB.96.104424.  https://www.osti.gov/servlets/purl/1514966.

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@article{osti_1514966,

  title        = {Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3},

  author       = {Clune, A. J. and Hughey, K. D. and Lee, C. and Abhyankar, N. and Ding, X. and Dalal, N. S. and Whangbo, M. -H. and Singleton, J. and Musfeldt, J. L.},

  abstractNote = {We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.},

  doi          = {10.1103/PhysRevB.96.104424},

  journal      = {Physical Review B},

  number       = [10],

  volume       = [96],

  place        = {United States},

  year         = {2017},

  month        = {9}

}

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Journal Article:

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DOI: 10.1103/PhysRevB.96.104424

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Cited by: 18 works

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Figures / Tables:

FIG. 1: (a) Crystal structure of [(CH₃)₂NH₂]Mn(HCOO)₃ in the low temperature phase. (b) Schematic depicting the electric and magnetic transitions that occur in this compound. (FE = ferroelectric, PE = paraelectric, cAFM = canted antiferromagnetic, and PM = paramagnetic)

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Works referenced in this record:

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Works referencing / citing this record:

On the origin of ferroelectric structural phases in perovskite-like metal–organic formate
journal, January 2018

Sieradzki, Adam; Mączka, Mirosław; Simenas, Mantas
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Title: Magnetic field-temperature phase diagram of multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3

Abstract

Citation Formats

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Magnetic field induced quantum phase transition of the S = 1 2 antiferromagnet K 2 NaCrO 8 journal, February 2010

Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal-Organic Framework journal, May 2011

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Title: Magnetic field-temperature phase diagram of multiferroic $[{({CH}_{3})}_{2} {NH}_{2}] Mn {(HCOO)}_{3}$

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journal, December 1994

Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
journal, August 2008

Computer graphics and graphical user interfaces as tools in simulations of matter at the atomic scale
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A 3D Porous Cobalt−Organic Framework Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition
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From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Understanding Ferroelectricity in the Pb-Free Perovskite-Like Metal–Organic Framework [(CH ₃ ) ₂ NH ₂ ]Zn(HCOO) ₃ : Dielectric, 2D NMR, and Theoretical Studies
journal, March 2017

Magnetoelectric coupling in the paramagnetic state of a metal-organic framework
journal, June 2013

Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework
journal, August 2014

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998

Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an $S = 1$ quantum antiferromagnet
journal, April 2017

Magnetochromic effect in multiferroic $R {In}_{1 - x} {Mn}_{x} O_{3}$ ( $R = Tb$ , Dy)
journal, May 2015

Quantum Critical Transition Amplifies Magnetoelastic Coupling in $Mn [N (CN)_{2}]_{2}$
journal, June 2013

Efficient synthesis and tailoring of magnetic and dielectric properties of Pb-free perovskite-like ABX ₃ metal-organic frameworks
journal, July 2016

Quantum criticality
journal, January 2005

Quantum Tunneling of Magnetization in a Metal-Organic Framework
journal, January 2014

Magnetoelastic Coupling through the Antiferromagnet-to-Ferromagnet Transition of Quasi-Two-Dimensional $[Cu ({HF}_{2}) (pyz)_{2}] {BF}_{4}$ Using Infrared Spectroscopy
journal, October 2009

Magnetic field induced quantum phase transition of the $S = \frac{1}{2}$ antiferromagnet $K_{2} {NaCrO}_{8}$
journal, February 2010

Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal-Organic Framework
journal, May 2011

Successive Magnetic-Field-Induced Transitions and Colossal Magnetoelectric Effect in ${Ni}_{3} {TeO}_{6}$
journal, September 2015

Growth of centimeter-sized [(CH ₃ ) ₂ NH ₂ ][Mn(HCOO) ₃ ] hybrid formate perovskite single crystals and Raman evidence of pressure-induced phase transitions
journal, January 2017

Muon spin relaxation investigation of magnetic ordering in the hybrid organic-inorganic perovskites $[{({CH}_{3})}_{2} {NH}_{2}] M {(HCOO)}_{3}$ $(M = Ni, Co, Mn, Cu)$
journal, July 2010

Strong spin-lattice coupling in CrSiTe ₃
journal, April 2015

Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX ₃ Architecture
journal, September 2009

Evolution of magnetic interactions in a pressure-induced Jahn-Teller driven magnetic dimensionality switch
journal, June 2013

Antiferromagnetic Spin Seebeck Effect
journal, March 2016

Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials
journal, July 2004

Magnetic behavior of the metal organic framework [(CH ₃ ) ₂ NH ₂ ]Co(HCOO) ₃
journal, January 2015

Magnetoelectric Coupling through the Spin Flop Transition in ${Ni}_{3} {TeO}_{6}$
journal, September 2016

Local structure of the metal–organic perovskite dimethylammonium manganese( ii ) formate
journal, January 2016

Switchable electric polarization and ferroelectric domains in a metal-organic-framework
journal, September 2016

On the origin of ferroelectric structural phases in perovskite-like metal–organic formate
journal, January 2018