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Title: Magnetic field-temperature phase diagram of multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3

Abstract

We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $$[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.

Authors:
 [1];  [1];  [2];  [3];  [4];  [5];  [6];  [4];  [7]
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  1. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
  2. North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry; Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of). Dept. of Chemistry
  3. Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Nanoscale Science and Technology
  4. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  5. Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry. National High Magnetic Field Lab. (MagLab)
  6. North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
  7. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry. Dept. of Physics and Astronomy
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Tennessee, Knoxville, TN (United States); Florida State Univ., Tallahassee, FL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1514966
Report Number(s):
LA-UR-17-27392
Journal ID: ISSN 2469-9950
Grant/Contract Number:  
89233218CNA000001; DMR-1707846; CHE 1464955; DMR-1157490
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 96; Journal Issue: 10; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; antiferromagnetism; magnetic phase transitions; molecular magnetism; phase diagrams

Citation Formats

Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3. United States: N. p., 2017. Web. doi:10.1103/PhysRevB.96.104424.
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Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., & Musfeldt, J. L. Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3. United States. doi:https://doi.org/10.1103/PhysRevB.96.104424
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Clune, A. J., Hughey, K. D., Lee, C., Abhyankar, N., Ding, X., Dalal, N. S., Whangbo, M. -H., Singleton, J., and Musfeldt, J. L. Mon . "Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3". United States. doi:https://doi.org/10.1103/PhysRevB.96.104424. https://www.osti.gov/servlets/purl/1514966.
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@article{osti_1514966,
title = {Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3},
author = {Clune, A. J. and Hughey, K. D. and Lee, C. and Abhyankar, N. and Ding, X. and Dalal, N. S. and Whangbo, M. -H. and Singleton, J. and Musfeldt, J. L.},
abstractNote = {We combined here pulsed field magnetization and first-principles spin-density calculations to reveal the magnetic field-temperature phase diagram and spin state character in multiferroic $[{({\mathrm{CH}}_{3})}_{2}{\mathrm{NH}}_{2}]\mathrm{Mn}{(\mathrm{HCOO})}_{3}$. Despite similarities with the rare earth manganites, the phase diagram is analogous to other Mn-based quantum magnets with a 0.31 T spin flop, a 15.3 T transition to the fully polarized state, and short-range correlations that persist above the ordering temperature. The experimentally accessible saturation field opens the door to exploration of the high-field phase.},
doi = {10.1103/PhysRevB.96.104424},
journal = {Physical Review B},
number = 10,
volume = 96,
place = {United States},
year = {2017},
month = {9}
}
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Journal Article:
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DOI:  https://doi.org/10.1103/PhysRevB.96.104424
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Cited by: 19 works
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Figures / Tables:

FIG. 1 FIG. 1: (a) Crystal structure of [(CH3)2NH2]Mn(HCOO)3 in the low temperature phase. (b) Schematic depicting the electric and magnetic transitions that occur in this compound. (FE = ferroelectric, PE = paraelectric, cAFM = canted antiferromagnetic, and PM = paramagnetic)
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