Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change
Abstract
Four principal intra-particle phenomena occur in a highly concerted manner during the pyrolysis of lignocellulosic materials: heat transfer, mass transfer, chemical reactions, and phase changes. Achieving a holistic understanding of these processes has been challenged by their intricate coupling, high temperatures, and rapid rates at which they occur. Heat and mass transfer have been well studied at the single-particle level but their coupling with chemical reactions and phase change within single particle models remains problematic. Equally challenging is the multiscale coupling of reactor- and single particle-scale models. Too little attention has been given to phase change. Similarly, the presence of oligomeric compounds (constituting up to 20% of the oil) has not been fully accounted for in chemical reaction schemes and physical models developed for pyrolysis. Recent studies have shown that a multiscale approach is key to predictive modelling across a variety of reactor systems. Historical and recent developments are outlined in this pyrolysis review paper regarding these four intra-particle phenomena, as well as modelling efforts to capture their effect on product yields and composition. It is critical for the design of future biomass pyrolysis systems to appropriately account for all four intra-particle phenomena and their inter-connectivities in order to predict,more »
- Authors:
-
[1];
[3];
[2];
[1]
- Biosciences Center, National Renewable Energy Laboratory, Golden, USA
- Facultad de Minas, Universidad Nacional de Colombia, Medellín, Colombia
- Biological Systems Engineering, Washington State University, Pullman, USA
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
- OSTI Identifier:
- 1514727
- Alternate Identifier(s):
- OSTI ID: 1510138; OSTI ID: 1512663
- Report Number(s):
- NREL/JA-2700-73833
Journal ID: ISSN 1463-9262; GRCHFJ
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Published Article
- Journal Name:
- Green Chemistry
- Additional Journal Information:
- Journal Name: Green Chemistry Journal Volume: 21 Journal Issue: 11; Journal ID: ISSN 1463-9262
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; lignocellulosic materials; pyrolysis
Citation Formats
Pecha, M. Brennan, Arbelaez, Jorge Ivan Montoya, Garcia-Perez, Manuel, Chejne, Farid, and Ciesielski, Peter N. Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9GC00585D.
Pecha, M. Brennan, Arbelaez, Jorge Ivan Montoya, Garcia-Perez, Manuel, Chejne, Farid, & Ciesielski, Peter N. Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change. United Kingdom. https://doi.org/10.1039/C9GC00585D
Pecha, M. Brennan, Arbelaez, Jorge Ivan Montoya, Garcia-Perez, Manuel, Chejne, Farid, and Ciesielski, Peter N. Tue .
"Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change". United Kingdom. https://doi.org/10.1039/C9GC00585D.
@article{osti_1514727,
title = {Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change},
author = {Pecha, M. Brennan and Arbelaez, Jorge Ivan Montoya and Garcia-Perez, Manuel and Chejne, Farid and Ciesielski, Peter N.},
abstractNote = {Four principal intra-particle phenomena occur in a highly concerted manner during the pyrolysis of lignocellulosic materials: heat transfer, mass transfer, chemical reactions, and phase changes. Achieving a holistic understanding of these processes has been challenged by their intricate coupling, high temperatures, and rapid rates at which they occur. Heat and mass transfer have been well studied at the single-particle level but their coupling with chemical reactions and phase change within single particle models remains problematic. Equally challenging is the multiscale coupling of reactor- and single particle-scale models. Too little attention has been given to phase change. Similarly, the presence of oligomeric compounds (constituting up to 20% of the oil) has not been fully accounted for in chemical reaction schemes and physical models developed for pyrolysis. Recent studies have shown that a multiscale approach is key to predictive modelling across a variety of reactor systems. Historical and recent developments are outlined in this pyrolysis review paper regarding these four intra-particle phenomena, as well as modelling efforts to capture their effect on product yields and composition. It is critical for the design of future biomass pyrolysis systems to appropriately account for all four intra-particle phenomena and their inter-connectivities in order to predict, achieve, and maintain optimal operation.},
doi = {10.1039/C9GC00585D},
journal = {Green Chemistry},
number = 11,
volume = 21,
place = {United Kingdom},
year = {Tue Jun 04 00:00:00 EDT 2019},
month = {Tue Jun 04 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9GC00585D
https://doi.org/10.1039/C9GC00585D
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 94 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Fig. 1: Depiction of the four primary phenomena that occur during biomass pyrolysis: heat and mass transfer occur as anisotropic processes due to the aspherical geometry and directional internal porosity of biomass particles (left); these are coupled to thermally-drivel chemical reactions which promote transition into molten and vapor phases (right).
All figures and tables
(22 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Cellulose-Lignin interactions during slow and fast pyrolysis
journal, July 2015
- Hilbers, Tim J.; Wang, Zhouhong; Pecha, Brennan
- Journal of Analytical and Applied Pyrolysis, Vol. 114
Influence of inorganic species on the formation of polysaccharide and lignin degradation products in the analytical pyrolysis of pulps
journal, October 1995
- Kleen, Marjatta; Gellerstedt, Göran
- Journal of Analytical and Applied Pyrolysis, Vol. 35, Issue 1
Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies
journal, May 2011
- White, John E.; Catallo, W. James; Legendre, Benjamin L.
- Journal of Analytical and Applied Pyrolysis, Vol. 91, Issue 1
An Integral Model for the Transient Pyrolysis of Solid Materials
journal, January 1997
- Moghtaderi, B.; Novozhilov, V.; Fletcher, D.
- Fire and Materials, Vol. 21, Issue 1
Temperature and heating rate of solid particles undergoing a thermal decomposition. Which criteria for characterizing fast pyrolysis?
journal, May 2015
- Lédé, Jacques; Authier, Olivier
- Journal of Analytical and Applied Pyrolysis, Vol. 113
Identification of the fractions responsible for morphology conservation in lignocellulosic pyrolysis: Visualization studies of sugarcane bagasse and its pseudo-components
journal, January 2017
- Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne
- Journal of Analytical and Applied Pyrolysis, Vol. 123
Chemical and morphological evaluation of chars produced from primary biomass constituents: Cellulose, xylan, and lignin
journal, September 2017
- Smith, Matthew W.; Pecha, Brennan; Helms, Greg
- Biomass and Bioenergy, Vol. 104
Effect of Pressure on Pyrolysis of Milled Wood Lignin and Acid-Washed Hybrid Poplar Wood
journal, August 2017
- Pecha, M. Brennan; Terrell, Evan; Montoya, Jorge Ivan
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 32
Product yields and kinetics from the vapor phase cracking of wood pyrolysis tars
journal, January 1989
- Boroson, Michael L.; Howard, Jack B.; Longwell, John P.
- AIChE Journal, Vol. 35, Issue 1
Mineral matter effects in rapid pyrolysis of beech wood
journal, March 1997
- Nik-Azar, M.; Hajaligol, M. R.; Sohrabi, M.
- Fuel Processing Technology, Vol. 51, Issue 1-2
Evaluation of Vapor-Phase Reactivity of Primary Tar Produced by Flash Pyrolysis of Coal
journal, March 1995
- Hayashi, Jun-ichiro; Amamoto, Shinobu; Kusakabe, Katsuki
- Energy & Fuels, Vol. 9, Issue 2
Modeling intra- and extra-particle processes of wood fast pyrolysis
journal, October 2002
- Di Blasi, Colomba
- AIChE Journal, Vol. 48, Issue 10
Influence of Biomass Pyrolysis Temperature, Heating Rate and Type of Biomass on Produced Char in a Fluidized Bed Reactor
journal, April 2014
- Iwasaki, Toshiyuki; Suzuki, Seiichi; Kojima, Toshinori
- Energy and Environment Research, Vol. 4, Issue 2
Modified Pyroprobe Captive Sample Reactor: Characterization of Reactor and Cellulose Pyrolysis at Vacuum and Atmospheric Pressures
journal, April 2017
- Pecha, M. Brennan; Montoya, Jorge Ivan; Ivory, Cornelius
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 18
Optical and Mass Spectrometric Study of the Pyrolysis Gas of Wood Particles
journal, February 2003
- Brackmann, Christian; Aldén, Marcus; Bengtsson, Per-Erik
- Applied Spectroscopy, Vol. 57, Issue 2
The chain length effect in pyrolysis: bridging the gap between glucose and cellulose
journal, January 2012
- Mettler, Matthew S.; Paulsen, Alex D.; Vlachos, Dionisios G.
- Green Chemistry, Vol. 14, Issue 5
Bio-oil production from Colombian bagasse by fast pyrolysis in a fluidized bed: An experimental study
journal, March 2015
- Montoya, J. I.; Valdés, C.; Chejne, F.
- Journal of Analytical and Applied Pyrolysis, Vol. 112
FTIR study of pyrolysis products evolving from typical agricultural residues
journal, July 2010
- Fu, Peng; Hu, Song; Xiang, Jun
- Journal of Analytical and Applied Pyrolysis, Vol. 88, Issue 2
Effect of temperature and heating rate on product distribution from the pyrolysis of sugarcane bagasse in a hot plate reactor
journal, January 2017
- Montoya, Jorge; Pecha, Brennan; Roman, David
- Journal of Analytical and Applied Pyrolysis, Vol. 123
Molecular weight decrease in the early pyrolysis of crystalline and amorphous cellulose
journal, December 1973
- Broido, A.; Javier-Son, A. C.; Ouano, A. C.
- Journal of Applied Polymer Science, Vol. 17, Issue 12
Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C
journal, August 2012
- Agarwal, Vishal; Dauenhauer, Paul J.; Huber, George W.
- Journal of the American Chemical Society, Vol. 134, Issue 36
An algorithm for determining the kinetics of devolatilisation of complex solid fuels from thermogravimetric experiments
journal, April 2006
- Scott, S. A.; Dennis, J. S.; Davidson, J. F.
- Chemical Engineering Science, Vol. 61, Issue 8
Influence of linkage position and orientation in pyrolysis of polysaccharides: A study of several glucans
journal, March 1992
- Ponder, Glenn R.; Richards, Geoffrey N.; Stevenson, Thomas T.
- Journal of Analytical and Applied Pyrolysis, Vol. 22, Issue 3
Five Rules for Measuring Biomass Pyrolysis Rates: Pulse-Heated Analysis of Solid Reaction Kinetics of Lignocellulosic Biomass
journal, November 2017
- Maduskar, Saurabh; Facas, Gregory G.; Papageorgiou, Costas
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 1
High-speed imaging of biomass particles heated with a laser
journal, September 2013
- Carlsson, Per; Lycksam, Henrik; Gren, Per
- Journal of Analytical and Applied Pyrolysis, Vol. 103
Mathematical modelling of biomass pyrolysis phenomena
journal, November 1985
- Antal, Michael Jerry
- Fuel, Vol. 64, Issue 11
Influence of mineral matter on pyrolysis of palm oil wastes
journal, September 2006
- Yang, H.; Yan, R.; Chen, H.
- Combustion and Flame, Vol. 146, Issue 4
Convection and radiation combined surface heat transfer coefficient in baking ovens
journal, October 2009
- Sakin, Melike; Kaymak-Ertekin, Figen; Ilicali, Coskan
- Journal of Food Engineering, Vol. 94, Issue 3-4
Effect of cellulose crystallinity on the formation of a liquid intermediate and on product distribution during pyrolysis
journal, March 2013
- Wang, Zhouhong; McDonald, Armando G.; Westerhof, Roel J. M.
- Journal of Analytical and Applied Pyrolysis, Vol. 100
Interactions of structurally different hemicelluloses with nanofibrillar cellulose
journal, August 2011
- Eronen, Paula; Österberg, Monika; Heikkinen, Susanna
- Carbohydrate Polymers, Vol. 86, Issue 3
Kinetic modeling of biomass pyrolysis
journal, June 1997
- Várhegyi, Gábor; Antal, Michael Jerry; Jakab, Emma
- Journal of Analytical and Applied Pyrolysis, Vol. 42, Issue 1
Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics
journal, April 1995
- Milosavljevic, Ivan; Suuberg, Eric M.
- Industrial & Engineering Chemistry Research, Vol. 34, Issue 4
Effect of Particle Geometry and Microstructure on Fast Pyrolysis of Beech Wood
journal, March 2012
- Westerhof, R. J. M.; Nygård, H. S.; van Swaaij, W. P. M.
- Energy & Fuels, Vol. 26, Issue 4
Application of the distributed activation energy model to biomass and biomass constituents devolatilization
journal, October 2009
- Navarro, María V.; Murillo, Ramón; Mastral, Ana M.
- AIChE Journal, Vol. 55, Issue 10
Modelling solid-convective flash pyrolysis of straw and wood in the Pyrolysis Centrifuge Reactor
journal, June 2009
- Bech, Niels; Larsen, Morten Boberg; Jensen, Peter Arendt
- Biomass and Bioenergy, Vol. 33, Issue 6-7
Bio-oil production from rapid pyrolysis of cottonseed cake: product yields and compositions
journal, June 2006
- Ozbay, Nurgül; Pütün, Ayşe E.; Pütün, Ersan
- International Journal of Energy Research, Vol. 30, Issue 7
In Situ Analysis of Biomass Pyrolysis by High Temperature Rheology in Relations with 1 H NMR
journal, October 2012
- Dufour, Anthony; Castro-Díaz, Miguel; Marchal, Philippe
- Energy & Fuels, Vol. 26, Issue 10
Pretreatment of poplar wood for fast pyrolysis: rate of cation removal
journal, February 2001
- Scott, Donald S.; Paterson, Lachlan; Piskorz, Jan
- Journal of Analytical and Applied Pyrolysis, Vol. 57, Issue 2, p. 169-176
Thermal Effects in Cellulose Pyrolysis: Relationship to Char Formation Processes
journal, January 1996
- Milosavljevic, Ivan; Oja, Vahur; Suuberg, Eric M.
- Industrial & Engineering Chemistry Research, Vol. 35, Issue 3
A mathematical model of wood pyrolysis
journal, April 1972
- Kung, Hsiang-Cheng
- Combustion and Flame, Vol. 18, Issue 2
Biomass pyrolysis—A review of modelling, process parameters and catalytic studies
journal, October 2015
- Sharma, Abhishek; Pareek, Vishnu; Zhang, Dongke
- Renewable and Sustainable Energy Reviews, Vol. 50
Effect of pyrolysis temperature on aromatic cluster size of cellulose char by quantitative multi cross-polarization 13C NMR with long range dipolar dephasing
journal, May 2017
- Smith, Matthew W.; Helms, Greg; McEwen, Jean-Sabin
- Carbon, Vol. 116
Is it possible to predict gas yields of any biomass after rapid pyrolysis at high temperature from its composition in cellulose, hemicellulose and lignin?
journal, March 2009
- Couhert, Carole; Commandre, Jean-Michel; Salvador, Sylvain
- Fuel, Vol. 88, Issue 3
A model for pyrolysis of wet wood
journal, January 1989
- Alves, S. S.; Figueiredo, J. L.
- Chemical Engineering Science, Vol. 44, Issue 12
Influence of extractives on mechanism of biomass pyrolysis
journal, February 2010
- Guo, Xiu-juan; Wang, Shu-rong; Wang, Kai-ge
- Journal of Fuel Chemistry and Technology, Vol. 38, Issue 1
Fast pyrolysis technology development
journal, March 2010
- Venderbosch, Rh; Prins, W.
- Biofuels, Bioproducts and Biorefining, Vol. 4, Issue 2
Quantitative and kinetic TG-FTIR investigation on three kinds of biomass pyrolysis
journal, November 2013
- Meng, Aihong; Zhou, Hui; Qin, Lin
- Journal of Analytical and Applied Pyrolysis, Vol. 104
Simultaneous drying and pyrolysis of solid fuel particles
journal, August 1996
- Saastamoinen, Jaakko; Richard, Jean-Robert
- Combustion and Flame, Vol. 106, Issue 3
Comprehensive Kinetic Modeling Study of Bio-oil Formation from Fast Pyrolysis of Biomass
journal, October 2010
- Calonaci, Matteo; Grana, Roberto; Barker Hemings, Emma
- Energy & Fuels, Vol. 24, Issue 10
Thermal Runaway in the Pyrolysis of Some Lignocellulosic Biomasses
journal, March 2014
- Di Blasi, C.; Branca, C.; Sarnataro, F. E.
- Energy & Fuels, Vol. 28, Issue 4
Cellulose char structure: a combined analytical Py-GC-MS, FTIR, and NMR study
journal, September 1994
- Pastorova, Ivana; Botto, Robert E.; Arisz, Peter W.
- Carbohydrate Research, Vol. 262, Issue 1
Pyrolytic oil from fixed bed pyrolysis of municipal solid waste and its characterization
journal, March 2005
- Nurul Islam, Mohammad; Nurul Islam, Mohammad; Rafiqul Alam Beg, Mohammad
- Renewable Energy, Vol. 30, Issue 3
The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis
journal, January 2009
- Mamleev, Vadim; Bourbigot, Serge; Le Bras, Michel
- Journal of Analytical and Applied Pyrolysis, Vol. 84, Issue 1
Transient behavior of devolatilization and char reaction during steam gasification of biomass
journal, April 2013
- Moon, Jihong; Lee, Jeungwoo; Lee, Uendo
- Bioresource Technology, Vol. 133
A review on operating parameters for optimum liquid oil yield in biomass pyrolysis
journal, September 2012
- Akhtar, Javaid; Saidina Amin, NorAishah
- Renewable and Sustainable Energy Reviews, Vol. 16, Issue 7
A mechanistic model of fast pyrolysis of glucose-based carbohydrates to predict bio-oil composition
journal, January 2012
- Vinu, R.; Broadbelt, Linda J.
- Energy & Environmental Science, Vol. 5, Issue 12
Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications
journal, July 2016
- Zhu, Hongli; Luo, Wei; Ciesielski, Peter N.
- Chemical Reviews, Vol. 116, Issue 16
Techno-economic comparison of biomass-to-transportation fuels via pyrolysis, gasification, and biochemical pathways
journal, November 2010
- Anex, Robert P.; Aden, Andy; Kazi, Feroz Kabir
- Fuel, Vol. 89, p. S29-S35
Vapor Pressures and Enthalpies of Sublimation of Polycyclic Aromatic Hydrocarbons and Their Derivatives
journal, May 1998
- Oja, Vahur; Suuberg, Eric M.
- Journal of Chemical & Engineering Data, Vol. 43, Issue 3
Approximations to the distributed activation energy model for the pyrolysis of coal
journal, April 2003
- Please, C. P.; McGuinness, M. J.; McElwain, D. L. S.
- Combustion and Flame, Vol. 133, Issue 1-2
Optimum conditions for maximising pyrolysis liquids of oil palm empty fruit bunches
journal, May 2011
- Sulaiman, F.; Abdullah, N.
- Energy, Vol. 36, Issue 5
Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins
journal, November 2011
- Asmadi, Mohd; Kawamoto, Haruo; Saka, Shiro
- Journal of Analytical and Applied Pyrolysis, Vol. 92, Issue 2
Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates
journal, January 2012
- Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D.
- Energy Environ. Sci., Vol. 5, Issue 1
Low temperature mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose
journal, January 2003
- McGrath, Thomas E.; Chan, W. Geoffrey; Hajaligol, Mohammad R.
- Journal of Analytical and Applied Pyrolysis, Vol. 66, Issue 1-2
Does energy consumption contribute to climate change? Evidence from major regions of the world
journal, August 2014
- Akhmat, Ghulam; Zaman, Khalid; Shukui, Tan
- Renewable and Sustainable Energy Reviews, Vol. 36
Current research on thermochemical conversion of biomass at the National Renewable Energy Laboratory
journal, April 2012
- Baldwin, Robert M.; Magrini-Bair, Kimberly A.; Nimlos, Mark R.
- Applied Catalysis B: Environmental, Vol. 115-116
Understanding the primary and secondary slow pyrolysis mechanisms of holocellulose, lignin and wood with laser-induced fluorescence
journal, August 2015
- Dieguez-Alonso, Alba; Anca-Couce, Andrés; Zobel, Nico
- Fuel, Vol. 153
Effect of different isolation methods on structure and properties of lignin from valonea of Quercus variabilis
journal, April 2016
- Yang, Lina; Wang, Dongmei; Zhou, Dan
- International Journal of Biological Macromolecules, Vol. 85
Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis
journal, March 2010
- Park, Won Chan; Atreya, Arvind; Baum, Howard R.
- Combustion and Flame, Vol. 157, Issue 3
Differences in Water-Soluble Intermediates from Slow Pyrolysis of Amorphous and Crystalline Cellulose
journal, February 2013
- Liu, Dawei; Yu, Yun; Wu, Hongwei
- Energy & Fuels, Vol. 27, Issue 3
Heterogeneous cracking of wood pyrolysis tars over fresh wood char surfaces
journal, November 1989
- Boroson, Michael L.; Howard, Jack B.; Longwell, John P.
- Energy & Fuels, Vol. 3, Issue 6
Bimetallic catalysts for upgrading of biomass to fuels and chemicals
journal, January 2012
- Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A.
- Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098
Hydrogen synthesis from biomass pyrolysis with in situ carbon dioxide capture using calcium oxide
journal, April 2011
- Widyawati, Meilina; Church, Tamara L.; Florin, Nicholas H.
- International Journal of Hydrogen Energy, Vol. 36, Issue 8
Heat and Mass Transfer Effects in a Furnace-Based Micropyrolyzer
journal, August 2016
- Proano-Aviles, Juan; Lindstrom, Jake K.; Johnston, Patrick A.
- Energy Technology, Vol. 5, Issue 1
Techno-Economic Analysis of Fast Pyrolysis as a Process Step Within Biomass-to-Liquid Fuel Production
journal, August 2010
- Trippe, Frederik; Fröhling, Magnus; Schultmann, Frank
- Waste and Biomass Valorization, Vol. 1, Issue 4
Reaction temperature of solid particles undergoing an endothermal volatilization. Application to the fast pyrolysis of biomass
journal, January 1994
- Lédé, J.
- Biomass and Bioenergy, Vol. 7, Issue 1-6
Cellulose Pyrolysis Kinetics: The Current State of Knowledge
journal, March 1995
- Antal, Michael Jerry Jr.; Varhegyi, Gabor
- Industrial & Engineering Chemistry Research, Vol. 34, Issue 3
Different pyrolytic pathways of levoglucosan in vapor- and liquid/solid-phases
journal, September 2008
- Hosoya, Takashi; Kawamoto, Haruo; Saka, Shiro
- Journal of Analytical and Applied Pyrolysis, Vol. 83, Issue 1
Role of Pretreatments in the Thermal Runaway of Hazelnut Shell Pyrolysis
journal, March 2015
- Di Blasi, C.; Branca, C.; Galgano, A.
- Energy & Fuels, Vol. 29, Issue 4
Influence of the interaction of components on the pyrolysis behavior of biomass
journal, May 2011
- Wang, Shurong; Guo, Xiujuan; Wang, Kaige
- Journal of Analytical and Applied Pyrolysis, Vol. 91, Issue 1
Modeling droplet breakup processes under micro-explosion conditions
journal, January 2007
- Zeng, Yangbing; Lee, Chia-fon F.
- Proceedings of the Combustion Institute, Vol. 31, Issue 2
Chemical Kinetics of Biomass Pyrolysis
journal, November 2008
- Ranzi, Eliseo; Cuoci, Alberto; Faravelli, Tiziano
- Energy & Fuels, Vol. 22, Issue 6
Formation of Anhydro-sugars in the Primary Volatiles and Solid Residues from Cellulose Fast Pyrolysis in a Wire-Mesh Reactor
journal, July 2014
- Gong, Xun; Yu, Yun; Gao, Xiangpeng
- Energy & Fuels, Vol. 28, Issue 8
Methodology for estimation of thermal ejection droplet size distribution and intensity during the pyrolysis of sugarcane bagasse and model compounds
journal, May 2017
- Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne
- Journal of Analytical and Applied Pyrolysis, Vol. 125
An experimental study of the competing processes of evaporation and polymerization of levoglucosan in cellulose pyrolysis
journal, January 2013
- Bai, Xianglan; Johnston, Patrick; Brown, Robert C.
- Journal of Analytical and Applied Pyrolysis, Vol. 99
The pyrolysis of biomass: A general review
journal, December 1982
- Zaror, C. A.; Pyle, D. L.
- Proceedings of the Indian Academy of Sciences Section C: Engineering Sciences, Vol. 5, Issue 4
A model for primary and heterogeneous secondary reactions of wood pyrolysis
journal, June 1996
- Ahuja, Pradeep; Kumar, Surendra; Singh, Prem Chand
- Chemical Engineering & Technology, Vol. 19, Issue 3
Pyrolysis of white pine
journal, November 1984
- Becker, H. A.; Phillips, A. M.; Keller, J.
- Combustion and Flame, Vol. 58, Issue 2
Effect of Biomass Size and Aspect Ratio on Intra-Particle Tar Decomposition during Wood Cylinder Pyrolysis
journal, January 2012
- Okekunle, Pious O.; Watanabe, Hirotatsu; Pattanotai, Teeranai
- Journal of Thermal Science and Technology, Vol. 7, Issue 1
Addressing the challenges of climate change and biofuel production for food and nutrition security
journal, August 2010
- Tirado, M. C.; Cohen, M. J.; Aberman, N.
- Food Research International, Vol. 43, Issue 7
Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review
journal, September 2017
- Wang, Shurong; Dai, Gongxin; Yang, Haiping
- Progress in Energy and Combustion Science, Vol. 62
Flash pyrolysis of cellulose for production of anhydro-oligomers
journal, November 2000
- Piskorz, J.; Majerski, P.; Radlein, D.
- Journal of Analytical and Applied Pyrolysis, Vol. 56, Issue 2
Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions
journal, May 2002
- Beis, S. H.; Onay, Ö.; Koçkar, Ö. M.
- Renewable Energy, Vol. 26, Issue 1
Predicting the rapid devolatilization of diverse forms of biomass with bio-flashchain
journal, January 2000
- Niksa, Stephen
- Proceedings of the Combustion Institute, Vol. 28, Issue 2
Modelling of tar formation and evolution for biomass gasification: A review
journal, November 2013
- Font Palma, Carolina
- Applied Energy, Vol. 111
Overview of water evolution during the thermal degradation of cellulose
journal, May 2001
- Scheirs, J.; Camino, G.; Tumiatti, W.
- European Polymer Journal, Vol. 37, Issue 5
Flash pyrolysis of cellulose pellets submitted to a concentrated radiation: experiments and modelling
journal, January 2002
- Boutin, Olivier; Ferrer, Monique; Lédé, Jacques
- Chemical Engineering Science, Vol. 57, Issue 1, p. 15-25
Kinetics of the pyrolysis of almond shells and almond shells impregnated with cobalt dichloride in a fluidized bed reactor and in a pyroprobe 100
journal, September 1990
- Font, Rafael; Marcilla, Antonio; Verdu, Emilio
- Industrial & Engineering Chemistry Research, Vol. 29, Issue 9
A second look at fast pyrolysis of biomass—the RTI process
journal, July 1999
- Scott, Donald S.; Majerski, Piotr; Piskorz, Jan
- Journal of Analytical and Applied Pyrolysis, Vol. 51, Issue 1-2
Estimation of Heat Transfer Coefficients for Biomass Particles by Direct Numerical Simulation Using Microstructured Particle Models in the Laminar Regime
journal, November 2016
- Pecha, M. Brennan; Garcia-Perez, Manuel; Foust, Thomas D.
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
Modelling intra-particle phenomena of biomass pyrolysis
journal, October 2011
- Dufour, Anthony; Ouartassi, Bajil; Bounaceur, Roda
- Chemical Engineering Research and Design, Vol. 89, Issue 10
Reaction kinetics in thermal analysis. Part 1. The sensitivity of kinetic equations to experimental errors. A mathematical analysis
journal, August 1982
- Várhegyi, Gábor; Székely, Tamás
- Thermochimica Acta, Vol. 57, Issue 1
The kinetics of vapour-phase cellulose fast pyrolysis reactions
journal, January 1994
- Graham, R. G.; Bergougnou, M. A.; Freel, B. A.
- Biomass and Bioenergy, Vol. 7, Issue 1-6
Mechanism of Formation and Consequent Evolution of Active Cellulose during Cellulose Pyrolysis
journal, November 2008
- Liu, Q.; Wang, S.; Wang, K.
- Acta Physico-Chimica Sinica, Vol. 24, Issue 11
A phenomenological model of the mechanisms of lignocellulosic biomass pyrolysis processes
journal, January 2014
- Sharma, Abhishek; Pareek, Vishnu; Wang, Shaobin
- Computers & Chemical Engineering, Vol. 60
Effects of particle size on the fast pyrolysis of oil mallee woody biomass
journal, October 2009
- Shen, Jun; Wang, Xiao-Shan; Garcia-Perez, Manuel
- Fuel, Vol. 88, Issue 10
Pyrolysis rates of biomass materials
journal, November 1998
- Rao, T. Rajeswara; Sharma, Atul
- Energy, Vol. 23, Issue 11
The Role of Sample Dimension and Temperature in Cellulose Pyrolysis
journal, March 2013
- Paulsen, Alex D.; Mettler, Matthew S.; Dauenhauer, Paul J.
- Energy & Fuels, Vol. 27, Issue 4
Pyrolytic Reactions of Carbohydrates. Part V. Isothermal Decomposition of Cellulose in Vacuo
journal, January 1969
- Halpern, Y.; Patai, S.
- Israel Journal of Chemistry, Vol. 7, Issue 5
Pyrolysis characteristics of bean dregs and in situ visualization of pyrolysis transformation
journal, December 2012
- Zhu, Guangyong; Zhu, Xian; Xiao, Zuobing
- Waste Management, Vol. 32, Issue 12
PAH formation in acetylene–benzene pyrolysis
journal, January 1999
- Böhm, Heidi; Jander, Helga
- Physical Chemistry Chemical Physics, Vol. 1, Issue 16
Product Distribution from the Fast Pyrolysis of Hemicellulose
journal, May 2011
- Patwardhan, Pushkaraj R.; Brown, Robert C.; Shanks, Brent H.
- ChemSusChem, Vol. 4, Issue 5
A Simple Method for Estimating f (E) and k 0 ( E ) in the Distributed Activation Energy Model
journal, September 1998
- Miura, Kouichi; Maki, Taisuke
- Energy & Fuels, Vol. 12, Issue 5
Fast pyrolysis in a novel wire-mesh reactor: Decomposition of pine wood and model compounds
journal, April 2012
- Hoekstra, Elly; Van Swaaij, Wim P. M.; Kersten, Sascha R. A.
- Chemical Engineering Journal, Vol. 187
Fast pyrolysis in a novel wire-mesh reactor: Design and initial results
journal, May 2012
- Hoekstra, Elly; van Swaaij, Wim P. M.; Kersten, Sascha R. A.
- Chemical Engineering Journal, Vol. 191
Real-Time and Post-reaction Microscopic Structural Analysis of Biomass Undergoing Pyrolysis
journal, July 2009
- Haas, Thomas J.; Nimlos, Mark R.; Donohoe, Bryon S.
- Energy & Fuels, Vol. 23, Issue 7
Kinetic scheme of biomass pyrolysis considering secondary charring reactions
journal, November 2014
- Anca-Couce, Andrés; Mehrabian, Ramin; Scharler, Robert
- Energy Conversion and Management, Vol. 87
Fast pyrolysis of wood: direct measurement and study of ablation rate
journal, November 1985
- Lede, Jacques; Panagopoulos, Janis; Li, Huai Zhi
- Fuel, Vol. 64, Issue 11
Pyrolysis behaviors of wood and its constituent polymers at gasification temperature
journal, March 2007
- Hosoya, T.; Kawamoto, H.; Saka, S.
- Journal of Analytical and Applied Pyrolysis, Vol. 78, Issue 2
Review of fast pyrolysis of biomass and product upgrading
journal, March 2012
- Bridgwater, A. V.
- Biomass and Bioenergy, Vol. 38, p. 68-94
Aerosol generation by reactive boiling ejection of molten cellulose
journal, January 2011
- Teixeira, Andrew R.; Mooney, Kyle G.; Kruger, Jacob S.
- Energy & Environmental Science, Vol. 4, Issue 10
Biomass Pyrolysis in a Fluidized Bed Reactor. Part 2: Experimental Validation of Model Results
journal, November 2005
- Wang, Xiaoquan; Kersten, Sascha R. A.; Prins, Wolter
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 23
Modelling the pyrolysis of wet wood – I. Three-dimensional formulation and analysis
journal, October 2007
- Yuen, R. K. K.; Yeoh, G. H.; de Vahl Davis, G.
- International Journal of Heat and Mass Transfer, Vol. 50, Issue 21-22
A comparative study on the pyrolysis of metal- and ash-enriched wood and the combustion properties of the gained char
journal, July 2012
- Mayer, Zsuzsa A.; Apfelbacher, Andreas; Hornung, Andreas
- Journal of Analytical and Applied Pyrolysis, Vol. 96
Logistic distributed activation energy model – Part 2: Application to cellulose pyrolysis
journal, February 2011
- Cai, Junmeng; Yang, Songyuan; Li, Tao
- Bioresource Technology, Vol. 102, Issue 3
Effects of Temperature on the Formation of Lignin-Derived Oligomers during the Fast Pyrolysis of Mallee Woody Biomass
journal, May 2008
- Garcia-Perez, Manuel; Wang, Shan; Shen, Jun
- Energy & Fuels, Vol. 22, Issue 3
Modeling of the devolatilization kinetics during pyrolysis of grape residues
journal, January 2012
- Fiori, Luca; Valbusa, Michele; Lorenzi, Denis
- Bioresource Technology, Vol. 103, Issue 1
Solar flash pyrolysis of biomass direct measurement of the optical properties of biomass components
journal, March 1999
- Boutin, O.; Lédé, J.; Olalde, G.
- Le Journal de Physique IV, Vol. 09, Issue PR3
Analysis of Cross-Linking Behavior during Pyrolysis of Cellulose for Elucidating Reaction Pathway
journal, December 2009
- Chaiwat, Weerawut; Hasegawa, Isao; Tani, Takaaki
- Energy & Fuels, Vol. 23, Issue 12
First chemical events in pyrolysis of wood
journal, April 1988
- Degroot, William F.; Pan, Wei-Ping; Rahman, M. Dalilur
- Journal of Analytical and Applied Pyrolysis, Vol. 13, Issue 3
An Indication of Molten Cellulose Produced in a Laser Beam
journal, February 1974
- Nordin, Soren B.; Nyren, Jan O.; Back, Ernst L.
- Textile Research Journal, Vol. 44, Issue 2
A Critical Review on Hemicellulose Pyrolysis
journal, August 2016
- Zhou, Xiaowei; Li, Wenjun; Mabon, Ross
- Energy Technology, Vol. 5, Issue 1
Biomass pyrolysis for chemicals
journal, March 2011
- de Wild, Paul; Reith, Hans; Heeres, Erik
- Biofuels, Vol. 2, Issue 2
Puffing and micro-explosion of diesel–biodiesel–ethanol blends
journal, February 2016
- Avulapati, Madan Mohan; Ganippa, Lionel Christopher; Xia, Jun
- Fuel, Vol. 166
Modeling of Lignin Thermolysis
journal, July 2008
- Klein, M. T.; Virk, P. S.
- Energy & Fuels, Vol. 22, Issue 4
On the presence of anhydro-oligosaccharides in the sirups from the fast pyrolysis of cellulose
journal, June 1987
- Radlein, Desmond S. T. A. G.; Grinshpun, Anna; Piskorz, Jan
- Journal of Analytical and Applied Pyrolysis, Vol. 12, Issue 1
Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds
journal, January 2016
- Xiong, Qingang; Zhang, Jingchao; Xu, Fei
- Journal of Analytical and Applied Pyrolysis, Vol. 117
Radiant flash pyrolysis of cellulose—Evidence for the formation of short life time intermediate liquid species
journal, September 1998
- Boutin, O.; Ferrer, M.; Lédé, J.
- Journal of Analytical and Applied Pyrolysis, Vol. 47, Issue 1
Heterogeneous and homogeneous reactions of pyrolysis vapors from pine wood
journal, November 2011
- Hoekstra, Elly; Westerhof, Roel J. M.; Brilman, Wim
- AIChE Journal, Vol. 58, Issue 9
Experimental study of nucleate pool boiling heat transfer of water on silicon oxide nanoparticle coated copper heating surface
journal, March 2016
- Das, Sudev; Kumar, D. S.; Bhaumik, Swapan
- Applied Thermal Engineering, Vol. 96
Effect of Cellulose Crystallinity on Solid/Liquid Phase Reactions Responsible for the Formation of Carbonaceous Residues during Pyrolysis
journal, February 2014
- Wang, Zhouhong; Pecha, Brennan; Westerhof, Roel J. M.
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 8
Pyrolysis kinetics of lignocellulosic materials—three independent reactions model
journal, February 1999
- Orfão, J. J. M.; Antunes, F. J. A.; Figueiredo, J. L.
- Fuel, Vol. 78, Issue 3
Integrated Particle- and Reactor-Scale Simulation of Pine Pyrolysis in a Fluidized Bed
journal, September 2018
- Pecha, M. Brennan; Ramirez, Emilio; Wiggins, Gavin M.
- Energy & Fuels, Vol. 32, Issue 10
Current technologies for analysis of biomass thermochemical processing: A review
journal, October 2009
- Bahng, Mi-Kyung; Mukarakate, Calvin; Robichaud, David J.
- Analytica Chimica Acta, Vol. 651, Issue 2
Coal pyrolysis: Experiments, kinetic rates and mechanisms
journal, January 1992
- Solomon, Peter R.; Serio, Michael A.; Suuberg, Eric M.
- Progress in Energy and Combustion Science, Vol. 18, Issue 2
Four Years of ACS Sustainable Chemistry & Engineering : Reflections and New Developments
journal, December 2016
- Allen, David T.; Carrier, Danielle Julie; Hwang, Bing-Joe
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
Comparison of the pyrolysis behavior of pyrolytic lignin and milled wood lignin by using TG–FTIR analysis
journal, July 2014
- Wang, Shurong; Lin, Haizhou; Ru, Bin
- Journal of Analytical and Applied Pyrolysis, Vol. 108
An experimental and modeling study of softening coal pyrolysis
journal, May 1989
- Oh, Myongsook S.; Peters, William A.; Howard, Jack B.
- AIChE Journal, Vol. 35, Issue 5
Modelling and experimental verification of physical and chemical processes during pyrolysis of a large biomass particle
journal, November 1985
- Chan, Wai-Chun R.; Kelbon, Marcia; Krieger, Barbara B.
- Fuel, Vol. 64, Issue 11
Evaluation of alternatives for the evolution of palm oil mills into biorefineries
journal, December 2016
- Garcia-Nunez, Jesus Alberto; Rodriguez, Deisy Tatiana; Fontanilla, Carlos Andrés
- Biomass and Bioenergy, Vol. 95
A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin
journal, October 2014
- Collard, François-Xavier; Blin, Joël
- Renewable and Sustainable Energy Reviews, Vol. 38
Secondary Vapor Phase Reactions of Lignin-Derived Oligomers Obtained by Fast Pyrolysis of Pine Wood
journal, March 2013
- Zhou, Shuai; Garcia-Perez, Manuel; Pecha, Brennan
- Energy & Fuels, Vol. 27, Issue 3
Thermal degradation mechanisms of wood under inert and oxidative environments using DAEM methods
journal, January 2011
- Shen, D. K.; Gu, S.; Jin, Baosheng
- Bioresource Technology, Vol. 102, Issue 2
Flash pyrolysis of biomass particles in fluidized bed for bio-oil production
journal, April 2005
- Wang, Shurong; Fang, Mengxiang; Yu, Chunjiang
- China Particuology, Vol. 3, Issue 1-2
State-of-the-art of fast pyrolysis in IEA bioenergy member countries
journal, April 2013
- Meier, Dietrich; van de Beld, Bert; Bridgwater, Anthony V.
- Renewable and Sustainable Energy Reviews, Vol. 20
On the Combustion of Wood II: The Influence of Internal Convection on the Transient Pyrolysis of Cellulose
journal, August 1970
- Kanury, A. Murty; Blackshear, Perry L.
- Combustion Science and Technology, Vol. 2, Issue 1
A coarse-grain force-field for xylan and its interaction with cellulose
journal, August 2015
- Li, Liang; Pérré, Patrick; Frank, Xavier
- Carbohydrate Polymers, Vol. 127
Fractional Condensation of Biomass Pyrolysis Vapors
journal, April 2011
- Westerhof, Roel J. M.; Brilman, D. Wim F.; Garcia-Perez, Manuel
- Energy & Fuels, Vol. 25, Issue 4
Chemical Effects of Heat on Cellulose
journal, August 1975
- Golova, O. P.
- Russian Chemical Reviews, Vol. 44, Issue 8
Modelling heat of reaction in biomass pyrolysis with detailed reaction schemes
journal, October 2017
- Anca-Couce, Andrés; Scharler, Robert
- Fuel, Vol. 206
Effect of particle size on the composition of lignin derived oligomers obtained by fast pyrolysis of beech wood
journal, June 2014
- Zhou, Shuai; Garcia-Perez, Manuel; Pecha, Brennan
- Fuel, Vol. 125
Cellulose–hemicellulose and cellulose–lignin interactions in wood pyrolysis at gasification temperature
journal, August 2007
- Hosoya, T.; Kawamoto, H.; Saka, S.
- Journal of Analytical and Applied Pyrolysis, Vol. 80, Issue 1
Biomass Pyrolysis in a Fluidized Bed Reactor. Part 1: Literature Review and Model Simulations
journal, November 2005
- Kersten, Sascha R. A.; Wang, Xiaoquan; Prins, Wolter
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 23
Effects of intraparticle heat and mass transfer during devolatilization of a single coal particle
journal, October 1985
- Bliek, Alfred; Van Poelje, W. M.; Van Swaaij, W. P. M.
- AIChE Journal, Vol. 31, Issue 10
Top ten fundamental challenges of biomass pyrolysis for biofuels
journal, January 2012
- Mettler, Matthew S.; Vlachos, Dionisios G.; Dauenhauer, Paul J.
- Energy & Environmental Science, Vol. 5, Issue 7
Kinetic analyses of biomass pyrolysis using the distributed activation energy model
journal, March 2008
- Sonobe, T.; Worasuwannarak, N.
- Fuel, Vol. 87, Issue 3
Vapor Pressures and Enthalpies of Sublimation of d -Glucose, d -Xylose, Cellobiose, and Levoglucosan
journal, January 1999
- Oja, V.; Suuberg, E. M.
- Journal of Chemical & Engineering Data, Vol. 44, Issue 1
Slow and fast pyrolysis of Douglas-fir lignin: Importance of liquid-intermediate formation on the distribution of products
journal, July 2014
- Zhou, Shuai; Pecha, Brennan; van Kuppevelt, Michiel
- Biomass and Bioenergy, Vol. 66
Influence of Particle Sizes and Environmental Conditions on High Temperature Pyrolysis of Cellulosic Material—I (Theoretical)
journal, August 1973
- Maa, Peter S.; Bailie, Richard C.
- Combustion Science and Technology, Vol. 7, Issue 6
Distinguishing primary and secondary reactions of cellulose pyrolysis
journal, April 2011
- Patwardhan, Pushkaraj R.; Dalluge, Dustin L.; Shanks, Brent H.
- Bioresource Technology, Vol. 102, Issue 8
Kinetics of reactions involved in pyrolysis of cellulose I. The three reaction model
journal, June 1988
- Agrawal, Ravindra K.
- The Canadian Journal of Chemical Engineering, Vol. 66, Issue 3
Is the Broido-Shafizadeh Model for Cellulose Pyrolysis True?
journal, November 1994
- Varhegyi, Gabor; Jakab, Emma; Antal, Michael Jerry
- Energy & Fuels, Vol. 8, Issue 6
Thermal conductivity of wood—models for different stages of combustion
journal, July 2002
- Thunman, Henrik; Leckner, Bo
- Biomass and Bioenergy, Vol. 23, Issue 1
Online experiments and modelling with a detailed reaction scheme of single particle biomass pyrolysis
journal, September 2017
- Anca-Couce, Andrés; Sommersacher, Peter; Scharler, Robert
- Journal of Analytical and Applied Pyrolysis, Vol. 127
Internal mass transfer considerations during the pyrolysis of an isolated spherical softening coal particle
journal, October 1989
- Sezen, Yusuf
- International Journal of Heat and Mass Transfer, Vol. 32, Issue 10
Coupled Structural and Kinetic Model of Lignin Fast Pyrolysis
journal, January 2018
- Yanez, Abraham J.; Natarajan, Pradeep; Li, Wenjun
- Energy & Fuels, Vol. 32, Issue 2
Transport phenomena in multi-particle systems—IV. Heat transfer to a large freely moving particle in gas fluidized bed of smaller particles
journal, January 1991
- Agarwal, Pradeep K.
- Chemical Engineering Science, Vol. 46, Issue 4
The combustion of wood. Part I
journal, June 1946
- Bamford, C. H.; Crank, J.; Malan, D. H.
- Mathematical Proceedings of the Cambridge Philosophical Society, Vol. 42, Issue 2
Mathematical model of wood pyrolysis including internal forced convection
journal, January 1977
- Kansa, Edward J.; Perlee, Henry E.; Chaiken, Robert F.
- Combustion and Flame, Vol. 29
Thermal Lag, Fusion, and the Compensation Effect during Biomass Pyrolysis †
journal, January 1996
- Narayan, Ravi; Antal, Michael Jerry
- Industrial & Engineering Chemistry Research, Vol. 35, Issue 5
Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor
journal, May 2007
- Onay, Ozlem
- Fuel Processing Technology, Vol. 88, Issue 5
High-Yield Biomass Charcoal †
journal, January 1996
- Antal,, Michael Jerry; Croiset, Eric; Dai, Xiangfeng
- Energy & Fuels, Vol. 10, Issue 3
Modeling the physiochemistry of levoglucosan during cellulose pyrolysis
journal, January 2014
- Bai, Xianglan; Brown, Robert C.
- Journal of Analytical and Applied Pyrolysis, Vol. 105
In-Depth Investigation of Biomass Pyrolysis Based on Three Major Components: Hemicellulose, Cellulose and Lignin
journal, January 2006
- Yang, Haiping; Yan, Rong; Chen, Hanping
- Energy & Fuels, Vol. 20, Issue 1
Single particle model for biomass pyrolysis with bubble formation dynamics inside the liquid intermediate and its contribution to aerosol formation by thermal ejection
journal, March 2017
- Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne
- Journal of Analytical and Applied Pyrolysis, Vol. 124
Radiation Heat Transfer in Fluidized Beds: A Comparison of Exact and Simplified Approaches
journal, August 1994
- Flamant, G.; Lu, J. D.; Variot, B.
- Journal of Heat Transfer, Vol. 116, Issue 3
Kinetic modelling of the pyrolysis of biomass and biomass components
journal, February 1989
- Koufopanos, C. A.; Lucchesi, A.; Maschio, G.
- The Canadian Journal of Chemical Engineering, Vol. 67, Issue 1
Distribution of activation energy model applied to the rapid pyrolysis of coal blends
journal, June 2004
- Ulloa, Claudia; Gordon, Alfredo L.; Garcı́a, Ximena
- Journal of Analytical and Applied Pyrolysis, Vol. 71, Issue 2
Experimental Study on Charcoal Production from Woody Biomass
journal, September 2016
- Wang, Liang; Skreiberg, Øyvind; Van Wesenbeeck, Sam
- Energy & Fuels, Vol. 30, Issue 10
Major trends and roadblocks in CFD-aided process intensification of biomass pyrolysis
journal, May 2018
- Xiong, Qingang; Xu, Fei; Pan, Yaoyu
- Chemical Engineering and Processing - Process Intensification, Vol. 127
Reaction kinetics in thermal analysis: a brief survey of fundamental research problems
journal, February 1987
- Várhegyi, Gábor
- Thermochimica Acta, Vol. 110
Effects of Intraparticle Heat and Mass Transfer on Biomass Devolatilization: Experimental Results and Model Predictions
journal, July 2004
- Bharadwaj, Anshu; Baxter, Larry L.; Robinson, Allen L.
- Energy & Fuels, Vol. 18, Issue 4
A model for the evaporation of biomass pyrolysis oil droplets
journal, March 2006
- Hallett, W. L. H.; Clark, N. A.
- Fuel, Vol. 85, Issue 4
A gas-solid reaction model for flash wood pyrolysis
journal, November 1989
- Hastaoglu, M. A.; Berruti, F.
- Fuel, Vol. 68, Issue 11
A kinetic model for pyrolysis of cellulose
journal, June 1979
- Bradbury, Allan G. W.; Sakai, Yoshio; Shafizadeh, Fred
- Journal of Applied Polymer Science, Vol. 23, Issue 11
Cellulose pyrolysis kinetics: An historical review on the existence and role of intermediate active cellulose
journal, March 2012
- Lédé, Jacques
- Journal of Analytical and Applied Pyrolysis, Vol. 94
A computational framework for the pyrolysis of anisotropic biomass particles
journal, August 2017
- Gentile, Giancarlo; Debiagi, Paulo Eduardo Amaral; Cuoci, Alberto
- Chemical Engineering Journal, Vol. 321
Modelling the fast pyrolysis of cellulosic particles in fluid-bed reactors
journal, December 2000
- Blasi, Colomba Di
- Chemical Engineering Science, Vol. 55, Issue 24
Mathematical modelling of slow pyrolysis of a particle of treated wood waste
journal, October 2009
- Ratte, J.; Marias, F.; Vaxelaire, J.
- Journal of Hazardous Materials, Vol. 170, Issue 2-3
Heat transfer and kinetics in the low temperature pyrolysis of solids
journal, January 1984
- Pyle, D. L.; Zaror, C. A.
- Chemical Engineering Science, Vol. 39, Issue 1
Study of the micro-explosion temperature of water in oil emulsion droplets during the Leidenfrost effect
journal, November 2012
- Mura, E.; Massoli, P.; Josset, C.
- Experimental Thermal and Fluid Science, Vol. 43
Influence of impregnated metal on the pyrolysis conversion of biomass constituents
journal, May 2012
- Collard, François-Xavier; Blin, Joël; Bensakhria, Ammar
- Journal of Analytical and Applied Pyrolysis, Vol. 95
A unified, global model for the pyrolysis of cellulose
journal, January 1994
- Diebold, James P.
- Biomass and Bioenergy, Vol. 7, Issue 1-6
Micro-explosion of liquid intermediates during the fast pyrolysis of sucrose and organosolv lignin
journal, November 2016
- Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne
- Journal of Analytical and Applied Pyrolysis, Vol. 122
Secondary reactions of flash pyrolysis tars measured in a fluidized bed pyrolysis reactor with some novel design features
journal, March 1989
- Stiles, H.; Kandiyoti, R.
- Fuel, Vol. 68, Issue 3
Effect of temperature on the fast pyrolysis of organic-acid leached pinewood; the potential of low temperature pyrolysis
journal, June 2016
- Oudenhoven, S. R. G.; Lievens, C.; Westerhof, R. J. M.
- Biomass and Bioenergy, Vol. 89
Study on the pyrolytic behaviour of xylan-based hemicellulose using TG–FTIR and Py–GC–FTIR
journal, March 2010
- Shen, D. K.; Gu, S.; Bridgwater, A. V.
- Journal of Analytical and Applied Pyrolysis, Vol. 87, Issue 2
Comparison of semi-global mechanisms for primary pyrolysis of lignocellulosic fuels
journal, September 1998
- Di Blasi, Colomba
- Journal of Analytical and Applied Pyrolysis, Vol. 47, Issue 1
Boiling point of levoglucosan and devolatilization temperatures in cellulose pyrolysis measured at different heating area temperatures
journal, September 2014
- Shoji, Taeko; Kawamoto, Haruo; Saka, Shiro
- Journal of Analytical and Applied Pyrolysis, Vol. 109
Influence of mineral matter on biomass pyrolysis characteristics
journal, December 1995
- Raveendran, K.; Ganesh, Anuradda; Khilar, Kartic C.
- Fuel, Vol. 74, Issue 12
Modeling the evolution of volatile species during tobacco pyrolysis
journal, January 2003
- Wójtowicz, Marek A.; Bassilakis, Rosemary; Smith, Wayne W.
- Journal of Analytical and Applied Pyrolysis, Vol. 66, Issue 1-2
Py-GC/MS studies and principal component analysis to evaluate the impact of feedstock and temperature on the distribution of products during fast pyrolysis
journal, September 2014
- Liaw, Shi-Shen; Haber Perez, Victor; Zhou, Shuai
- Journal of Analytical and Applied Pyrolysis, Vol. 109
Mechanisms and kinetics of homogeneous secondary reactions of tar from continuous pyrolysis of wood chips
journal, May 2002
- Morf, Philipp; Hasler, Philipp; Nussbaumer, Thomas
- Fuel, Vol. 81, Issue 7
The role of temperature in the fast pyrolysis of cellulose and wood
journal, January 1988
- Scott, Donald S.; Piskorz, Jan; Bergougnou, Maurice A.
- Industrial & Engineering Chemistry Research, Vol. 27, Issue 1
Influence of inorganic salts on the primary pyrolysis products of cellulose
journal, June 2010
- Patwardhan, Pushkaraj R.; Satrio, Justinus A.; Brown, Robert C.
- Bioresource Technology, Vol. 101, Issue 12
The Origin of Molecular Mobility During Biomass Pyrolysis as Revealed by In situ 1H NMR Spectroscopy
journal, May 2012
- Dufour, Anthony; Castro-Diaz, Miguel; Brosse, Nicolas
- ChemSusChem, Vol. 5, Issue 7
X-ray Computed Tomography Visualization of the Woody Char Intraparticle Pore Structure and Its Role on Anisotropic Evolution during Char Gasification
journal, January 2018
- Watanabe, Hirotatsu
- Energy & Fuels, Vol. 32, Issue 4
Pyrolysis of Turkish Zonguldak bituminous coal. Part 1. Effect of mineral matter
journal, August 2000
- Öztaş, N. A.; Yürüm, Y.
- Fuel, Vol. 79, Issue 10
Effects of side-chain hydroxyl groups on pyrolytic β-ether cleavage of phenolic lignin model dimer
journal, June 2007
- Kawamoto, Haruo; Horigoshi, Sunao; Saka, Shiro
- Journal of Wood Science, Vol. 53, Issue 3
Influence of metal ions and of salts on products from pyrolysis of wood: Applications to thermochemical processing of newsprint and biomass
journal, September 1991
- Richards, Geoffrey N.; Zheng, Guangcheng
- Journal of Analytical and Applied Pyrolysis, Vol. 21, Issue 1-2
Time and temperature depended fuel gas generation from pyrolysis of real world municipal plastic waste
journal, June 2016
- Singh, Rohit Kumar; Ruj, Biswajit
- Fuel, Vol. 174
Comparison of gasification and pyrolysis of thermal pre-treated wood board waste
journal, May 2009
- Girods, Pierre; Dufour, Anthony; Rogaume, Yann
- Journal of Analytical and Applied Pyrolysis, Vol. 85, Issue 1-2
Biomass Particle Models with Realistic Morphology and Resolved Microstructure for Simulations of Intraparticle Transport Phenomena
journal, December 2014
- Ciesielski, Peter N.; Crowley, Michael F.; Nimlos, Mark R.
- Energy & Fuels, Vol. 29, Issue 1
Biomass Pyrolysis: Comments on Some Sources of Confusions in the Definitions of Temperatures and Heating Rates
journal, April 2010
- Lédé, Jacques
- Energies, Vol. 3, Issue 4
Heat transfer mechanisms and multi-step kinetics in the ablative pyrolysis of cellulose
journal, May 1996
- Di Blasi, Colomba
- Chemical Engineering Science, Vol. 51, Issue 10
Processing of TGA data: Analysis of isoconversional and model fitting methods
journal, February 2016
- Jain, Ankit A.; Mehra, Anurag; Ranade, Vivek V.
- Fuel, Vol. 165
Extractives Extend the Applicability of Multistep Kinetic Scheme of Biomass Pyrolysis
journal, September 2015
- Debiagi, Paulo Eduardo Amaral; Pecchi, Chiara; Gentile, Giancarlo
- Energy & Fuels, Vol. 29, Issue 10
Low-Order Modeling of Internal Heat Transfer in Biomass Particle Pyrolysis
journal, May 2016
- Wiggins, Gavin M.; Ciesielski, Peter N.; Daw, C. Stuart
- Energy & Fuels, Vol. 30, Issue 6
Overview of Computational Fluid Dynamics Simulation of Reactor-Scale Biomass Pyrolysis
journal, March 2017
- Xiong, Qingang; Yang, Yang; Xu, Fei
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 4
Kinetics and Mechanism of Cellulose Pyrolysis
journal, October 2009
- Lin, Yu-Chuan; Cho, Joungmo; Tompsett, Geoffrey A.
- The Journal of Physical Chemistry C, Vol. 113, Issue 46
Radionuclide re-entrainment at bubbling water pool surfaces
journal, September 2000
- Koch, M. K.; Voßnacke, A.; Starflinger, J.
- Journal of Aerosol Science, Vol. 31, Issue 9
Influence of Pyrolysis Operating Conditions on Bio-Oil Components: A Microscale Study in a Pyroprobe
journal, March 2011
- Thangalazhy-Gopakumar, Suchithra; Adhikari, Sushil; Gupta, Ram B.
- Energy & Fuels, Vol. 25, Issue 3
A critical study of the Miura–Maki integral method for the estimation of the kinetic parameters of the distributed activation energy model
journal, February 2011
- Cai, Junmeng; Li, Tao; Liu, Ronghou
- Bioresource Technology, Vol. 102, Issue 4
Thermal decomposition kinetics of wood pyrolysis
journal, February 1972
- Murty Kanury, A.
- Combustion and Flame, Vol. 18, Issue 1
Plate reactor as an analysis tool for rapid pyrolysis of biomass
journal, July 2011
- Sepman, A. V.; de Goey, L. P. H.
- Biomass and Bioenergy, Vol. 35, Issue 7
Mechanism and modelling of bamboo pyrolysis
journal, February 2013
- Oyedun, Adetoyese Olajire; Gebreegziabher, Tesfaldet; Hui, Chi Wai
- Fuel Processing Technology, Vol. 106
Combustion kinetics of wet-torrefied forest residues using the distributed activation energy model (DAEM)
journal, January 2017
- Bach, Quang-Vu; Tran, Khanh-Quang; Skreiberg, Øyvind
- Applied Energy, Vol. 185
Fusion-like behaviour of wood pyrolysis
journal, May 1987
- Lédé, Jacques; Li, Huai Zhi; Villermaux, Jacques
- Journal of Analytical and Applied Pyrolysis, Vol. 10, Issue 4
Recent developments in fast pyrolysis of ligno-cellulosic materials
journal, June 2013
- Kersten, Sascha; Garcia-Perez, Manuel
- Current Opinion in Biotechnology, Vol. 24, Issue 3
Effect of operating parameters on methanation reaction for the production of synthetic natural gas
journal, May 2013
- Kang, Woo Ram; Lee, Ki Bong
- Korean Journal of Chemical Engineering, Vol. 30, Issue 7
Pyrolysis behavior and kinetics of biomass derived materials
journal, February 2002
- Fisher, Travis; Hajaligol, Mohammad; Waymack, Bruce
- Journal of Analytical and Applied Pyrolysis, Vol. 62, Issue 2
Kinetic analysis of the gas-phase pyrolysis of carbohydrates
journal, October 2001
- Shin, Eun-Jae; Nimlos, Mark R.; Evans, Robert J.
- Fuel, Vol. 80, Issue 12
Effect of a Vacuum on the Fast Pyrolysis of Cellulose: Nature of Secondary Reactions in a Liquid Intermediate
journal, April 2017
- Pecha, M. Brennan; Montoya, Jorge Ivan; Chejne, Farid
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 15
New distributed activation energy model: Numerical solution and application to pyrolysis kinetics of some types of biomass
journal, May 2008
- Cai, Junmeng; Liu, Ronghou
- Bioresource Technology, Vol. 99, Issue 8
Pool boiling and flow boiling on micro- and nanostructured surfaces
journal, May 2015
- Shojaeian, Mostafa; Koşar, Ali
- Experimental Thermal and Fluid Science, Vol. 63
Evidence for oligomers in pyrolysates of microcrystalline cellulose
journal, March 1989
- Pouwels, Aloys D.; Eijkel, Gert B.; Arisz, Peter W.
- Journal of Analytical and Applied Pyrolysis, Vol. 15
A mathematical model for pyrolysis of a solid particle: Effects of the lewis number
journal, February 1977
- Fan, L. T.; Fan, Liang-Shih; Miyanami, Kei
- The Canadian Journal of Chemical Engineering, Vol. 55, Issue 1
Cellulose pyrolysis: the kinetics of hydroxyacetaldehyde evolution
journal, February 2001
- Banyasz, Joseph L.; Li, San; Lyons-Hart, Jim L.
- Journal of Analytical and Applied Pyrolysis, Vol. 57, Issue 2
Phenols and aromatics from fast pyrolysis of variously prepared lignins from hard- and softwoods
journal, September 2015
- Custodis, Victoria B. F.; Bährle, Christian; Vogel, Frédéric
- Journal of Analytical and Applied Pyrolysis, Vol. 115
Tar destruction and coke formation during rapid pyrolysis and gasification of biomass in a drop-tube furnace
journal, February 2010
- Zhang, Yan; Kajitani, Shiro; Ashizawa, Masami
- Fuel, Vol. 89, Issue 2
Multistep Mechanism for the Devolatilization of Biomass Fast Pyrolysis Oils
journal, August 2006
- Branca, Carmen; Di Blasi, Colomba
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 17
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.