Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change

Pecha, M. Brennan; Arbelaez, Jorge Ivan Montoya; Garcia-Perez, Manuel; Chejne, Farid; Ciesielski, Peter N.

doi:10.1039/C9GC00585D

Title: Progress in understanding the four dominant intra-particle phenomena of lignocellulose pyrolysis: chemical reactions, heat transfer, mass transfer, and phase change

Journal Article · 17 April 2019 · Green Chemistry

DOI: https://doi.org/10.1039/C9GC00585D · OSTI ID:1514727

^[1]; Arbelaez, Jorge Ivan Montoya ^[2];

^[3];

^[2];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)
Univ. Nacional de Colombia, Medellín (Colombia)
Washington State Univ., Pullman, WA (United States)

Four principal intra-particle phenomena occur in a highly concerted manner during the pyrolysis of lignocellulosic materials: heat transfer, mass transfer, chemical reactions, and phase changes. Achieving a holistic understanding of these processes has been challenged by their intricate coupling, high temperatures, and rapid rates at which they occur. Heat and mass transfer have been well studied at the single-particle level but their coupling with chemical reactions and phase change within single particle models remains problematic. Equally challenging is the multiscale coupling of reactor- and single particle-scale models. Too little attention has been given to phase change. Similarly, the presence of oligomeric compounds (constituting up to 20% of the oil) has not been fully accounted for in chemical reaction schemes and physical models developed for pyrolysis. Recent studies have shown that a multiscale approach is key to predictive modelling across a variety of reactor systems. Historical and recent developments are outlined in this pyrolysis review paper regarding these four intra-particle phenomena, as well as modelling efforts to capture their effect on product yields and composition. It is critical for the design of future biomass pyrolysis systems to appropriately account for all four intra-particle phenomena and their inter-connectivities in order to predict, achieve, and maintain optimal operation.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation and Fuels. Bioenergy Technologies Office (BETO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1514727

Alternate ID(s):: OSTI ID: 1510138; OSTI ID: 1512663

Report Number(s):: NREL/JA-2700-73833; GRCHFJ

Journal Information:: Green Chemistry, Vol. 21, Issue 11; ISSN 1463-9262

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (254)

Cellulose-Lignin interactions during slow and fast pyrolysis Hilbers, Tim J.; Wang, Zhouhong; Pecha, Brennan Journal of Analytical and Applied Pyrolysis, Vol. 114 https://doi.org/10.1016/j.jaap.2015.05.020	journal	July 2015
Influence of inorganic species on the formation of polysaccharide and lignin degradation products in the analytical pyrolysis of pulps Kleen, Marjatta; Gellerstedt, Göran Journal of Analytical and Applied Pyrolysis, Vol. 35, Issue 1 https://doi.org/10.1016/0165-2370(95)00893-J	journal	October 1995
Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies White, John E.; Catallo, W. James; Legendre, Benjamin L. Journal of Analytical and Applied Pyrolysis, Vol. 91, Issue 1 https://doi.org/10.1016/j.jaap.2011.01.004	journal	May 2011
An Integral Model for the Transient Pyrolysis of Solid Materials Moghtaderi, B.; Novozhilov, V.; Fletcher, D. Fire and Materials, Vol. 21, Issue 1 https://doi.org/10.1002/(SICI)1099-1018(199701)21:1<7::AID-FAM588>3.0.CO;2-T	journal	January 1997
Temperature and heating rate of solid particles undergoing a thermal decomposition. Which criteria for characterizing fast pyrolysis? Lédé, Jacques; Authier, Olivier Journal of Analytical and Applied Pyrolysis, Vol. 113 https://doi.org/10.1016/j.jaap.2014.11.013	journal	May 2015
Identification of the fractions responsible for morphology conservation in lignocellulosic pyrolysis: Visualization studies of sugarcane bagasse and its pseudo-components Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne Journal of Analytical and Applied Pyrolysis, Vol. 123 https://doi.org/10.1016/j.jaap.2016.11.015	journal	January 2017
Chemical and morphological evaluation of chars produced from primary biomass constituents: Cellulose, xylan, and lignin Smith, Matthew W.; Pecha, Brennan; Helms, Greg Biomass and Bioenergy, Vol. 104 https://doi.org/10.1016/j.biombioe.2017.05.015	journal	September 2017
Effect of Pressure on Pyrolysis of Milled Wood Lignin and Acid-Washed Hybrid Poplar Wood Pecha, M. Brennan; Terrell, Evan; Montoya, Jorge Ivan Industrial & Engineering Chemistry Research, Vol. 56, Issue 32 https://doi.org/10.1021/acs.iecr.7b02085	journal	August 2017
Product yields and kinetics from the vapor phase cracking of wood pyrolysis tars Boroson, Michael L.; Howard, Jack B.; Longwell, John P. AIChE Journal, Vol. 35, Issue 1 https://doi.org/10.1002/aic.690350113	journal	January 1989
Mineral matter effects in rapid pyrolysis of beech wood Nik-Azar, M.; Hajaligol, M. R.; Sohrabi, M. Fuel Processing Technology, Vol. 51, Issue 1-2 https://doi.org/10.1016/S0378-3820(96)01074-0	journal	March 1997
Evaluation of Vapor-Phase Reactivity of Primary Tar Produced by Flash Pyrolysis of Coal Hayashi, Jun-ichiro; Amamoto, Shinobu; Kusakabe, Katsuki Energy & Fuels, Vol. 9, Issue 2 https://doi.org/10.1021/ef00050a012	journal	March 1995
Modeling intra- and extra-particle processes of wood fast pyrolysis Di Blasi, Colomba AIChE Journal, Vol. 48, Issue 10 https://doi.org/10.1002/aic.690481028	journal	October 2002
Influence of Biomass Pyrolysis Temperature, Heating Rate and Type of Biomass on Produced Char in a Fluidized Bed Reactor Iwasaki, Toshiyuki; Suzuki, Seiichi; Kojima, Toshinori Energy and Environment Research, Vol. 4, Issue 2 https://doi.org/10.5539/eer.v4n2p64	journal	April 2014
Modified Pyroprobe Captive Sample Reactor: Characterization of Reactor and Cellulose Pyrolysis at Vacuum and Atmospheric Pressures Pecha, M. Brennan; Montoya, Jorge Ivan; Ivory, Cornelius Industrial & Engineering Chemistry Research, Vol. 56, Issue 18 https://doi.org/10.1021/acs.iecr.7b00463	journal	April 2017
Optical and Mass Spectrometric Study of the Pyrolysis Gas of Wood Particles Brackmann, Christian; Aldén, Marcus; Bengtsson, Per-Erik Applied Spectroscopy, Vol. 57, Issue 2 https://doi.org/10.1366/000370203321535141	journal	February 2003
The chain length effect in pyrolysis: bridging the gap between glucose and cellulose Mettler, Matthew S.; Paulsen, Alex D.; Vlachos, Dionisios G. Green Chemistry, Vol. 14, Issue 5 https://doi.org/10.1039/c2gc35184f	journal	January 2012
Bio-oil production from Colombian bagasse by fast pyrolysis in a fluidized bed: An experimental study Montoya, J. I.; Valdés, C.; Chejne, F. Journal of Analytical and Applied Pyrolysis, Vol. 112 https://doi.org/10.1016/j.jaap.2014.11.007	journal	March 2015
FTIR study of pyrolysis products evolving from typical agricultural residues Fu, Peng; Hu, Song; Xiang, Jun Journal of Analytical and Applied Pyrolysis, Vol. 88, Issue 2 https://doi.org/10.1016/j.jaap.2010.03.004	journal	July 2010
Effect of temperature and heating rate on product distribution from the pyrolysis of sugarcane bagasse in a hot plate reactor Montoya, Jorge; Pecha, Brennan; Roman, David Journal of Analytical and Applied Pyrolysis, Vol. 123 https://doi.org/10.1016/j.jaap.2016.11.008	journal	January 2017
Molecular weight decrease in the early pyrolysis of crystalline and amorphous cellulose Broido, A.; Javier-Son, A. C.; Ouano, A. C. Journal of Applied Polymer Science, Vol. 17, Issue 12 https://doi.org/10.1002/app.1973.070171207	journal	December 1973
Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C Agarwal, Vishal; Dauenhauer, Paul J.; Huber, George W. Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja305135u	journal	August 2012
An algorithm for determining the kinetics of devolatilisation of complex solid fuels from thermogravimetric experiments Scott, S. A.; Dennis, J. S.; Davidson, J. F. Chemical Engineering Science, Vol. 61, Issue 8 https://doi.org/10.1016/j.ces.2005.11.002	journal	April 2006
Influence of linkage position and orientation in pyrolysis of polysaccharides: A study of several glucans Ponder, Glenn R.; Richards, Geoffrey N.; Stevenson, Thomas T. Journal of Analytical and Applied Pyrolysis, Vol. 22, Issue 3 https://doi.org/10.1016/0165-2370(92)85015-D	journal	March 1992
Five Rules for Measuring Biomass Pyrolysis Rates: Pulse-Heated Analysis of Solid Reaction Kinetics of Lignocellulosic Biomass Maduskar, Saurabh; Facas, Gregory G.; Papageorgiou, Costas ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 1 https://doi.org/10.1021/acssuschemeng.7b03785	journal	November 2017
High-speed imaging of biomass particles heated with a laser Carlsson, Per; Lycksam, Henrik; Gren, Per Journal of Analytical and Applied Pyrolysis, Vol. 103 https://doi.org/10.1016/j.jaap.2012.11.020	journal	September 2013
Mathematical modelling of biomass pyrolysis phenomena Antal, Michael Jerry Fuel, Vol. 64, Issue 11 https://doi.org/10.1016/0016-2361(85)90360-6	journal	November 1985
Influence of mineral matter on pyrolysis of palm oil wastes Yang, H.; Yan, R.; Chen, H. Combustion and Flame, Vol. 146, Issue 4 https://doi.org/10.1016/j.combustflame.2006.07.006	journal	September 2006
Convection and radiation combined surface heat transfer coefficient in baking ovens Sakin, Melike; Kaymak-Ertekin, Figen; Ilicali, Coskan Journal of Food Engineering, Vol. 94, Issue 3-4 https://doi.org/10.1016/j.jfoodeng.2009.03.027	journal	October 2009
Effect of cellulose crystallinity on the formation of a liquid intermediate and on product distribution during pyrolysis Wang, Zhouhong; McDonald, Armando G.; Westerhof, Roel J. M. Journal of Analytical and Applied Pyrolysis, Vol. 100 https://doi.org/10.1016/j.jaap.2012.11.017	journal	March 2013
Interactions of structurally different hemicelluloses with nanofibrillar cellulose Eronen, Paula; Österberg, Monika; Heikkinen, Susanna Carbohydrate Polymers, Vol. 86, Issue 3 https://doi.org/10.1016/j.carbpol.2011.06.031	journal	August 2011
Kinetic modeling of biomass pyrolysis Várhegyi, Gábor; Antal, Michael Jerry; Jakab, Emma Journal of Analytical and Applied Pyrolysis, Vol. 42, Issue 1 https://doi.org/10.1016/S0165-2370(96)00971-0	journal	June 1997
Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics Milosavljevic, Ivan; Suuberg, Eric M. Industrial & Engineering Chemistry Research, Vol. 34, Issue 4 https://doi.org/10.1021/ie00043a009	journal	April 1995
Effect of Particle Geometry and Microstructure on Fast Pyrolysis of Beech Wood Westerhof, R. J. M.; Nygård, H. S.; van Swaaij, W. P. M. Energy & Fuels, Vol. 26, Issue 4 https://doi.org/10.1021/ef201688n	journal	March 2012
Application of the distributed activation energy model to biomass and biomass constituents devolatilization Navarro, María V.; Murillo, Ramón; Mastral, Ana M. AIChE Journal, Vol. 55, Issue 10 https://doi.org/10.1002/aic.11848	journal	October 2009
Modelling solid-convective flash pyrolysis of straw and wood in the Pyrolysis Centrifuge Reactor Bech, Niels; Larsen, Morten Boberg; Jensen, Peter Arendt Biomass and Bioenergy, Vol. 33, Issue 6-7 https://doi.org/10.1016/j.biombioe.2009.03.009	journal	June 2009
Bio-oil production from rapid pyrolysis of cottonseed cake: product yields and compositions Ozbay, Nurgül; Pütün, Ayşe E.; Pütün, Ersan International Journal of Energy Research, Vol. 30, Issue 7 https://doi.org/10.1002/er.1165	journal	June 2006
In Situ Analysis of Biomass Pyrolysis by High Temperature Rheology in Relations with ¹ H NMR Dufour, Anthony; Castro-Díaz, Miguel; Marchal, Philippe Energy & Fuels, Vol. 26, Issue 10 https://doi.org/10.1021/ef301310x	journal	October 2012
Pretreatment of poplar wood for fast pyrolysis: rate of cation removal Scott, Donald S.; Paterson, Lachlan; Piskorz, Jan Journal of Analytical and Applied Pyrolysis, Vol. 57, Issue 2, p. 169-176 https://doi.org/10.1016/S0165-2370(00)00108-X	journal	February 2001
Thermal Effects in Cellulose Pyrolysis: Relationship to Char Formation Processes Milosavljevic, Ivan; Oja, Vahur; Suuberg, Eric M. Industrial & Engineering Chemistry Research, Vol. 35, Issue 3 https://doi.org/10.1021/ie950438l	journal	January 1996
A mathematical model of wood pyrolysis Kung, Hsiang-Cheng Combustion and Flame, Vol. 18, Issue 2 https://doi.org/10.1016/S0010-2180(72)80134-2	journal	April 1972
Biomass pyrolysis—A review of modelling, process parameters and catalytic studies Sharma, Abhishek; Pareek, Vishnu; Zhang, Dongke Renewable and Sustainable Energy Reviews, Vol. 50 https://doi.org/10.1016/j.rser.2015.04.193	journal	October 2015
Effect of pyrolysis temperature on aromatic cluster size of cellulose char by quantitative multi cross-polarization 13C NMR with long range dipolar dephasing Smith, Matthew W.; Helms, Greg; McEwen, Jean-Sabin Carbon, Vol. 116 https://doi.org/10.1016/j.carbon.2017.01.078	journal	May 2017
Is it possible to predict gas yields of any biomass after rapid pyrolysis at high temperature from its composition in cellulose, hemicellulose and lignin? Couhert, Carole; Commandre, Jean-Michel; Salvador, Sylvain Fuel, Vol. 88, Issue 3 https://doi.org/10.1016/j.fuel.2008.09.019	journal	March 2009
A model for pyrolysis of wet wood Alves, S. S.; Figueiredo, J. L. Chemical Engineering Science, Vol. 44, Issue 12 https://doi.org/10.1016/0009-2509(89)85096-1	journal	January 1989
Influence of extractives on mechanism of biomass pyrolysis Guo, Xiu-juan; Wang, Shu-rong; Wang, Kai-ge Journal of Fuel Chemistry and Technology, Vol. 38, Issue 1 https://doi.org/10.1016/S1872-5813(10)60019-9	journal	February 2010
Fast pyrolysis technology development Venderbosch, Rh; Prins, W. Biofuels, Bioproducts and Biorefining, Vol. 4, Issue 2 https://doi.org/10.1002/bbb.205	journal	March 2010
Quantitative and kinetic TG-FTIR investigation on three kinds of biomass pyrolysis Meng, Aihong; Zhou, Hui; Qin, Lin Journal of Analytical and Applied Pyrolysis, Vol. 104 https://doi.org/10.1016/j.jaap.2013.09.013	journal	November 2013
Simultaneous drying and pyrolysis of solid fuel particles Saastamoinen, Jaakko; Richard, Jean-Robert Combustion and Flame, Vol. 106, Issue 3 https://doi.org/10.1016/0010-2180(96)00001-6	journal	August 1996
Comprehensive Kinetic Modeling Study of Bio-oil Formation from Fast Pyrolysis of Biomass Calonaci, Matteo; Grana, Roberto; Barker Hemings, Emma Energy & Fuels, Vol. 24, Issue 10 https://doi.org/10.1021/ef1008902	journal	October 2010
Thermal Runaway in the Pyrolysis of Some Lignocellulosic Biomasses Di Blasi, C.; Branca, C.; Sarnataro, F. E. Energy & Fuels, Vol. 28, Issue 4 https://doi.org/10.1021/ef500296g	journal	March 2014
Cellulose char structure: a combined analytical Py-GC-MS, FTIR, and NMR study Pastorova, Ivana; Botto, Robert E.; Arisz, Peter W. Carbohydrate Research, Vol. 262, Issue 1 https://doi.org/10.1016/0008-6215(94)84003-2	journal	September 1994
Pyrolytic oil from fixed bed pyrolysis of municipal solid waste and its characterization Nurul Islam, Mohammad; Nurul Islam, Mohammad; Rafiqul Alam Beg, Mohammad Renewable Energy, Vol. 30, Issue 3 https://doi.org/10.1016/j.renene.2004.05.002	journal	March 2005
The facts and hypotheses relating to the phenomenological model of cellulose pyrolysis Mamleev, Vadim; Bourbigot, Serge; Le Bras, Michel Journal of Analytical and Applied Pyrolysis, Vol. 84, Issue 1 https://doi.org/10.1016/j.jaap.2008.10.014	journal	January 2009
Transient behavior of devolatilization and char reaction during steam gasification of biomass Moon, Jihong; Lee, Jeungwoo; Lee, Uendo Bioresource Technology, Vol. 133 https://doi.org/10.1016/j.biortech.2013.01.148	journal	April 2013
A review on operating parameters for optimum liquid oil yield in biomass pyrolysis Akhtar, Javaid; Saidina Amin, NorAishah Renewable and Sustainable Energy Reviews, Vol. 16, Issue 7 https://doi.org/10.1016/j.rser.2012.05.033	journal	September 2012
A mechanistic model of fast pyrolysis of glucose-based carbohydrates to predict bio-oil composition Vinu, R.; Broadbelt, Linda J. Energy & Environmental Science, Vol. 5, Issue 12 https://doi.org/10.1039/c2ee22784c	journal	January 2012
Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications Zhu, Hongli; Luo, Wei; Ciesielski, Peter N. Chemical Reviews, Vol. 116, Issue 16 https://doi.org/10.1021/acs.chemrev.6b00225	journal	July 2016
Techno-economic comparison of biomass-to-transportation fuels via pyrolysis, gasification, and biochemical pathways Anex, Robert P.; Aden, Andy; Kazi, Feroz Kabir Fuel, Vol. 89, p. S29-S35 https://doi.org/10.1016/j.fuel.2010.07.015	journal	November 2010
Vapor Pressures and Enthalpies of Sublimation of Polycyclic Aromatic Hydrocarbons and Their Derivatives Oja, Vahur; Suuberg, Eric M. Journal of Chemical & Engineering Data, Vol. 43, Issue 3 https://doi.org/10.1021/je970222l	journal	May 1998
Approximations to the distributed activation energy model for the pyrolysis of coal Please, C. P.; McGuinness, M. J.; McElwain, D. L. S. Combustion and Flame, Vol. 133, Issue 1-2 https://doi.org/10.1016/S0010-2180(02)00554-0	journal	April 2003
Optimum conditions for maximising pyrolysis liquids of oil palm empty fruit bunches Sulaiman, F.; Abdullah, N. Energy, Vol. 36, Issue 5 https://doi.org/10.1016/j.energy.2010.12.067	journal	May 2011
Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins Asmadi, Mohd; Kawamoto, Haruo; Saka, Shiro Journal of Analytical and Applied Pyrolysis, Vol. 92, Issue 2 https://doi.org/10.1016/j.jaap.2011.08.003	journal	November 2011
Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates Mettler, Matthew S.; Mushrif, Samir H.; Paulsen, Alex D. Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02743C	journal	January 2012
Low temperature mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose McGrath, Thomas E.; Chan, W. Geoffrey; Hajaligol, Mohammad R. Journal of Analytical and Applied Pyrolysis, Vol. 66, Issue 1-2 https://doi.org/10.1016/S0165-2370(02)00105-5	journal	January 2003
Does energy consumption contribute to climate change? Evidence from major regions of the world Akhmat, Ghulam; Zaman, Khalid; Shukui, Tan Renewable and Sustainable Energy Reviews, Vol. 36 https://doi.org/10.1016/j.rser.2014.04.044	journal	August 2014
Current research on thermochemical conversion of biomass at the National Renewable Energy Laboratory Baldwin, Robert M.; Magrini-Bair, Kimberly A.; Nimlos, Mark R. Applied Catalysis B: Environmental, Vol. 115-116 https://doi.org/10.1016/j.apcatb.2011.10.033	journal	April 2012
Understanding the primary and secondary slow pyrolysis mechanisms of holocellulose, lignin and wood with laser-induced fluorescence Dieguez-Alonso, Alba; Anca-Couce, Andrés; Zobel, Nico Fuel, Vol. 153 https://doi.org/10.1016/j.fuel.2015.02.097	journal	August 2015
Effect of different isolation methods on structure and properties of lignin from valonea of Quercus variabilis Yang, Lina; Wang, Dongmei; Zhou, Dan International Journal of Biological Macromolecules, Vol. 85 https://doi.org/10.1016/j.ijbiomac.2016.01.005	journal	April 2016
Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis Park, Won Chan; Atreya, Arvind; Baum, Howard R. Combustion and Flame, Vol. 157, Issue 3 https://doi.org/10.1016/j.combustflame.2009.10.006	journal	March 2010
Differences in Water-Soluble Intermediates from Slow Pyrolysis of Amorphous and Crystalline Cellulose Liu, Dawei; Yu, Yun; Wu, Hongwei Energy & Fuels, Vol. 27, Issue 3 https://doi.org/10.1021/ef301823g	journal	February 2013
Heterogeneous cracking of wood pyrolysis tars over fresh wood char surfaces Boroson, Michael L.; Howard, Jack B.; Longwell, John P. Energy & Fuels, Vol. 3, Issue 6 https://doi.org/10.1021/ef00018a014	journal	November 1989
Bimetallic catalysts for upgrading of biomass to fuels and chemicals Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A. Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098 https://doi.org/10.1039/c2cs35188a	journal	January 2012
Hydrogen synthesis from biomass pyrolysis with in situ carbon dioxide capture using calcium oxide Widyawati, Meilina; Church, Tamara L.; Florin, Nicholas H. International Journal of Hydrogen Energy, Vol. 36, Issue 8 https://doi.org/10.1016/j.ijhydene.2010.11.103	journal	April 2011
Heat and Mass Transfer Effects in a Furnace-Based Micropyrolyzer Proano-Aviles, Juan; Lindstrom, Jake K.; Johnston, Patrick A. Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600279	journal	August 2016
Techno-Economic Analysis of Fast Pyrolysis as a Process Step Within Biomass-to-Liquid Fuel Production Trippe, Frederik; Fröhling, Magnus; Schultmann, Frank Waste and Biomass Valorization, Vol. 1, Issue 4 https://doi.org/10.1007/s12649-010-9039-1	journal	August 2010
Reaction temperature of solid particles undergoing an endothermal volatilization. Application to the fast pyrolysis of biomass Lédé, J. Biomass and Bioenergy, Vol. 7, Issue 1-6 https://doi.org/10.1016/0961-9534(94)00046-V	journal	January 1994
Cellulose Pyrolysis Kinetics: The Current State of Knowledge Antal, Michael Jerry Jr.; Varhegyi, Gabor Industrial & Engineering Chemistry Research, Vol. 34, Issue 3 https://doi.org/10.1021/ie00042a001	journal	March 1995
Different pyrolytic pathways of levoglucosan in vapor- and liquid/solid-phases Hosoya, Takashi; Kawamoto, Haruo; Saka, Shiro Journal of Analytical and Applied Pyrolysis, Vol. 83, Issue 1 https://doi.org/10.1016/j.jaap.2008.06.008	journal	September 2008
Role of Pretreatments in the Thermal Runaway of Hazelnut Shell Pyrolysis Di Blasi, C.; Branca, C.; Galgano, A. Energy & Fuels, Vol. 29, Issue 4 https://doi.org/10.1021/acs.energyfuels.5b00171	journal	March 2015
Influence of the interaction of components on the pyrolysis behavior of biomass Wang, Shurong; Guo, Xiujuan; Wang, Kaige Journal of Analytical and Applied Pyrolysis, Vol. 91, Issue 1 https://doi.org/10.1016/j.jaap.2011.02.006	journal	May 2011
Modeling droplet breakup processes under micro-explosion conditions Zeng, Yangbing; Lee, Chia-fon F. Proceedings of the Combustion Institute, Vol. 31, Issue 2 https://doi.org/10.1016/j.proci.2006.07.237	journal	January 2007
Chemical Kinetics of Biomass Pyrolysis Ranzi, Eliseo; Cuoci, Alberto; Faravelli, Tiziano Energy & Fuels, Vol. 22, Issue 6 https://doi.org/10.1021/ef800551t	journal	November 2008
Formation of Anhydro-sugars in the Primary Volatiles and Solid Residues from Cellulose Fast Pyrolysis in a Wire-Mesh Reactor Gong, Xun; Yu, Yun; Gao, Xiangpeng Energy & Fuels, Vol. 28, Issue 8 https://doi.org/10.1021/ef501112q	journal	July 2014
Methodology for estimation of thermal ejection droplet size distribution and intensity during the pyrolysis of sugarcane bagasse and model compounds Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne Journal of Analytical and Applied Pyrolysis, Vol. 125 https://doi.org/10.1016/j.jaap.2017.04.017	journal	May 2017
An experimental study of the competing processes of evaporation and polymerization of levoglucosan in cellulose pyrolysis Bai, Xianglan; Johnston, Patrick; Brown, Robert C. Journal of Analytical and Applied Pyrolysis, Vol. 99 https://doi.org/10.1016/j.jaap.2012.10.012	journal	January 2013
A model for primary and heterogeneous secondary reactions of wood pyrolysis Ahuja, Pradeep; Kumar, Surendra; Singh, Prem Chand Chemical Engineering & Technology, Vol. 19, Issue 3 https://doi.org/10.1002/ceat.270190312	journal	June 1996
Pyrolysis of white pine Becker, H. A.; Phillips, A. M.; Keller, J. Combustion and Flame, Vol. 58, Issue 2 https://doi.org/10.1016/0010-2180(84)90091-9	journal	November 1984
Effect of Biomass Size and Aspect Ratio on Intra-Particle Tar Decomposition during Wood Cylinder Pyrolysis Okekunle, Pious O.; Watanabe, Hirotatsu; Pattanotai, Teeranai Journal of Thermal Science and Technology, Vol. 7, Issue 1 https://doi.org/10.1299/jtst.7.1	journal	January 2012
Addressing the challenges of climate change and biofuel production for food and nutrition security Tirado, M. C.; Cohen, M. J.; Aberman, N. Food Research International, Vol. 43, Issue 7 https://doi.org/10.1016/j.foodres.2010.03.010	journal	August 2010
Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review Wang, Shurong; Dai, Gongxin; Yang, Haiping Progress in Energy and Combustion Science, Vol. 62 https://doi.org/10.1016/j.pecs.2017.05.004	journal	September 2017
Flash pyrolysis of cellulose for production of anhydro-oligomers Piskorz, J.; Majerski, P.; Radlein, D. Journal of Analytical and Applied Pyrolysis, Vol. 56, Issue 2 https://doi.org/10.1016/S0165-2370(00)00089-9	journal	November 2000
Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions Beis, S. H.; Onay, Ö.; Koçkar, Ö. M. Renewable Energy, Vol. 26, Issue 1 https://doi.org/10.1016/S0960-1481(01)00109-4	journal	May 2002
Predicting the rapid devolatilization of diverse forms of biomass with bio-flashchain Niksa, Stephen Proceedings of the Combustion Institute, Vol. 28, Issue 2 https://doi.org/10.1016/S0082-0784(00)80693-1	journal	January 2000
Modelling of tar formation and evolution for biomass gasification: A review Font Palma, Carolina Applied Energy, Vol. 111 https://doi.org/10.1016/j.apenergy.2013.04.082	journal	November 2013
Overview of water evolution during the thermal degradation of cellulose Scheirs, J.; Camino, G.; Tumiatti, W. European Polymer Journal, Vol. 37, Issue 5 https://doi.org/10.1016/S0014-3057(00)00211-1	journal	May 2001
Flash pyrolysis of cellulose pellets submitted to a concentrated radiation: experiments and modelling Boutin, Olivier; Ferrer, Monique; Lédé, Jacques Chemical Engineering Science, Vol. 57, Issue 1, p. 15-25 https://doi.org/10.1016/S0009-2509(01)00360-8	journal	January 2002
Kinetics of the pyrolysis of almond shells and almond shells impregnated with cobalt dichloride in a fluidized bed reactor and in a pyroprobe 100 Font, Rafael; Marcilla, Antonio; Verdu, Emilio Industrial & Engineering Chemistry Research, Vol. 29, Issue 9 https://doi.org/10.1021/ie00105a016	journal	September 1990
A second look at fast pyrolysis of biomass—the RTI process Scott, Donald S.; Majerski, Piotr; Piskorz, Jan Journal of Analytical and Applied Pyrolysis, Vol. 51, Issue 1-2 https://doi.org/10.1016/S0165-2370(99)00006-6	journal	July 1999
Estimation of Heat Transfer Coefficients for Biomass Particles by Direct Numerical Simulation Using Microstructured Particle Models in the Laminar Regime Pecha, M. Brennan; Garcia-Perez, Manuel; Foust, Thomas D. ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1 https://doi.org/10.1021/acssuschemeng.6b02341	journal	November 2016
Modelling intra-particle phenomena of biomass pyrolysis Dufour, Anthony; Ouartassi, Bajil; Bounaceur, Roda Chemical Engineering Research and Design, Vol. 89, Issue 10 https://doi.org/10.1016/j.cherd.2011.01.005	journal	October 2011
Reaction kinetics in thermal analysis. Part 1. The sensitivity of kinetic equations to experimental errors. A mathematical analysis Várhegyi, Gábor; Székely, Tamás Thermochimica Acta, Vol. 57, Issue 1 https://doi.org/10.1016/0040-6031(82)87019-6	journal	August 1982
The kinetics of vapour-phase cellulose fast pyrolysis reactions Graham, R. G.; Bergougnou, M. A.; Freel, B. A. Biomass and Bioenergy, Vol. 7, Issue 1-6 https://doi.org/10.1016/0961-9534(94)00045-U	journal	January 1994
Mechanism of Formation and Consequent Evolution of Active Cellulose during Cellulose Pyrolysis Liu, Q.; Wang, S.; Wang, K. Acta Physico-Chimica Sinica, Vol. 24, Issue 11 https://doi.org/10.1016/S1872-1508(08)60078-9	journal	November 2008
A phenomenological model of the mechanisms of lignocellulosic biomass pyrolysis processes Sharma, Abhishek; Pareek, Vishnu; Wang, Shaobin Computers & Chemical Engineering, Vol. 60 https://doi.org/10.1016/j.compchemeng.2013.09.008	journal	January 2014
Effects of particle size on the fast pyrolysis of oil mallee woody biomass Shen, Jun; Wang, Xiao-Shan; Garcia-Perez, Manuel Fuel, Vol. 88, Issue 10 https://doi.org/10.1016/j.fuel.2009.05.001	journal	October 2009
Pyrolysis rates of biomass materials Rao, T. Rajeswara; Sharma, Atul Energy, Vol. 23, Issue 11 https://doi.org/10.1016/S0360-5442(98)00037-1	journal	November 1998
The Role of Sample Dimension and Temperature in Cellulose Pyrolysis Paulsen, Alex D.; Mettler, Matthew S.; Dauenhauer, Paul J. Energy & Fuels, Vol. 27, Issue 4 https://doi.org/10.1021/ef302117j	journal	March 2013
Pyrolytic Reactions of Carbohydrates. Part V. Isothermal Decomposition of Cellulose in Vacuo Halpern, Y.; Patai, S. Israel Journal of Chemistry, Vol. 7, Issue 5 https://doi.org/10.1002/ijch.196900088	journal	January 1969
Pyrolysis characteristics of bean dregs and in situ visualization of pyrolysis transformation Zhu, Guangyong; Zhu, Xian; Xiao, Zuobing Waste Management, Vol. 32, Issue 12 https://doi.org/10.1016/j.wasman.2012.07.004	journal	December 2012
PAH formation in acetylene–benzene pyrolysis Böhm, Heidi; Jander, Helga Physical Chemistry Chemical Physics, Vol. 1, Issue 16 https://doi.org/10.1039/a903306h	journal	January 1999
Product Distribution from the Fast Pyrolysis of Hemicellulose Patwardhan, Pushkaraj R.; Brown, Robert C.; Shanks, Brent H. ChemSusChem, Vol. 4, Issue 5 https://doi.org/10.1002/cssc.201000425	journal	May 2011
A Simple Method for Estimating f (E) and k ₀ ( E ) in the Distributed Activation Energy Model Miura, Kouichi; Maki, Taisuke Energy & Fuels, Vol. 12, Issue 5 https://doi.org/10.1021/ef970212q	journal	September 1998
Fast pyrolysis in a novel wire-mesh reactor: Decomposition of pine wood and model compounds Hoekstra, Elly; Van Swaaij, Wim P. M.; Kersten, Sascha R. A. Chemical Engineering Journal, Vol. 187 https://doi.org/10.1016/j.cej.2012.01.118	journal	April 2012
Fast pyrolysis in a novel wire-mesh reactor: Design and initial results Hoekstra, Elly; van Swaaij, Wim P. M.; Kersten, Sascha R. A. Chemical Engineering Journal, Vol. 191 https://doi.org/10.1016/j.cej.2012.01.117	journal	May 2012
Real-Time and Post-reaction Microscopic Structural Analysis of Biomass Undergoing Pyrolysis Haas, Thomas J.; Nimlos, Mark R.; Donohoe, Bryon S. Energy & Fuels, Vol. 23, Issue 7 https://doi.org/10.1021/ef900201b	journal	July 2009
Kinetic scheme of biomass pyrolysis considering secondary charring reactions Anca-Couce, Andrés; Mehrabian, Ramin; Scharler, Robert Energy Conversion and Management, Vol. 87 https://doi.org/10.1016/j.enconman.2014.07.061	journal	November 2014
Fast pyrolysis of wood: direct measurement and study of ablation rate Lede, Jacques; Panagopoulos, Janis; Li, Huai Zhi Fuel, Vol. 64, Issue 11 https://doi.org/10.1016/0016-2361(85)90365-5	journal	November 1985
Pyrolysis behaviors of wood and its constituent polymers at gasification temperature Hosoya, T.; Kawamoto, H.; Saka, S. Journal of Analytical and Applied Pyrolysis, Vol. 78, Issue 2 https://doi.org/10.1016/j.jaap.2006.08.008	journal	March 2007
Review of fast pyrolysis of biomass and product upgrading Bridgwater, A. V. Biomass and Bioenergy, Vol. 38, p. 68-94 https://doi.org/10.1016/j.biombioe.2011.01.048	journal	March 2012
Aerosol generation by reactive boiling ejection of molten cellulose Teixeira, Andrew R.; Mooney, Kyle G.; Kruger, Jacob S. Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01876k	journal	January 2011
Biomass Pyrolysis in a Fluidized Bed Reactor. Part 2: Experimental Validation of Model Results Wang, Xiaoquan; Kersten, Sascha R. A.; Prins, Wolter Industrial & Engineering Chemistry Research, Vol. 44, Issue 23 https://doi.org/10.1021/ie050486y	journal	November 2005
Modelling the pyrolysis of wet wood – I. Three-dimensional formulation and analysis Yuen, R. K. K.; Yeoh, G. H.; de Vahl Davis, G. International Journal of Heat and Mass Transfer, Vol. 50, Issue 21-22 https://doi.org/10.1016/j.ijheatmasstransfer.2007.01.008	journal	October 2007
A comparative study on the pyrolysis of metal- and ash-enriched wood and the combustion properties of the gained char Mayer, Zsuzsa A.; Apfelbacher, Andreas; Hornung, Andreas Journal of Analytical and Applied Pyrolysis, Vol. 96 https://doi.org/10.1016/j.jaap.2012.04.007	journal	July 2012
Logistic distributed activation energy model – Part 2: Application to cellulose pyrolysis Cai, Junmeng; Yang, Songyuan; Li, Tao Bioresource Technology, Vol. 102, Issue 3 https://doi.org/10.1016/j.biortech.2010.11.073	journal	February 2011
Effects of Temperature on the Formation of Lignin-Derived Oligomers during the Fast Pyrolysis of Mallee Woody Biomass Garcia-Perez, Manuel; Wang, Shan; Shen, Jun Energy & Fuels, Vol. 22, Issue 3 https://doi.org/10.1021/ef7007634	journal	May 2008
Modeling of the devolatilization kinetics during pyrolysis of grape residues Fiori, Luca; Valbusa, Michele; Lorenzi, Denis Bioresource Technology, Vol. 103, Issue 1 https://doi.org/10.1016/j.biortech.2011.09.113	journal	January 2012
Solar flash pyrolysis of biomass direct measurement of the optical properties of biomass components Boutin, O.; Lédé, J.; Olalde, G. Le Journal de Physique IV, Vol. 09, Issue PR3 https://doi.org/10.1051/jp4:1999357	journal	March 1999
Analysis of Cross-Linking Behavior during Pyrolysis of Cellulose for Elucidating Reaction Pathway Chaiwat, Weerawut; Hasegawa, Isao; Tani, Takaaki Energy & Fuels, Vol. 23, Issue 12 https://doi.org/10.1021/ef900674b	journal	December 2009
First chemical events in pyrolysis of wood Degroot, William F.; Pan, Wei-Ping; Rahman, M. Dalilur Journal of Analytical and Applied Pyrolysis, Vol. 13, Issue 3 https://doi.org/10.1016/0165-2370(88)80024-X	journal	April 1988
An Indication of Molten Cellulose Produced in a Laser Beam Nordin, Soren B.; Nyren, Jan O.; Back, Ernst L. Textile Research Journal, Vol. 44, Issue 2 https://doi.org/10.1177/004051757404400211	journal	February 1974
A Critical Review on Hemicellulose Pyrolysis Zhou, Xiaowei; Li, Wenjun; Mabon, Ross Energy Technology, Vol. 5, Issue 1 https://doi.org/10.1002/ente.201600327	journal	August 2016
Biomass pyrolysis for chemicals de Wild, Paul; Reith, Hans; Heeres, Erik Biofuels, Vol. 2, Issue 2 https://doi.org/10.4155/bfs.10.88	journal	March 2011
Puffing and micro-explosion of diesel–biodiesel–ethanol blends Avulapati, Madan Mohan; Ganippa, Lionel Christopher; Xia, Jun Fuel, Vol. 166 https://doi.org/10.1016/j.fuel.2015.10.107	journal	February 2016
Modeling of Lignin Thermolysis Klein, M. T.; Virk, P. S. Energy & Fuels, Vol. 22, Issue 4 https://doi.org/10.1021/ef800285f	journal	July 2008
On the presence of anhydro-oligosaccharides in the sirups from the fast pyrolysis of cellulose Radlein, Desmond S. T. A. G.; Grinshpun, Anna; Piskorz, Jan Journal of Analytical and Applied Pyrolysis, Vol. 12, Issue 1 https://doi.org/10.1016/0165-2370(87)80013-X	journal	June 1987
Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds Xiong, Qingang; Zhang, Jingchao; Xu, Fei Journal of Analytical and Applied Pyrolysis, Vol. 117 https://doi.org/10.1016/j.jaap.2015.11.015	journal	January 2016
Radiant flash pyrolysis of cellulose—Evidence for the formation of short life time intermediate liquid species Boutin, O.; Ferrer, M.; Lédé, J. Journal of Analytical and Applied Pyrolysis, Vol. 47, Issue 1 https://doi.org/10.1016/S0165-2370(98)00088-6	journal	September 1998
Heterogeneous and homogeneous reactions of pyrolysis vapors from pine wood Hoekstra, Elly; Westerhof, Roel J. M.; Brilman, Wim AIChE Journal, Vol. 58, Issue 9 https://doi.org/10.1002/aic.12799	journal	November 2011
Experimental study of nucleate pool boiling heat transfer of water on silicon oxide nanoparticle coated copper heating surface Das, Sudev; Kumar, D. S.; Bhaumik, Swapan Applied Thermal Engineering, Vol. 96 https://doi.org/10.1016/j.applthermaleng.2015.11.117	journal	March 2016
Effect of Cellulose Crystallinity on Solid/Liquid Phase Reactions Responsible for the Formation of Carbonaceous Residues during Pyrolysis Wang, Zhouhong; Pecha, Brennan; Westerhof, Roel J. M. Industrial & Engineering Chemistry Research, Vol. 53, Issue 8 https://doi.org/10.1021/ie4014259	journal	February 2014
Pyrolysis kinetics of lignocellulosic materials—three independent reactions model Orfão, J. J. M.; Antunes, F. J. A.; Figueiredo, J. L. Fuel, Vol. 78, Issue 3 https://doi.org/10.1016/S0016-2361(98)00156-2	journal	February 1999
Integrated Particle- and Reactor-Scale Simulation of Pine Pyrolysis in a Fluidized Bed Pecha, M. Brennan; Ramirez, Emilio; Wiggins, Gavin M. Energy & Fuels, Vol. 32, Issue 10 https://doi.org/10.1021/acs.energyfuels.8b02309	journal	September 2018
Current technologies for analysis of biomass thermochemical processing: A review Bahng, Mi-Kyung; Mukarakate, Calvin; Robichaud, David J. Analytica Chimica Acta, Vol. 651, Issue 2 https://doi.org/10.1016/j.aca.2009.08.016	journal	October 2009
Coal pyrolysis: Experiments, kinetic rates and mechanisms Solomon, Peter R.; Serio, Michael A.; Suuberg, Eric M. Progress in Energy and Combustion Science, Vol. 18, Issue 2 https://doi.org/10.1016/0360-1285(92)90021-R	journal	January 1992
Four Years of ACS Sustainable Chemistry & Engineering : Reflections and New Developments Allen, David T.; Carrier, Danielle Julie; Hwang, Bing-Joe ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1 https://doi.org/10.1021/acssuschemeng.6b03062	journal	December 2016
Comparison of the pyrolysis behavior of pyrolytic lignin and milled wood lignin by using TG–FTIR analysis Wang, Shurong; Lin, Haizhou; Ru, Bin Journal of Analytical and Applied Pyrolysis, Vol. 108 https://doi.org/10.1016/j.jaap.2014.05.014	journal	July 2014
An experimental and modeling study of softening coal pyrolysis Oh, Myongsook S.; Peters, William A.; Howard, Jack B. AIChE Journal, Vol. 35, Issue 5 https://doi.org/10.1002/aic.690350509	journal	May 1989
Modelling and experimental verification of physical and chemical processes during pyrolysis of a large biomass particle Chan, Wai-Chun R.; Kelbon, Marcia; Krieger, Barbara B. Fuel, Vol. 64, Issue 11 https://doi.org/10.1016/0016-2361(85)90364-3	journal	November 1985
Evaluation of alternatives for the evolution of palm oil mills into biorefineries Garcia-Nunez, Jesus Alberto; Rodriguez, Deisy Tatiana; Fontanilla, Carlos Andrés Biomass and Bioenergy, Vol. 95 https://doi.org/10.1016/j.biombioe.2016.05.020	journal	December 2016
A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin Collard, François-Xavier; Blin, Joël Renewable and Sustainable Energy Reviews, Vol. 38 https://doi.org/10.1016/j.rser.2014.06.013	journal	October 2014
Secondary Vapor Phase Reactions of Lignin-Derived Oligomers Obtained by Fast Pyrolysis of Pine Wood Zhou, Shuai; Garcia-Perez, Manuel; Pecha, Brennan Energy & Fuels, Vol. 27, Issue 3 https://doi.org/10.1021/ef3019832	journal	March 2013
Thermal degradation mechanisms of wood under inert and oxidative environments using DAEM methods Shen, D. K.; Gu, S.; Jin, Baosheng Bioresource Technology, Vol. 102, Issue 2 https://doi.org/10.1016/j.biortech.2010.09.081	journal	January 2011
Flash pyrolysis of biomass particles in fluidized bed for bio-oil production Wang, Shurong; Fang, Mengxiang; Yu, Chunjiang China Particuology, Vol. 3, Issue 1-2 https://doi.org/10.1016/S1672-2515(07)60181-X	journal	April 2005
State-of-the-art of fast pyrolysis in IEA bioenergy member countries Meier, Dietrich; van de Beld, Bert; Bridgwater, Anthony V. Renewable and Sustainable Energy Reviews, Vol. 20 https://doi.org/10.1016/j.rser.2012.11.061	journal	April 2013
On the Combustion of Wood II: The Influence of Internal Convection on the Transient Pyrolysis of Cellulose Kanury, A. Murty; Blackshear, Perry L. Combustion Science and Technology, Vol. 2, Issue 1 https://doi.org/10.1080/00102207008952230	journal	August 1970
A coarse-grain force-field for xylan and its interaction with cellulose Li, Liang; Pérré, Patrick; Frank, Xavier Carbohydrate Polymers, Vol. 127 https://doi.org/10.1016/j.carbpol.2015.04.003	journal	August 2015
Fractional Condensation of Biomass Pyrolysis Vapors Westerhof, Roel J. M.; Brilman, D. Wim F.; Garcia-Perez, Manuel Energy & Fuels, Vol. 25, Issue 4 https://doi.org/10.1021/ef2000322	journal	April 2011
Chemical Effects of Heat on Cellulose Golova, O. P. Russian Chemical Reviews, Vol. 44, Issue 8 https://doi.org/10.1070/RC1975v044n08ABEH002369	journal	August 1975
Modelling heat of reaction in biomass pyrolysis with detailed reaction schemes Anca-Couce, Andrés; Scharler, Robert Fuel, Vol. 206 https://doi.org/10.1016/j.fuel.2017.06.011	journal	October 2017
Effect of particle size on the composition of lignin derived oligomers obtained by fast pyrolysis of beech wood Zhou, Shuai; Garcia-Perez, Manuel; Pecha, Brennan Fuel, Vol. 125 https://doi.org/10.1016/j.fuel.2014.01.016	journal	June 2014
Cellulose–hemicellulose and cellulose–lignin interactions in wood pyrolysis at gasification temperature Hosoya, T.; Kawamoto, H.; Saka, S. Journal of Analytical and Applied Pyrolysis, Vol. 80, Issue 1 https://doi.org/10.1016/j.jaap.2007.01.006	journal	August 2007
Reactive boiling of cellulose for integrated catalysis through an intermediate liquid Dauenhauer, Paul J.; Colby, Joshua L.; Balonek, Christine M. Green Chemistry, Vol. 11, Issue 10 https://doi.org/10.1039/b915068b	journal	January 2009
Biomass Pyrolysis in a Fluidized Bed Reactor. Part 1: Literature Review and Model Simulations Kersten, Sascha R. A.; Wang, Xiaoquan; Prins, Wolter Industrial & Engineering Chemistry Research, Vol. 44, Issue 23 https://doi.org/10.1021/ie0504856	journal	November 2005
Effects of intraparticle heat and mass transfer during devolatilization of a single coal particle Bliek, Alfred; Van Poelje, W. M.; Van Swaaij, W. P. M. AIChE Journal, Vol. 31, Issue 10 https://doi.org/10.1002/aic.690311010	journal	October 1985
Top ten fundamental challenges of biomass pyrolysis for biofuels Mettler, Matthew S.; Vlachos, Dionisios G.; Dauenhauer, Paul J. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21679e	journal	January 2012
Kinetic analyses of biomass pyrolysis using the distributed activation energy model Sonobe, T.; Worasuwannarak, N. Fuel, Vol. 87, Issue 3 https://doi.org/10.1016/j.fuel.2007.05.004	journal	March 2008
Vapor Pressures and Enthalpies of Sublimation of d -Glucose, d -Xylose, Cellobiose, and Levoglucosan Oja, V.; Suuberg, E. M. Journal of Chemical & Engineering Data, Vol. 44, Issue 1 https://doi.org/10.1021/je980119b	journal	January 1999
Slow and fast pyrolysis of Douglas-fir lignin: Importance of liquid-intermediate formation on the distribution of products Zhou, Shuai; Pecha, Brennan; van Kuppevelt, Michiel Biomass and Bioenergy, Vol. 66 https://doi.org/10.1016/j.biombioe.2014.03.064	journal	July 2014
Influence of Particle Sizes and Environmental Conditions on High Temperature Pyrolysis of Cellulosic Material—I (Theoretical) Maa, Peter S.; Bailie, Richard C. Combustion Science and Technology, Vol. 7, Issue 6 https://doi.org/10.1080/00102207308952366	journal	August 1973
Distinguishing primary and secondary reactions of cellulose pyrolysis Patwardhan, Pushkaraj R.; Dalluge, Dustin L.; Shanks, Brent H. Bioresource Technology, Vol. 102, Issue 8 https://doi.org/10.1016/j.biortech.2011.02.018	journal	April 2011
Kinetics of reactions involved in pyrolysis of cellulose I. The three reaction model Agrawal, Ravindra K. The Canadian Journal of Chemical Engineering, Vol. 66, Issue 3 https://doi.org/10.1002/cjce.5450660309	journal	June 1988
Is the Broido-Shafizadeh Model for Cellulose Pyrolysis True? Varhegyi, Gabor; Jakab, Emma; Antal, Michael Jerry Energy & Fuels, Vol. 8, Issue 6 https://doi.org/10.1021/ef00048a025	journal	November 1994
Thermal conductivity of wood—models for different stages of combustion Thunman, Henrik; Leckner, Bo Biomass and Bioenergy, Vol. 23, Issue 1 https://doi.org/10.1016/S0961-9534(02)00031-4	journal	July 2002
Online experiments and modelling with a detailed reaction scheme of single particle biomass pyrolysis Anca-Couce, Andrés; Sommersacher, Peter; Scharler, Robert Journal of Analytical and Applied Pyrolysis, Vol. 127 https://doi.org/10.1016/j.jaap.2017.07.008	journal	September 2017
Internal mass transfer considerations during the pyrolysis of an isolated spherical softening coal particle Sezen, Yusuf International Journal of Heat and Mass Transfer, Vol. 32, Issue 10 https://doi.org/10.1016/0017-9310(89)90251-2	journal	October 1989
Coupled Structural and Kinetic Model of Lignin Fast Pyrolysis Yanez, Abraham J.; Natarajan, Pradeep; Li, Wenjun Energy & Fuels, Vol. 32, Issue 2 https://doi.org/10.1021/acs.energyfuels.7b03311	journal	January 2018
Transport phenomena in multi-particle systems—IV. Heat transfer to a large freely moving particle in gas fluidized bed of smaller particles Agarwal, Pradeep K. Chemical Engineering Science, Vol. 46, Issue 4 https://doi.org/10.1016/0009-2509(91)85104-6	journal	January 1991
The combustion of wood. Part I Bamford, C. H.; Crank, J.; Malan, D. H. Mathematical Proceedings of the Cambridge Philosophical Society, Vol. 42, Issue 2 https://doi.org/10.1017/S030500410002288X	journal	June 1946
Mathematical model of wood pyrolysis including internal forced convection Kansa, Edward J.; Perlee, Henry E.; Chaiken, Robert F. Combustion and Flame, Vol. 29 https://doi.org/10.1016/0010-2180(77)90121-3	journal	January 1977
Thermal Lag, Fusion, and the Compensation Effect during Biomass Pyrolysis ^† Narayan, Ravi; Antal, Michael Jerry Industrial & Engineering Chemistry Research, Vol. 35, Issue 5 https://doi.org/10.1021/ie950368i	journal	January 1996
Influence of pyrolysis temperature and heating rate on the production of bio-oil and char from safflower seed by pyrolysis, using a well-swept fixed-bed reactor Onay, Ozlem Fuel Processing Technology, Vol. 88, Issue 5 https://doi.org/10.1016/j.fuproc.2007.01.001	journal	May 2007
High-Yield Biomass Charcoal ^† Antal,, Michael Jerry; Croiset, Eric; Dai, Xiangfeng Energy & Fuels, Vol. 10, Issue 3 https://doi.org/10.1021/ef9501859	journal	January 1996
Modeling the physiochemistry of levoglucosan during cellulose pyrolysis Bai, Xianglan; Brown, Robert C. Journal of Analytical and Applied Pyrolysis, Vol. 105 https://doi.org/10.1016/j.jaap.2013.11.026	journal	January 2014
In-Depth Investigation of Biomass Pyrolysis Based on Three Major Components: Hemicellulose, Cellulose and Lignin Yang, Haiping; Yan, Rong; Chen, Hanping Energy & Fuels, Vol. 20, Issue 1 https://doi.org/10.1021/ef0580117	journal	January 2006
Single particle model for biomass pyrolysis with bubble formation dynamics inside the liquid intermediate and its contribution to aerosol formation by thermal ejection Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne Journal of Analytical and Applied Pyrolysis, Vol. 124 https://doi.org/10.1016/j.jaap.2017.02.004	journal	March 2017
Radiation Heat Transfer in Fluidized Beds: A Comparison of Exact and Simplified Approaches Flamant, G.; Lu, J. D.; Variot, B. Journal of Heat Transfer, Vol. 116, Issue 3 https://doi.org/10.1115/1.2910919	journal	August 1994
Kinetic modelling of the pyrolysis of biomass and biomass components Koufopanos, C. A.; Lucchesi, A.; Maschio, G. The Canadian Journal of Chemical Engineering, Vol. 67, Issue 1 https://doi.org/10.1002/cjce.5450670111	journal	February 1989
Distribution of activation energy model applied to the rapid pyrolysis of coal blends Ulloa, Claudia; Gordon, Alfredo L.; Garcı́a, Ximena Journal of Analytical and Applied Pyrolysis, Vol. 71, Issue 2 https://doi.org/10.1016/S0165-2370(03)00132-3	journal	June 2004
Experimental Study on Charcoal Production from Woody Biomass Wang, Liang; Skreiberg, Øyvind; Van Wesenbeeck, Sam Energy & Fuels, Vol. 30, Issue 10 https://doi.org/10.1021/acs.energyfuels.6b01039	journal	September 2016
Major trends and roadblocks in CFD-aided process intensification of biomass pyrolysis Xiong, Qingang; Xu, Fei; Pan, Yaoyu Chemical Engineering and Processing - Process Intensification, Vol. 127 https://doi.org/10.1016/j.cep.2018.04.005	journal	May 2018
Reaction kinetics in thermal analysis: a brief survey of fundamental research problems Várhegyi, Gábor Thermochimica Acta, Vol. 110 https://doi.org/10.1016/0040-6031(87)88215-1	journal	February 1987
Effects of Intraparticle Heat and Mass Transfer on Biomass Devolatilization: Experimental Results and Model Predictions Bharadwaj, Anshu; Baxter, Larry L.; Robinson, Allen L. Energy & Fuels, Vol. 18, Issue 4 https://doi.org/10.1021/ef0340357	journal	July 2004
A model for the evaporation of biomass pyrolysis oil droplets Hallett, W. L. H.; Clark, N. A. Fuel, Vol. 85, Issue 4 https://doi.org/10.1016/j.fuel.2005.08.006	journal	March 2006
A gas-solid reaction model for flash wood pyrolysis Hastaoglu, M. A.; Berruti, F. Fuel, Vol. 68, Issue 11 https://doi.org/10.1016/0016-2361(89)90038-0	journal	November 1989
A kinetic model for pyrolysis of cellulose Bradbury, Allan G. W.; Sakai, Yoshio; Shafizadeh, Fred Journal of Applied Polymer Science, Vol. 23, Issue 11 https://doi.org/10.1002/app.1979.070231112	journal	June 1979
Cellulose pyrolysis kinetics: An historical review on the existence and role of intermediate active cellulose Lédé, Jacques Journal of Analytical and Applied Pyrolysis, Vol. 94 https://doi.org/10.1016/j.jaap.2011.12.019	journal	March 2012
A computational framework for the pyrolysis of anisotropic biomass particles Gentile, Giancarlo; Debiagi, Paulo Eduardo Amaral; Cuoci, Alberto Chemical Engineering Journal, Vol. 321 https://doi.org/10.1016/j.cej.2017.03.113	journal	August 2017
Modelling the fast pyrolysis of cellulosic particles in fluid-bed reactors Blasi, Colomba Di Chemical Engineering Science, Vol. 55, Issue 24 https://doi.org/10.1016/S0009-2509(00)00406-1	journal	December 2000
Mathematical modelling of slow pyrolysis of a particle of treated wood waste Ratte, J.; Marias, F.; Vaxelaire, J. Journal of Hazardous Materials, Vol. 170, Issue 2-3 https://doi.org/10.1016/j.jhazmat.2009.05.077	journal	October 2009
Heat transfer and kinetics in the low temperature pyrolysis of solids Pyle, D. L.; Zaror, C. A. Chemical Engineering Science, Vol. 39, Issue 1 https://doi.org/10.1016/0009-2509(84)80140-2	journal	January 1984
Study of the micro-explosion temperature of water in oil emulsion droplets during the Leidenfrost effect Mura, E.; Massoli, P.; Josset, C. Experimental Thermal and Fluid Science, Vol. 43 https://doi.org/10.1016/j.expthermflusci.2012.03.027	journal	November 2012
Influence of impregnated metal on the pyrolysis conversion of biomass constituents Collard, François-Xavier; Blin, Joël; Bensakhria, Ammar Journal of Analytical and Applied Pyrolysis, Vol. 95 https://doi.org/10.1016/j.jaap.2012.02.009	journal	May 2012
A unified, global model for the pyrolysis of cellulose Diebold, James P. Biomass and Bioenergy, Vol. 7, Issue 1-6 https://doi.org/10.1016/0961-9534(94)00039-V	journal	January 1994
Micro-explosion of liquid intermediates during the fast pyrolysis of sucrose and organosolv lignin Montoya, Jorge; Pecha, Brennan; Janna, Farid Chejne Journal of Analytical and Applied Pyrolysis, Vol. 122 https://doi.org/10.1016/j.jaap.2016.10.010	journal	November 2016
Secondary reactions of flash pyrolysis tars measured in a fluidized bed pyrolysis reactor with some novel design features Stiles, H.; Kandiyoti, R. Fuel, Vol. 68, Issue 3 https://doi.org/10.1016/0016-2361(89)90087-2	journal	March 1989
Effect of temperature on the fast pyrolysis of organic-acid leached pinewood; the potential of low temperature pyrolysis Oudenhoven, S. R. G.; Lievens, C.; Westerhof, R. J. M. Biomass and Bioenergy, Vol. 89 https://doi.org/10.1016/j.biombioe.2015.12.019	journal	June 2016
Study on the pyrolytic behaviour of xylan-based hemicellulose using TG–FTIR and Py–GC–FTIR Shen, D. K.; Gu, S.; Bridgwater, A. V. Journal of Analytical and Applied Pyrolysis, Vol. 87, Issue 2 https://doi.org/10.1016/j.jaap.2009.12.001	journal	March 2010
Comparison of semi-global mechanisms for primary pyrolysis of lignocellulosic fuels Di Blasi, Colomba Journal of Analytical and Applied Pyrolysis, Vol. 47, Issue 1 https://doi.org/10.1016/S0165-2370(98)00079-5	journal	September 1998
Boiling point of levoglucosan and devolatilization temperatures in cellulose pyrolysis measured at different heating area temperatures Shoji, Taeko; Kawamoto, Haruo; Saka, Shiro Journal of Analytical and Applied Pyrolysis, Vol. 109 https://doi.org/10.1016/j.jaap.2014.06.014	journal	September 2014
Influence of mineral matter on biomass pyrolysis characteristics Raveendran, K.; Ganesh, Anuradda; Khilar, Kartic C. Fuel, Vol. 74, Issue 12 https://doi.org/10.1016/0016-2361(95)80013-8	journal	December 1995
Modeling the evolution of volatile species during tobacco pyrolysis Wójtowicz, Marek A.; Bassilakis, Rosemary; Smith, Wayne W. Journal of Analytical and Applied Pyrolysis, Vol. 66, Issue 1-2 https://doi.org/10.1016/S0165-2370(02)00116-X	journal	January 2003
Py-GC/MS studies and principal component analysis to evaluate the impact of feedstock and temperature on the distribution of products during fast pyrolysis Liaw, Shi-Shen; Haber Perez, Victor; Zhou, Shuai Journal of Analytical and Applied Pyrolysis, Vol. 109 https://doi.org/10.1016/j.jaap.2014.06.018	journal	September 2014
Mechanisms and kinetics of homogeneous secondary reactions of tar from continuous pyrolysis of wood chips Morf, Philipp; Hasler, Philipp; Nussbaumer, Thomas Fuel, Vol. 81, Issue 7 https://doi.org/10.1016/S0016-2361(01)00216-2	journal	May 2002
The role of temperature in the fast pyrolysis of cellulose and wood Scott, Donald S.; Piskorz, Jan; Bergougnou, Maurice A. Industrial & Engineering Chemistry Research, Vol. 27, Issue 1 https://doi.org/10.1021/ie00073a003	journal	January 1988
Isolation of lignin Obst, John R.; Kirk, T. Kent Methods in Enzymology https://doi.org/10.1016/0076-6879(88)61003-2	book	January 1988
Influence of inorganic salts on the primary pyrolysis products of cellulose Patwardhan, Pushkaraj R.; Satrio, Justinus A.; Brown, Robert C. Bioresource Technology, Vol. 101, Issue 12 https://doi.org/10.1016/j.biortech.2010.01.112	journal	June 2010
The Origin of Molecular Mobility During Biomass Pyrolysis as Revealed by In situ 1H NMR Spectroscopy Dufour, Anthony; Castro-Diaz, Miguel; Brosse, Nicolas ChemSusChem, Vol. 5, Issue 7 https://doi.org/10.1002/cssc.201100442	journal	May 2012
X-ray Computed Tomography Visualization of the Woody Char Intraparticle Pore Structure and Its Role on Anisotropic Evolution during Char Gasification Watanabe, Hirotatsu Energy & Fuels, Vol. 32, Issue 4 https://doi.org/10.1021/acs.energyfuels.7b03227	journal	January 2018
Pyrolysis of Turkish Zonguldak bituminous coal. Part 1. Effect of mineral matter Öztaş, N. A.; Yürüm, Y. Fuel, Vol. 79, Issue 10 https://doi.org/10.1016/S0016-2361(99)00255-0	journal	August 2000
Effects of side-chain hydroxyl groups on pyrolytic β-ether cleavage of phenolic lignin model dimer Kawamoto, Haruo; Horigoshi, Sunao; Saka, Shiro Journal of Wood Science, Vol. 53, Issue 3 https://doi.org/10.1007/s10086-006-0839-7	journal	June 2007
Influence of metal ions and of salts on products from pyrolysis of wood: Applications to thermochemical processing of newsprint and biomass Richards, Geoffrey N.; Zheng, Guangcheng Journal of Analytical and Applied Pyrolysis, Vol. 21, Issue 1-2 https://doi.org/10.1016/0165-2370(91)80021-Y	journal	September 1991
Time and temperature depended fuel gas generation from pyrolysis of real world municipal plastic waste Singh, Rohit Kumar; Ruj, Biswajit Fuel, Vol. 174 https://doi.org/10.1016/j.fuel.2016.01.049	journal	June 2016
Comparison of gasification and pyrolysis of thermal pre-treated wood board waste Girods, Pierre; Dufour, Anthony; Rogaume, Yann Journal of Analytical and Applied Pyrolysis, Vol. 85, Issue 1-2 https://doi.org/10.1016/j.jaap.2008.11.014	journal	May 2009
Biomass Particle Models with Realistic Morphology and Resolved Microstructure for Simulations of Intraparticle Transport Phenomena Ciesielski, Peter N.; Crowley, Michael F.; Nimlos, Mark R. Energy & Fuels, Vol. 29, Issue 1 https://doi.org/10.1021/ef502204v	journal	December 2014
Biomass Pyrolysis: Comments on Some Sources of Confusions in the Definitions of Temperatures and Heating Rates Lédé, Jacques Energies, Vol. 3, Issue 4 https://doi.org/10.3390/en3040886	journal	April 2010
The interplay between chemistry and heat/mass transfer during the fast pyrolysis of cellulose Westerhof, R. J. M.; Oudenhoven, S. R. G.; Marathe, P. S. Reaction Chemistry & Engineering, Vol. 1, Issue 5 https://doi.org/10.1039/C6RE00100A	journal	January 2016
Heat transfer mechanisms and multi-step kinetics in the ablative pyrolysis of cellulose Di Blasi, Colomba Chemical Engineering Science, Vol. 51, Issue 10 https://doi.org/10.1016/0009-2509(96)00078-4	journal	May 1996
Processing of TGA data: Analysis of isoconversional and model fitting methods Jain, Ankit A.; Mehra, Anurag; Ranade, Vivek V. Fuel, Vol. 165 https://doi.org/10.1016/j.fuel.2015.10.042	journal	February 2016
Extractives Extend the Applicability of Multistep Kinetic Scheme of Biomass Pyrolysis Debiagi, Paulo Eduardo Amaral; Pecchi, Chiara; Gentile, Giancarlo Energy & Fuels, Vol. 29, Issue 10 https://doi.org/10.1021/acs.energyfuels.5b01753	journal	September 2015
Low-Order Modeling of Internal Heat Transfer in Biomass Particle Pyrolysis Wiggins, Gavin M.; Ciesielski, Peter N.; Daw, C. Stuart Energy & Fuels, Vol. 30, Issue 6 https://doi.org/10.1021/acs.energyfuels.6b00554	journal	May 2016
Overview of Computational Fluid Dynamics Simulation of Reactor-Scale Biomass Pyrolysis Xiong, Qingang; Yang, Yang; Xu, Fei ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 4 https://doi.org/10.1021/acssuschemeng.6b02634	journal	March 2017
Kinetics and Mechanism of Cellulose Pyrolysis Lin, Yu-Chuan; Cho, Joungmo; Tompsett, Geoffrey A. The Journal of Physical Chemistry C, Vol. 113, Issue 46 https://doi.org/10.1021/jp906702p	journal	October 2009
Radionuclide re-entrainment at bubbling water pool surfaces Koch, M. K.; Voßnacke, A.; Starflinger, J. Journal of Aerosol Science, Vol. 31, Issue 9 https://doi.org/10.1016/S0021-8502(00)00025-2	journal	September 2000
Influence of Pyrolysis Operating Conditions on Bio-Oil Components: A Microscale Study in a Pyroprobe Thangalazhy-Gopakumar, Suchithra; Adhikari, Sushil; Gupta, Ram B. Energy & Fuels, Vol. 25, Issue 3 https://doi.org/10.1021/ef101032s	journal	March 2011
A critical study of the Miura–Maki integral method for the estimation of the kinetic parameters of the distributed activation energy model Cai, Junmeng; Li, Tao; Liu, Ronghou Bioresource Technology, Vol. 102, Issue 4 https://doi.org/10.1016/j.biortech.2010.11.110	journal	February 2011
Thermal decomposition kinetics of wood pyrolysis Murty Kanury, A. Combustion and Flame, Vol. 18, Issue 1 https://doi.org/10.1016/S0010-2180(72)80228-1	journal	February 1972
Plate reactor as an analysis tool for rapid pyrolysis of biomass Sepman, A. V.; de Goey, L. P. H. Biomass and Bioenergy, Vol. 35, Issue 7 https://doi.org/10.1016/j.biombioe.2011.03.030	journal	July 2011
Mechanism and modelling of bamboo pyrolysis Oyedun, Adetoyese Olajire; Gebreegziabher, Tesfaldet; Hui, Chi Wai Fuel Processing Technology, Vol. 106 https://doi.org/10.1016/j.fuproc.2012.09.031	journal	February 2013
Combustion kinetics of wet-torrefied forest residues using the distributed activation energy model (DAEM) Bach, Quang-Vu; Tran, Khanh-Quang; Skreiberg, Øyvind Applied Energy, Vol. 185 https://doi.org/10.1016/j.apenergy.2016.02.056	journal	January 2017
Fusion-like behaviour of wood pyrolysis Lédé, Jacques; Li, Huai Zhi; Villermaux, Jacques Journal of Analytical and Applied Pyrolysis, Vol. 10, Issue 4 https://doi.org/10.1016/0165-2370(87)80019-0	journal	May 1987
Recent developments in fast pyrolysis of ligno-cellulosic materials Kersten, Sascha; Garcia-Perez, Manuel Current Opinion in Biotechnology, Vol. 24, Issue 3 https://doi.org/10.1016/j.copbio.2013.04.003	journal	June 2013
Effect of operating parameters on methanation reaction for the production of synthetic natural gas Kang, Woo Ram; Lee, Ki Bong Korean Journal of Chemical Engineering, Vol. 30, Issue 7 https://doi.org/10.1007/s11814-013-0047-2	journal	May 2013
Pyrolysis behavior and kinetics of biomass derived materials Fisher, Travis; Hajaligol, Mohammad; Waymack, Bruce Journal of Analytical and Applied Pyrolysis, Vol. 62, Issue 2 https://doi.org/10.1016/S0165-2370(01)00129-2	journal	February 2002
Kinetic analysis of the gas-phase pyrolysis of carbohydrates Shin, Eun-Jae; Nimlos, Mark R.; Evans, Robert J. Fuel, Vol. 80, Issue 12 https://doi.org/10.1016/S0016-2361(01)00056-4	journal	October 2001
Effect of a Vacuum on the Fast Pyrolysis of Cellulose: Nature of Secondary Reactions in a Liquid Intermediate Pecha, M. Brennan; Montoya, Jorge Ivan; Chejne, Farid Industrial & Engineering Chemistry Research, Vol. 56, Issue 15 https://doi.org/10.1021/acs.iecr.7b00476	journal	April 2017
New distributed activation energy model: Numerical solution and application to pyrolysis kinetics of some types of biomass Cai, Junmeng; Liu, Ronghou Bioresource Technology, Vol. 99, Issue 8 https://doi.org/10.1016/j.biortech.2007.06.033	journal	May 2008
Pool boiling and flow boiling on micro- and nanostructured surfaces Shojaeian, Mostafa; Koşar, Ali Experimental Thermal and Fluid Science, Vol. 63 https://doi.org/10.1016/j.expthermflusci.2014.12.016	journal	May 2015
Evidence for oligomers in pyrolysates of microcrystalline cellulose Pouwels, Aloys D.; Eijkel, Gert B.; Arisz, Peter W. Journal of Analytical and Applied Pyrolysis, Vol. 15 https://doi.org/10.1016/0165-2370(89)85023-5	journal	March 1989
A mathematical model for pyrolysis of a solid particle: Effects of the lewis number Fan, L. T.; Fan, Liang-Shih; Miyanami, Kei The Canadian Journal of Chemical Engineering, Vol. 55, Issue 1 https://doi.org/10.1002/cjce.5450550109	journal	February 1977
Cellulose pyrolysis: the kinetics of hydroxyacetaldehyde evolution Banyasz, Joseph L.; Li, San; Lyons-Hart, Jim L. Journal of Analytical and Applied Pyrolysis, Vol. 57, Issue 2 https://doi.org/10.1016/S0165-2370(00)00135-2	journal	February 2001
Phenols and aromatics from fast pyrolysis of variously prepared lignins from hard- and softwoods Custodis, Victoria B. F.; Bährle, Christian; Vogel, Frédéric Journal of Analytical and Applied Pyrolysis, Vol. 115 https://doi.org/10.1016/j.jaap.2015.07.018	journal	September 2015
Tar destruction and coke formation during rapid pyrolysis and gasification of biomass in a drop-tube furnace Zhang, Yan; Kajitani, Shiro; Ashizawa, Masami Fuel, Vol. 89, Issue 2 https://doi.org/10.1016/j.fuel.2009.08.045	journal	February 2010
Multistep Mechanism for the Devolatilization of Biomass Fast Pyrolysis Oils Branca, Carmen; Di Blasi, Colomba Industrial & Engineering Chemistry Research, Vol. 45, Issue 17 https://doi.org/10.1021/ie060161x	journal	August 2006
An Indication of Molten Cellulose Produced in a Laser Beam Back, Ernst; Nordin, Sören; Nyrén, Jan Textile Research Journal, Vol. 44, Issue 11 https://doi.org/10.1177/004051757404401119	journal	November 1974