A multi-functional interface derived from thiol-modified mesoporous carbon in lithium–sulfur batteries

Li, Yun; Murphy, Ian A.; Chen, Ying; Lin, Francis; Wang, Xiang; Wang, Shanyu; Hubble, Dion; Jang, Sei-Hum; Muller, Karl T.; Wang, Chongmin; Jen, Alex K. -Y.; Yang, Jihui

doi:10.1039/C9TA02743B

Title: A multi-functional interface derived from thiol-modified mesoporous carbon in lithium–sulfur batteries

Journal Article · 28 May 2019 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/C9TA02743B · OSTI ID:1514723

^[1];

^[2];

^[3]; Lin, Francis ^[2];

^[4];

^[1];

^[5]; Jang, Sei-Hum ^[2];

^[3]; Wang, Chongmin ^[3];

^[6];

^[1]

Department of Materials Science and Engineering, University of Washington, Seattle, USA
Department of Chemistry, University of Washington, Seattle, USA
Environmental Molecular Sciences Laboratory (EMSL), Pacific Northwestern National Laboratory, Richland, USA
Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, USA
Molecular Engineering & Science, University of Washington, Seattle, USA
Department of Materials Science and Engineering, University of Washington, Seattle, USA, Department of Chemistry

Li–S batteries hold great promise as the utility of a thiol-based interface facilitates LiPS-trapping and improves the electrolyte wetting.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007791

OSTI ID:: 1514723

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Vol. 7 Journal Issue: 21; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (65)

A Conductive Molecular Framework Derived Li ₂ S/N,P-Codoped Carbon Cathode for Advanced Lithium-Sulfur Batteries Zhang, Jun; Shi, Ye; Ding, Yu Advanced Energy Materials, Vol. 7, Issue 14 https://doi.org/10.1002/aenm.201602876	journal	April 2017
Fibrous Hybrid of Graphene and Sulfur Nanocrystals for High-Performance Lithium–Sulfur Batteries Zhou, Guangmin; Yin, Li-Chang; Wang, Da-Wei ACS Nano, Vol. 7, Issue 6 https://doi.org/10.1021/nn401228t	journal	May 2013
Progress in Mechanistic Understanding and Characterization Techniques of Li-S Batteries Xu, Rui; Lu, Jun; Amine, Khalil Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201500408	journal	May 2015
Facile synthesis of Ti ₄ O ₇ on hollow carbon spheres with enhanced polysulfide binding for high-performance lithium–sulfur batteries Wang, Fang; Ding, Xian; Shi, Ruyue Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/C9TA00544G	journal	January 2019
Rational designs and engineering of hollow micro-/nanostructures as sulfur hosts for advanced lithium–sulfur batteries Li, Zhen; Wu, Hao Bin; (David) Lou, Xiong Wen Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02364A	journal	January 2016
Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of Lithium–Sulfur Battery Zhou, Weidong; Chen, Hao; Yu, Yingchao ACS Nano, Vol. 7, Issue 10 https://doi.org/10.1021/nn403237b	journal	September 2013
Optimization of Pore Structure of Cathodic Carbon Supports for Solvate Ionic Liquid Electrolytes Based Lithium–Sulfur Batteries Zhang, Shiguo; Ikoma, Ai; Li, Zhe ACS Applied Materials & Interfaces, Vol. 8, Issue 41 https://doi.org/10.1021/acsami.6b09989	journal	October 2016
The impact of the particle size of a metal–organic framework for sulfur storage in Li–S batteries Zhou, Junwen; Yu, Xiaosong; Fan, Xinxin Journal of Materials Chemistry A, Vol. 3, Issue 16 https://doi.org/10.1039/C5TA00524H	journal	January 2015
Research Progress toward the Practical Applications of Lithium–Sulfur Batteries Lochala, Joshua; Liu, Dianying; Wu, Bingbin ACS Applied Materials & Interfaces, Vol. 9, Issue 29 https://doi.org/10.1021/acsami.7b06208	journal	July 2017
Suppressed Polysulfide Crossover in Li–S Batteries through a High-Flux Graphene Oxide Membrane Supported on a Sulfur Cathode Shaibani, Mahdokht; Akbari, Abozar; Sheath, Phillip ACS Nano, Vol. 10, Issue 8 https://doi.org/10.1021/acsnano.6b03285	journal	July 2016
Greatly Suppressed Shuttle Effect for Improved Lithium Sulfur Battery Performance through Short Chain Intermediates Xu, Na; Qian, Tao; Liu, Xuejun Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04610	journal	December 2016
A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Song, Min-Kyu; Zhang, Yuegang; Cairns, Elton J. Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl402793z	journal	November 2013
Low-cost disordered carbons for Li/S batteries: A high-performance carbon with dual porosity derived from cherry pits Hernández-Rentero, Celia; Córdoba, Rafael; Moreno, Noelia Nano Research, Vol. 11, Issue 1 https://doi.org/10.1007/s12274-017-1608-1	journal	June 2017
Ultrafine Sulfur Nanoparticles in Conducting Polymer Shell as Cathode Materials for High Performance Lithium/Sulfur Batteries Chen, Hongwei; Dong, Weiling; Ge, Jun Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01910	journal	May 2013
X-ray Photoelectron Spectroscopy Sulfur 2p Study of Organic Thiol and Disulfide Binding Interactions with Gold Surfaces Castner, David G.; Hinds, Kenneth; Grainger, David W. Langmuir, Vol. 12, Issue 21 https://doi.org/10.1021/la960465w	journal	January 1996
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Sandwich-Type NbS ₂ @S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate, and Long-Life Lithium–Sulfur Batteries Xiao, Zhubing; Yang, Zhi; Zhang, Linjie ACS Nano, Vol. 11, Issue 8 https://doi.org/10.1021/acsnano.7b04442	journal	August 2017
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells Hagen, Markus; Hanselmann, Dominik; Ahlbrecht, Katharina Advanced Energy Materials, Vol. 5, Issue 16, 1401986 https://doi.org/10.1002/aenm.201401986	journal	April 2015
Electrochemical Behavior of Diphenyl Disulfide and Thiophenol on Glassy Carbon and Gold Electrodes in Aprotic Media Borsari, Marco; Cannio, Maria; Gavioli, Giovanna Electroanalysis, Vol. 15, Issue 14 https://doi.org/10.1002/elan.200390146	journal	August 2003
Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion Xia, Wei; Mahmood, Asif; Zou, Ruqiang Energy & Environmental Science, Vol. 8, Issue 7 https://doi.org/10.1039/C5EE00762C	journal	January 2015
Designing high-energy lithium–sulfur batteries Seh, Zhi Wei; Sun, Yongming; Zhang, Qianfan Chemical Society Reviews, Vol. 45, Issue 20 https://doi.org/10.1039/C5CS00410A	journal	January 2016
Enhanced Li–S Batteries Using Amine-Functionalized Carbon Nanotubes in the Cathode Ma, Lin; Zhuang, Houlong L.; Wei, Shuya ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b06373	journal	December 2015
Polysulfide-Scission Reagents for the Suppression of the Shuttle Effect in Lithium–Sulfur Batteries Hua, Wuxing; Yang, Zhi; Nie, Huagui ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b08627	journal	February 2017
Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries Li, Guoxing; Sun, Jinhua; Hou, Wenpeng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10601	journal	February 2016
Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes Pang, Quan; Liang, Xiao; Kwok, Chun Yuen Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.132	journal	September 2016
Lithium Bond Chemistry in Lithium-Sulfur Batteries Hou, Ting-Zheng; Xu, Wen-Tao; Chen, Xiang Angewandte Chemie International Edition, Vol. 56, Issue 28 https://doi.org/10.1002/anie.201704324	journal	June 2017
Restricting the Solubility of Polysulfides in Li-S Batteries Via Electrolyte Salt Selection Chen, Junzheng; Han, Kee Sung; Henderson, Wesley A. Advanced Energy Materials, Vol. 6, Issue 11 https://doi.org/10.1002/aenm.201600160	journal	March 2016
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
High-rate FeS2/CNT neural network nanostructure composite anodes for stable, high-capacity sodium-ion batteries Chen, Yuanyuan; Hu, Xudong; Evanko, Brian Nano Energy, Vol. 46 https://doi.org/10.1016/j.nanoen.2018.01.039	journal	April 2018
Synthesis and electrochemical properties of olivine LiFePO4 as a cathode material prepared by mechanical alloying Kwon, Sang Jun; Kim, Cheol Woo; Jeong, Woon Tae Journal of Power Sources, Vol. 137, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.05.048	journal	October 2004
Tuning Transition Metal Oxide-Sulfur Interactions for Long Life Lithium Sulfur Batteries: The “Goldilocks” Principle Liang, Xiao; Kwok, Chun Yuen; Lodi-Marzano, Fernanda Advanced Energy Materials, Vol. 6, Issue 6 https://doi.org/10.1002/aenm.201501636	journal	December 2015
A Two-Dimensional Porous Carbon-Modified Separator for High-Energy-Density Li-S Batteries Pei, Fei; Lin, Lele; Fu, Ang Joule, Vol. 2, Issue 2 https://doi.org/10.1016/j.joule.2017.12.003	journal	February 2018
Stabilization of Insoluble Discharge Products by Facile Aniline Modification for High Performance Li-S Batteries Kim, Jae Ho; Kim, Taehoon; Jeong, Yo Chan Advanced Energy Materials, Vol. 5, Issue 14 https://doi.org/10.1002/aenm.201500268	journal	May 2015
Thiol functionalized carbon nanotubes: Synthesis by sulfur chemistry and their multi-purpose applications Mao, Junxia; Wang, Yan; Zhu, Jing Applied Surface Science, Vol. 447 https://doi.org/10.1016/j.apsusc.2018.03.188	journal	July 2018
A functional separator coated with sulfonated metal–organic framework/Nafion hybrids for Li–S batteries Kim, Seon Hwa; Yeon, Jeong Seok; Kim, Raekyung Journal of Materials Chemistry A, Vol. 6, Issue 48 https://doi.org/10.1039/C8TA08843H	journal	January 2018
Effective Trapping of Lithium Polysulfides Using a Functionalized Carbon Nanotube-Coated Separator for Lithium–Sulfur Cells with Enhanced Cycling Stability Ponraj, Rubha; Kannan, Aravindaraj G.; Ahn, Jun Hwan ACS Applied Materials & Interfaces, Vol. 9, Issue 44 https://doi.org/10.1021/acsami.7b10641	journal	October 2017
Nanostructured Metal Oxides and Sulfides for Lithium-Sulfur Batteries Liu, Xue; Huang, Jia-Qi; Zhang, Qiang Advanced Materials, Vol. 29, Issue 20 https://doi.org/10.1002/adma.201601759	journal	February 2017
X-ray Absorption Near-Edge Structure and Nuclear Magnetic Resonance Study of the Lithium-Sulfur Battery and its Components Patel, Manu U. M.; Arčon, Iztok; Aquilanti, Giuliana ChemPhysChem, Vol. 15, Issue 5 https://doi.org/10.1002/cphc.201300972	journal	February 2014
Graphene-enveloped sulfur in a one pot reaction: a cathode with good coulombic efficiency and high practical sulfur content Evers, Scott; Nazar, Linda F. Chem. Commun., Vol. 48, Issue 9 https://doi.org/10.1039/C2CC16726C	journal	January 2012
Hierarchical Free-Standing Carbon-Nanotube Paper Electrodes with Ultrahigh Sulfur-Loading for Lithium-Sulfur Batteries Yuan, Zhe; Peng, Hong-Jie; Huang, Jia-Qi Advanced Functional Materials, Vol. 24, Issue 39 https://doi.org/10.1002/adfm.201401501	journal	July 2014
Synthesis of three-dimensionally interconnected sulfur-rich polymers for cathode materials of high-rate lithium–sulfur batteries Kim, Hoon; Lee, Joungphil; Ahn, Hyungmin Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8278	journal	June 2015
Polysulfide Shuttle Study in the Li/S Battery System Mikhaylik, Yuriy V.; Akridge, James R. Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976 https://doi.org/10.1149/1.1806394	journal	January 2004
Spontaneous Functionalization of Carbon Black by Reaction with 4-Nitrophenyldiazonium Cations Toupin, Mathieu; Bélanger, Daniel Langmuir, Vol. 24, Issue 5 https://doi.org/10.1021/la702556n	journal	March 2008
Dense Graphene Monolith for High Volumetric Energy Density Li-S Batteries Li, Huan; Tao, Ying; Zhang, Chen Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201703438	journal	March 2018
Review—The Importance of Chemical Interactions between Sulfur Host Materials and Lithium Polysulfides for Advanced Lithium-Sulfur Batteries Pang, Quan; Liang, Xiao; Kwok, C. Y. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0171514jes	journal	January 2015
Electrochemical Properties of Organic Disulfide/Thiolate Redox Couples Liu, Meilin Journal of The Electrochemical Society, Vol. 136, Issue 9 https://doi.org/10.1149/1.2097478	journal	January 1989
Layered structure of crystalline compounds silver thiolates (AgSR) Dance, Ian G.; Fisher, Keith J.; Banda, R. M. Herath. Inorganic Chemistry, Vol. 30, Issue 2 https://doi.org/10.1021/ic00002a008	journal	January 1991
Covalent grafting onto self-adhesive surfaces based on aryldiazonium salt seed layers Viel, Pascal; Le, Xuan Tuan; Huc, Vincent Journal of Materials Chemistry, Vol. 18, Issue 48 https://doi.org/10.1039/b811299a	journal	January 2008
Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries Pang, Quan; Kundu, Dipan; Cuisinier, Marine Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5759	journal	August 2014
Nitrogen-rich hierarchically porous carbon as a high-rate anode material with ultra-stable cyclability and high capacity for capacitive sodium-ion batteries Hu, Xudong; Sun, Xiaohong; Yoo, Seung Joon Nano Energy, Vol. 56 https://doi.org/10.1016/j.nanoen.2018.11.081	journal	February 2019
A Simple One-Pot Strategy for Synthesizing Ultrafine SnS ₂ Nanoparticle/Graphene Composites as Anodes for Lithium/Sodium-Ion Batteries Li, Xin; Sun, Xiaohong; Gao, Zhiwen ChemSusChem, Vol. 11, Issue 9 https://doi.org/10.1002/cssc.201800073	journal	April 2018
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
Cathode materials for lithium–sulfur batteries: a practical perspective Eftekhari, Ali; Kim, Dong-Won Journal of Materials Chemistry A, Vol. 5, Issue 34 https://doi.org/10.1039/C7TA00799J	journal	January 2017
A highly efficient polysulfide mediator for lithium–sulfur batteries Liang, Xiao; Hart, Connor; Pang, Quan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6682	journal	January 2015
Solvent Effect of Room Temperature Ionic Liquids on Electrochemical Reactions in Lithium–Sulfur Batteries Park, Jun-Woo; Yamauchi, Kento; Takashima, Eriko The Journal of Physical Chemistry C, Vol. 117, Issue 9 https://doi.org/10.1021/jp400153m	journal	February 2013
Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8760	journal	July 2015
Covalently Grafted Polysulfur–Graphene Nanocomposites for Ultrahigh Sulfur-Loading Lithium–Polysulfur Batteries Chang, Chi-Hao; Manthiram, Arumugam ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01031	journal	November 2017
Mechanism for the Stable Performance of Sulfur-Copolymer Cathode in Lithium–Sulfur Battery Studied by Solid-State NMR Spectroscopy Hoefling, Alexander; Nguyen, Dan Thien; Partovi-Azar, Pouya Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.7b05105	journal	April 2018
Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries Sun, Zhenhua; Zhang, Jingqi; Yin, Lichang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14627	journal	March 2017
Carbon onion/sulfur hybrid cathodes via inverse vulcanization for lithium–sulfur batteries Choudhury, Soumyadip; Srimuk, Pattarachai; Raju, Kumar Sustainable Energy & Fuels, Vol. 2, Issue 1 https://doi.org/10.1039/C7SE00452D	journal	January 2018
Synthesis of dithiols as reducing agents for disulfides in neutral aqueous solution and comparison of reduction potentials Lamoureux, Guy V.; Whitesides, George M. The Journal of Organic Chemistry, Vol. 58, Issue 3 https://doi.org/10.1021/jo00055a015	journal	January 1993
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes Lv, Dongping; Zheng, Jianming; Li, Qiuyan Advanced Energy Materials, Vol. 5, Issue 16, Article No. 1402290 https://doi.org/10.1002/aenm.201402290	journal	March 2015
Conducting linear chains of sulphur inside carbon nanotubes Fujimori, Toshihiko; Morelos-Gómez, Aarón; Zhu, Zhen Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3162	journal	July 2013

Similar Records

A multi-functional interface derived from thiol-modified mesoporous carbon in lithium–sulfur batteries

Journal Article · 2019 · Journal of Materials Chemistry A · OSTI ID:1544787

Li, Yun; Murphy, Ian A.; Chen, Ying; +9 more

Functionalization of Cathode–Electrolyte Interface with Ionic Liquids for High-Performance Quasi-Solid-State Lithium–Sulfur Batteries: A Low-Sulfur Loading Study

Journal Article · 2024 · Batteries · OSTI ID:2342172

Koralalage, Milinda Kalutara; Shreyas, Varun; Arnold, William R.; +6 more

Palladium nanocrystals-imbedded mesoporous hollow carbon spheres with enhanced electrochemical kinetics for high performance lithium sulfur batteries

Journal Article · 2018 · Carbon · OSTI ID:1504769

Ma, Shaobo; Wang, Liguang; Wang, Yang; +6 more

Title: A multi-functional interface derived from thiol-modified mesoporous carbon in lithium–sulfur batteries

Citation Formats

References (65)

Similar Records

Related Subjects