Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries
Abstract
While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g–1 and a remarkably high capacity retention of ~87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy.
- Authors:
-
[3];
[1];
[6];
[1];
[1]
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Florida State Univ., Tallahassee, FL (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Florida State Univ., Tallahassee, FL (United States); National High Magnetic Field Lab., Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1514702
- Alternate Identifier(s):
- OSTI ID: 1548293
- Report Number(s):
- BNL-211624-2019-JAAM
Journal ID: ISSN 0002-7863
- Grant/Contract Number:
- SC0012704; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 141; Journal Issue: 16; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Yang, Lufeng, Li, Xiang, Liu, Jue, Xiong, Shan, Ma, Xuetian, Liu, Pan, Bai, Jianming, Xu, Wenqian, Tang, Yuanzhi, Hu, Yan -Yan, Liu, Meilin, and Chen, Hailong. Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries. United States: N. p., 2019.
Web. doi:10.1021/jacs.9b01855.
Yang, Lufeng, Li, Xiang, Liu, Jue, Xiong, Shan, Ma, Xuetian, Liu, Pan, Bai, Jianming, Xu, Wenqian, Tang, Yuanzhi, Hu, Yan -Yan, Liu, Meilin, & Chen, Hailong. Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries. United States. https://doi.org/10.1021/jacs.9b01855
Yang, Lufeng, Li, Xiang, Liu, Jue, Xiong, Shan, Ma, Xuetian, Liu, Pan, Bai, Jianming, Xu, Wenqian, Tang, Yuanzhi, Hu, Yan -Yan, Liu, Meilin, and Chen, Hailong. Mon .
"Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries". United States. https://doi.org/10.1021/jacs.9b01855. https://www.osti.gov/servlets/purl/1514702.
@article{osti_1514702,
title = {Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries},
author = {Yang, Lufeng and Li, Xiang and Liu, Jue and Xiong, Shan and Ma, Xuetian and Liu, Pan and Bai, Jianming and Xu, Wenqian and Tang, Yuanzhi and Hu, Yan -Yan and Liu, Meilin and Chen, Hailong},
abstractNote = {While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g–1 and a remarkably high capacity retention of ~87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy.},
doi = {10.1021/jacs.9b01855},
journal = {Journal of the American Chemical Society},
number = 16,
volume = 141,
place = {United States},
year = {Mon Apr 01 00:00:00 EDT 2019},
month = {Mon Apr 01 00:00:00 EDT 2019}
}
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