Selective Benzyl Alcohol Oxidation over Pd Catalysts
Abstract
In the last decades, the selective liquid phase oxidation of alcohols to the corresponding carbonyl compounds has been a subject of growing interest. Research has focused on green methods that use “clean” oxidants such as O2 in combination with supported metal nanoparticles as the catalyst. Among the alcohols, benzyl alcohol is one of the most studied substrates. Indeed, benzyl alcohol can be converted to benzaldehyde, largely for use in the pharmaceutical and agricultural industries. This conversion serves as model reaction in testing new potential catalysts, that can then be applied to other systems. Pd based catalysts have been extensively studied as active catalytic metals for alcohol oxidation for their high activity and selectivity to the corresponding aldehyde. Several catalytic materials obtained by careful control of the morphology of Pd nanoparticles, (including bimetallic systems) and by tuning the support properties have been developed. Moreover, reaction conditions, including solvent, temperature, pressure and alcohol concentration have been investigated to tune the selectivity to the desired products. Different reaction mechanisms and microkinetic models have been proposed. The aim of this review is to provide a critical description of the recent advances on Pd catalyzed benzyl alcohol oxidation.
- Authors:
-
[3]
- Univ. d'Antananarivo, Antananarivo (Madagascar)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. degli Studi di Milano, Milano (Italy)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1513407
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysts
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 10; Journal ID: ISSN 2073-4344
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; palladium; benzyl alcohol; oxidation
Citation Formats
Chan-Thaw, Carine Edith, Savara, Aditya, and Villa, Alberto. Selective Benzyl Alcohol Oxidation over Pd Catalysts. United States: N. p., 2018.
Web. doi:10.3390/catal8100431.
Chan-Thaw, Carine Edith, Savara, Aditya, & Villa, Alberto. Selective Benzyl Alcohol Oxidation over Pd Catalysts. United States. https://doi.org/10.3390/catal8100431
Chan-Thaw, Carine Edith, Savara, Aditya, and Villa, Alberto. Sun .
"Selective Benzyl Alcohol Oxidation over Pd Catalysts". United States. https://doi.org/10.3390/catal8100431. https://www.osti.gov/servlets/purl/1513407.
@article{osti_1513407,
title = {Selective Benzyl Alcohol Oxidation over Pd Catalysts},
author = {Chan-Thaw, Carine Edith and Savara, Aditya and Villa, Alberto},
abstractNote = {In the last decades, the selective liquid phase oxidation of alcohols to the corresponding carbonyl compounds has been a subject of growing interest. Research has focused on green methods that use “clean” oxidants such as O2 in combination with supported metal nanoparticles as the catalyst. Among the alcohols, benzyl alcohol is one of the most studied substrates. Indeed, benzyl alcohol can be converted to benzaldehyde, largely for use in the pharmaceutical and agricultural industries. This conversion serves as model reaction in testing new potential catalysts, that can then be applied to other systems. Pd based catalysts have been extensively studied as active catalytic metals for alcohol oxidation for their high activity and selectivity to the corresponding aldehyde. Several catalytic materials obtained by careful control of the morphology of Pd nanoparticles, (including bimetallic systems) and by tuning the support properties have been developed. Moreover, reaction conditions, including solvent, temperature, pressure and alcohol concentration have been investigated to tune the selectivity to the desired products. Different reaction mechanisms and microkinetic models have been proposed. The aim of this review is to provide a critical description of the recent advances on Pd catalyzed benzyl alcohol oxidation.},
doi = {10.3390/catal8100431},
journal = {Catalysts},
number = 10,
volume = 8,
place = {United States},
year = {Sun Sep 30 00:00:00 EDT 2018},
month = {Sun Sep 30 00:00:00 EDT 2018}
}
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Figures / Tables:
Figure 1: Conversions of benzyl alcohol versus reaction time over the 1.35 wt% Pd/NaX catalysts with different mean sizes of Pd particles. The mean size of Pd (in nm) was shown in the parenthesis. Reprinted from ref. [33]. Copyright 2008, with permission from Elsevier.
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Salep as a biological source for the synthesis of biochar with utility for the catalysis
text, January 2020
- Heravi, Majid Mommahed; Sadjadi, Samaheh; Kahangi, Fatemeh Ghoreyshi
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.