The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances

Shen, Hongxian; Luo, Lin; Xing, Dawei; Jiang, Sida; Liu, Jingshun; Huang, Yongjiang; Guo, Shu; Sun, Haichao; Liu, Yanfen; Sun, Jianfei; Phan, Manh‐Huong

doi:10.1002/pssa.201900090

Title: The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances

Abstract

A new magnetocaloric composite composed of three types of soft ferromagnetic Gd‐based microwires with equal mass ratio and close magnetocaloric performances is designed. The Curie temperatures ( T _C ) of these three wires are ≈97, ≈100, and ≈101 K, respectively. However, the magnetization versus temperature curve of the composite sample shows almost a single ferromagnetic–paramagnetic transition at ≈97 K. For a field change of µ ₀ Δ H = 5 T, the maximum entropy change () and refrigerant capacity (RC) of this composite are calculated to be ≈9.98 J kg ⁻¹ K ⁻¹ and ≈665 J kg ⁻¹ , respectively. There is a good agreement between the calculated −Δ S _M ( T ) curve and the experimental data, indicating weak magnetic interactions among different wire compositions. Additionally, the calculated universal master curves of the composite and its Gd‐Al‐Co components are fitted very well, which reveals the second‐order type of the magnetic transition for the composite. The designed composite integrates all magnetocaloric properties of its components, suggesting that the Gd‐based amorphous wires with close magnetocaloric properties can be designed as an excellent refrigerant for use in active magnetic refrigerators.

Authors:

Shen, Hongxian ^[1]; Luo, Lin ^[2]; Xing, Dawei ^[2]; Jiang, Sida ^[2]; Liu, Jingshun ^[3]; Huang, Yongjiang ^[2]; Guo, Shu ^[2]; Sun, Haichao ^[2]; Liu, Yanfen ^[4];

^[2]; Phan, Manh‐Huong ^[5]

School of Materials Science and Engineering Harbin Institute of Technology Harbin 150001 P. R. China, Department of Physics University of South Florida Tampa, Florida 33620 USA
School of Materials Science and Engineering Harbin Institute of Technology Harbin 150001 P. R. China
School of Materials Science and Engineering Inner Mongolia University of Technology No. 49 Aimin Street Hohhot 010051 P. R. China
Department of physics Qiqihar University Qiqihar 161006 P. R. China
Department of Physics University of South Florida Tampa, Florida 33620 USA

Publication Date:: Wed May 15 00:00:00 EDT 2019

Sponsoring Org.:: USDOE

OSTI Identifier:: 1512823

Grant/Contract Number:: DE‐FG02‐07ER 46438

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physica Status Solidi. A, Applications and Materials Science

Additional Journal Information:: Journal Name: Physica Status Solidi. A, Applications and Materials Science Journal Volume: 216 Journal Issue: 16; Journal ID: ISSN 1862-6300

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Shen, Hongxian, Luo, Lin, Xing, Dawei, Jiang, Sida, Liu, Jingshun, Huang, Yongjiang, Guo, Shu, Sun, Haichao, Liu, Yanfen, Sun, Jianfei, and Phan, Manh‐Huong. The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances.  Germany: N. p., 2019. 
Web.  doi:10.1002/pssa.201900090.

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                    Shen, Hongxian, Luo, Lin, Xing, Dawei, Jiang, Sida, Liu, Jingshun, Huang, Yongjiang, Guo, Shu, Sun, Haichao, Liu, Yanfen, Sun, Jianfei, & Phan, Manh‐Huong. The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances.  Germany.  https://doi.org/10.1002/pssa.201900090

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                    Shen, Hongxian, Luo, Lin, Xing, Dawei, Jiang, Sida, Liu, Jingshun, Huang, Yongjiang, Guo, Shu, Sun, Haichao, Liu, Yanfen, Sun, Jianfei, and Phan, Manh‐Huong. Wed .  
"The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances".  Germany.  https://doi.org/10.1002/pssa.201900090.

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@article{osti_1512823,

  title        = {The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances},

  author       = {Shen, Hongxian and Luo, Lin and Xing, Dawei and Jiang, Sida and Liu, Jingshun and Huang, Yongjiang and Guo, Shu and Sun, Haichao and Liu, Yanfen and Sun, Jianfei and Phan, Manh‐Huong},

  abstractNote = {A new magnetocaloric composite composed of three types of soft ferromagnetic Gd‐based microwires with equal mass ratio and close magnetocaloric performances is designed. The Curie temperatures ( T C ) of these three wires are ≈97, ≈100, and ≈101 K, respectively. However, the magnetization versus temperature curve of the composite sample shows almost a single ferromagnetic–paramagnetic transition at ≈97 K. For a field change of µ 0 Δ H  = 5 T, the maximum entropy change () and refrigerant capacity (RC) of this composite are calculated to be ≈9.98 J kg −1  K −1 and ≈665 J kg −1 , respectively. There is a good agreement between the calculated −Δ S M ( T ) curve and the experimental data, indicating weak magnetic interactions among different wire compositions. Additionally, the calculated universal master curves of the composite and its Gd‐Al‐Co components are fitted very well, which reveals the second‐order type of the magnetic transition for the composite. The designed composite integrates all magnetocaloric properties of its components, suggesting that the Gd‐based amorphous wires with close magnetocaloric properties can be designed as an excellent refrigerant for use in active magnetic refrigerators.},

  doi          = {10.1002/pssa.201900090},

  journal      = {Physica Status Solidi. A, Applications and Materials Science},

  number       = 16,

  volume       = 216,

  place        = {Germany},

  year         = {Wed May 15 00:00:00 EDT 2019},

  month        = {Wed May 15 00:00:00 EDT 2019}

}

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Title: The Magnetocaloric Composite Designed by Multi‐Gd‐Al‐Co Microwires with Close Performances

Abstract

Citation Formats

Enhanced magnetocaloric and mechanical properties of melt-extracted Gd55Al25Co20 micro-fibers journal, August 2014

Effect of rare earth additions on magnetic properties of Fe82Nb2B14RE2 (RE=Y, Gd, Tb and Dy) amorphous alloys journal, October 2011

Structure and magnetocaloric effect of La0.7Ce0.3(Fe0.92Co0.08)11.4Si1.6 bulk alloy prepared by powder metallurgy journal, November 2016

Field dependence of the magnetocaloric effect in materials with a second order phase transition: A master curve for the magnetic entropy change journal, November 2006

Magnetocaloric Effect in Uncoated Gd55Al20Co25 Amorphous Wires journal, November 2015

Numerical analysis of a reciprocating active magnetic regenerator made of gadolinium wires journal, May 2012

Table-like magnetocaloric effect in the Gd-Co-Al alloys with multi-phase structure journal, February 2014

Scaling laws for the magnetocaloric effect in second order phase transitions: From physics to applications for the characterization of materials journal, May 2010

A novel Ho36Dy20Al24Co20 bulk metallic glass with large magnetocaloric effect journal, April 2008

Magnetocaloric effect and critical behavior in melt-extracted Gd 60 Co 15 Al 25 microwires : Magnetocaloric effect and critical behavior in Gd journal, May 2015

Factors limiting the operation frequency of magnetic refrigerators journal, June 2007

Nanostructuring as a procedure to control the field dependence of the magnetocaloric effect journal, January 2017

Controllable ferromagnetic/re-entrant spin glass state and magnetocaloric response of Gd-Er-Al-Co metallic glasses journal, November 2017

Magnetic properties and magnetocaloric effect in Heusler-type glass-coated NiMnGa microwires journal, October 2013

Optimization of the refrigerant capacity in multiphase magnetocaloric materials journal, March 2011

Magnetocaloric effect: From materials research to refrigeration devices journal, April 2018

Tuning the structural and magnetocaloric properties of Gd 5 Si 2 Ge 2 with Nd substitution journal, January 2015

Magnetocaloric effect in rare earth-based bulk metallic glasses journal, April 2010

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Magnetic and magnetocaloric properties of Mn0·98Fe0·02P1-xAsx compounds journal, January 2017

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Enhanced magnetocaloric properties of melt-extracted GdAlCo metallic glass microwires journal, December 2014

Enhanced magnetocaloric and mechanical properties of melt-extracted Gd55Al25Co20 micro-fibers
journal, August 2014

Effect of rare earth additions on magnetic properties of Fe82Nb2B14RE2 (RE=Y, Gd, Tb and Dy) amorphous alloys
journal, October 2011

Structure and magnetocaloric effect of La0.7Ce0.3(Fe0.92Co0.08)11.4Si1.6 bulk alloy prepared by powder metallurgy
journal, November 2016

Field dependence of the magnetocaloric effect in materials with a second order phase transition: A master curve for the magnetic entropy change
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Magnetocaloric Effect in Uncoated Gd55Al20Co25 Amorphous Wires
journal, November 2015

Numerical analysis of a reciprocating active magnetic regenerator made of gadolinium wires
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Table-like magnetocaloric effect in the Gd-Co-Al alloys with multi-phase structure
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Scaling laws for the magnetocaloric effect in second order phase transitions: From physics to applications for the characterization of materials
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