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Title: Phonon mode links ferroicities in multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3

Journal Article · · Physical Review B
 [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3];  [4]; ORCiD logo [5];  [6];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Florida State Univ., Tallahassee, FL (United States); National High Magnetic Lab., Tallahassee, FL (United States); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
  3. Fudan Univ., Shanghai (China); Collaborative Innovation Center of Advanced Microstructures, Nanjing (China)
  4. National High Magnetic Lab., Tallahassee, FL (United States)
  5. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  6. Florida State Univ., Tallahassee, FL (United States); National High Magnetic Lab., Tallahassee, FL (United States)
+ Show Author Affiliations

In this work, we combined magnetoinfrared spectroscopy, magnetization, and lattice dynamics calculations to explore the phase transitions in multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3 Both the 185 K ferroelectric transition and the magnetically driven transition to the fully saturated state at 15.3 T involve the formate bending mode, direct evidence of a common connection between the two types of ferroicities and for how lattice distortions advance high-temperature magnetoelectric coupling in this system.

Research Organization:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE; USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1512737
Report Number(s):
LA-UR--17-22717
Journal Information:
Physical Review B, Journal Name: Physical Review B Journal Issue: 18 Vol. 96; ISSN 2469-9950; ISSN PRBMDO
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

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Cited By (7)

Electron paramagnetic resonance of a copper doped [(CH 3 ) 2 NH 2 ][Zn(HCOO) 3 ] hybrid perovskite framework journal January 2018
On the origin of ferroelectric structural phases in perovskite-like metal–organic formate journal January 2018
Tilts and shifts in molecular perovskites journal January 2020
Elucidation of dipolar dynamics and the nature of structural phases in the [(CH 3 ) 2 NH 2 ][Zn(HCOO) 3 ] hybrid perovskite framework journal January 2019
First-principles study of the structural, electronic, magnetic, and ferroelectric properties of a charge-ordered iron( ii )-iron( iii ) formate framework journal September 2019
Near-field infrared spectroscopy of monolayer MnPS 3 journal August 2019
First-principles study of the structural, electronic, magnetic and ferroelectric properties of a charge ordered Iron(II)- Iron(III) formate framework text January 2019

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