skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Phonon mode links ferroicities in multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3

Abstract

In this work, we combined magnetoinfrared spectroscopy, magnetization, and lattice dynamics calculations to explore the phase transitions in multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3 Both the 185 K ferroelectric transition and the magnetically driven transition to the fully saturated state at 15.3 T involve the formate bending mode, direct evidence of a common connection between the two types of ferroicities and for how lattice distortions advance high-temperature magnetoelectric coupling in this system.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3];  [4]; ORCiD logo [5];  [6];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Florida State Univ., Tallahassee, FL (United States); National High Magnetic Lab., Tallahassee, FL (United States); ; National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
  3. Fudan Univ., Shanghai (China); Collaborative Innovation Center of Advanced Microstructures, Nanjing (China)
  4. National High Magnetic Lab., Tallahassee, FL (United States)
  5. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  6. Florida State Univ., Tallahassee, FL (United States); National High Magnetic Lab., Tallahassee, FL (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1512737
Alternate Identifier(s):
OSTI ID: 1409874
Report Number(s):
[LA-UR-17-22717]
[Journal ID: ISSN 2469-9950; PRBMDO]
Grant/Contract Number:  
[89233218CNA000001]
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
[ Journal Volume: 96; Journal Issue: 18]; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; High Magnetic Field Science

Citation Formats

Hughey, Kendall D., Clune, Amanda J., Yokosuk, Michael O., al-Wahish, Amal, O'Neal, Kenneth R., Fan, Shiyu, Abhyankar, Nandita, Xiang, Hongjun, Li, Zhiqiang, Singleton, John, Dalal, Naresh S., and Musfeldt, Janice L. Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3. United States: N. p., 2017. Web. doi:10.1103/PhysRevB.96.180305.
Hughey, Kendall D., Clune, Amanda J., Yokosuk, Michael O., al-Wahish, Amal, O'Neal, Kenneth R., Fan, Shiyu, Abhyankar, Nandita, Xiang, Hongjun, Li, Zhiqiang, Singleton, John, Dalal, Naresh S., & Musfeldt, Janice L. Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3. United States. doi:10.1103/PhysRevB.96.180305.
Hughey, Kendall D., Clune, Amanda J., Yokosuk, Michael O., al-Wahish, Amal, O'Neal, Kenneth R., Fan, Shiyu, Abhyankar, Nandita, Xiang, Hongjun, Li, Zhiqiang, Singleton, John, Dalal, Naresh S., and Musfeldt, Janice L. Wed . "Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3". United States. doi:10.1103/PhysRevB.96.180305. https://www.osti.gov/servlets/purl/1512737.
@article{osti_1512737,
title = {Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3},
author = {Hughey, Kendall D. and Clune, Amanda J. and Yokosuk, Michael O. and al-Wahish, Amal and O'Neal, Kenneth R. and Fan, Shiyu and Abhyankar, Nandita and Xiang, Hongjun and Li, Zhiqiang and Singleton, John and Dalal, Naresh S. and Musfeldt, Janice L.},
abstractNote = {In this work, we combined magnetoinfrared spectroscopy, magnetization, and lattice dynamics calculations to explore the phase transitions in multiferroic [(CH3)2NH2]Mn(HCOO)3 Both the 185 K ferroelectric transition and the magnetically driven transition to the fully saturated state at 15.3 T involve the formate bending mode, direct evidence of a common connection between the two types of ferroicities and for how lattice distortions advance high-temperature magnetoelectric coupling in this system.},
doi = {10.1103/PhysRevB.96.180305},
journal = {Physical Review B},
number = [18],
volume = [96],
place = {United States},
year = {2017},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Figures / Tables:

FIG. 1 FIG. 1: (a) Crystal structure of [(CH3)2NH2]Mn(HCOO)3 showing the metal-formate framework and dynamically disordered dimethylammonium [6, 10]. Ferroelectricity develops across the order-disorder transition [6, 7]. The formate bridges define the Mn-O-C-O-Mn superexchange pathway (J = -0.69 K) [17, 18]. (b) Summary of important temperature and magnetic energy scales [6, 10,more » 17]. PM = paramagnetic, cAFM = canted antiferromagnet, PE = paraelectric, FE = ferroelectric, BSF = spin-flop field, and BC = saturation field.« less

Save / Share:

Works referenced in this record:

Electric-Magneto-Optical Kerr Effect in a Hybrid Organic–Inorganic Perovskite
journal, September 2017

  • Fan, Feng-Ren; Wu, Hua; Nabok, Dmitrii
  • Journal of the American Chemical Society, Vol. 139, Issue 37
  • DOI: 10.1021/jacs.7b04911

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Projector augmented-wave method
journal, December 1994


Large spin-phonon coupling and magnetically induced phonon anisotropy in Sr M O 3 perovskites ( M = V ,Cr,Mn,Fe,Co)
journal, September 2011


Spectroscopic studies of the ferroelectric and magnetic phase transitions in multiferroic Sr 1− x Ba x MnO 3
journal, March 2016


Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Magnetic field-temperature phase diagram of multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3
journal, September 2017


Unconventional critical behaviour in a quasi-two-dimensional organic conductor
journal, July 2005


Spectral origin of the colossal magnetodielectric effect in multiferroic DyMn 2 O 5
journal, August 2014


Multiferroics of spin origin
journal, July 2014


Magnetic Ordering-Induced Multiferroic Behavior in [CH 3 NH 3 ][Co(HCOO) 3 ] Metal–Organic Framework
journal, January 2016

  • Gómez-Aguirre, L. Claudia; Pato-Doldán, Breogán; Mira, J.
  • Journal of the American Chemical Society, Vol. 138, Issue 4
  • DOI: 10.1021/jacs.5b11688

Magnetic ordering effects in the Raman spectra of La 1 x Mn 1 x O 3
journal, November 1999


Magnetoelastic coupling in [Ru 2 (O 2 CMe) 4 ] 3 [Cr(CN) 6 ] molecule-based magnet
journal, December 2012


Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

  • Hill, Nicola A.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 29
  • DOI: 10.1021/jp000114x

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Spin-Lattice Interactions Mediated by Magnetic Field
journal, May 2008


Magnetoelectric coupling in the paramagnetic state of a metal-organic framework
journal, June 2013

  • Wang, W.; Yan, L. -Q.; Cong, J. -Z.
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02024

Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework
journal, August 2014

  • Tian, Ying; Stroppa, Alessandro; Chai, Yisheng
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06062

Characterization of the Order−Disorder Dielectric Transition in the Hybrid Organic−Inorganic Perovskite-Like Formate Mn(HCOO) 3 [(CH 3 ) 2 NH 2 ]
journal, February 2010

  • Sánchez-Andújar, M.; Presedo, S.; Yáñez-Vilar, S.
  • Inorganic Chemistry, Vol. 49, Issue 4
  • DOI: 10.1021/ic901872g

Far-infrared optical excitations in multiferroic TbMnO3
journal, June 2009


Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn [ N ( CN ) 2 ] 2
journal, June 2013


Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators
journal, August 1995


Classifying multiferroics: Mechanisms and effects
journal, March 2009


Tuning the Ferroelectric Polarization in a Multiferroic Metal–Organic Framework
journal, November 2013

  • Di Sante, Domenico; Stroppa, Alessandro; Jain, Prashant
  • Journal of the American Chemical Society, Vol. 135, Issue 48
  • DOI: 10.1021/ja408283a

Emerging routes to multiferroics
journal, October 2009


Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX 3 Architecture
journal, September 2009

  • Jain, Prashant; Ramachandran, Vasanth; Clark, Ronald J.
  • Journal of the American Chemical Society, Vol. 131, Issue 38
  • DOI: 10.1021/ja904156s

Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials
journal, July 2004

  • Wang, Xin-Yi; Gan, Lin; Zhang, Shi-Wei
  • Inorganic Chemistry, Vol. 43, Issue 15
  • DOI: 10.1021/ic0498081

Hybrid Improper Ferroelectricity: A Mechanism for Controllable Polarization-Magnetization Coupling
journal, March 2011


Magnetic behavior of the metal organic framework [(CH 3 ) 2 NH 2 ]Co(HCOO) 3
journal, January 2015

  • Vinod, K.; Deepak, C. S.; Sharma, Shilpam
  • RSC Advances, Vol. 5, Issue 47
  • DOI: 10.1039/C5RA01417D

Local structure of the metal–organic perovskite dimethylammonium manganese( ii ) formate
journal, January 2016

  • Duncan, Helen D.; Dove, Martin T.; Keen, David A.
  • Dalton Transactions, Vol. 45, Issue 10
  • DOI: 10.1039/C5DT03687A

Temperature-dependent IR and Raman studies of metal–organic frameworks [(CH3)2NH2][M(HCOO)3], M=Mg and Cd
journal, April 2016

  • Szymborska-Małek, K.; Trzebiatowska-Gusowska, M.; Mączka, M.
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 159
  • DOI: 10.1016/j.saa.2016.01.031

Switchable electric polarization and ferroelectric domains in a metal-organic-framework
journal, September 2016


    Works referencing / citing this record:

    On the origin of ferroelectric structural phases in perovskite-like metal–organic formate
    journal, January 2018

    • Sieradzki, Adam; Mączka, Mirosław; Simenas, Mantas
    • Journal of Materials Chemistry C, Vol. 6, Issue 35
    • DOI: 10.1039/c8tc02421a

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.