skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Defect‐Tailoring Mediated Electron–Hole Separation in Single‐Unit‐Cell Bi 3 O 4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation

Authors:
 [1];  [2];  [3];  [4];  [5];  [6];  [7];  [8];  [8];  [8];  [9];  [3];  [9]; ORCiD logo [5];  [10]
  1. School of Chemistry and Chemical EngineeringInstitute for Energy ResearchJiangsu University 301 Xuefu Road Zhenjiang 212013 P. R. China, Center for Programmable MaterialsSchool of Materials Science and EngineeringNanyang Technological University Singapore 639798 Singapore
  2. School of Chemistry and Chemical EngineeringInstitute for Energy ResearchJiangsu University 301 Xuefu Road Zhenjiang 212013 P. R. China, Chemical Sciences DivisionOak Ridge National Laboratory Oak Ridge 37830 TN USA
  3. Materials Science and Technology DivisionOak Ridge National Laboratory Oak Ridge 37830 TN USA
  4. Institute of Functional Nano and Soft MaterialsSoochow University Suzhou 215123 P. R. China
  5. Center for Programmable MaterialsSchool of Materials Science and EngineeringNanyang Technological University Singapore 639798 Singapore
  6. Multi‐Discipline Research DivisionInstitute of High Energy PhysicsChinese Academy of Sciences Beijing 100049 P. R. China
  7. College of Environment and ResourcesChongqing Technology and Business University Chongqing 400067 P. R. China
  8. Laboratory of Soft Matter PhysicsInstitute of PhysicsChinese Academy of Sciences Beijing 100190 P. R. China
  9. School of Chemistry and Chemical EngineeringInstitute for Energy ResearchJiangsu University 301 Xuefu Road Zhenjiang 212013 P. R. China
  10. Chemical Sciences DivisionOak Ridge National Laboratory Oak Ridge 37830 TN USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1512325
Grant/Contract Number:  
DE‐AC02‐05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 31 Journal Issue: 28; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Di, Jun, Xia, Jiexiang, Chisholm, Matthew F., Zhong, Jun, Chen, Chao, Cao, Xingzhong, Dong, Fan, Chi, Zhen, Chen, Hailong, Weng, Yu‐Xiang, Xiong, Jun, Yang, Shi‐Ze, Li, Huaming, Liu, Zheng, and Dai, Sheng. Defect‐Tailoring Mediated Electron–Hole Separation in Single‐Unit‐Cell Bi 3 O 4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation. Germany: N. p., 2019. Web. doi:10.1002/adma.201807576.
Di, Jun, Xia, Jiexiang, Chisholm, Matthew F., Zhong, Jun, Chen, Chao, Cao, Xingzhong, Dong, Fan, Chi, Zhen, Chen, Hailong, Weng, Yu‐Xiang, Xiong, Jun, Yang, Shi‐Ze, Li, Huaming, Liu, Zheng, & Dai, Sheng. Defect‐Tailoring Mediated Electron–Hole Separation in Single‐Unit‐Cell Bi 3 O 4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation. Germany. doi:10.1002/adma.201807576.
Di, Jun, Xia, Jiexiang, Chisholm, Matthew F., Zhong, Jun, Chen, Chao, Cao, Xingzhong, Dong, Fan, Chi, Zhen, Chen, Hailong, Weng, Yu‐Xiang, Xiong, Jun, Yang, Shi‐Ze, Li, Huaming, Liu, Zheng, and Dai, Sheng. Sun . "Defect‐Tailoring Mediated Electron–Hole Separation in Single‐Unit‐Cell Bi 3 O 4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation". Germany. doi:10.1002/adma.201807576.
@article{osti_1512325,
title = {Defect‐Tailoring Mediated Electron–Hole Separation in Single‐Unit‐Cell Bi 3 O 4 Br Nanosheets for Boosting Photocatalytic Hydrogen Evolution and Nitrogen Fixation},
author = {Di, Jun and Xia, Jiexiang and Chisholm, Matthew F. and Zhong, Jun and Chen, Chao and Cao, Xingzhong and Dong, Fan and Chi, Zhen and Chen, Hailong and Weng, Yu‐Xiang and Xiong, Jun and Yang, Shi‐Ze and Li, Huaming and Liu, Zheng and Dai, Sheng},
abstractNote = {},
doi = {10.1002/adma.201807576},
journal = {Advanced Materials},
number = 28,
volume = 31,
place = {Germany},
year = {2019},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adma.201807576

Citation Metrics:
Cited by: 20 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Vacancy Engineering for Tuning Electron and Phonon Structures of Two-Dimensional Materials
journal, August 2016


Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting
journal, May 2014

  • Lei, Fengcai; Sun, Yongfu; Liu, Katong
  • Journal of the American Chemical Society, Vol. 136, Issue 19
  • DOI: 10.1021/ja501866r

Enhanced Photoexcited Carrier Separation in Oxygen-Doped ZnIn 2 S 4 Nanosheets for Hydrogen Evolution
journal, April 2016

  • Yang, Wenlong; Zhang, Lei; Xie, Junfeng
  • Angewandte Chemie International Edition, Vol. 55, Issue 23
  • DOI: 10.1002/anie.201602543

Promoting Photogenerated Holes Utilization in Pore-Rich WO 3 Ultrathin Nanosheets for Efficient Oxygen-Evolving Photoanode
journal, October 2016

  • Liu, Youwen; Liang, Lin; Xiao, Chong
  • Advanced Energy Materials, Vol. 6, Issue 23
  • DOI: 10.1002/aenm.201600437

Generation of defect clusters for 1 O 2 production for molecular oxygen activation in photocatalysis
journal, January 2017

  • Ding, Jie; Dai, Zan; Tian, Fan
  • Journal of Materials Chemistry A, Vol. 5, Issue 45
  • DOI: 10.1039/C7TA08117K

Light-Switchable Oxygen Vacancies in Ultrafine Bi 5 O 7 Br Nanotubes for Boosting Solar-Driven Nitrogen Fixation in Pure Water
journal, June 2017


Defect-Rich Bi 12 O 17 Cl 2 Nanotubes Self-Accelerating Charge Separation for Boosting Photocatalytic CO 2 Reduction
journal, October 2018

  • Di, Jun; Zhu, Chao; Ji, Mengxia
  • Angewandte Chemie International Edition, Vol. 57, Issue 45
  • DOI: 10.1002/anie.201809492

Ultrathin two-dimensional materials for photo- and electrocatalytic hydrogen evolution
journal, September 2018


Ultrathin 2D Photocatalysts: Electronic-Structure Tailoring, Hybridization, and Applications
journal, November 2017


Titanium-Defected Undoped Anatase TiO 2 with p-Type Conductivity, Room-Temperature Ferromagnetism, and Remarkable Photocatalytic Performance
journal, February 2015

  • Wang, Songbo; Pan, Lun; Song, Jia-Jia
  • Journal of the American Chemical Society, Vol. 137, Issue 8
  • DOI: 10.1021/ja512047k

Superior visible light hydrogen evolution of Janus bilayer junctions via atomic-level charge flow steering
journal, May 2016

  • Li, Jie; Zhan, Guangming; Yu, Ying
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11480

Atomically Thick Bismuth Selenide Freestanding Single Layers Achieving Enhanced Thermoelectric Energy Harvesting
journal, December 2012

  • Sun, Yongfu; Cheng, Hao; Gao, Shan
  • Journal of the American Chemical Society, Vol. 134, Issue 50
  • DOI: 10.1021/ja3102049

Catalysis with two-dimensional materials and their heterostructures
journal, March 2016

  • Deng, Dehui; Novoselov, K. S.; Fu, Qiang
  • Nature Nanotechnology, Vol. 11, Issue 3
  • DOI: 10.1038/nnano.2015.340

Defect-Rich Ultrathin ZnAl-Layered Double Hydroxide Nanosheets for Efficient Photoreduction of CO 2 to CO with Water
journal, October 2015


New Reaction Pathway Induced by Plasmon for Selective Benzyl Alcohol Oxidation on BiOCl Possessing Oxygen Vacancies
journal, February 2017

  • Li, Hao; Qin, Feng; Yang, Zhiping
  • Journal of the American Chemical Society, Vol. 139, Issue 9
  • DOI: 10.1021/jacs.6b12850

Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets
journal, May 2015

  • Li, Hao; Shang, Jian; Ai, Zhihui
  • Journal of the American Chemical Society, Vol. 137, Issue 19
  • DOI: 10.1021/jacs.5b03105

Fabrication of flexible and freestanding zinc chalcogenide single layers
journal, January 2012

  • Sun, Yongfu; Sun, Zhihu; Gao, Shan
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms2066

Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles
journal, March 2018


Giant Enhancement of Internal Electric Field Boosting Bulk Charge Separation for Photocatalysis
journal, March 2016


Solar Water Splitting and Nitrogen Fixation with Layered Bismuth Oxyhalides
journal, December 2016


Tunable Oxygen Activation for Catalytic Organic Oxidation: Schottky Junction versus Plasmonic Effects
journal, February 2014

  • Long, Ran; Mao, Keke; Gong, Ming
  • Angewandte Chemie International Edition, Vol. 53, Issue 12
  • DOI: 10.1002/anie.201309660

Holey Graphitic Carbon Nitride Nanosheets with Carbon Vacancies for Highly Improved Photocatalytic Hydrogen Production
journal, October 2015

  • Liang, Qinghua; Li, Zhi; Huang, Zheng-Hong
  • Advanced Functional Materials, Vol. 25, Issue 44
  • DOI: 10.1002/adfm.201503221

Vacancy Associates Promoting Solar-Driven Photocatalytic Activity of Ultrathin Bismuth Oxychloride Nanosheets
journal, May 2013

  • Guan, Meili; Xiao, Chong; Zhang, Jie
  • Journal of the American Chemical Society, Vol. 135, Issue 28
  • DOI: 10.1021/ja402956f

Nitrogenase-mimic iron-containing chalcogels for photochemical reduction of dinitrogen to ammonia
journal, May 2016

  • Liu, Jian; Kelley, Matthew S.; Wu, Weiqiang
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 20
  • DOI: 10.1073/pnas.1605512113

Metal-complex chromophores for solar hydrogen generation
journal, January 2017

  • Yuan, Yong-Jun; Yu, Zhen-Tao; Chen, Da-Qin
  • Chemical Society Reviews, Vol. 46, Issue 3
  • DOI: 10.1039/C6CS00436A

Refining Defect States in W 18 O 49 by Mo Doping: A Strategy for Tuning N 2 Activation towards Solar-Driven Nitrogen Fixation
journal, July 2018

  • Zhang, Ning; Jalil, Abdul; Wu, Daoxiong
  • Journal of the American Chemical Society, Vol. 140, Issue 30
  • DOI: 10.1021/jacs.8b02076

Atomically-thin two-dimensional sheets for understanding active sites in catalysis
journal, January 2015

  • Sun, Yongfu; Gao, Shan; Lei, Fengcai
  • Chemical Society Reviews, Vol. 44, Issue 3
  • DOI: 10.1039/C4CS00236A

Layered-Double-Hydroxide Nanosheets as Efficient Visible-Light-Driven Photocatalysts for Dinitrogen Fixation
journal, September 2017

  • Zhao, Yufei; Zhao, Yunxuan; Waterhouse, Geoffrey I. N.
  • Advanced Materials, Vol. 29, Issue 42
  • DOI: 10.1002/adma.201703828

Advanced Nanoarchitectures for Solar Photocatalytic Applications
journal, November 2011

  • Kubacka, Anna; Fernández-García, Marcos; Colón, Gerardo
  • Chemical Reviews, Vol. 112, Issue 3
  • DOI: 10.1021/cr100454n

Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols
journal, June 2018


Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis
journal, September 2015

  • Zhou, Yangen; Zhang, Yongfan; Lin, Mousheng
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9340