Solvent-Induced Self-Assembly Strategy to Synthesize Well-Defined Hierarchically Porous Polymers

Gao, Tu‐Nan; Wang, Tao; Wu, Wei; Liu, Yali; Huo, Qisheng; Qiao, Zhen‐An; Dai, Sheng

doi:10.1002/adma.201806254

Title: Solvent-Induced Self-Assembly Strategy to Synthesize Well-Defined Hierarchically Porous Polymers

Journal Article · 24 January 2019 · Advanced Materials

DOI: https://doi.org/10.1002/adma.201806254 · OSTI ID:1511925

Gao, Tu‐Nan ^[1]; Wang, Tao ^[1]; Wu, Wei ^[1]; Liu, Yali ^[1]; Huo, Qisheng ^[1];

^[1]; Dai, Sheng ^[2]

Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Porous polymers with well-orchestrated nanomorphologies are useful in many fields, but high surface area, hierarchical structure, and ordered pores are difficult to be satisfied in one polymer simultaneously. A solvent-induced self-assembly strategy to synthesize hierarchical porous polymers with tunable morphology, mesoporous structure, and microporous pore wall is reported. The poly(ethylene oxide)-b-polystyrene (PEO-b-PS) diblock copolymer micelles are cross-linked via Friedel–Crafts reaction, which is a new way to anchor micelles into porous polymers with well-defined structure. Varying the polarity of the solvent has a dramatic effect upon the oleophobic/oleophylic interaction, and the self-assembly structure of PEO-b-PS can be tailored from aggregated nanoparticles to hollow spheres even mesoporous bulk. A morphological phase diagram is accomplished to systematically evaluate the influence of the composition of PEO-b-PS and the mixed solvent component on the pore structure and morphology of products. The hypercrosslinked hollow polymer spheres provide a confined microenvironment for the in situ reduction of K₂PdCl₄ to ultrasmall Pd nanoparticles, which exhibit excellent catalytic performance in solvent-free catalytic oxidation of hydrocarbons and alcohols.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jilin Univ., Changchun (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Young Thousand Talented Program (China); National Natural Science Foundation of China (NSFC); “111” Project of the Ministry of Education of China

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1511925

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 11 Vol. 31; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
hierarchical porous polymer
hypercrosslinked polymer
porous material
solvent-free catalysis
solvent-induced self-assembly

Title: Solvent-Induced Self-Assembly Strategy to Synthesize Well-Defined Hierarchically Porous Polymers

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