Structural analyses of blended Nafion/PVDF electrospun nanofibers

Nawn, G.; Vezzù, K.; Negro, E.; Pace, G.; Park, J. W.; Wycisk, R.; Cavinato, G.; Pintauro, P. N.; Di Noto, V.

doi:10.1039/C9CP01891C

Title: Structural analyses of blended Nafion/PVDF electrospun nanofibers

Journal Article · 22 May 2019 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/C9CP01891C · OSTI ID:1511877

Nawn, G. ^[1];

^[1]; Negro, E. ^[1]; Pace, G. ^[2]; Park, J. W. ^[3];

^[3]; Cavinato, G. ^[4];

^[3];

^[1]

Section of Chemistry for the Technology (ChemTech), Department of Industrial Engineering, University of Padova, I-35131 Padova (PD), Italy
CNR-ICMATE, I-35131 Padova (PD), Italy
Department of Chemical and Biomolecular Engineering, Vanderbilt University, Nashville, USA
Department of Chemical Sciences, University of Padova, I-35131 Padova (PD), Italy

A new type of polymer blend, prepared by electrospinning nanofibers containing the immiscible polymer polyvinylidene fluoride (PVDF, 10 wt%) and Nafion® perfluorosulfonic acid (90 wt%), has been characterized experimentally.

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Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC02-05CH1123

OSTI ID:: 1511877

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Vol. 21 Journal Issue: 20; ISSN 1463-9076

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (46)

The Piezoelectricity of Poly (vinylidene Fluoride) Kawai, Heiji Japanese Journal of Applied Physics, Vol. 8, Issue 7 https://doi.org/10.1143/JJAP.8.975	journal	July 1969
New inorganic–organic proton conducting membranes based on Nafion® and [(ZrO2)·(SiO2)0.67] nanoparticles: Synthesis vibrational studies and conductivity Di Noto, Vito; Piga, Matteo; Piga, Luigi Journal of Power Sources, Vol. 178, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.09.043	journal	April 2008
Nafion/PVDF nanofiber composite membranes for regenerative hydrogen/bromine fuel cells Park, Jun Woo; Wycisk, Ryszard; Pintauro, Peter N. Journal of Membrane Science, Vol. 490 https://doi.org/10.1016/j.memsci.2015.04.044	journal	September 2015
Battery Separators Arora, Pankaj; Zhang, Zhengming (John) Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020738u	journal	October 2004
State of Understanding of Nafion Mauritz, Kenneth A.; Moore, Robert B. Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr0207123	journal	October 2004
Nafion–Nafion/polyvinylidene fluoride–Nafion laminated polymer membrane for direct methanol fuel cells Kim, Hyun Jae; Kim, Hyun Jong; Shul, Yong Gun Journal of Power Sources, Vol. 135, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2004.04.001	journal	September 2004
Study of blend membranes consisting of NafionR and vinylidene fluoride-hexafluoropropylene copolymer Lin, Jung-Chou; Ouyang, Meng; Fenton, James M. Journal of Applied Polymer Science, Vol. 70, Issue 1 https://doi.org/10.1002/(SICI)1097-4628(19981003)70:1<121::AID-APP12>3.0.CO;2-A	journal	October 1998
Interplay between Mechanical, Electrical, and Thermal Relaxations in Nanocomposite Proton Conducting Membranes Based on Nafion and a [(ZrO ₂ )·(Ta ₂ O ₅ ) _0.119 ] Core–Shell Nanofiller Di Noto, Vito; Piga, Matteo; Giffin, Guinevere A. Journal of the American Chemical Society, Vol. 134, Issue 46 https://doi.org/10.1021/ja3071336	journal	November 2012
Characterization of sulfated-zirconia/Nafion® composite membranes for proton exchange membrane fuel cells Giffin, Guinevere A.; Piga, Matteo; Lavina, Sandra Journal of Power Sources, Vol. 198 https://doi.org/10.1016/j.jpowsour.2011.09.093	journal	January 2012
Vibrational Analysis of Polytetrafluoroethylene Hannon, M. J.; Boerio, F. J.; Koenig, J. L. The Journal of Chemical Physics, Vol. 50, Issue 7 https://doi.org/10.1063/1.1671471	journal	April 1969
Nafion/polyvinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application Mai, Zhensheng; Zhang, Huamin; Li, Xianfeng Journal of Power Sources, Vol. 196, Issue 13 https://doi.org/10.1016/j.jpowsour.2011.02.048	journal	July 2011
Effects of hydrothermal/thermal treatments on the water-uptake of Nafion membranes and relations with changes of conformation, counter-elastic force and tensile modulus of the matrix Alberti, G.; Narducci, R.; Sganappa, M. Journal of Power Sources, Vol. 178, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.09.034	journal	April 2008
Ion−Oligomer Interactions in Poly(ethylene glycol)400/(LiCl) _x Electrolyte Complexes Di Noto, Vito; Longo, Daniela; Münchow, Vera The Journal of Physical Chemistry B, Vol. 103, Issue 14 https://doi.org/10.1021/jp983764y	journal	April 1999
Chemically-modified Nafion^®/poly(vinylidene fluoride) blend ionomers for proton exchange membrane fuel cells Song, Min-Kyu; Kim, Young-Taek; Fenton, James M. Journal of Power Sources, Vol. 117, Issue 1-2, p. 14-21 https://doi.org/10.1016/S0378-7753(03)00166-6	journal	May 2003
Effect of SiO ₂ on Relaxation Phenomena and Mechanism of Ion Conductivity of [Nafion/(SiO ₂ ) _x ] Composite Membranes ^† Di Noto, Vito; Gliubizzi, Rocco; Negro, Enrico The Journal of Physical Chemistry B, Vol. 110, Issue 49 https://doi.org/10.1021/jp0650331	journal	December 2006
The molecular conformations of polytetrafluoroethylene: forms II and IV Clark, E. S. Polymer, Vol. 40, Issue 16 https://doi.org/10.1016/S0032-3861(99)00109-3	journal	July 1999
The influence of the cationic form and degree of hydration on the structure of Nafion™ Negro, Enrico; Vittadello, Michele; Vezzù, Keti Solid State Ionics, Vol. 252 https://doi.org/10.1016/j.ssi.2013.09.017	journal	December 2013
Crystal polymorphism in electrospun composite nanofibers of poly(vinylidene fluoride) with nanoclay Yu, Lei; Cebe, Peggy Polymer, Vol. 50, Issue 9 https://doi.org/10.1016/j.polymer.2009.03.003	journal	April 2009
Corona charging and the piezoelectric effect in polyvinylidene fluoride Das‐Gupta, D. K.; Doughty, K. Journal of Applied Physics, Vol. 49, Issue 8 https://doi.org/10.1063/1.325441	journal	August 1978
Lattice dynamics of polytetrafluoroethylene Piseri, L.; Powell, B. M.; Dolling, G. The Journal of Chemical Physics, Vol. 58, Issue 1 https://doi.org/10.1063/1.1678900	journal	January 1973
Interplay Between Hydroxyl Density and Relaxations in Poly(vinylbenzyltrimethylammonium)- b -poly(methylbutylene) Membranes for Electrochemical Applications Vezzù, Keti; Maes, Ashley M.; Bertasi, Federico Journal of the American Chemical Society, Vol. 140, Issue 4 https://doi.org/10.1021/jacs.7b10524	journal	January 2018
Determination of the α, β, and γ crystalline phases of poly(vinylidene fluoride) films prepared at different conditions Gregorio, Rinaldo Journal of Applied Polymer Science, Vol. 100, Issue 4 https://doi.org/10.1002/app.23137	journal	January 2006
Nafion-impregnated electrospun polyvinylidene fluoride composite membranes for direct methanol fuel cells Choi, S. W.; Fu, Y.-Z.; Ahn, Y. R. Journal of Power Sources, Vol. 180, Issue 1, p. 167-171 https://doi.org/10.1016/j.jpowsour.2008.02.042	journal	May 2008
Interplay between solid state transitions, conductivity mechanisms, and electrical relaxations in a [PVBTMA] [Br]-b-PMB diblock copolymer membrane for electrochemical applications Noto, Vito Di; Giffin, Guinevere A.; Vezzù, Keti Physical Chemistry Chemical Physics, Vol. 17, Issue 46 https://doi.org/10.1039/C5CP05545H	journal	January 2015
Thermal Behavior of Nafion Membranes de Almeida, S. H.; Kawano, Y. Journal of Thermal Analysis and Calorimetry, Vol. 58, Issue 3, p. 569-577 https://doi.org/10.1023/A:1010196226309	journal	January 1999
Highly porous electrospun polyvinylidene fluoride (PVDF)-based carbon fiber Yang, Ying; Centrone, Andrea; Chen, Liang Carbon, Vol. 49, Issue 11 https://doi.org/10.1016/j.carbon.2011.04.015	journal	September 2011
Structures of Molecules and Crystals of Fluoro-Carbons Bunn, C. W.; Howells, E. R. Nature, Vol. 174, Issue 4429 https://doi.org/10.1038/174549a0	journal	September 1954
Vibrational spectra and disorder-order transition of poly(vinylidene fluoride) form III Tashiro, Kohji; Kobayashi, Masamichi; Tadokoro, Hiroyuki Macromolecules, Vol. 14, Issue 6 https://doi.org/10.1021/ma50007a028	journal	November 1981
Influence of Anions on Proton-Conducting Membranes Based on Neutralized Nafion 117, Triethylammonium Methanesulfonate, and Triethylammonium Perfluorobutanesulfonate. 1. Synthesis and Properties Noto, Vito Di; Piga, Matteo; Giffin, Guinevere A. The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp204241y	journal	December 2011
Hybrid inorganic–organic proton conducting membranes based on Nafion and 5wt.% of MxOy (M=Ti, Zr, Hf, Ta and W) Di Noto, Vito; Gliubizzi, Rocco; Negro, Enrico Electrochimica Acta, Vol. 53, Issue 4 https://doi.org/10.1016/j.electacta.2007.05.009	journal	December 2007
Piezoelectric activity and field‐induced crystal structure transitions in poled poly(vinylidene fluoride) films Newman, B. A.; Yoon, C. H.; Pae, K. D. Journal of Applied Physics, Vol. 50, Issue 10 https://doi.org/10.1063/1.325778	journal	October 1979
Preparation of Nafion 117™-SnO2 composite membranes using an ion-exchange method Nørgaard, C. F.; Nielsen, U. G.; Skou, E. M. Solid State Ionics, Vol. 213 https://doi.org/10.1016/j.ssi.2011.10.014	journal	April 2012
New inorganic–organic proton conducting membranes based on Nafion and hydrophobic fluoroalkylated silica nanoparticles Di Noto, Vito; Boaretto, Nicola; Negro, Enrico Journal of Power Sources, Vol. 195, Issue 23 https://doi.org/10.1016/j.jpowsour.2009.10.028	journal	December 2010
Investigation of Water Structure in Nafion Membranes by Infrared Spectroscopy and Molecular Dynamics Simulation Hofmann, Detlef W. M.; Kuleshova, Liudmila; D’Aguanno, Bruno The Journal of Physical Chemistry B, Vol. 113, Issue 3 https://doi.org/10.1021/jp806761h	journal	January 2009
Characterization of Electrospun PVdF Fiber-Based Polymer Electrolytes Choi, Sung Won; Kim, Jeong Rae; Ahn, Young Rack Chemistry of Materials, Vol. 19, Issue 1 https://doi.org/10.1021/cm060223+	journal	December 2006
Electro-mechanical properties of the piezoelectric polymer PVDF Vinogradov, Aleksandra; Holloway, Frank Ferroelectrics, Vol. 226, Issue 1 https://doi.org/10.1080/00150199908230298	journal	April 1999
Effect of drawing on the dielectric properties and polarization of pressed solution cast β-PVDF films da Silva, Aline Bruna; Wisniewski, Celio; Esteves, João Victor Almeida Journal of Materials Science, Vol. 45, Issue 15 https://doi.org/10.1007/s10853-010-4515-3	journal	April 2010
Dynamics of Polymers as Structurally Disordered Systems. Vibrational Spectrum and Structure of Poly(tetrafluoroethylene) Zerbi, Giuseppe; Sacchi, Mario Macromolecules, Vol. 6, Issue 5 https://doi.org/10.1021/ma60035a010	journal	September 1973
Vibrational Studies and Properties of Hybrid Inorganic−Organic Proton Conducting Membranes Based on Nafion and Hafnium Oxide Nanoparticles Vittadello, Michele; Negro, Enrico; Lavina, Sandra The Journal of Physical Chemistry B, Vol. 112, Issue 51 https://doi.org/10.1021/jp804117w	journal	December 2008
Electrospun Nafion/PVDF single-fiber blended membranes for regenerative H2/Br2 fuel cells Woo Park, Jun; Wycisk, Ryszard; Lin, Guangyu Journal of Membrane Science, Vol. 541 https://doi.org/10.1016/j.memsci.2017.06.086	journal	November 2017
Conformational Order and Disorder in Poly(tetrafluoroethylene) from the Infrared Spectrum Masetti, G.; Cabassi, F.; Morelli, G. Macromolecules, Vol. 6, Issue 5 https://doi.org/10.1021/ma60035a011	journal	September 1973
Structure, properties and proton conductivity of nanocomposite membranes Di Noto, Vito; Piga, Matteo; Lavina, Sandra Electrochimica Acta, Vol. 55, Issue 4 https://doi.org/10.1016/j.electacta.2009.06.011	journal	January 2010
Thermal analysis of conductive blends of PVDF and poly(o-methoxyaniline) Malmonge, L. Polymer, Vol. 41, Issue 23 https://doi.org/10.1016/S0032-3861(00)00182-8	journal	November 2000
Small-angle x-ray scattering study of perfluorinated ionomer membranes. 1. Origin of two scattering maxima Fujimura, Mineo; Hashimoto, Takeji; Kawai, Hiromichi Macromolecules, Vol. 14, Issue 5 https://doi.org/10.1021/ma50006a032	journal	September 1981
Molecular Vibrations of Three Crystal Forms of Poly(vinylidene fluoride) Kobayashi, Masamichi; Tashiro, Kohji; Tadokoro, Hiroyuki Macromolecules, Vol. 8, Issue 2 https://doi.org/10.1021/ma60044a013	journal	March 1975
Crystallization of PVDF in the PVDF/PMMA blends precipitated from their non-solvents: Special “orientation” behavior, morphology, and thermal properties Zhao, Xuejuan; Chen, Shuangjun; Zhang, Jun Journal of Crystal Growth, Vol. 328, Issue 1 https://doi.org/10.1016/j.jcrysgro.2011.06.036	journal	August 2011

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