Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation

Wang, Liang; Guan, Erjia; Zhang, Jian; Yang, Junhao; Zhu, Yihan; Han, Yu; Yang, Ming; Cen, Cheng; Fu, Gang; Gates, Bruce C.; Xiao, Feng-Shou

doi:10.1038/s41467-018-03810-y

Title: Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation

Journal Article · 10 April 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-03810-y · OSTI ID:1511705

Wang, Liang ^[1]; Guan, Erjia ^[2]; Zhang, Jian ^[1]; Yang, Junhao ^[3]; Zhu, Yihan ^[4];

^[4]; Yang, Ming ^[5]; Cen, Cheng ^[5]; Fu, Gang ^[6]; Gates, Bruce C. ^[2]; Xiao, Feng-Shou ^[1]

Zhejiang Univ., Hangzhou (China)
Univ. of California, Davis, CA (United States)
Chinese Academy of Sciences (CAS), Dalian (China)
King Abdullah Univ. of Science and Tech., Thuwal (Saudi Arabia)
West Virginia Univ., Morgantown, WV (United States)
Xiamen Univ., Xiamen (China)

Atomically dispersed supported metal catalysts are drawing wide attention because of the opportunities they offer for new catalytic properties combined with efficient use of the metals. We extend this class of materials to catalysts that incorporate atomically dispersed metal atoms as promoters. The catalysts are used for the challenging nitroarene hydrogenation and found to have both high activity and selectivity. The promoters are single-site Sn on TiO₂ supports that incorporate metal nanoparticle catalysts. Represented as M/Sn-TiO₂ (M = Au, Ru, Pt, Ni), these catalysts decidedly outperform the unpromoted supported metals, even for hydrogenation of nitroarenes substituted with various reducible groups. The high activity and selectivity of these catalysts result from the creation of oxygen vacancies on the TiO₂ surface by single-site Sn, which leads to efficient, selective activation of the nitro group coupled with a reaction involving hydrogen atoms activated on metal nanoparticles.

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Research Organization:: Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-04ER15513

OSTI ID:: 1511705

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 146 works

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A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores Zhang, Jian; Wang, Liang; Shao, Yi Angewandte Chemie, Vol. 129, Issue 33 https://doi.org/10.1002/ange.201703938	journal	May 2017
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Pd-Pb Alloy Nanocrystals with Tailored Composition for Semihydrogenation: Taking Advantage of Catalyst Poisoning Niu, Wenxin; Gao, Yongjun; Zhang, Weiqing Angewandte Chemie, Vol. 127, Issue 28 https://doi.org/10.1002/ange.201503148	journal	May 2015
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Pd-Pb Alloy Nanocrystals with Tailored Composition for Semihydrogenation: Taking Advantage of Catalyst Poisoning Niu, Wenxin; Gao, Yongjun; Zhang, Weiqing Angewandte Chemie, Vol. 127, Issue 28 https://doi.org/10.1002/ange.201503148	journal	May 2015
Reduction of Nitroaromatic Compounds on Supported Gold Nanoparticles by Visible and Ultraviolet Light Zhu, Huaiyong; Ke, Xuebin; Yang, Xuzhuang Angewandte Chemie International Edition, Vol. 49, Issue 50 https://doi.org/10.1002/anie.201003908	journal	November 2010
Gold-Catalyzed Direct Hydrogenative Coupling of Nitroarenes To Synthesize Aromatic Azo Compounds Liu, Xiang; Li, Hai-Qian; Ye, Sen Angewandte Chemie International Edition, Vol. 53, Issue 29 https://doi.org/10.1002/anie.201404543	journal	June 2014
A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores Zhang, Jian; Wang, Liang; Shao, Yi Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201703938	journal	May 2017
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Effect of potassium promoter on precipitated iron-manganese catalyst for Fischer?Tropsch synthesis Yang, Y. Applied Catalysis A: General, Vol. 266, Issue 2 https://doi.org/10.1016/j.apcata.2004.02.018	journal	July 2004
Activity and Selectivity in Nitroarene Hydrogenation over Au Nanoparticles on the Edge/Corner of Anatase Wang, Liang; Zhang, Jian; Wang, Hong ACS Catalysis, Vol. 6, Issue 7 https://doi.org/10.1021/acscatal.6b00530	journal	May 2016
Highly Efficient and Selective Hydrogenation of Nitroaromatics on Photoactivated Rutile Titanium Dioxide Shiraishi, Yasuhiro; Togawa, Yoshiki; Tsukamoto, Daijiro ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs300500p	journal	October 2012
Probing the Low-Temperature Water–Gas Shift Activity of Alkali-Promoted Platinum Catalysts Stabilized on Carbon Supports Zugic, Branko; Zhang, Shiran; Bell, David C. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja4123889	journal	February 2014
Transforming Nonselective into Chemoselective Metal Catalysts for the Hydrogenation of Substituted Nitroaromatics Corma, Avelino; Serna, Pedro; Concepción, Patricia Journal of the American Chemical Society, Vol. 130, Issue 27 https://doi.org/10.1021/ja800959g	journal	July 2008
One-step Synthesis of Core-Gold/Shell-Ceria Nanomaterial and Its Catalysis for Highly Selective Semihydrogenation of Alkynes Mitsudome, Takato; Yamamoto, Masaaki; Maeno, Zen Journal of the American Chemical Society, Vol. 137, Issue 42 https://doi.org/10.1021/jacs.5b07521	journal	October 2015
High Catalytic Activity and Chemoselectivity of Sub-nanometric Pd Clusters on Porous Nanorods of CeO ₂ for Hydrogenation of Nitroarenes Zhang, Sai; Chang, Chun-Ran; Huang, Zheng-Qing Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b11413	journal	February 2016
Product Selectivity Controlled by Zeolite Crystals in Biomass Hydrogenation over a Palladium Catalyst Wang, Chengtao; Wang, Liang; Zhang, Jian Journal of the American Chemical Society, Vol. 138, Issue 25 https://doi.org/10.1021/jacs.6b04951	journal	June 2016
Enhanced Photoactivity of Oxygen-Deficient Anatase TiO ₂ Sheets with Dominant {001} Facets Liu, Gang; Yang, Hua Gui; Wang, Xuewen The Journal of Physical Chemistry C, Vol. 113, Issue 52 https://doi.org/10.1021/jp907749r	journal	December 2009
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Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes Westerhaus, Felix A.; Jagadeesh, Rajenahally V.; Wienhöfer, Gerrit Nature Chemistry, Vol. 5, Issue 6 https://doi.org/10.1038/nchem.1645	journal	May 2013
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank Nature Chemistry, Vol. 6, Issue 4 https://doi.org/10.1038/nchem.1873	journal	March 2014
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