Suppression of atom motion and metal deposition in mixed ionic electronic conductors
Abstract
Many superionic mixed ionic–electronic conductors with a liquid-like sublattice have been identified as high efficiency thermoelectric materials, but their applications are limited due to the possibility of decomposition when subjected to high electronic currents and large temperature gradients. Here, through systematically investigating electromigration in copper sulfide/selenide thermoelectric materials, we reveal the mechanism for atom migration and deposition based on a critical chemical potential difference. Then, a strategy for stable use is proposed: constructing a series of electronically conducting, but ion-blocking barriers to reset the chemical potential of such conductors to keep it below the threshold for decomposition, even if it is used with high electric currents and/or large temperature differences. This strategy not only opens the possibility of using such conductors in thermoelectric applications, but may also provide approaches to engineer perovskite photovoltaic materials and the experimental methods may be applicable to understanding dendrite growth in lithium ion batteries.
- Authors:
-
- Chinese Academy of Sciences, Shanghai (China)
- Northwestern Univ., Evanston, IL (United States)
- Chinese Academy of Sciences, Shanghai (China); Univ. of Chinese Academy of Sciences, Beijing (China)
- Shanghai Univ., Shanghai (China)
- South Univ. of Science and Technology of China, Shenzhen (China)
- Justus-Liebig-Univ. Giessen, Giessen (Germany)
- Univ. of Michigan, Ann Arbor, MI (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1511492
- Grant/Contract Number:
- SC0001299
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Qiu, Pengfei, Agne, Matthias T., Liu, Yongying, Zhu, Yaqin, Chen, Hongyi, Mao, Tao, Yang, Jiong, Zhang, Wenqing, Haile, Sossina M., Zeier, Wolfgang G., Janek, Jürgen, Uher, Ctirad, Shi, Xun, Chen, Lidong, and Snyder, G. Jeffrey. Suppression of atom motion and metal deposition in mixed ionic electronic conductors. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-05248-8.
Qiu, Pengfei, Agne, Matthias T., Liu, Yongying, Zhu, Yaqin, Chen, Hongyi, Mao, Tao, Yang, Jiong, Zhang, Wenqing, Haile, Sossina M., Zeier, Wolfgang G., Janek, Jürgen, Uher, Ctirad, Shi, Xun, Chen, Lidong, & Snyder, G. Jeffrey. Suppression of atom motion and metal deposition in mixed ionic electronic conductors. United States. https://doi.org/10.1038/s41467-018-05248-8
Qiu, Pengfei, Agne, Matthias T., Liu, Yongying, Zhu, Yaqin, Chen, Hongyi, Mao, Tao, Yang, Jiong, Zhang, Wenqing, Haile, Sossina M., Zeier, Wolfgang G., Janek, Jürgen, Uher, Ctirad, Shi, Xun, Chen, Lidong, and Snyder, G. Jeffrey. Wed .
"Suppression of atom motion and metal deposition in mixed ionic electronic conductors". United States. https://doi.org/10.1038/s41467-018-05248-8. https://www.osti.gov/servlets/purl/1511492.
@article{osti_1511492,
title = {Suppression of atom motion and metal deposition in mixed ionic electronic conductors},
author = {Qiu, Pengfei and Agne, Matthias T. and Liu, Yongying and Zhu, Yaqin and Chen, Hongyi and Mao, Tao and Yang, Jiong and Zhang, Wenqing and Haile, Sossina M. and Zeier, Wolfgang G. and Janek, Jürgen and Uher, Ctirad and Shi, Xun and Chen, Lidong and Snyder, G. Jeffrey},
abstractNote = {Many superionic mixed ionic–electronic conductors with a liquid-like sublattice have been identified as high efficiency thermoelectric materials, but their applications are limited due to the possibility of decomposition when subjected to high electronic currents and large temperature gradients. Here, through systematically investigating electromigration in copper sulfide/selenide thermoelectric materials, we reveal the mechanism for atom migration and deposition based on a critical chemical potential difference. Then, a strategy for stable use is proposed: constructing a series of electronically conducting, but ion-blocking barriers to reset the chemical potential of such conductors to keep it below the threshold for decomposition, even if it is used with high electric currents and/or large temperature differences. This strategy not only opens the possibility of using such conductors in thermoelectric applications, but may also provide approaches to engineer perovskite photovoltaic materials and the experimental methods may be applicable to understanding dendrite growth in lithium ion batteries.},
doi = {10.1038/s41467-018-05248-8},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {7}
}
Web of Science
Works referenced in this record:
Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015
- Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
- Nature Communications, Vol. 6, Issue 1
Disordered zinc in Zn4Sb3 with phonon-glass and electron-crystal thermoelectric properties
journal, June 2004
- Snyder, G. Jeffrey; Christensen, Mogens; Nishibori, Eiji
- Nature Materials, Vol. 3, Issue 7
Nanoionics-based resistive switching memories
journal, November 2007
- Waser, Rainer; Aono, Masakazu
- Nature Materials, Vol. 6, Issue 11, p. 833-840
Are Binary Copper Sulfides/Selenides Really New and Promising Thermoelectric Materials?
journal, February 2014
- Dennler, Gilles; Chmielowski, Radoslaw; Jacob, Stéphane
- Advanced Energy Materials, Vol. 4, Issue 9
Enhanced Thermoelectric Figure-of-Merit in Nanostructured p-type Silicon Germanium Bulk Alloys
journal, December 2008
- Joshi, Giri; Lee, Hohyun; Lan, Yucheng
- Nano Letters, Vol. 8, Issue 12
Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics
journal, April 2015
- Kim, Sang Il; Lee, Kyu Hyoung; Mun, Hyeon A.
- Science, Vol. 348, Issue 6230
Biomimetic ant-nest ionogel electrolyte boosts the performance of dendrite-free lithium batteries
journal, January 2017
- Chen, Nan; Dai, Yujuan; Xing, Yi
- Energy & Environmental Science, Vol. 10, Issue 7
Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport
journal, April 1997
- Korte, C.; Janek, J.
- Journal of Physics and Chemistry of Solids, Vol. 58, Issue 4
Thermoelectric Transport in Cu 7 PSe 6 with High Copper Ionic Mobility
journal, August 2014
- Weldert, Kai S.; Zeier, Wolfgang G.; Day, Tristan W.
- Journal of the American Chemical Society, Vol. 136, Issue 34
Mixed ionic–electronic conductors—material properties and applications
journal, February 2003
- Riess, I.
- Solid State Ionics, Vol. 157, Issue 1-4
Solid-State Ionics: Roots, Status, and Future Prospects
journal, July 2002
- Knauth, Philippe; Tuller, Harry L.
- Journal of the American Ceramic Society, Vol. 85, Issue 7
On the Electrical Conductivity of Cuprous Sulfide: A Diffusion Theory
journal, September 1953
- Yokota, Isaaki
- Journal of the Physical Society of Japan, Vol. 8, Issue 5
High Performance Thermoelectricity in Earth-Abundant Compounds Based on Natural Mineral Tetrahedrites
journal, October 2012
- Lu, Xu; Morelli, Donald T.; Xia, Yi
- Advanced Energy Materials, Vol. 3, Issue 3, p. 342-348
Recent advances in high-performance bulk thermoelectric materials
journal, May 2016
- Shi, X.; Chen, L.; Uher, C.
- International Materials Reviews, Vol. 61, Issue 6
Chemical Stability of (Ag,Cu)2Se: a Historical Overview
journal, March 2013
- Brown, David R.; Day, Tristan; Caillat, Thierry
- Journal of Electronic Materials, Vol. 42, Issue 7
Extremely high electron mobility in a phonon-glass semimetal
journal, April 2013
- Ishiwata, S.; Shiomi, Y.; Lee, J. S.
- Nature Materials, Vol. 12, Issue 6
High-performance bulk thermoelectrics with all-scale hierarchical architectures
journal, September 2012
- Biswas, Kanishka; He, Jiaqing; Blum, Ivan D.
- Nature, Vol. 489, Issue 7416, p. 414-418
Electronic and crystal structure of : Full-potential electronic structure calculations
journal, November 2007
- Lukashev, Pavel; Lambrecht, Walter R. L.; Kotani, Takao
- Physical Review B, Vol. 76, Issue 19
Ionic conductivity and chemical diffusion in superionic LixCu2−xS (0≤x≤ 0.25)
journal, January 2004
- Balapanov, M. Kh.; Gafurov, I. G.; Mukhamed'yanov, U. Kh.
- physica status solidi (b), Vol. 241, Issue 1
Superionic Phase Transition in Silver Chalcogenide Nanocrystals Realizing Optimized Thermoelectric Performance
journal, February 2012
- Xiao, Chong; Xu, Jie; Li, Kun
- Journal of the American Chemical Society, Vol. 134, Issue 9
The thermoelectric power of cells with ionic compounds involving ionic and electronic conduction
journal, January 1972
- Wagner, Carl
- Progress in Solid State Chemistry, Vol. 7
Copper ion liquid-like thermoelectrics
journal, March 2012
- Liu, Huili; Shi, Xun; Xu, Fangfang
- Nature Materials, Vol. 11, Issue 5, p. 422-425
Superionic conductors: Transitions, structures, dynamics
journal, April 1979
- Boyce, J. B.; Huberman, B. A.
- Physics Reports, Vol. 51, Issue 4
Sulfide bornite thermoelectric material: a natural mineral with ultralow thermal conductivity
journal, January 2014
- Qiu, Pengfei; Zhang, Tiansong; Qiu, Yuting
- Energy Environ. Sci., Vol. 7, Issue 12
An improved understanding of efficiency limiting defects in polycrystalline CdTe/CdS solar cells
conference, January 1992
- Rohatgi, A.; Chou, H. C.; Bhat, A.
- Photovoltaic advanced research and development project, AIP Conference Proceedings
An improved understanding of efficiency limiting defects in polycrystalline CdTe/CdS solar cells
conference, January 1991
- Rohatgi, A.; Ringel, S. A.; Sudharsanan, R.
- The Conference Record of the Twenty-Second IEEE Photovoltaic Specialists Conference - 1991
Atomic Transport in Solids
journal, February 1995
- Kärger, J.
- Zeitschrift für Physikalische Chemie, Vol. 189, Issue 2
Works referencing / citing this record:
Recent Advances in Liquid‐Like Thermoelectric Materials
journal, August 2019
- Zhao, Kunpeng; Qiu, Pengfei; Shi, Xun
- Advanced Functional Materials, Vol. 30, Issue 8
Are Cu 2 Te‐Based Compounds Excellent Thermoelectric Materials?
journal, October 2019
- Zhao, Kunpeng; Liu, Ke; Yue, Zhongmou
- Advanced Materials, Vol. 31, Issue 49
Promising and Eco‐Friendly Cu 2 X‐Based Thermoelectric Materials: Progress and Applications
journal, January 2020
- Liu, Wei‐Di; Yang, Lei; Chen, Zhi‐Gang
- Advanced Materials, Vol. 32, Issue 8
Decoupling Thermoelectric Performance and Stability in Liquid‐Like Thermoelectric Materials
journal, October 2019
- Mao, Tao; Qiu, Pengfei; Hu, Ping
- Advanced Science, Vol. 7, Issue 1
Nanosheets‐Assembled CuSe Crystal Pillar as a Stable and High‐Power Anode for Sodium‐Ion and Potassium‐Ion Batteries
journal, April 2019
- Lin, Hezhe; Li, Malin; Yang, Xu
- Advanced Energy Materials, Vol. 9, Issue 20
High thermoelectric performance and low thermal conductivity in Cu2-xNaxSe bulk materials with micro-pores
journal, July 2019
- Zhu, Zheng; Zhang, Yuewen; Song, Hongzhang
- Applied Physics A, Vol. 125, Issue 8
Thermoelectric Properties of Zn4Sb3 Composites with Incomplete Reaction
journal, December 2018
- Lin, Jianping; Ma, Lingzhi; Zheng, Zhonghua
- Journal of Electronic Materials, Vol. 48, Issue 2
Copper chalcogenide thermoelectric materials
journal, August 2018
- Wei, Tian-Ran; Qin, Yuting; Deng, Tingting
- Science China Materials, Vol. 62, Issue 1
Remarkably high thermoelectric performance of Cu 2−x Li x Se bulks with nanopores
journal, January 2018
- Hu, Qiujun; Zhu, Zheng; Zhang, Yuewen
- Journal of Materials Chemistry A, Vol. 6, Issue 46
Effect of anion substitution on the structural and transport properties of argyrodites Cu 7 PSe 6−x S x
journal, January 2019
- Reissig, Friederike; Heep, Barbara; Panthöfer, Martin
- Dalton Transactions, Vol. 48, Issue 42
Chloride transport in conductive polymer films for an n-type thermoelectric platform
journal, January 2020
- Kim, Byeonggwan; Hwang, Jong Un; Kim, Eunkyoung
- Energy & Environmental Science, Vol. 13, Issue 3
Realizing high-efficiency power generation in low-cost PbS-based thermoelectric materials
journal, January 2020
- Jiang, Binbin; Liu, Xixi; Wang, Qi
- Energy & Environmental Science, Vol. 13, Issue 2
Thermoelectric properties of n-type Cu 4 Sn 7 S 16 -based compounds
journal, January 2019
- Deng, Tingting; Wei, Tian-Ran; Song, Qingfeng
- RSC Advances, Vol. 9, Issue 14
Oxygen migration and proton diffusivity in transition-metal (Mn, Fe, Co, and Cu) doped Ruddlesden–Popper oxides
journal, January 2019
- Zhang, Lifang; Yao, Fen; Meng, Junling
- Journal of Materials Chemistry A, Vol. 7, Issue 31
Kinetic condition driven phase and vacancy enhancing thermoelectric performance of low-cost and eco-friendly Cu 2−x S
journal, January 2019
- Liu, Wei-Di; Shi, Xiao-Lei; Gao, Han
- Journal of Materials Chemistry C, Vol. 7, Issue 18
Effectively restricting MnSi precipitates for simultaneously enhancing the Seebeck coefficient and electrical conductivity in higher manganese silicide
journal, January 2019
- Liu, Wei-Di; Shi, Xiao-Lei; Moshwan, Raza
- Journal of Materials Chemistry C, Vol. 7, Issue 24
Quasi-two-dimensional GeSbTe compounds as promising thermoelectric materials with anisotropic transport properties
journal, February 2019
- Wei, Tian-Ran; Hu, Ping; Chen, Hongyi
- Applied Physics Letters, Vol. 114, Issue 5
A p -type thermoelectric material BaCu 4 S 3 with high electronic band degeneracy
journal, July 2019
- Zong, Peng-an; Kimata, Kana; Li, Zheng
- Journal of Applied Physics, Vol. 126, Issue 2
Anharmonic lattice dynamics and superionic transition in AgCrSe 2
journal, February 2020
- Ding, Jingxuan; Niedziela, Jennifer L.; Bansal, Dipanshu
- Proceedings of the National Academy of Sciences, Vol. 117, Issue 8
Thermoelectric power generation: from new materials to devices
journal, July 2019
- Tan, Gangjian; Ohta, Michihiro; Kanatzidis, Mercouri G.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152