Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes
Abstract
A conductive polymer is developed for solving the long-standing volume change issue in lithium battery electrodes. Here, a combination of synthesis, spectroscopy and simulation techniques tailors the electronic structure of the polymer to enable in situ lithium doping. Composite anodes based on this polymer and commercial Si particles exhibit 2100 mAh g-1 in Si after 650 cycles without any conductive additive.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1511333
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 23; Journal Issue: 40; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium batteries; conducting polymers; X‐ray spectroscopy; density functional theory; binders
Citation Formats
Liu, Gao, Xun, Shidi, Vukmirovic, Nenad, Song, Xiangyun, Olalde-Velasco, Paul, Zheng, Honghe, Battaglia, Vince S., Wang, Linwang, and Yang, Wanli. Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes. United States: N. p., 2011.
Web. doi:10.1002/adma.201102421.
Liu, Gao, Xun, Shidi, Vukmirovic, Nenad, Song, Xiangyun, Olalde-Velasco, Paul, Zheng, Honghe, Battaglia, Vince S., Wang, Linwang, & Yang, Wanli. Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes. United States. https://doi.org/10.1002/adma.201102421
Liu, Gao, Xun, Shidi, Vukmirovic, Nenad, Song, Xiangyun, Olalde-Velasco, Paul, Zheng, Honghe, Battaglia, Vince S., Wang, Linwang, and Yang, Wanli. Mon .
"Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes". United States. https://doi.org/10.1002/adma.201102421. https://www.osti.gov/servlets/purl/1511333.
@article{osti_1511333,
title = {Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes},
author = {Liu, Gao and Xun, Shidi and Vukmirovic, Nenad and Song, Xiangyun and Olalde-Velasco, Paul and Zheng, Honghe and Battaglia, Vince S. and Wang, Linwang and Yang, Wanli},
abstractNote = {A conductive polymer is developed for solving the long-standing volume change issue in lithium battery electrodes. Here, a combination of synthesis, spectroscopy and simulation techniques tailors the electronic structure of the polymer to enable in situ lithium doping. Composite anodes based on this polymer and commercial Si particles exhibit 2100 mAh g-1 in Si after 650 cycles without any conductive additive.},
doi = {10.1002/adma.201102421},
journal = {Advanced Materials},
number = 40,
volume = 23,
place = {United States},
year = {Mon Sep 12 00:00:00 EDT 2011},
month = {Mon Sep 12 00:00:00 EDT 2011}
}
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Figure 1: Schematics of the technical approaches to address volume change issue in battery materials. (a) Traditional approaches use acetylene black (AB) as the conductive additive and PVDF polymer as mechanical binder. (b) Conductive polymer with dual functionality, as a conductor and binder, could keep both electric and mechanical integritymore »
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