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Title: Finding a soft spot for vanadium: a P-bound OCP ligand

Abstract

The first example of a P-bound phosphaethynolato ligand, [OCP] , to an early 3d transition metal is presented, along with detailed characterization by single crystal X-ray diffraction, SQuID magnetometry, HFEPR spectroscopy, and computational studies.

Authors:
ORCiD logo [1];  [2];  [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Department of Chemistry, University of Pennsylvania, Philadelphia, USA
  2. National High Magnetic Field Laboratory, Florida State University, Tallahassee, USA
  3. Department of Chemistry, Universidad Técnica Federico Santa María, Valparaíso, Chile
  4. Department of Biological, Physical and Health Sciences, Roosevelt University, Chicago, USA
  5. Department of Chemistry and Applied Biosciences, ETH Zürich, Hönggerberg, Switzerland
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1510553
Grant/Contract Number:  
DEFG02-07ER15893
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 42; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, and Mindiola, Daniel J. Finding a soft spot for vanadium: a P-bound OCP ligand. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC01500K.
Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, & Mindiola, Daniel J. Finding a soft spot for vanadium: a P-bound OCP ligand. United Kingdom. doi:10.1039/C9CC01500K.
Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, and Mindiola, Daniel J. Tue . "Finding a soft spot for vanadium: a P-bound OCP ligand". United Kingdom. doi:10.1039/C9CC01500K.
@article{osti_1510553,
title = {Finding a soft spot for vanadium: a P-bound OCP ligand},
author = {Grant, Lauren N. and Krzystek, J. and Pinter, Balazs and Telser, Joshua and Grützmacher, Hansjörg and Mindiola, Daniel J.},
abstractNote = {The first example of a P-bound phosphaethynolato ligand, [OCP] − , to an early 3d transition metal is presented, along with detailed characterization by single crystal X-ray diffraction, SQuID magnetometry, HFEPR spectroscopy, and computational studies.},
doi = {10.1039/C9CC01500K},
journal = {Chemical Communications},
number = 42,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {5}
}

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This content will become publicly available on April 5, 2020
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