skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on April 25, 2020

Title: Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor

Abstract

Phenolic commodity chemicals were produced from lignin with high yield and selectivity in a flow reactor, valorizing the biorefinery process.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Biological Systems Engineering, University of Wisconsin-Madison, Madison, USA, DOE Great Lakes Bioenergy Research Center
  2. DOE Great Lakes Bioenergy Research Center, University of Wisconsin-Madison, Madison, USA, Department of Chemical and Biological Engineering
  3. DOE Great Lakes Bioenergy Research Center, University of Wisconsin-Madison, Madison, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1510534
Grant/Contract Number:  
SC0018409
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Name: Green Chemistry; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Li, Yanding, Demir, Benginur, Vázquez Ramos, Leida M., Chen, Mingjie, Dumesic, James A., and Ralph, John. Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor. United Kingdom: N. p., 2019. Web. doi:10.1039/C9GC00986H.
Li, Yanding, Demir, Benginur, Vázquez Ramos, Leida M., Chen, Mingjie, Dumesic, James A., & Ralph, John. Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor. United Kingdom. doi:10.1039/C9GC00986H.
Li, Yanding, Demir, Benginur, Vázquez Ramos, Leida M., Chen, Mingjie, Dumesic, James A., and Ralph, John. Tue . "Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor". United Kingdom. doi:10.1039/C9GC00986H.
@article{osti_1510534,
title = {Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor},
author = {Li, Yanding and Demir, Benginur and Vázquez Ramos, Leida M. and Chen, Mingjie and Dumesic, James A. and Ralph, John},
abstractNote = {Phenolic commodity chemicals were produced from lignin with high yield and selectivity in a flow reactor, valorizing the biorefinery process.},
doi = {10.1039/C9GC00986H},
journal = {Green Chemistry},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on April 25, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014

  • Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
  • Science, Vol. 344, Issue 6185, p. 1246843-1246843
  • DOI: 10.1126/science.1246843

Cleavage and hydrodeoxygenation (HDO) of C�O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis
journal, January 2013

  • Parsell, Trenton H.; Owen, Benjamin C.; Klein, Ian
  • Chem. Sci., Vol. 4, Issue 2, p. 806-813
  • DOI: 10.1039/C2SC21657D

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers
journal, April 2011


Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin
journal, April 2013

  • Rahimi, Alireza; Azarpira, Ali; Kim, Hoon
  • Journal of the American Chemical Society, Vol. 135, Issue 17, p. 6415-6418
  • DOI: 10.1021/ja401793n

Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation�hydrogenolysis process
journal, January 2013

  • Song, Qi; Wang, Feng; Cai, Jiaying
  • Energy & Environmental Science, Vol. 6, Issue 3, p. 994-1007
  • DOI: 10.1039/c2ee23741e

Lignin Biosynthesis and Structure
journal, May 2010

  • Vanholme, R.; Demedts, B.; Morreel, K.
  • Plant Physiology, Vol. 153, Issue 3, p. 895-905
  • DOI: 10.1104/pp.110.155119