Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Real Time Spectroscopic Ellipsometry Analysis of First Stage CuIn1-xGaxSe2 Growth: Indium-Gallium Selenide Co-Evaporation

Abstract

Real time spectroscopic ellipsometry (RTSE) has been applied for in-situ monitoring of the first stage of copper indium-gallium diselenide (CIGS) thin film deposition by the three-stage co-evaporation process used for fabrication of high efficiency thin film photovoltaic (PV) devices. The first stage entails the growth of indium-gallium selenide (In1-xGax)2Se3 (IGS) on a substrate of Mo-coated soda lime glass maintained at a temperature of 400 °C. This is a critical stage of CIGS deposition because a large fraction of the final film thickness is deposited, and as a result precise compositional control is desired in order to achieve the optimum performance of the resulting CIGS solar cell. RTSE is sensitive to monolayer level film growth processes and can provide accurate measurements of bulk and surface roughness layer thicknesses. These in turn enable accurate measurements of the bulk layer optical response in the form of the complex dielectric function ε = ε1 - iε2, spectra. Here, RTSE has been used to obtain the (ε1, ε2) spectra at the measurement temperature of 400 °C for IGS thin films of different Ga contents (x) deduced from different ranges of accumulated bulk layer thickness during the deposition process. Applying an analytical expression in common formore » each of the (ε1, ε2) spectra of these IGS films, oscillator parameters have been obtained in the best fits and these parameters in turn have been fitted with polynomials in x. From the resulting database of polynomial coefficients, the (ε1, ε2) spectra can be generated for any composition of IGS from the single parameter, x. The results have served as an RTSE fingerprint for IGS composition and have provided further structural information beyond simply thicknesses, for example information related to film density and grain size. The deduced IGS structural evolution and the (ε1, ε2) spectra have been interpreted as well in relation to observations from scanning electron microscopy, X-ray diffractometry and energy-dispersive X-ray spectroscopy profiling analyses. Overall the structural, optical and compositional analysis possible by RTSE has assisted in understanding the growth and properties of three stage CIGS absorbers for solar cells and shows future promise for enhancing cell performance through monitoring and control.« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [1];  [1]
+ Show Author Affiliations
  1. Univ. of Toledo, OH (United States). Wright Center for Photovoltaics Innovation and Commercialization (PVIC) and Dept. of Physics and Astronomy
  2. Old Dominion Univ., Norfolk, VA (United States). Virginia Inst. of Photovoltaics
Publication Date:
Research Org.:
Old Dominion Univ., Norfolk, VA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1510466
Grant/Contract Number:  
EE0005400
Resource Type:
Accepted Manuscript
Journal Name:
Materials
Additional Journal Information:
Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 1996-1944
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; spectroscopic ellipsometry; III2-VI3 semiconductor materials; real time analysis; complex dielectric function; photovoltaic cells; thicknessmeasurement; compositional analysis; CuIn1􀀀xGaxSe2

Citation Formats

Pradhan, Puja, Aryal, Puruswottam, Attygalle, Dinesh, Ibdah, Abdel-Rahman, Koirala, Prakash, Li, Jian, Bhandari, Khagendra, Liyanage, Geethika, Ellingson, Randy, Heben, Michael, Marsillac, Sylvain, Collins, Robert, and Podraza, Nikolas. Real Time Spectroscopic Ellipsometry Analysis of First Stage CuIn1-xGaxSe2 Growth: Indium-Gallium Selenide Co-Evaporation. United States: N. p., 2018. Web. doi:10.3390/ma11010145.
Copy to clipboard
Pradhan, Puja, Aryal, Puruswottam, Attygalle, Dinesh, Ibdah, Abdel-Rahman, Koirala, Prakash, Li, Jian, Bhandari, Khagendra, Liyanage, Geethika, Ellingson, Randy, Heben, Michael, Marsillac, Sylvain, Collins, Robert, & Podraza, Nikolas. Real Time Spectroscopic Ellipsometry Analysis of First Stage CuIn1-xGaxSe2 Growth: Indium-Gallium Selenide Co-Evaporation. United States. https://doi.org/10.3390/ma11010145
Copy to clipboard
Pradhan, Puja, Aryal, Puruswottam, Attygalle, Dinesh, Ibdah, Abdel-Rahman, Koirala, Prakash, Li, Jian, Bhandari, Khagendra, Liyanage, Geethika, Ellingson, Randy, Heben, Michael, Marsillac, Sylvain, Collins, Robert, and Podraza, Nikolas. Tue . "Real Time Spectroscopic Ellipsometry Analysis of First Stage CuIn1-xGaxSe2 Growth: Indium-Gallium Selenide Co-Evaporation". United States. https://doi.org/10.3390/ma11010145. https://www.osti.gov/servlets/purl/1510466.
Copy to clipboard
@article{osti_1510466,
title = {Real Time Spectroscopic Ellipsometry Analysis of First Stage CuIn1-xGaxSe2 Growth: Indium-Gallium Selenide Co-Evaporation},
author = {Pradhan, Puja and Aryal, Puruswottam and Attygalle, Dinesh and Ibdah, Abdel-Rahman and Koirala, Prakash and Li, Jian and Bhandari, Khagendra and Liyanage, Geethika and Ellingson, Randy and Heben, Michael and Marsillac, Sylvain and Collins, Robert and Podraza, Nikolas},
abstractNote = {Real time spectroscopic ellipsometry (RTSE) has been applied for in-situ monitoring of the first stage of copper indium-gallium diselenide (CIGS) thin film deposition by the three-stage co-evaporation process used for fabrication of high efficiency thin film photovoltaic (PV) devices. The first stage entails the growth of indium-gallium selenide (In1-xGax)2Se3 (IGS) on a substrate of Mo-coated soda lime glass maintained at a temperature of 400 °C. This is a critical stage of CIGS deposition because a large fraction of the final film thickness is deposited, and as a result precise compositional control is desired in order to achieve the optimum performance of the resulting CIGS solar cell. RTSE is sensitive to monolayer level film growth processes and can provide accurate measurements of bulk and surface roughness layer thicknesses. These in turn enable accurate measurements of the bulk layer optical response in the form of the complex dielectric function ε = ε1 - iε2, spectra. Here, RTSE has been used to obtain the (ε1, ε2) spectra at the measurement temperature of 400 °C for IGS thin films of different Ga contents (x) deduced from different ranges of accumulated bulk layer thickness during the deposition process. Applying an analytical expression in common for each of the (ε1, ε2) spectra of these IGS films, oscillator parameters have been obtained in the best fits and these parameters in turn have been fitted with polynomials in x. From the resulting database of polynomial coefficients, the (ε1, ε2) spectra can be generated for any composition of IGS from the single parameter, x. The results have served as an RTSE fingerprint for IGS composition and have provided further structural information beyond simply thicknesses, for example information related to film density and grain size. The deduced IGS structural evolution and the (ε1, ε2) spectra have been interpreted as well in relation to observations from scanning electron microscopy, X-ray diffractometry and energy-dispersive X-ray spectroscopy profiling analyses. Overall the structural, optical and compositional analysis possible by RTSE has assisted in understanding the growth and properties of three stage CIGS absorbers for solar cells and shows future promise for enhancing cell performance through monitoring and control.},
doi = {10.3390/ma11010145},
journal = {Materials},
number = 1,
volume = 11,
place = {United States},
year = {Tue Jan 16 00:00:00 EST 2018},
month = {Tue Jan 16 00:00:00 EST 2018}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.3390/ma11010145
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Band-gap engineering in Cu(In,Ga) Se2 thin films grown from (In,Ga)2Se3 precursors
journal, June 1996

Phase Study on Binary System Ga-Se
journal, March 1974

  • Suzuki, Hiromichi; Mori, Ryûichi
  • Japanese Journal of Applied Physics, Vol. 13, Issue 3
  • DOI: 10.1143/JJAP.13.417

Alignment and calibration of the MgF_2 biplate compensator for applications in rotating-compensator multichannel ellipsometry
journal, January 2001

  • Lee, Joungchel; Rovira, P. I.; An, Ilsin
  • Journal of the Optical Society of America A, Vol. 18, Issue 8
  • DOI: 10.1364/JOSAA.18.001980

Optical characterization of continuous compositional gradients in thin films by real time spectroscopic ellipsometry
journal, November 1995

  • Kim, Sangbo; Collins, R. W.
  • Applied Physics Letters, Vol. 67, Issue 20
  • DOI: 10.1063/1.114935

Chemical Vapor Deposition of Indium Selenide and Gallium Selenide Thin Films from Mixed Alkyl/Dialkylselenophosphorylamides
journal, November 2003

  • Park, Jin-Ho; Afzaal, Mohammad; Helliwell, Madeleine
  • Chemistry of Materials, Vol. 15, Issue 22
  • DOI: 10.1021/cm0310420

Optical detection of melting point depression for silver nanoparticles via in situ real time spectroscopic ellipsometry
journal, January 2012

  • Little, S. A.; Begou, T.; Collins, R. W.
  • Applied Physics Letters, Vol. 100, Issue 5
  • DOI: 10.1063/1.3681367

X-ray diffraction study and semiconducting properties of the system Ga2Se3-In2Se3
journal, May 1977

  • Popović, S.; Čelustka, B.; Ružic-Toroš, Ž.
  • Physica Status Solidi (a), Vol. 41, Issue 1
  • DOI: 10.1002/pssa.2210410131

Quantifying the accuracy of ellipsometer systems
journal, May 2008

Correlation of structure parameters of absorber layer with efficiency of Cu(In, Ga)Se2 solar cell
journal, May 2008

In Situ and Ex Situ Investigations of KF Postdeposition Treatment Effects on CIGS Solar Cells
journal, March 2017

New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%
journal, January 2011

  • Jackson, Philip; Hariskos, Dimitrios; Lotter, Erwin
  • Progress in Photovoltaics: Research and Applications, Vol. 19, Issue 7
  • DOI: 10.1002/pip.1078

Perovskite Solar Cells: The Birth of a New Era in Photovoltaics
journal, March 2017

Solar cell efficiency tables (version 47): Solar cell efficiency tables
journal, November 2015

  • Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro
  • Progress in Photovoltaics: Research and Applications, Vol. 24, Issue 1
  • DOI: 10.1002/pip.2728

Crystal structure of Ga0.5In1.5Se3 solid solution
journal, January 2016

High quality baseline for high efficiency, Cu(In1−x,Gax)Se2 solar cells
journal, January 2007

  • Jackson, Philip; Würz, Roland; Rau, Uwe
  • Progress in Photovoltaics: Research and Applications, Vol. 15, Issue 6
  • DOI: 10.1002/pip.757

KF post deposition treatment in co-evaporated Cu(In,Ga)Se 2 thin film solar cells: Beneficial or detrimental effect induced by the absorber characteristics
journal, July 2017

  • Lepetit, Thomas; Harel, Sylvie; Arzel, Ludovic
  • Progress in Photovoltaics: Research and Applications, Vol. 25, Issue 12
  • DOI: 10.1002/pip.2924

In situ determination of dielectric functions and optical gap of ultrathin amorphous silicon by real time spectroscopic ellipsometry
journal, November 1991

  • An, Ilsin; Li, Y. M.; Wronski, C. R.
  • Applied Physics Letters, Vol. 59, Issue 20
  • DOI: 10.1063/1.105947

Monolithic Perovskite-CIGS Tandem Solar Cells via In Situ Band Gap Engineering
journal, September 2015

  • Todorov, Teodor; Gershon, Talia; Gunawan, Oki
  • Advanced Energy Materials, Vol. 5, Issue 23
  • DOI: 10.1002/aenm.201500799

Real-time analysis of the microstructural evolution and optical properties of Cu(In,Ga)Se2 thin films as a function of Cu content
journal, October 2011

  • Ranjan, Vikash; Collins, R. W.; Marsillac, Sylvain
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 6, Issue 1
  • DOI: 10.1002/pssr.201105385

Broadening of optical transitions in polycrystalline CdS and CdTe thin films
journal, November 2010

  • Li, Jian; Chen, Jie; Collins, R. W.
  • Applied Physics Letters, Vol. 97, Issue 18
  • DOI: 10.1063/1.3511744

Real-time spectroscopic ellipsometry studies of the nucleation and grain growth processes in microcrystalline silicon thin films
journal, February 2001

Optical Design of Textured Thin-Film CIGS Solar Cells with Nearly-Invisible Nanowire Assisted Front Contacts
journal, April 2017

  • Deelen, Joop; Omar, Ahmed; Barink, Marco
  • Materials, Vol. 10, Issue 4
  • DOI: 10.3390/ma10040392

Effects of heavy alkali elements in Cu(In,Ga)Se 2 solar cells with efficiencies up to 22.6%
journal, July 2016

  • Jackson, Philip; Wuerz, Roland; Hariskos, Dimitrios
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8
  • DOI: 10.1002/pssr.201600199

Evolution of the optical functions of thin-film aluminum: A real-time spectroscopic ellipsometry study
journal, February 1993

Progress in thin film CIGS photovoltaics - Research and development, manufacturing, and applications: Progress in thin film CIGS photovoltaics
journal, October 2016

  • Feurer, Thomas; Reinhard, Patrick; Avancini, Enrico
  • Progress in Photovoltaics: Research and Applications, Vol. 25, Issue 7
  • DOI: 10.1002/pip.2811

MoSe 2 layer formation at Cu(In,Ga)Se 2/Mo Interfaces in High Efficiency Cu(In1- xGa x)Se 2 Solar Cells
journal, January 1998

  • Nishiwaki, Shiro; Kohara, Naoki; Negami, Takayuki
  • Japanese Journal of Applied Physics, Vol. 37, Issue Part 2, No. 1A/B
  • DOI: 10.1143/JJAP.37.L71

Annihilation of structural defects in chalcogenide absorber films for high-efficiency solar cells
text, January 2016

Device and material characterization of Cu(InGa)Se2 solar cells with increasing band gap
journal, May 1996

  • Shafarman, William N.; Klenk, Reiner; McCandless, Brian E.
  • Journal of Applied Physics, Vol. 79, Issue 9
  • DOI: 10.1063/1.361431

Dielectric function representation by B-splines
journal, April 2008

Correlation of real time spectroellipsometry and atomic force microscopy measurements of surface roughness on amorphous semiconductor thin films
journal, August 1996

  • Koh, Joohyun; Lu, Yiwei; Wronski, C. R.
  • Applied Physics Letters, Vol. 69, Issue 9
  • DOI: 10.1063/1.117397

Theoretical study of Ga 2 Se 3 , Ga 2 Te 3 and Ga 2 ( Se 1 - x Te x ) 3 : Band-gap engineering
journal, June 2014

Real time spectroscopic ellipsometry of Ag/ZnO and Al/ZnO interfaces for back-reflectors in thin film Si:H photovoltaics
journal, February 2011

Review of Progress Toward 20% Efficiency Flexible CIGS Solar Cells and Manufacturing Issues of Solar Modules
journal, January 2013

19·9%-efficient ZnO/CdS/CuInGaSe 2 solar cell with 81·2% fill factor
journal, May 2008

  • Repins, Ingrid; Contreras, Miguel A.; Egaas, Brian
  • Progress in Photovoltaics: Research and Applications, Vol. 16, Issue 3
  • DOI: 10.1002/pip.822

Large-Area Compositional Mapping of Cu(In$_{1-x}$Ga $_{x}$)Se $_{2}$ Materials and Devices with Spectroscopic Ellipsometry
journal, January 2013

Structural and optical characterization of single-phase γ-In2Se3 films with room-temperature photoluminescence
journal, June 2010

Spectroscopic Ellipsometry Studies of n-i-p Hydrogenated Amorphous Silicon Based Photovoltaic Devices
journal, February 2016

  • Karki Gautam, Laxmi; Junda, Maxwell; Haneef, Hamna
  • Materials, Vol. 9, Issue 3
  • DOI: 10.3390/ma9030128

Formation of CuInSe 2 and CuGaSe 2 Thin-Films Deposited by Three-Stage Thermal Co-Evaporation: A Real-Time X-Ray Diffraction and Fluorescence Study
journal, June 2013

  • Rodriguez-Alvarez, Humberto; Weber, Alfons; Lauche, Jakob
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm.201300339

Evolutionary phase diagrams for plasma-enhanced chemical vapor deposition of silicon thin films from hydrogen-diluted silane
journal, October 1999

  • Koh, Joohyun; Ferlauto, A. S.; Rovira, P. I.
  • Applied Physics Letters, Vol. 75, Issue 15
  • DOI: 10.1063/1.124992

Texture and morphology variations in (In,Ga) 2 Se 3 and Cu(In,Ga)Se 2 thin films grown with various Se source conditions : Texture and morphology variations in (In,Ga)
journal, November 2011

  • Ishizuka, Shogo; Yamada, Akimasa; Fons, Paul
  • Progress in Photovoltaics: Research and Applications
  • DOI: 10.1002/pip.1227

Effects of heavy alkali elements in Cu(In,Ga)Se2 solar cells with efficiencies up to 22.6%
text, January 2016

Review of progress toward 20% efficiency flexible CIGS solar cells and manufacturing issues of solar modules
conference, June 2012

  • Reinhard, Patrick; Chirila, Adrian; Blosch, Patrick
  • 2012 IEEE 38th Photovoltaic Specialists Conference (PVSC) PART 2
  • DOI: 10.1109/pvsc-vol2.2012.6656789

Review of progress toward 20% efficiency flexible CIGS solar cells and manufacturing issues of solar modules
conference, June 2013

  • Reinhard, Patrick; Chirila, Adrian; Blosch, Patrick
  • 2012 IEEE 38th Photovoltaic Specialists Conference (PVSC) PART 2
  • DOI: 10.1109/pvsc-vol2.2013.6656789

Formation of CuInSe 2 and CuGaSe 2 Thin-Films Deposited by Three-Stage Thermal Co-Evaporation: A Real-Time X-Ray Diffraction and Fluorescence Study
journal, June 2013

  • Rodriguez-Alvarez, Humberto; Weber, Alfons; Lauche, Jakob
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm.201300339

Monolithic Perovskite-CIGS Tandem Solar Cells via In Situ Band Gap Engineering
journal, September 2015

  • Todorov, Teodor; Gershon, Talia; Gunawan, Oki
  • Advanced Energy Materials, Vol. 5, Issue 23
  • DOI: 10.1002/aenm.201500799

Progress in thin film CIGS photovoltaics - Research and development, manufacturing, and applications: Progress in thin film CIGS photovoltaics
journal, October 2016

  • Feurer, Thomas; Reinhard, Patrick; Avancini, Enrico
  • Progress in Photovoltaics: Research and Applications, Vol. 25, Issue 7
  • DOI: 10.1002/pip.2811

19·9%-efficient ZnO/CdS/CuInGaSe 2 solar cell with 81·2% fill factor
journal, May 2008

  • Repins, Ingrid; Contreras, Miguel A.; Egaas, Brian
  • Progress in Photovoltaics: Research and Applications, Vol. 16, Issue 3
  • DOI: 10.1002/pip.822

Dielectric function representation by B-splines
journal, April 2008

X-ray diffraction study and semiconducting properties of the system Ga2Se3-In2Se3
journal, May 1977

  • Popović, S.; Čelustka, B.; Ružic-Toroš, Ž.
  • Physica Status Solidi (a), Vol. 41, Issue 1
  • DOI: 10.1002/pssa.2210410131

Quantifying the accuracy of ellipsometer systems
journal, May 2008

Real-time analysis of the microstructural evolution and optical properties of Cu(In,Ga)Se2 thin films as a function of Cu content
journal, October 2011

  • Ranjan, Vikash; Collins, R. W.; Marsillac, Sylvain
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 6, Issue 1
  • DOI: 10.1002/pssr.201105385

Effects of heavy alkali elements in Cu(In,Ga)Se 2 solar cells with efficiencies up to 22.6%
journal, July 2016

  • Jackson, Philip; Wuerz, Roland; Hariskos, Dimitrios
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8
  • DOI: 10.1002/pssr.201600199

Correlation of structure parameters of absorber layer with efficiency of Cu(In, Ga)Se2 solar cell
journal, May 2008

Band-gap engineering in Cu(In,Ga) Se2 thin films grown from (In,Ga)2Se3 precursors
journal, June 1996

Theoretical study of Ga 2 Se 3 , Ga 2 Te 3 and Ga 2 ( Se 1 - x Te x ) 3 : Band-gap engineering
journal, June 2014

Real time spectroscopic ellipsometry of Ag/ZnO and Al/ZnO interfaces for back-reflectors in thin film Si:H photovoltaics
journal, February 2011

Influence of the Ga-content on the bulk defect densities of Cu(In,Ga)Se2
journal, May 2001

Perovskite Solar Cells: The Birth of a New Era in Photovoltaics
journal, March 2017

Annihilation of structural defects in chalcogenide absorber films for high-efficiency solar cells
journal, January 2016

  • Mainz, Roland; Simsek Sanli, Ekin; Stange, Helena
  • Energy & Environmental Science, Vol. 9, Issue 5
  • DOI: 10.1039/c6ee00402d

In situ determination of dielectric functions and optical gap of ultrathin amorphous silicon by real time spectroscopic ellipsometry
journal, November 1991

  • An, Ilsin; Li, Y. M.; Wronski, C. R.
  • Applied Physics Letters, Vol. 59, Issue 20
  • DOI: 10.1063/1.105947

Optical characterization of continuous compositional gradients in thin films by real time spectroscopic ellipsometry
journal, November 1995

  • Kim, Sangbo; Collins, R. W.
  • Applied Physics Letters, Vol. 67, Issue 20
  • DOI: 10.1063/1.114935

Correlation of real time spectroellipsometry and atomic force microscopy measurements of surface roughness on amorphous semiconductor thin films
journal, August 1996

  • Koh, Joohyun; Lu, Yiwei; Wronski, C. R.
  • Applied Physics Letters, Vol. 69, Issue 9
  • DOI: 10.1063/1.117397

Evolutionary phase diagrams for plasma-enhanced chemical vapor deposition of silicon thin films from hydrogen-diluted silane
journal, October 1999

  • Koh, Joohyun; Ferlauto, A. S.; Rovira, P. I.
  • Applied Physics Letters, Vol. 75, Issue 15
  • DOI: 10.1063/1.124992

Broadening of optical transitions in polycrystalline CdS and CdTe thin films
journal, November 2010

  • Li, Jian; Chen, Jie; Collins, R. W.
  • Applied Physics Letters, Vol. 97, Issue 18
  • DOI: 10.1063/1.3511744

Device and material characterization of Cu(InGa)Se2 solar cells with increasing band gap
journal, May 1996

  • Shafarman, William N.; Klenk, Reiner; McCandless, Brian E.
  • Journal of Applied Physics, Vol. 79, Issue 9
  • DOI: 10.1063/1.361431

Optical detection of melting point depression for silver nanoparticles via in situ real time spectroscopic ellipsometry
journal, January 2012

  • Little, S. A.; Begou, T.; Collins, R. W.
  • Applied Physics Letters, Vol. 100, Issue 5
  • DOI: 10.1063/1.3681367

Revised and new crystal data for indium selenides
journal, August 1979

  • Popović, S.; Tonejc, A.; Gržeta-Plenković, B.
  • Journal of Applied Crystallography, Vol. 12, Issue 4
  • DOI: 10.1107/s0021889879012863
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: