Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Lattice Strained Ni-Co alloy as a High-Performance Catalyst for Catalytic Dry Reforming of Methane

Abstract

Dry reforming of methane (DRM) is an effective route to convert methane and carbon dioxide to syngas. IN this work, we report an efficient nickel cobalt bimetallic catalyst with an activity of 4.97 molCH4 molNi-1s-1 at 800 °C. It is active at low temperature as well, and near thermodynamic equilibrium conversion was achieved as low as 350 °C, with a high yield of H2 implying inhibition of side reactions: i.e., a reverse water-gas shift (RWGS) reaction. The formation of Ni-Co alloy during the reaction was observed, and its lattice contraction was revealed by HAADF-STEM and EXAFS experiments. The lattice-strained Ni-Co alloy has good CO2 dissociation ability, which is responsible for its superior catalytic performance. Its weak chemisorption with H2 results in inhibition of RWGS side reactions. This research is helpful in the design and development of other metal alloy materials with novel structures and/or electronic configurations for catalytic applications.

Authors:
 [1];  [2];  [3];  [3];  [4];  [5];  [5]; ORCiD logo [6];  [3]; ORCiD logo [4]
+ Show Author Affiliations
  1. Peking Univ., Beijing (China); Chinese Academy of Sciences (CAS), Beijing (China)
  2. Chinese Academy of Sciences (CAS), Beijing (China); Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Chinese Academy of Sciences (CAS), Beijing (China)
  4. Peking Univ., Beijing (China)
  5. Argonne National Lab. (ANL), Lemont, IL (United States)
  6. Univ. of New Haven, West Haven, CT (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
OSTI Identifier:
1510302
Grant/Contract Number:  
AC02-06CH11357; 2017YFB0602200
Resource Type:
Accepted Manuscript
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Volume: 9; Journal Issue: 4; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Ni-Co alloy; activity; dry reforming; lattice contraction; methane

Citation Formats

Wu, Zhaoxuan, Yang, Bing, Miao, Shu, Liu, Wei, Xie, Jinglin, Lee, Sungsik, Pellin, Michael J., Xiao, Dequan, Su, Dangsheng, and Ma, Ding. Lattice Strained Ni-Co alloy as a High-Performance Catalyst for Catalytic Dry Reforming of Methane. United States: N. p., 2019. Web. doi:10.1021/acscatal.8b02821.
Copy to clipboard
Wu, Zhaoxuan, Yang, Bing, Miao, Shu, Liu, Wei, Xie, Jinglin, Lee, Sungsik, Pellin, Michael J., Xiao, Dequan, Su, Dangsheng, & Ma, Ding. Lattice Strained Ni-Co alloy as a High-Performance Catalyst for Catalytic Dry Reforming of Methane. United States. https://doi.org/10.1021/acscatal.8b02821
Copy to clipboard
Wu, Zhaoxuan, Yang, Bing, Miao, Shu, Liu, Wei, Xie, Jinglin, Lee, Sungsik, Pellin, Michael J., Xiao, Dequan, Su, Dangsheng, and Ma, Ding. Fri . "Lattice Strained Ni-Co alloy as a High-Performance Catalyst for Catalytic Dry Reforming of Methane". United States. https://doi.org/10.1021/acscatal.8b02821. https://www.osti.gov/servlets/purl/1510302.
Copy to clipboard
@article{osti_1510302,
title = {Lattice Strained Ni-Co alloy as a High-Performance Catalyst for Catalytic Dry Reforming of Methane},
author = {Wu, Zhaoxuan and Yang, Bing and Miao, Shu and Liu, Wei and Xie, Jinglin and Lee, Sungsik and Pellin, Michael J. and Xiao, Dequan and Su, Dangsheng and Ma, Ding},
abstractNote = {Dry reforming of methane (DRM) is an effective route to convert methane and carbon dioxide to syngas. IN this work, we report an efficient nickel cobalt bimetallic catalyst with an activity of 4.97 molCH4 molNi-1s-1 at 800 °C. It is active at low temperature as well, and near thermodynamic equilibrium conversion was achieved as low as 350 °C, with a high yield of H2 implying inhibition of side reactions: i.e., a reverse water-gas shift (RWGS) reaction. The formation of Ni-Co alloy during the reaction was observed, and its lattice contraction was revealed by HAADF-STEM and EXAFS experiments. The lattice-strained Ni-Co alloy has good CO2 dissociation ability, which is responsible for its superior catalytic performance. Its weak chemisorption with H2 results in inhibition of RWGS side reactions. This research is helpful in the design and development of other metal alloy materials with novel structures and/or electronic configurations for catalytic applications.},
doi = {10.1021/acscatal.8b02821},
journal = {ACS Catalysis},
number = 4,
volume = 9,
place = {United States},
year = {Fri Jan 04 00:00:00 EST 2019},
month = {Fri Jan 04 00:00:00 EST 2019}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscatal.8b02821
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 67 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Reaction engineering investigations of CO2 reforming in a fluidized-bed reactor
journal, September 2000

Design and Synthesis of Copper-Cobalt Catalysts for the Selective Conversion of Synthesis Gas to Ethanol and Higher Alcohols
journal, May 2014

  • Prieto, Gonzalo; Beijer, Steven; Smith, Miranda L.
  • Angewandte Chemie International Edition, Vol. 53, Issue 25
  • DOI: 10.1002/anie.201402680

Dry reforming of methane has no future for hydrogen production: Comparison with steam reforming at high pressure in standard and membrane reactors
journal, July 2012

Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins
journal, February 2012

  • Torres Galvis, H. M.; Bitter, J. H.; Khare, C. B.
  • Science, Vol. 335, Issue 6070, p. 835-838
  • DOI: 10.1126/science.1215614

Recent progress in the electrochemical conversion and utilization of CO2
journal, January 2012

  • Spinner, Neil S.; Vega, Jose A.; Mustain, William E.
  • Catal. Sci. Technol., Vol. 2, Issue 1
  • DOI: 10.1039/C1CY00314C

Worldwide innovations in the development of carbon capture technologies and the utilization of CO2
journal, January 2012

  • Markewitz, Peter; Kuckshinrichs, Wilhelm; Leitner, Walter
  • Energy & Environmental Science, Vol. 5, Issue 6
  • DOI: 10.1039/c2ee03403d

The Li–CO2 battery: a novel method for CO2 capture and utilization
journal, January 2013

  • Xu, Shaomao; Das, Shyamal K.; Archer, Lynden A.
  • RSC Advances, Vol. 3, Issue 18
  • DOI: 10.1039/c3ra40394g

Photocatalytic Conversion of CO 2 to Hydrocarbon Fuels via Plasmon-Enhanced Absorption and Metallic Interband Transitions
journal, July 2011

  • Hou, Wenbo; Hung, Wei Hsuan; Pavaskar, Prathamesh
  • ACS Catalysis, Vol. 1, Issue 8
  • DOI: 10.1021/cs2001434

Photocatalytic reduction of CO2 on Cu2O-loaded Zn-Cr layered double hydroxides
journal, May 2018

Photocatalytic CO 2 Reduction by Mesoporous Polymeric Carbon Nitride Photocatalysts
journal, August 2018

  • Tasbihi, Minoo; Acharjya, Amitava; Thomas, Arne
  • Journal of Nanoscience and Nanotechnology, Vol. 18, Issue 8
  • DOI: 10.1166/jnn.2018.15445

Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen
journal, May 2014

Ni-based catalysts for reforming of methane with CO2
journal, November 2012

Co and Ni supported on CeO2 as selective bimetallic catalyst for dry reforming of methane
journal, November 2012

  • Luisetto, Igor; Tuti, Simonetta; Di Bartolomeo, Elisabetta
  • International Journal of Hydrogen Energy, Vol. 37, Issue 21
  • DOI: 10.1016/j.ijhydene.2012.08.006

Stable low-temperature dry reforming of methane over mesoporous La2O3-ZrO2 supported Ni catalyst
journal, February 2012

  • Sokolov, Sergey; Kondratenko, Evgenii V.; Pohl, Marga-Martina
  • Applied Catalysis B: Environmental, Vol. 113-114
  • DOI: 10.1016/j.apcatb.2011.09.035

Particle size effect in the low temperature reforming of methane by carbon dioxide on silica-supported Ni nanoparticles
journal, January 2013

Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO 2 to CO
journal, May 2014

  • Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal
  • Angewandte Chemie International Edition, Vol. 53, Issue 26
  • DOI: 10.1002/anie.201404109

Titania-supported cobalt and nickel bimetallic catalysts for carbon dioxide reforming of methane
journal, June 2005

A solar thermochemical pipe based on the CO2CH4 (1:1) system
journal, January 1986

Dry reforming of methane: Influence of process parameters—A review
journal, May 2015

  • Usman, Muhammad; Wan Daud, W. M. A.; Abbas, Hazzim F.
  • Renewable and Sustainable Energy Reviews, Vol. 45
  • DOI: 10.1016/j.rser.2015.02.026

Population and hierarchy of active species in gold iron oxide catalysts for carbon monoxide oxidation
journal, September 2016

  • He, Qian; Freakley, Simon J.; Edwards, Jennifer K.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12905

Effects of metal content on activity and stability of Ni-Co bimetallic catalysts for CO2 reforming of CH4
journal, May 2008

Development of stable bimetallic catalysts for carbon dioxide reforming of methane
journal, July 2007

Coprecipitated Ni-Co Bimetallic Nanocatalysts for Methane Dry Reforming
journal, May 2014

  • Mirzaei, Fateme; Rezaei, Mehran; Meshkani, Fereshsteh
  • Chemical Engineering & Technology, Vol. 37, Issue 6
  • DOI: 10.1002/ceat.201300729

Ni stabilised on inorganic complex structures: superior catalysts for chemical CO2 recycling via dry reforming of methane
journal, November 2018

Characterization of alumina-supported Pt, Ni and PtNi alloy catalysts for the dry reforming of methane
journal, August 2010

  • García-Diéguez, Mónica; Finocchio, Elisabetta; Larrubia, María Ángeles
  • Journal of Catalysis, Vol. 274, Issue 1
  • DOI: 10.1016/j.jcat.2010.05.020

Ni, Co and bimetallic Ni–Co catalysts for the dry reforming of methane
journal, December 2009

  • San-José-Alonso, D.; Juan-Juan, J.; Illán-Gómez, M. J.
  • Applied Catalysis A: General, Vol. 371, Issue 1-2
  • DOI: 10.1016/j.apcata.2009.09.026

Highly Coke-Resistant Ni Nanoparticle Catalysts with Minimal Sintering in Dry Reforming of Methane
journal, January 2014

A highly dispersed and anti-coking Ni–La2O3/SiO2 catalyst for syngas production from dry carbon dioxide reforming of methane
journal, January 2014

  • Mo, Liuye; Leong, Kerina Kai Mun; Kawi, Sibudjing
  • Catalysis Science & Technology, Vol. 4, Issue 7
  • DOI: 10.1039/c3cy00869j
    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Effects of alumina morphology on dry reforming of methane over Ni/Al 2 O 3 catalysts
    journal, January 2020

    • Shen, Dongyang; Huo, Miaomiao; Li, Lin
    • Catalysis Science & Technology, Vol. 10, Issue 2
    • DOI: 10.1039/c9cy02093d
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: