skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]
  1. Department of ChemistryThe George Washington University Washington D.C. 20052 USA, Chemical Sciences DivisionLawrence Berkeley National Laboratory Berkeley CA 94720 USA
  2. Department of ChemistryThe George Washington University Washington D.C. 20052 USA
  3. Department of ChemistryThe George Washington University Washington D.C. 20052 USA, Department of Chemistry and BiochemistryUniversity of California San Diego, La Jolla CA 92093 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1510096
Grant/Contract Number:  
FG02-05ER15736
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Name: Chemistry - A European Journal Journal Volume: 25 Journal Issue: 29; Journal ID: ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Carter, Korey P., Ridenour, J. August, Kalaj, Mark, and Cahill, Christopher L. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability. Germany: N. p., 2019. Web. doi:10.1002/chem.201901610.
Carter, Korey P., Ridenour, J. August, Kalaj, Mark, & Cahill, Christopher L. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability. Germany. doi:10.1002/chem.201901610.
Carter, Korey P., Ridenour, J. August, Kalaj, Mark, and Cahill, Christopher L. Tue . "A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability". Germany. doi:10.1002/chem.201901610.
@article{osti_1510096,
title = {A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability},
author = {Carter, Korey P. and Ridenour, J. August and Kalaj, Mark and Cahill, Christopher L.},
abstractNote = {},
doi = {10.1002/chem.201901610},
journal = {Chemistry - A European Journal},
number = 29,
volume = 25,
place = {Germany},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/chem.201901610

Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Iodine Adsorption in Metal Organic Frameworks in the Presence of Humidity
journal, March 2018

  • Banerjee, Debasis; Chen, Xianyin; Lobanov, Sergey S.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 13
  • DOI: 10.1021/acsami.8b02651

[(Th 2 F 5 )(NC 7 H 5 O 4 ) 2 (H 2 O)][NO 3 ]:  An Actinide−Organic Open Framework
journal, October 2003

  • Kim, Jong-Young; Norquist, Alexander J.; O'Hare, Dermot
  • Journal of the American Chemical Society, Vol. 125, Issue 42
  • DOI: 10.1021/ja036832p

Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products
journal, October 2012

  • Knope, Karah E.; Soderholm, L.
  • Chemical Reviews, Vol. 113, Issue 2
  • DOI: 10.1021/cr300212f

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018


Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers
journal, January 2016

  • Martin, Nicolas P.; Volkringer, Christophe; Falaise, Clément
  • Crystal Growth & Design, Vol. 16, Issue 3
  • DOI: 10.1021/acs.cgd.5b01746

Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth
journal, June 2009

  • Tsuruoka, Takaaki; Furukawa, Shuhei; Takashima, Yohei
  • Angewandte Chemie, Vol. 121, Issue 26
  • DOI: 10.1002/ange.200901177

Adsorption-based atmospheric water harvesting device for arid climates
journal, March 2018


Exploration of porous metal–organic frameworks for gas separation and purification
journal, January 2019


Surface-Functionalization of Zr-Fumarate MOF for Selective Cytotoxicity and Immune System Compatibility in Nanoscale Drug Delivery
journal, August 2018

  • Abánades Lázaro, Isabel; Haddad, Salame; Rodrigo-Muñoz, Jose M.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 37
  • DOI: 10.1021/acsami.8b11652

Homo- and heterometallic coordination polymers from the f elements
journal, January 2007

  • Cahill, Christopher L.; de Lill, Daniel T.; Frisch, Mark
  • CrystEngComm, Vol. 9, Issue 1
  • DOI: 10.1039/B615696G

Lanthanide metal–organic frameworks based on the 4,4′-oxybisbenzoic acid ligand: synthesis, structures and physical properties
journal, January 2015

  • Li, Yun; Wang, Ning; Xiong, Yan-Ju
  • New Journal of Chemistry, Vol. 39, Issue 12
  • DOI: 10.1039/C5NJ01930C

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

  • Carboni, Michaël; Abney, Carter W.; Liu, Shubin
  • Chemical Science, Vol. 4, Issue 6, p. 2396-2402
  • DOI: 10.1039/c3sc50230a

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments
journal, January 2015

  • Li, Yuxiang; Weng, Zhehui; Wang, Yanlong
  • Dalton Transactions, Vol. 44, Issue 48
  • DOI: 10.1039/C5DT03363B

Solution Thermodynamics and Kinetics of Metal Complexation with a Hydroxypyridinone Chelator Designed for Thorium-227 Targeted Alpha Therapy
journal, October 2018


Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth
journal, June 2009

  • Tsuruoka, Takaaki; Furukawa, Shuhei; Takashima, Yohei
  • Angewandte Chemie International Edition, Vol. 48, Issue 26
  • DOI: 10.1002/anie.200901177

Synthesis and Characterization of a Praseodymium–Adipate Framework Templated with 1,2-bis(4-Pyridyl)ethane: Host–Guest Interactions and Structural Survey
journal, December 2007

  • Lill, Daniel T. de; Cahill, Christopher L.
  • Crystal Growth & Design, Vol. 7, Issue 12
  • DOI: 10.1021/cg700741v

Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
journal, May 2014

  • Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K.
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja5006866

Employing an Unsaturated Th 4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation
journal, April 2018


Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery
journal, October 2011

  • Della Rocca, Joseph; Liu, Demin; Lin, Wenbin
  • Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968
  • DOI: 10.1021/ar200028a

Thorium coordination: A comprehensive review based on coordination number
journal, February 2017


Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF
journal, October 2018

  • Andreo, Jacopo; Priola, Emanuele; Alberto, Gabriele
  • Journal of the American Chemical Society, Vol. 140, Issue 43
  • DOI: 10.1021/jacs.8b07113

Restricted Speciation and Supramolecular Assembly in the 5f Block
journal, July 2018

  • Carter, Korey P.; Surbella, Robert G.; Kalaj, Mark
  • Chemistry - A European Journal, Vol. 24, Issue 49
  • DOI: 10.1002/chem.201801044

Metal–organic and covalent organic frameworks as single-site catalysts
journal, January 2017

  • Rogge, S. M. J.; Bavykina, A.; Hajek, J.
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C7CS00033B

Metal–organic frameworks for membrane-based separations
journal, November 2016


Capture of iodine in highly stable metal–organic frameworks: a systematic study
journal, January 2013

  • Falaise, Clément; Volkringer, Christophe; Facqueur, Jacques
  • Chemical Communications, Vol. 49, Issue 87
  • DOI: 10.1039/c3cc43728k

Redox and environmentally relevant aspects of actinide(IV) coordination chemistry
journal, May 2014

  • Natrajan, Louise S.; Swinburne, Adam N.; Andrews, Michael B.
  • Coordination Chemistry Reviews, Vol. 266-267
  • DOI: 10.1016/j.ccr.2013.12.021

Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework
journal, February 2019


Hydrolysis of thorium( iv ) at variable temperatures
journal, January 2016

  • Zanonato, P. L.; Di Bernardo, P.; Zhang, Z.
  • Dalton Transactions, Vol. 45, Issue 32
  • DOI: 10.1039/C6DT01868H

Applications of metal–organic frameworks in heterogeneous supramolecular catalysis
journal, January 2014

  • Liu, Jiewei; Chen, Lianfen; Cui, Hao
  • Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061
  • DOI: 10.1039/C4CS00094C

Acid-Resistant Mesoporous Metal–Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release
journal, April 2018

  • Chen, Yijing; Li, Peng; Modica, Justin A.
  • Journal of the American Chemical Society, Vol. 140, Issue 17
  • DOI: 10.1021/jacs.8b02089

Actinide-based MOFs: a middle ground in solution and solid-state structural motifs
journal, January 2018

  • Dolgopolova, Ekaterina A.; Rice, Allison M.; Shustova, Natalia B.
  • Chemical Communications, Vol. 54, Issue 50
  • DOI: 10.1039/C7CC09780H

Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective
journal, June 2018


Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle
journal, November 2013

  • Li, Mian; Li, Dan; O’Keeffe, Michael
  • Chemical Reviews, Vol. 114, Issue 2
  • DOI: 10.1021/cr400392k

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H 2 O System
journal, February 2015

  • Falaise, Clément; Charles, Jean-Sébastien; Volkringer, Christophe
  • Inorganic Chemistry, Vol. 54, Issue 5
  • DOI: 10.1021/ic502725y

Topos: Program package for topological analysis of crystal structures
journal, January 1994

  • Blatov, V. A.; Shevchenko, A. P.; Serezhkin, V. N.
  • Journal of Structural Chemistry, Vol. 34, Issue 5
  • DOI: 10.1007/BF00753587

A Series of Lanthanide-Based Metal–Organic Frameworks: Synthesis, Structures, and Multicolor Tuning of Single Component
journal, February 2017


A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Single-crystal structure validation with the program PLATON
journal, January 2003


Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks
journal, November 2017

  • Dolgopolova, Ekaterina A.; Ejegbavwo, Otega A.; Martin, Corey R.
  • Journal of the American Chemical Society, Vol. 139, Issue 46
  • DOI: 10.1021/jacs.7b09496

Thorium Oxo‐Clusters as Building Blocks for Open Frameworks
journal, August 2018

  • Falaise, Clément; Kozma, Karoly; Nyman, May
  • Chemistry – A European Journal, Vol. 24, Issue 53
  • DOI: 10.1002/chem.201802671

Metal–organic framework with optimally selective xenon adsorption and separation
journal, June 2016

  • Banerjee, Debasis; Simon, Cory M.; Plonka, Anna M.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11831

Employing an Unsaturated Th 4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation
journal, April 2018

  • Wang, Yanlong; Liu, Wei; Bai, Zhuanling
  • Angewandte Chemie International Edition, Vol. 57, Issue 20
  • DOI: 10.1002/anie.201802173

A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants
journal, November 2017


TOF-2:  A Large 1D Channel Thorium Organic Framework
journal, March 2008

  • Ok, Kang Min; Sung, Jaeyoung; Hu, Gang
  • Journal of the American Chemical Society, Vol. 130, Issue 12
  • DOI: 10.1021/ja800395q