161Dy Time-Domain Synchrotron Mössbauer Spectroscopy for Investigating Single-Molecule Magnets Incorporating Dy Ions [161Dy time-domain synchrotron Mössbauer spectroscopy as a new way forward for investigating single molecule magnets incorporating Dy ions]
Abstract
Abstract Time‐domain synchrotron Mössbauer spectroscopy (SMS) based on the Mössbauer effect of 161 Dy has been used to investigate the magnetic properties of a Dy III ‐based single‐molecule magnet (SMM). The magnetic hyperfine field of [Dy(Cy 3 PO) 2 (H 2 O) 5 ]Br 3 ⋅2 (Cy 3 PO)⋅2 H 2 O⋅2 EtOH is with B 0 =582.3(5) T significantly larger than that of the free‐ion Dy III with a 6 H 15/2 ground state. This difference is attributed to the influence of the coordinating ligands on the Fermi contact interaction between the s and 4f electrons of the Dy III ion. This study demonstrates that 161 Dy SMS is an effective local probe of the influence of the coordinating ligands on the magnetic structure of Dy‐containing compounds.
- Authors:
-
[1];
[1];
[4];
[1]
- Technische Univ. Kaiserslautern, Kaiserslautern (Germany)
- Karlsruhe Inst. of Technology, Karlsruhe (Germany)
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Northern Illinois Univ., DeKalb, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); German Research Foundation (DFG)
- OSTI Identifier:
- 1510086
- Alternate Identifier(s):
- OSTI ID: 1490114
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 11; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; dysprosium; lanthanides; magnetic properties; Mössbauer spectroscopy; single-molecule magnets
Citation Formats
Scherthan, Lena, Schmidt, Sebastian F. M., Auerbach, Hendrik, Hochdörffer, Tim, Wolny, Juliusz A., Bi, Wenli, Zhao, Jiyong, Hu, Michael Y., Toellner, Tom, Alp, E. Ercan, Brown, Dennis E., Anson, Christopher E., Powell, Annie K., and Schünemann, Volker. 161Dy Time-Domain Synchrotron Mössbauer Spectroscopy for Investigating Single-Molecule Magnets Incorporating Dy Ions [161Dy time-domain synchrotron Mössbauer spectroscopy as a new way forward for investigating single molecule magnets incorporating Dy ions]. United States: N. p., 2018.
Web. doi:10.1002/anie.201810505.
Scherthan, Lena, Schmidt, Sebastian F. M., Auerbach, Hendrik, Hochdörffer, Tim, Wolny, Juliusz A., Bi, Wenli, Zhao, Jiyong, Hu, Michael Y., Toellner, Tom, Alp, E. Ercan, Brown, Dennis E., Anson, Christopher E., Powell, Annie K., & Schünemann, Volker. 161Dy Time-Domain Synchrotron Mössbauer Spectroscopy for Investigating Single-Molecule Magnets Incorporating Dy Ions [161Dy time-domain synchrotron Mössbauer spectroscopy as a new way forward for investigating single molecule magnets incorporating Dy ions]. United States. https://doi.org/10.1002/anie.201810505
Scherthan, Lena, Schmidt, Sebastian F. M., Auerbach, Hendrik, Hochdörffer, Tim, Wolny, Juliusz A., Bi, Wenli, Zhao, Jiyong, Hu, Michael Y., Toellner, Tom, Alp, E. Ercan, Brown, Dennis E., Anson, Christopher E., Powell, Annie K., and Schünemann, Volker. Wed .
"161Dy Time-Domain Synchrotron Mössbauer Spectroscopy for Investigating Single-Molecule Magnets Incorporating Dy Ions [161Dy time-domain synchrotron Mössbauer spectroscopy as a new way forward for investigating single molecule magnets incorporating Dy ions]". United States. https://doi.org/10.1002/anie.201810505. https://www.osti.gov/servlets/purl/1510086.
@article{osti_1510086,
title = {161Dy Time-Domain Synchrotron Mössbauer Spectroscopy for Investigating Single-Molecule Magnets Incorporating Dy Ions [161Dy time-domain synchrotron Mössbauer spectroscopy as a new way forward for investigating single molecule magnets incorporating Dy ions]},
author = {Scherthan, Lena and Schmidt, Sebastian F. M. and Auerbach, Hendrik and Hochdörffer, Tim and Wolny, Juliusz A. and Bi, Wenli and Zhao, Jiyong and Hu, Michael Y. and Toellner, Tom and Alp, E. Ercan and Brown, Dennis E. and Anson, Christopher E. and Powell, Annie K. and Schünemann, Volker},
abstractNote = {Abstract Time‐domain synchrotron Mössbauer spectroscopy (SMS) based on the Mössbauer effect of 161 Dy has been used to investigate the magnetic properties of a Dy III ‐based single‐molecule magnet (SMM). The magnetic hyperfine field of [Dy(Cy 3 PO) 2 (H 2 O) 5 ]Br 3 ⋅2 (Cy 3 PO)⋅2 H 2 O⋅2 EtOH is with B 0 =582.3(5) T significantly larger than that of the free‐ion Dy III with a 6 H 15/2 ground state. This difference is attributed to the influence of the coordinating ligands on the Fermi contact interaction between the s and 4f electrons of the Dy III ion. This study demonstrates that 161 Dy SMS is an effective local probe of the influence of the coordinating ligands on the magnetic structure of Dy‐containing compounds.},
doi = {10.1002/anie.201810505},
journal = {Angewandte Chemie (International Edition)},
number = 11,
volume = 58,
place = {United States},
year = {Wed Dec 12 00:00:00 EST 2018},
month = {Wed Dec 12 00:00:00 EST 2018}
}
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