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Title: Universality in size-driven evolution towards bulk polarizability of metals

Abstract

The properties and characteristics of materials on the subnano/nano scale are very different from those of their bulk counterparts. The evolution of materials properties with size is the holy grail of nanoscience. An intriguing question then is: Can one predict what type of material (metal, semiconductor or insulator) an unidentified element will be, when in bulk quantities, solely from the properties it exhibits over a limited range of the subnano/nano size-regime? We demonstrate here that for nominally metallic elements (i.e., elements that are metals in bulk quantities) the answer to this question is "yes", and the very identity of the element also can be established. Most importantly, we show that the phenomenon of size-induced transition to metallicity, as gauged by polarizability, is characterized by features and trends that are universal for all metals. Combining numerical simulation data with an analytical model we introduce a universal constant and derive equations that express the universality explicitly.

Authors:
;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science - Office of Basic Energy Sciences - Chemical Sciences, Geosciences, and Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1510021
Alternate Identifier(s):
OSTI ID: 1471250
Grant/Contract Number:  
AC02-06CH11357; SC0001330
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 10; Journal Issue: 37
Country of Publication:
United States
Language:
English
Subject:
nanoscale materials; polarizability; size-driven transition to metallicity; universality

Citation Formats

Jellinek, Julius, and Jackson, Koblar. Universality in size-driven evolution towards bulk polarizability of metals. United States: N. p., 2018. Web. doi:10.1039/c8nr06307a.
Jellinek, Julius, & Jackson, Koblar. Universality in size-driven evolution towards bulk polarizability of metals. United States. doi:10.1039/c8nr06307a.
Jellinek, Julius, and Jackson, Koblar. Sun . "Universality in size-driven evolution towards bulk polarizability of metals". United States. doi:10.1039/c8nr06307a. https://www.osti.gov/servlets/purl/1510021.
@article{osti_1510021,
title = {Universality in size-driven evolution towards bulk polarizability of metals},
author = {Jellinek, Julius and Jackson, Koblar},
abstractNote = {The properties and characteristics of materials on the subnano/nano scale are very different from those of their bulk counterparts. The evolution of materials properties with size is the holy grail of nanoscience. An intriguing question then is: Can one predict what type of material (metal, semiconductor or insulator) an unidentified element will be, when in bulk quantities, solely from the properties it exhibits over a limited range of the subnano/nano size-regime? We demonstrate here that for nominally metallic elements (i.e., elements that are metals in bulk quantities) the answer to this question is "yes", and the very identity of the element also can be established. Most importantly, we show that the phenomenon of size-induced transition to metallicity, as gauged by polarizability, is characterized by features and trends that are universal for all metals. Combining numerical simulation data with an analytical model we introduce a universal constant and derive equations that express the universality explicitly.},
doi = {10.1039/c8nr06307a},
journal = {Nanoscale},
number = 37,
volume = 10,
place = {United States},
year = {2018},
month = {10}
}

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