Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid

Denk, Christoph; Foraita, Sebastian; Kovarik, Libor; Stoerzinger, Kelsey; Liu, Yue; Baráth, Eszter; Lercher, Johannes A.

doi:10.1039/C9CY00181F

Title: Rate enhancement by Cu in Ni _x Cu _1−x /ZrO ₂ bimetallic catalysts for hydrodeoxygenation of stearic acid

Abstract

The combination of Cu and Ni in bimetallic catalysts on ZrO ₂ , leads to a more efficient HDO of stearic acid.

Authors:

Denk, Christoph ^[1]; Foraita, Sebastian ^[1]; Kovarik, Libor ^[2];

^[3];

^[1];

^[1]; Lercher, Johannes A. ^[4]

Department of Chemistry and Catalysis Research Center, Technische Universität München, 85747 Garching, Germany
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, USA, Environmental Molecular Sciences Laboratory
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, USA, Physical and Computational Sciences Directorate
Department of Chemistry and Catalysis Research Center, Technische Universität München, 85747 Garching, Germany, Institute for Integrated Catalysis

Publication Date:: 2019-05-20

Sponsoring Org.:: USDOE

OSTI Identifier:: 1509930

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Catalysis Science and Technology

Additional Journal Information:: Journal Name: Catalysis Science and Technology Journal Volume: 9 Journal Issue: 10; Journal ID: ISSN 2044-4753

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Denk, Christoph, Foraita, Sebastian, Kovarik, Libor, Stoerzinger, Kelsey, Liu, Yue, Baráth, Eszter, and Lercher, Johannes A. Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9CY00181F.

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                    Denk, Christoph, Foraita, Sebastian, Kovarik, Libor, Stoerzinger, Kelsey, Liu, Yue, Baráth, Eszter, & Lercher, Johannes A. Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid.  United Kingdom.  https://doi.org/10.1039/C9CY00181F

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                    Denk, Christoph, Foraita, Sebastian, Kovarik, Libor, Stoerzinger, Kelsey, Liu, Yue, Baráth, Eszter, and Lercher, Johannes A. Mon .  
"Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid".  United Kingdom.  https://doi.org/10.1039/C9CY00181F.

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@article{osti_1509930,

  title        = {Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid},

  author       = {Denk, Christoph and Foraita, Sebastian and Kovarik, Libor and Stoerzinger, Kelsey and Liu, Yue and Baráth, Eszter and Lercher, Johannes A.},

  abstractNote = {The combination of Cu and Ni in bimetallic catalysts on ZrO 2 , leads to a more efficient HDO of stearic acid.},

  doi          = {10.1039/C9CY00181F},

  journal      = {Catalysis Science and Technology},

  number       = 10,

  volume       = 9,

  place        = {United Kingdom},

  year         = {2019},

  month        = {5}

}

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Title: Rate enhancement by Cu in Ni x Cu 1−x /ZrO 2 bimetallic catalysts for hydrodeoxygenation of stearic acid

Abstract

Citation Formats

A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis journal, March 2015

Stabilizing Catalytic Pathways via Redundancy: Selective Reduction of Microalgae Oil to Alkanes journal, May 2012

Synthesis of alcohols and diols by hydrogenation of carboxylic acids and esters over Ru–Sn–Al2O3 catalysts journal, December 1999

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The influence of d-band structure on stacking-fault energy journal, August 1966

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The Catalytic Hydrogenolysis of Esters to Alcohols journal, November 1994

High Performances of Pt/ZnO Catalysts in Selective Hydrogenation of Crotonaldehyde journal, November 1999

Impact of the Oxygen Defects and the Hydrogen Concentration on the Surface of Tetragonal and Monoclinic ZrO 2 on the Reduction Rates of Stearic Acid on Ni/ZrO 2 journal, December 2014

Adsorption of CO and NO on surface studied by infrared-visible sum frequency generation spectroscopy journal, October 1997

Catalytic reaction pathways in liquid-phase deoxygenation of C18 free fatty acids journal, February 2010

Surface and catalytic properties of ZrO2 journal, September 1985

The formation of ketones and aldehydes from carboxylic acids, structure-activity relationship for two competitive reactions journal, November 1995

Production of Biofuel Additives from Esterification and Acetalization of Bioglycerol over SnO 2 -Based Solid Acids journal, March 2014

Development of a process for refining rape seed oil into biodiesel and high-cetane components of diesel fuel journal, May 2010

Supported iron nanoparticles for the hydrodeoxygenation of microalgal oil to green diesel journal, May 2014

Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons journal, May 2008

Bimetallic Ni–Cu catalyst supported on CeO2 for high-temperature water–gas shift reaction: Methane suppression via enhanced CO adsorption journal, May 2014

Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst journal, December 2014

Palladium-based alloy and monometallic catalysts for gas phase hydrogenation of crotonaldehyde: effects of alloying and alloy crystallite size journal, April 2005

Facile Synthesis of Pure Monoclinic and Tetragonal Zirconia Nanoparticles and Their Phase Effects on the Behavior of Supported Molybdena Catalysts for Methanol-Selective Oxidation journal, August 2008

Selective hydrogenation of fatty acids to alcohols over highly dispersed ReO /TiO2 catalyst journal, August 2015

Tungsten-Based Catalysts for Selective Deoxygenation journal, April 2013

Reactions of Carboxylic Acids on Oxides journal, June 1997

Reactions of Carboxylic Acids on Oxides journal, June 1997

Bulk and Surface Properties of Copper-Containing Oxides of the General Formula LaZr1-xCuxO3 journal, February 1994

Catalytic deoxygenation of microalgae oil to green hydrocarbons journal, January 2013

Chemistry of Catalytic Hydrodeoxygenation journal, August 1983

Bifunctional Adsorbent-Catalytic Nanoparticles for the Refining of Renewable Feedstocks journal, November 2013

Comparison of Tungsten and Molybdenum Carbide Catalysts for the Hydrodeoxygenation of Oleic Acid journal, November 2013

Selectivity of Ni$z.sbnd;Cu and Pt$z.sbnd;Au alloys in reactions of butanol and related compounds journal, September 1978

On electronic and geometric effects of alloying An infrared spectroscopic investigation of the adsorption of carbon monoxide on platinum-copper alloys journal, July 1983

Effect of the Ni/Cu ratio on the composition and catalytic properties of nickel-copper alloy in anisole hydrodeoxygenation journal, January 2014

Towards Quantitative Conversion of Microalgae Oil to Diesel-Range Alkanes with Bifunctional Catalysts journal, November 2011

Surface composition and catalysis on alloys journal, February 1979

Interaction of Carbon Dioxide with the Surface of Zirconia Polymorphs journal, June 1998

Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts journal, January 2014

Controlling Hydrodeoxygenation of Stearic Acid to n -Heptadecane and n -Octadecane by Adjusting the Chemical Properties of Ni/SiO 2 -ZrO 2 Catalyst journal, November 2016

Effect of the reduction treatment on the structure and reactivity of silica-supported copper particles journal, September 1991

Influence of Mo on catalytic activity of Ni-based catalysts in hydrodeoxygenation of esters journal, February 2015

A Quantitative Scale of Oxophilicity and Thiophilicity journal, August 2016

Synergistic Interaction between Oxides of Copper and Iron for Production of Fatty Alcohols from Fatty Acids journal, October 2015

Bimetallic catalysts for upgrading of biomass to fuels and chemicals journal, January 2012

Title: Rate enhancement by Cu in Ni _x Cu _1−x /ZrO ₂ bimetallic catalysts for hydrodeoxygenation of stearic acid

A Study on the Oxygen Vacancies in ZnPd/ZnO-Al and their Promoting Role in Glycerol Hydrogenolysis
journal, March 2015

Stabilizing Catalytic Pathways via Redundancy: Selective Reduction of Microalgae Oil to Alkanes
journal, May 2012

Synthesis of alcohols and diols by hydrogenation of carboxylic acids and esters over Ru–Sn–Al2O3 catalysts
journal, December 1999

A comparison of surface acidic features between tetragonal and monoclinic nanostructured zirconia
journal, June 2002

An efficiently tuned d-orbital occupation of IrO ₂ by doping with Cu for enhancing the oxygen evolution reaction activity
journal, January 2015

Catalytic hydrodeoxygenation of palmitic acid over a bifunctional Co-doped MoO ₂ /CNTs catalyst: an insight into the promoting effect of cobalt
journal, January 2016

Promotion effect in Pt–ZnO catalysts for selective hydrogenation of crotonaldehyde to crotyl alcohol: A structural investigation
journal, October 2009

Magnetic and infrared study of CO chemisorption on silica supported nickel-copper alloys
journal, May 1975

Highly selective and efficient hydrogenation of carboxylic acids to alcohols using titania supported Pt catalysts
journal, January 2010

Molecular Orbital View of Chemisorbed Carbon Monoxide
journal, October 1964

Structure-activity relation and ethane formation in the hydrogenolysis of methyl acetate on silicasupported copper catalysts
journal, April 1994

The influence of d-band structure on stacking-fault energy
journal, August 1966

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006

Manipulating Catalytic Pathways: Deoxygenation of Palmitic Acid on Multifunctional Catalysts
journal, March 2013

Catalytic Reduction of Acetic Acid, Methyl Acetate, and Ethyl Acetate over Silica-Supported Copper
journal, July 2000

Infrared Studies on Bimetallic Copper/Nickel Catalysts Supported on Zirconia and Ceria/Zirconia
journal, April 2013

Quantitative Analysis of Polymorphic Mixes of Zirconia by X-ray Diffraction
journal, May 1987

Catalytic Performance of Brønsted and Lewis Acid Sites in Phenylglyoxal Conversion on Flame-Derived Silica-Zirconia
journal, September 2014

The Catalytic Hydrogenation of Esters to Alcohols
journal, March 1931

Nickel catalysts for the hydrodeoxygenation of biodiesel
journal, October 2010

Heterogeneous Catalytic Deoxygenation of Stearic Acid for Production of Biodiesel
journal, August 2006

Ester hydrogenolysis over promoted Cu/SiO2 catalysts
journal, August 1999

Importance of Size and Distribution of Ni Nanoparticles for the Hydrodeoxygenation of Microalgae Oil
journal, June 2013

On the growth of Ni on Cu(100)
journal, January 1994

The Catalytic Hydrogenolysis of Esters to Alcohols
journal, November 1994

High Performances of Pt/ZnO Catalysts in Selective Hydrogenation of Crotonaldehyde
journal, November 1999

Impact of the Oxygen Defects and the Hydrogen Concentration on the Surface of Tetragonal and Monoclinic ZrO ₂ on the Reduction Rates of Stearic Acid on Ni/ZrO ₂
journal, December 2014

Adsorption of CO and NO on surface studied by infrared-visible sum frequency generation spectroscopy
journal, October 1997

Catalytic reaction pathways in liquid-phase deoxygenation of C18 free fatty acids
journal, February 2010

Surface and catalytic properties of ZrO2
journal, September 1985

The formation of ketones and aldehydes from carboxylic acids, structure-activity relationship for two competitive reactions
journal, November 1995

Production of Biofuel Additives from Esterification and Acetalization of Bioglycerol over SnO ₂ -Based Solid Acids
journal, March 2014

Development of a process for refining rape seed oil into biodiesel and high-cetane components of diesel fuel
journal, May 2010

Supported iron nanoparticles for the hydrodeoxygenation of microalgal oil to green diesel
journal, May 2014

Catalytic deoxygenation of unsaturated renewable feedstocks for production of diesel fuel hydrocarbons
journal, May 2008

Bimetallic Ni–Cu catalyst supported on CeO2 for high-temperature water–gas shift reaction: Methane suppression via enhanced CO adsorption
journal, May 2014

Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst
journal, December 2014

Palladium-based alloy and monometallic catalysts for gas phase hydrogenation of crotonaldehyde: effects of alloying and alloy crystallite size
journal, April 2005

Facile Synthesis of Pure Monoclinic and Tetragonal Zirconia Nanoparticles and Their Phase Effects on the Behavior of Supported Molybdena Catalysts for Methanol-Selective Oxidation
journal, August 2008

Selective hydrogenation of fatty acids to alcohols over highly dispersed ReO /TiO2 catalyst
journal, August 2015

Tungsten-Based Catalysts for Selective Deoxygenation
journal, April 2013

Reactions of Carboxylic Acids on Oxides
journal, June 1997

Reactions of Carboxylic Acids on Oxides
journal, June 1997

Bulk and Surface Properties of Copper-Containing Oxides of the General Formula LaZr1-xCuxO3
journal, February 1994

Catalytic deoxygenation of microalgae oil to green hydrocarbons
journal, January 2013

Chemistry of Catalytic Hydrodeoxygenation
journal, August 1983

Bifunctional Adsorbent-Catalytic Nanoparticles for the Refining of Renewable Feedstocks
journal, November 2013

Comparison of Tungsten and Molybdenum Carbide Catalysts for the Hydrodeoxygenation of Oleic Acid
journal, November 2013

Selectivity of Ni$z.sbnd;Cu and Pt$z.sbnd;Au alloys in reactions of butanol and related compounds
journal, September 1978

On electronic and geometric effects of alloying An infrared spectroscopic investigation of the adsorption of carbon monoxide on platinum-copper alloys
journal, July 1983

Effect of the Ni/Cu ratio on the composition and catalytic properties of nickel-copper alloy in anisole hydrodeoxygenation
journal, January 2014

Towards Quantitative Conversion of Microalgae Oil to Diesel-Range Alkanes with Bifunctional Catalysts
journal, November 2011

Surface composition and catalysis on alloys
journal, February 1979

Interaction of Carbon Dioxide with the Surface of Zirconia Polymorphs
journal, June 1998

Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts
journal, January 2014

Controlling Hydrodeoxygenation of Stearic Acid to n -Heptadecane and n -Octadecane by Adjusting the Chemical Properties of Ni/SiO ₂ -ZrO ₂ Catalyst
journal, November 2016

Effect of the reduction treatment on the structure and reactivity of silica-supported copper particles
journal, September 1991

Influence of Mo on catalytic activity of Ni-based catalysts in hydrodeoxygenation of esters
journal, February 2015

A Quantitative Scale of Oxophilicity and Thiophilicity
journal, August 2016

Synergistic Interaction between Oxides of Copper and Iron for Production of Fatty Alcohols from Fatty Acids
journal, October 2015

Bimetallic catalysts for upgrading of biomass to fuels and chemicals
journal, January 2012