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Title: Catalytic Applications of Vanadium: A Mechanistic Perspective

Abstract

The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [1]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1509906
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Volume: 119; Journal Issue: 4; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States: N. p., 2018. Web. doi:10.1021/acs.chemrev.8b00245.
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., & Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States. https://doi.org/10.1021/acs.chemrev.8b00245
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Mon . "Catalytic Applications of Vanadium: A Mechanistic Perspective". United States. https://doi.org/10.1021/acs.chemrev.8b00245. https://www.osti.gov/servlets/purl/1509906.
@article{osti_1509906,
title = {Catalytic Applications of Vanadium: A Mechanistic Perspective},
author = {Langeslay, Ryan R. and Kaphan, David M. and Marshall, Christopher L. and Stair, Peter C. and Sattelberger, Alfred P. and Delferro, Massimiliano},
abstractNote = {The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.},
doi = {10.1021/acs.chemrev.8b00245},
journal = {Chemical Reviews},
number = 4,
volume = 119,
place = {United States},
year = {2018},
month = {10}
}

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Figures / Tables:

Figure 1 Figure 1: (a) FeV cofactor in the turnover state and (b) FeV cofactor in the resting state (Protein Data Bank ID, 5N6Y). Bond distances are in Angstroms (Å). Adapted with permission from ref 13. Copyright 2018 by American Association for the Advancement of Science. Color legend: V (green), N (blue),more » S (yellow), Fe (gray), C (black), and O (red).« less

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Synthesis, Characterization, Catalytic and Antiamoebic Activity of Vanadium Complexes of Binucleating Bis(dibasic tridentate ONS donor) Ligand Systems
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Vanadium-catalyzed, microwave-assisted oxidations with H2O2 in ionic liquids
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Synthesis, characterization and catalytic activities of vanadium complexes containing ONN donor ligand derived from 2-aminoethylpyridine
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Synthesis, Characterization, and Application of Vanadium−Salan Complexes in Oxygen Transfer Reactions
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Vanadium complexes with multidentate amine bisphenols
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Synthesis, characterization, EPR spectroscopy and catalytic activity of a new oxidovanadium(IV) complex with N2O2-donor ligand
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Oxidovanadium complexes with tetradentate Schiff bases: Synthesis, structural, electrochemical and catalytic studies
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Oxovanadium(IV) Schiff base complexes derived from 2,2′-dimethylpropandiamine: A homogeneous catalyst for cyclooctene and styrene oxidation
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Epoxidation of alkenes by an oxidovanadium(IV) tetradentate Schiff base complex as an efficient catalyst with tert-butyl hydroperoxide
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Synthesis, spectral, catalytic, and thermal studies of vanadium complexes with quadridentate schiff bases
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Electron deficient nonplanar β-octachlorovanadylporphyrin as a highly efficient and selective epoxidation catalyst for olefins
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Binuclear vanadium(V) complexes of bis(aryl)adipohydrazone: synthesis, spectroscopic studies, crystal structure and catalytic activity
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Epoxidation of alkenes and oxidation of sulfides catalyzed by a new binuclear vanadium bis-oxazoline complex
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Vanadium-salen and -salan complexes: Characterization and application in oxygen-transfer reactions
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Synthesis, structure and catalytic activity of an oxo-bridged dinuclear oxovanadium complex of an isonicotinohydrazide ligand
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Pyridoxal based ONS and ONO vanadium(V) complexes: Structural analysis and catalytic application in organic solvent free epoxidation
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Vanadium(V) peroxy complexes. New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons
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Mechanism of Arene Hydroxylation by Vanadium Picolinato Peroxo Complexes
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Studies on vanadium catalyzed direct hydroxylation of aromatic hydrocarbons using hydrogen peroxide as oxidant
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Chemo- and Regioselective Direct Hydroxylation of Arenes with Hydrogen Peroxide Catalyzed by a Divanadium-Substituted Phosphotungstate
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Selective oxidation of pseudocumene and 2-methylnaphthalene with aqueous hydrogen peroxide catalyzed by γ-Keggin divanadium-substituted polyoxotungstate
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Understanding the Regioselectivity of Aromatic Hydroxylation over Divanadium-Substituted γ-Keggin Polyoxotungstate
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Synthesis of coenzyme Q 0 through divanadium-catalyzed oxidation of 3,4,5-trimethoxytoluene with hydrogen peroxide
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Kinetic study of the oxovanadium(IV)–salen-catalyzed H2O2 oxidation of phenols
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Highly Selective Oxidation of Alkylphenols to p -Benzoquinones with Aqueous Hydrogen Peroxide Catalyzed by Divanadium-Substituted Polyoxotungstates
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Synthesis, crystal structure and catecholase activity of a vanadium(V) Schiff base complex
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Hydroxylation of Phenol Catalyzed by Oxovanadium(IV) of Salen-Type Schiff Base Complexes with Hydrogen Peroxide
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Synthesis, catalytic activity, phosphatase inhibition activity, and X-ray structural characterization of vanadium scorpionate complexes, (Tpms)VCl2(DMF) and (Tpms)VOCl(DMF)
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Synthesis, characterization, magnetic, thermal and electrochemical studies of oxidovanadium (IV) picolyl hydrazones as functional catechol oxidase models
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Transition metal based catalysts in the aerobic oxidation of alcohols
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812. Oxidations of organic compounds with quinquevalent vanadium. Part III. The oxidation of cyclohexanol
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The kinetics and mechanism of oxidation of isopropanol with the hydrogen peroxide-vanadate ion-pyrazine-2-carboxylic acid system
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Oxovanadium Complex-Catalyzed Aerobic Oxidation of Propargylic Alcohols
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Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant
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Slow Hydrogen Atom Transfer Reactions of Oxo- and Hydroxo-Vanadium Compounds: The Importance of Intrinsic Barriers
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Surface-Inspired Molecular Vanadium Oxide Catalysts for the Oxidative Dehydrogenation of Alcohols: Evidence for Metal Cooperation and Peroxide Intermediates
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Direct Proof for a Lower Reactivity of Monomeric vs. Dimeric Oxidovanadium Complexes in Alcohol Oxidation: Monomeric Oxidovanadium Complexes
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Tetranuclear vanadium complex, (VO)4(hpic)4: a recyclable catalyst for oxidation of benzyl alcohols with molecular oxygen
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Three New Imidazole-Functionalized Hexanuclear Oxidovanadium Clusters with Exceptional Catalytic Oxidation Properties for Alcohols
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The effects of halogen substituents on the catalytic oxidation of benzyl-alcohols in the presence of dinuclear oxidovanadium(IV) complex
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Novel Heterotetranuclear V 2 Mo 2 or V 2 W 2 Complexes with 4,4′-Di- tert -butyl-2,2′-bipyridine: Syntheses, Crystal Structures, and Catalytic Activities
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Mechanism of Alcohol Oxidation by Dipicolinate Vanadium(V): Unexpected Role of Pyridine
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Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III)
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Pyro without Fire: Synthesis, Structure, and Reactivity of a Dimeric Vanadyl Pyrophosphate Coordination Complex
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A Biomimetic Pathway for Vanadium-Catalyzed Aerobic Oxidation of Alcohols: Evidence for a Base-Assisted Dehydrogenation Mechanism
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Mild and Selective Vanadium-Catalyzed Oxidation of Benzylic, Allylic, and Propargylic Alcohols Using Air
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Room-temperature catalytic oxidation of alcohols with the polyoxovanadate salt Cs 5 (V 14 As 8 O 42 Cl)
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Vanadium-catalyzed Atmospheric Oxidation of Benzyl Alcohols Using Water as Solvent
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Vanadium-catalyzed green oxidation of benzylic alcohols in water under air atmosphere
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An oxidovanadium(IV) complex having a perrhenato ligand: An efficient catalyst for aerobic oxidation reactions of benzylic and propargylic alcohols
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Complexes of cis-dioxomolybdenum(VI) and oxovanadium(IV) with a tridentate ONS donor ligand: Synthesis, spectroscopic properties, X-ray crystal structure and catalytic activity
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Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes
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Oxidovanadium complexes with tridentate aroylhydrazone as catalyst precursors for solvent-free microwave-assisted oxidation of alcohols
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Enantioselective Aerobic Oxidation of α-Hydroxy-Ketones Catalyzed by Oxidovanadium(V) Methoxides Bearing Chiral, N -Salicylidene- tert -butylglycinates
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Synthesis of (−)-Octalactin A by a Strategic Vanadium-Catalyzed Oxidative Kinetic Resolution
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Simply air: Vanadium-catalyzed oxidative kinetic resolution of methyl o-chloromandelate by ambient air
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Density functional theory study of the oxidation of methanol to formaldehyde on a hydrated vanadia cluster
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Catalytic Oxidation of Methanol to Formaldehyde by Mass-Selected Vanadium Oxide Clusters Supported on a TiO 2 (110) Surface
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Methanol Oxidation to Formate on ALD-Prepared VO x /θ-Al 2 O 3 Catalysts: A Mechanistic Study
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Oxidation of Methanol to Formaldehyde on Supported Vanadium Oxide Catalysts Compared to Gas Phase Molecules
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Support Effect in Oxide Catalysis: Methanol Oxidation on Vanadia/Ceria
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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48
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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Zirconia
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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Anatase
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A Theoretical Study of Methanol Oxidation Catalyzed by Isolated Vanadia Clusters Supported on the (101) Surface of Anatase
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Oxidative Dehydrogenation of Methanol to Formaldehyde by a Vanadium Oxide Cluster Supported on Rutile TiO 2 (110): Which Oxygen is Involved?
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Oxidative Dehydrogenation of Methanol to Formaldehyde by Isolated Vanadium, Molybdenum, and Chromium Oxide Clusters Supported on Rutile TiO 2 (110)
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Active component of supported vanadium catalysts in the selective oxidation of methanol
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Unraveling the Mechanisms of the Selective Oxidation of Methanol to Formaldehyde in Vanadia Supported on Titania Catalyst
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The effect of support on redox properties and methanol-oxidation activity of vanadia catalysts
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Atomic Structure and Special Reactivity Toward Methanol Oxidation of Vanadia Nanoclusters on TiO 2 (110)
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Metal nature effect on catalytic reactions in furfural-H2O2-H2O-group V or VI d-metal salt systems in acid media
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Vanadyl species-catalyzed complementary β-oxidative carbonylation of styrene derivatives with aldehydes
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Evidence for the presence of alternative mechanisms in the oxidation of cyclohexanone to adipic acid with oxygen, catalysed by Keggin polyoxometalates
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Efficient and selective oxidation of aldehydes with dioxygen catalysed by vanadium-containing heteropolyanions
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The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
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Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future
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Effective cleavage of ditertiary glycols via vanadium(V)-catalyzed aerobic oxidation
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Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst
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Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models
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Non-Oxidative Vanadium-Catalyzed C-O Bond Cleavage: Application to Degradation of Lignin Model Compounds
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Mechanistic studies on the VO(acac) 2 -catalyzed oxidative cleavage of lignin model compounds in acetic acid
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Aerobic Oxidation Reactions Catalyzed by Vanadium Complexes of Bis(Phenolate) Ligands
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Aerobic Oxidation of 2-Phenoxyethanol Lignin Model Compounds Using Vanadium and Copper Catalysts
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Lignin chemistry?past, present and future
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Aerobic Oxidation of β-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts
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Mechanism of Vanadium-Catalyzed Selective C–O and C–C Cleavage of Lignin Model Compound
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Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin
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Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose
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Oxidation of 5-hydroxymethylfurfural to maleic anhydride with molecular oxygen
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Transformation of 5-Hydroxymethylfurfural (HMF) to Maleic Anhydride by Aerobic Oxidation with Heteropolyacid Catalysts
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Oxidative C−C Bond Cleavage of Primary Alcohols and Vicinal Diols Catalyzed by H 5 PV 2 Mo 10 O 40 by an Electron Transfer and Oxygen Transfer Reaction Mechanism
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Catalytic conversion of biomass-derived carbohydrates to formic acid using molecular oxygen
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Transformation of Cellulose and its Derived Carbohydrates into Formic and Lactic Acids Catalyzed by Vanadyl Cations
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Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen
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Selective oxidation of complex, water-insoluble biomass to formic acid using additives as reaction accelerators
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Catalytic Air Oxidation of Biomass‐Derived Carbohydrates to Formic Acid
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Polyoxometalate-based Ionic liquid as thermoregulated and environmentally friendly catalyst for starch oxidation
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Effect of Cs content on CsxH5−xPMo10V2O40 properties and oxidative catalytic activity on starch oxidation by H2O2
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Vanadium-Catalyzed Regioselective Oxidative Coupling of 2-Hydroxycarbazoles
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Oxidative Cross-Coupling of sp 3 - and sp 2 -Hybridized C–H Bonds: Vanadium-Catalyzed Aminomethylation of Imidazo[1,2- a ]pyridines
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C1-Substituted N-Alkyl Tetrahydroisoquinoline Derivatives through V-Catalyzed Oxidative Coupling
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Iron-Catalyzed Homocoupling of Bromide Compounds
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DFT Studies on the Mechanism of the Vanadium-Catalyzed Deoxydehydration of Diols
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A Radical Mechanism for the Vanadium-Catalyzed Deoxydehydration of Glycols
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Mechanism of Vanadium-Catalyzed Deoxydehydration of Vicinal Diols: Spin-Crossover-Involved Processes
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Carbon Monoxide (CO)- and Hydrogen-Driven, Vanadium-Catalyzed Deoxydehydration of Glycols
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Benzannulation via Ruthenium-Catalyzed Diol–Diene [4+2] Cycloaddition: One- and Two-Directional Syntheses of Fluoranthenes and Acenes
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Mechanistic considerations of halogenating enzymes
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Vanadium-Catalyzed Oxidative Bromination under Atmospheric Oxygen
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A sustainable two-phase procedure for V-catalyzed toluene oxidative bromination with H2O2–KBr
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Thymol Bromination - A Comparison between Enzymatic and Chemical Catalysis: Thymol Bromination
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Vanadium-catalyzed oxidative bromination promoted by Brønsted acid or Lewis acid
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An amino acid coordinated vanadium (IV) complex: Synthesis, structure, DFT calculations and VHPO mimicking catalytic bromoperoxidation of organic substrates
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Bromide oxidation mechanism by vanadium bromoperoxidase functional models with new tripodal amine ligands: A comprehensive theoretical calculations study
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Synthesis, structure and properties of a series of scorpionate oxovanadium(IV)–carboxylate complexes
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Novel vanadium complexes with rigid carboxylate ligands: Synthesis, structure and catalytic bromine dynamics of phenol red
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Asymmetric addition of trimethylsilylcyanide to N-benzylimines catalyzed by recyclable chiral dimeric V(V) salen complex
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Figures / Tables found in this record:

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