Catalytic Applications of Vanadium: A Mechanistic Perspective
Abstract
The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1509906
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Reviews
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 4; Journal ID: ISSN 0009-2665
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States: N. p., 2018.
Web. doi:10.1021/acs.chemrev.8b00245.
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., & Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States. https://doi.org/10.1021/acs.chemrev.8b00245
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Mon .
"Catalytic Applications of Vanadium: A Mechanistic Perspective". United States. https://doi.org/10.1021/acs.chemrev.8b00245. https://www.osti.gov/servlets/purl/1509906.
@article{osti_1509906,
title = {Catalytic Applications of Vanadium: A Mechanistic Perspective},
author = {Langeslay, Ryan R. and Kaphan, David M. and Marshall, Christopher L. and Stair, Peter C. and Sattelberger, Alfred P. and Delferro, Massimiliano},
abstractNote = {The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.},
doi = {10.1021/acs.chemrev.8b00245},
journal = {Chemical Reviews},
number = 4,
volume = 119,
place = {United States},
year = {Mon Oct 08 00:00:00 EDT 2018},
month = {Mon Oct 08 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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