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Title: Catalytic Applications of Vanadium: A Mechanistic Perspective

Abstract

The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [1]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1509906
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Volume: 119; Journal Issue: 4; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States: N. p., 2018. Web. doi:10.1021/acs.chemrev.8b00245.
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., & Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States. https://doi.org/10.1021/acs.chemrev.8b00245
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Mon . "Catalytic Applications of Vanadium: A Mechanistic Perspective". United States. https://doi.org/10.1021/acs.chemrev.8b00245. https://www.osti.gov/servlets/purl/1509906.
@article{osti_1509906,
title = {Catalytic Applications of Vanadium: A Mechanistic Perspective},
author = {Langeslay, Ryan R. and Kaphan, David M. and Marshall, Christopher L. and Stair, Peter C. and Sattelberger, Alfred P. and Delferro, Massimiliano},
abstractNote = {The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.},
doi = {10.1021/acs.chemrev.8b00245},
journal = {Chemical Reviews},
number = 4,
volume = 119,
place = {United States},
year = {Mon Oct 08 00:00:00 EDT 2018},
month = {Mon Oct 08 00:00:00 EDT 2018}
}

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Figures / Tables:

Figure 1 Figure 1: (a) FeV cofactor in the turnover state and (b) FeV cofactor in the resting state (Protein Data Bank ID, 5N6Y). Bond distances are in Angstroms (Å). Adapted with permission from ref 13. Copyright 2018 by American Association for the Advancement of Science. Color legend: V (green), N (blue),more » S (yellow), Fe (gray), C (black), and O (red).« less

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A novel oxovanadium(V) complex of 2-(2-butoxyethoxy)ethanolate with high catalytic activities for polymerisation and epoxidation
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Synthesis, Characterization, Catalytic and Antiamoebic Activity of Vanadium Complexes of Binucleating Bis(dibasic tridentate ONS donor) Ligand Systems
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Vanadium-catalyzed, microwave-assisted oxidations with H2O2 in ionic liquids
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Synthesis, characterization and catalytic activities of vanadium complexes containing ONN donor ligand derived from 2-aminoethylpyridine
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Synthesis, Characterization, and Application of Vanadium−Salan Complexes in Oxygen Transfer Reactions
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Vanadium complexes with multidentate amine bisphenols
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Synthesis, characterization, EPR spectroscopy and catalytic activity of a new oxidovanadium(IV) complex with N2O2-donor ligand
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Oxidovanadium complexes with tetradentate Schiff bases: Synthesis, structural, electrochemical and catalytic studies
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Oxovanadium(IV) Schiff base complexes derived from 2,2′-dimethylpropandiamine: A homogeneous catalyst for cyclooctene and styrene oxidation
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Epoxidation of alkenes by an oxidovanadium(IV) tetradentate Schiff base complex as an efficient catalyst with tert-butyl hydroperoxide
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Synthesis, spectral, catalytic, and thermal studies of vanadium complexes with quadridentate schiff bases
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Electron deficient nonplanar β-octachlorovanadylporphyrin as a highly efficient and selective epoxidation catalyst for olefins
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Binuclear vanadium(V) complexes of bis(aryl)adipohydrazone: synthesis, spectroscopic studies, crystal structure and catalytic activity
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Epoxidation of alkenes and oxidation of sulfides catalyzed by a new binuclear vanadium bis-oxazoline complex
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Vanadium-salen and -salan complexes: Characterization and application in oxygen-transfer reactions
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Synthesis, structure and catalytic activity of an oxo-bridged dinuclear oxovanadium complex of an isonicotinohydrazide ligand
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Pyridoxal based ONS and ONO vanadium(V) complexes: Structural analysis and catalytic application in organic solvent free epoxidation
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Vanadium(V) peroxy complexes. New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons
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Mechanism of Arene Hydroxylation by Vanadium Picolinato Peroxo Complexes
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Studies on vanadium catalyzed direct hydroxylation of aromatic hydrocarbons using hydrogen peroxide as oxidant
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Chemo- and Regioselective Direct Hydroxylation of Arenes with Hydrogen Peroxide Catalyzed by a Divanadium-Substituted Phosphotungstate
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Selective oxidation of pseudocumene and 2-methylnaphthalene with aqueous hydrogen peroxide catalyzed by γ-Keggin divanadium-substituted polyoxotungstate
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Understanding the Regioselectivity of Aromatic Hydroxylation over Divanadium-Substituted γ-Keggin Polyoxotungstate
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Synthesis of coenzyme Q 0 through divanadium-catalyzed oxidation of 3,4,5-trimethoxytoluene with hydrogen peroxide
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Kinetic study of the oxovanadium(IV)–salen-catalyzed H2O2 oxidation of phenols
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Highly Selective Oxidation of Alkylphenols to p -Benzoquinones with Aqueous Hydrogen Peroxide Catalyzed by Divanadium-Substituted Polyoxotungstates
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Synthesis, crystal structure and catecholase activity of a vanadium(V) Schiff base complex
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Hydroxylation of Phenol Catalyzed by Oxovanadium(IV) of Salen-Type Schiff Base Complexes with Hydrogen Peroxide
journal, March 2010

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Synthesis, catalytic activity, phosphatase inhibition activity, and X-ray structural characterization of vanadium scorpionate complexes, (Tpms)VCl2(DMF) and (Tpms)VOCl(DMF)
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Synthesis, characterization, magnetic, thermal and electrochemical studies of oxidovanadium (IV) picolyl hydrazones as functional catechol oxidase models
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Transition metal based catalysts in the aerobic oxidation of alcohols
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812. Oxidations of organic compounds with quinquevalent vanadium. Part III. The oxidation of cyclohexanol
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The kinetics and mechanism of oxidation of isopropanol with the hydrogen peroxide-vanadate ion-pyrazine-2-carboxylic acid system
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Oxovanadium Complex-Catalyzed Aerobic Oxidation of Propargylic Alcohols
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Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant
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Slow Hydrogen Atom Transfer Reactions of Oxo- and Hydroxo-Vanadium Compounds: The Importance of Intrinsic Barriers
journal, March 2009

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Surface-Inspired Molecular Vanadium Oxide Catalysts for the Oxidative Dehydrogenation of Alcohols: Evidence for Metal Cooperation and Peroxide Intermediates
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Direct Proof for a Lower Reactivity of Monomeric vs. Dimeric Oxidovanadium Complexes in Alcohol Oxidation: Monomeric Oxidovanadium Complexes
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Tetranuclear vanadium complex, (VO)4(hpic)4: a recyclable catalyst for oxidation of benzyl alcohols with molecular oxygen
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Three New Imidazole-Functionalized Hexanuclear Oxidovanadium Clusters with Exceptional Catalytic Oxidation Properties for Alcohols
journal, February 2013

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The effects of halogen substituents on the catalytic oxidation of benzyl-alcohols in the presence of dinuclear oxidovanadium(IV) complex
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Novel Heterotetranuclear V 2 Mo 2 or V 2 W 2 Complexes with 4,4′-Di- tert -butyl-2,2′-bipyridine: Syntheses, Crystal Structures, and Catalytic Activities
journal, October 2011

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Mechanism of Alcohol Oxidation by Dipicolinate Vanadium(V): Unexpected Role of Pyridine
journal, December 2010

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Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III)
journal, January 2009

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Pyro without Fire: Synthesis, Structure, and Reactivity of a Dimeric Vanadyl Pyrophosphate Coordination Complex
journal, September 2012

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A Biomimetic Pathway for Vanadium-Catalyzed Aerobic Oxidation of Alcohols: Evidence for a Base-Assisted Dehydrogenation Mechanism
journal, October 2012

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Mild and Selective Vanadium-Catalyzed Oxidation of Benzylic, Allylic, and Propargylic Alcohols Using Air
journal, April 2011

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Room-temperature catalytic oxidation of alcohols with the polyoxovanadate salt Cs 5 (V 14 As 8 O 42 Cl)
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Vanadium-catalyzed Atmospheric Oxidation of Benzyl Alcohols Using Water as Solvent
journal, May 2011

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Vanadium-catalyzed green oxidation of benzylic alcohols in water under air atmosphere
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An oxidovanadium(IV) complex having a perrhenato ligand: An efficient catalyst for aerobic oxidation reactions of benzylic and propargylic alcohols
journal, August 2017


Complexes of cis-dioxomolybdenum(VI) and oxovanadium(IV) with a tridentate ONS donor ligand: Synthesis, spectroscopic properties, X-ray crystal structure and catalytic activity
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Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes
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Oxidovanadium complexes with tridentate aroylhydrazone as catalyst precursors for solvent-free microwave-assisted oxidation of alcohols
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Enantioselective Aerobic Oxidation of α-Hydroxy-Ketones Catalyzed by Oxidovanadium(V) Methoxides Bearing Chiral, N -Salicylidene- tert -butylglycinates
journal, January 2011

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Synthesis of (−)-Octalactin A by a Strategic Vanadium-Catalyzed Oxidative Kinetic Resolution
journal, May 2008

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Simply air: Vanadium-catalyzed oxidative kinetic resolution of methyl o-chloromandelate by ambient air
journal, July 2010


Density functional theory study of the oxidation of methanol to formaldehyde on a hydrated vanadia cluster
journal, January 2010

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Catalytic Oxidation of Methanol to Formaldehyde by Mass-Selected Vanadium Oxide Clusters Supported on a TiO 2 (110) Surface
journal, April 2014

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Methanol Oxidation to Formate on ALD-Prepared VO x /θ-Al 2 O 3 Catalysts: A Mechanistic Study
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Oxidation of Methanol to Formaldehyde on Supported Vanadium Oxide Catalysts Compared to Gas Phase Molecules
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Support Effect in Oxide Catalysis: Methanol Oxidation on Vanadia/Ceria
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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48
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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Zirconia
journal, March 2008

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Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Anatase
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A Theoretical Study of Methanol Oxidation Catalyzed by Isolated Vanadia Clusters Supported on the (101) Surface of Anatase
journal, August 2012

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Oxidative Dehydrogenation of Methanol to Formaldehyde by a Vanadium Oxide Cluster Supported on Rutile TiO 2 (110): Which Oxygen is Involved?
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Oxidative Dehydrogenation of Methanol to Formaldehyde by Isolated Vanadium, Molybdenum, and Chromium Oxide Clusters Supported on Rutile TiO 2 (110)
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Active component of supported vanadium catalysts in the selective oxidation of methanol
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Unraveling the Mechanisms of the Selective Oxidation of Methanol to Formaldehyde in Vanadia Supported on Titania Catalyst
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The effect of support on redox properties and methanol-oxidation activity of vanadia catalysts
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Atomic Structure and Special Reactivity Toward Methanol Oxidation of Vanadia Nanoclusters on TiO 2 (110)
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Metal nature effect on catalytic reactions in furfural-H2O2-H2O-group V or VI d-metal salt systems in acid media
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Vanadyl species-catalyzed complementary β-oxidative carbonylation of styrene derivatives with aldehydes
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Evidence for the presence of alternative mechanisms in the oxidation of cyclohexanone to adipic acid with oxygen, catalysed by Keggin polyoxometalates
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Efficient and selective oxidation of aldehydes with dioxygen catalysed by vanadium-containing heteropolyanions
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The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
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Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future
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Effective cleavage of ditertiary glycols via vanadium(V)-catalyzed aerobic oxidation
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Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst
journal, June 2010

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Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models
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Non-Oxidative Vanadium-Catalyzed C-O Bond Cleavage: Application to Degradation of Lignin Model Compounds
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Mechanistic studies on the VO(acac) 2 -catalyzed oxidative cleavage of lignin model compounds in acetic acid
journal, January 2016

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Aerobic Oxidation Reactions Catalyzed by Vanadium Complexes of Bis(Phenolate) Ligands
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Aerobic Oxidation of 2-Phenoxyethanol Lignin Model Compounds Using Vanadium and Copper Catalysts
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Lignin chemistry?past, present and future
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Aerobic Oxidation of β-1 Lignin Model Compounds with Copper and Oxovanadium Catalysts
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Mechanism of Vanadium-Catalyzed Selective C–O and C–C Cleavage of Lignin Model Compound
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Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin
journal, April 2013

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Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose
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Oxidation of 5-hydroxymethylfurfural to maleic anhydride with molecular oxygen
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Transformation of 5-Hydroxymethylfurfural (HMF) to Maleic Anhydride by Aerobic Oxidation with Heteropolyacid Catalysts
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Oxidative C−C Bond Cleavage of Primary Alcohols and Vicinal Diols Catalyzed by H 5 PV 2 Mo 10 O 40 by an Electron Transfer and Oxygen Transfer Reaction Mechanism
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Catalytic conversion of biomass-derived carbohydrates to formic acid using molecular oxygen
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Transformation of Cellulose and its Derived Carbohydrates into Formic and Lactic Acids Catalyzed by Vanadyl Cations
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Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen
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Selective oxidation of complex, water-insoluble biomass to formic acid using additives as reaction accelerators
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Catalytic Air Oxidation of Biomass‐Derived Carbohydrates to Formic Acid
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Polyoxometalate-based Ionic liquid as thermoregulated and environmentally friendly catalyst for starch oxidation
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Effect of Cs content on CsxH5−xPMo10V2O40 properties and oxidative catalytic activity on starch oxidation by H2O2
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Vanadium-Catalyzed Oxidative C(CO)–C(CO) Bond Cleavage for C–N Bond Formation: One-Pot Domino Transformation of 1,2-Diketones and Amidines into Imides and Amides
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Analysis of the reactions used for the preparation of drug candidate molecules
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Asymmetric oxidation of sulfides catalyzed by titanium and vanadium complexes in the synthesis of biologically active sulfoxides
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Mechanistic Analysis of Nucleophilic Substrates Oxidation by Functional Models of Vanadium-Dependent Haloperoxidases: A Density Functional Theory Study
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Oxidation of organic sulfides by a vanadium(5+) oxo–monoperoxo–picolinate complex: Kinetics and mechanism
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VO2F(dmpz)2: a new catalyst for selective oxidation of organic sulfides to sulfoxides with H2O2
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Chiral schiff bases synthesized from terpenes of pinane series in asymmetric metall complex oxidation of sulfides
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New chiral Schiff bases derived from (+)- and (−)-α-pinenes in the metal complex catalyzed asymmetric oxidation of sulfides
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Synthesis of new chiral schiff bases from (+)-3-carene and their use in asymmetric oxidation of sulfides catalyzed by metal complexes
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Vanadium(V) complex with Schiff-base ligand containing a flexible amino side chain: Synthesis, structure and reactivity
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Vanadium-Catalyzed Asymmetric Oxidation of Sulfides Using Schiff Base Ligands Derived from β-Amino Alcohols with Two Stereogenic Centers
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Enantioselective Vanadium-Catalyzed Oxidation of 1,3-Dithianes from Aldehydes and Ketones using β-Amino Alcohol Derived Schiff Base Ligands
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Camphor-Based Schiff Base Of 3- Endo -Aminoborneol (SBAB): Novel Ligand for Vanadium-Catalyzed Asymmetric Sulfoxidation and Subsequent Kinetic Resolution
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Cyclodextrin inclusion compounds of vanadium complexes: Structural characterization and catalytic sulfoxidation
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Chiral oxovanadium(V) complexes with a 6-amino-6-deoxyglucopyranoside-based Schiff-base ligand: Catalytic asymmetric sulfoxidation and structural characterization
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Asymmetric vanadium- and iron-catalyzed oxidations: new mild (R)-modafinil synthesis and formation of epoxides using aqueous H2O2 as a terminal oxidant
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Vanadium-catalyzed enantioselective oxidation of allyl sulfides
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Amino Alcohol-Derived Reduced Schiff Base V IV O and V V Compounds as Catalysts for Asymmetric Sulfoxidation of Thioanisole with Hydrogen Peroxide
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Helical Oxidovanadium(IV) Salen-Type Complexes: Synthesis, Characterisation and Catalytic Behaviour: Helical Oxidovanadium(IV) Salen-Type Complexes
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Salophen and salen oxo vanadium complexes as catalysts of sulfides oxidation with H2O2: Mechanistic insights
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Vanadium Thiolate Complexes for Efficient and Selective Sulfoxidation Catalysis: A Mechanistic Investigation
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Role of Intermolecular Interactions in Oxygen Transfer Catalyzed by Silsesquioxane Trisilanolate Vanadium(V)
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Synthesis of C3- and C2-symmetric tris- and bis-sulfoxide ligands by asymmetric oxidation
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C 3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models
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Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts
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Sulfoxygenation Catalysed by Oxidovanadium Complexes
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Vanadium Diaminebis(phenolate) Complexes: Syntheses, Structures, and Reactivity in Sulfoxidation Catalysis
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Hemicryptophane–oxidovanadium(V) complexes: Lead of a new class of efficient supramolecular catalysts
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Sulfoxidation inside a C 3 -Vanadium(V) Bowl-Shaped Catalyst
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Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
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Selected Copper-Based Reactions for C−N, C−O, C−S, and C−C Bond Formation
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Active Species and Mechanistic Pathways in Iron-Catalyzed C–C Bond-Forming Cross-Coupling Reactions
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Catalytic Asymmetric Coupling of 2-Naphthols by Chiral Tridentate Oxovanadium(IV) Complexes
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Chiral oxovanadium complex catalyzed enantioselective oxidative coupling of 2-naphthols
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Chiral dinuclear vanadium(v) catalysts for oxidative coupling of 2-naphthols
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Dual activation in oxidative coupling of 2-naphthols catalyzed by chiral dinuclear vanadium complexes
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Enantioselective and aerobic oxidative coupling of 2-naphthol derivatives using chiral dinuclear vanadium(V) complex in water
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Enantioselective oxidative-coupling of polycyclic phenols
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Efficient Enantioselective Synthesis of Oxahelicenes Using Redox/Acid Cooperative Catalysts
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Reversal of Enantioselectivity Approach to BINOLs via Single and Dual 2-Naphthol Activation Modes
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Vanadium-Catalyzed Regioselective Oxidative Coupling of 2-Hydroxycarbazoles
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Asymmetric Oxidative Coupling of Phenols and Hydroxycarbazoles
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A Modified Mannich-Type Reaction Catalyzed by VO(acac) 2
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Oxidative Cross-Coupling of sp 3 - and sp 2 -Hybridized C–H Bonds: Vanadium-Catalyzed Aminomethylation of Imidazo[1,2- a ]pyridines
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Development and a Practical Synthesis of the JAK2 Inhibitor LY2784544
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An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines
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C1-Substituted N-Alkyl Tetrahydroisoquinoline Derivatives through V-Catalyzed Oxidative Coupling
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Oxovanadium(V)-induced oxidative transformations of main-group organometallics
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Iron-Catalyzed Homocoupling of Bromide Compounds
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Vanadium-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents
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Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass
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Vanadium-catalyzed deoxydehydration of glycols
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DFT Studies on the Mechanism of the Vanadium-Catalyzed Deoxydehydration of Diols
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A Radical Mechanism for the Vanadium-Catalyzed Deoxydehydration of Glycols
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Mechanism of Vanadium-Catalyzed Deoxydehydration of Vicinal Diols: Spin-Crossover-Involved Processes
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Carbon Monoxide (CO)- and Hydrogen-Driven, Vanadium-Catalyzed Deoxydehydration of Glycols
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Benzannulation via Ruthenium-Catalyzed Diol–Diene [4+2] Cycloaddition: One- and Two-Directional Syntheses of Fluoranthenes and Acenes
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Vanadium-Catalyzed Deoxydehydration of Glycerol Without an External Reductant
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The future of/for vanadium
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Halofunctionalization of alkenes by vanadium chloroperoxidase from Curvularia inaequalis
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Mechanistic considerations of halogenating enzymes
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X-ray crystal structures of active site mutants of the vanadium-containing chloroperoxidase from the fungus Curvularia inaequalis
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Vanadium catalyzed oxidation with hydrogen peroxide
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Sustainable vanadium-catalyzed oxidation of organic substrates with H2O2
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Vanadium-Bromoperoxidase-Mimicking Systems: Direct Evidence of a Hypobromite-Like Vanadium Intermediate
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Vanadium-Catalyzed Oxidative Bromination under Atmospheric Oxygen
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A sustainable two-phase procedure for V-catalyzed toluene oxidative bromination with H2O2–KBr
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Thymol Bromination - A Comparison between Enzymatic and Chemical Catalysis: Thymol Bromination
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Vanadium-catalyzed oxidative bromination promoted by Brønsted acid or Lewis acid
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Oxidative bromination reaction using vanadium catalyst and aluminum halide under molecular oxygen
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An amino acid coordinated vanadium (IV) complex: Synthesis, structure, DFT calculations and VHPO mimicking catalytic bromoperoxidation of organic substrates
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Bromide oxidation mechanism by vanadium bromoperoxidase functional models with new tripodal amine ligands: A comprehensive theoretical calculations study
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Vanadium( v ) complexes of a tripodal ligand, their characterisation and biological implications
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Synthesis, structure and properties of a series of scorpionate oxovanadium(IV)–carboxylate complexes
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Novel vanadium(iii) complexes with rigid phenylpolycarboxylate ligands: synthesis, structures and application in C–H bond activation
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Novel vanadium complexes with rigid carboxylate ligands: Synthesis, structure and catalytic bromine dynamics of phenol red
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Mimicking vanadium haloperoxidases: vanadium( iii )–carboxylic acid complexes and their application in H 2 O 2 detection
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Vanadium(V) complexes of some bidentate hydrazone ligands and their bromoperoxidase activity
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Synthesis, structures and properties of the catalytic bromination reaction of a series of novel scorperate oxidovanadium complexes with the potential detection of hydrogen peroxide in water
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Haloperoxidase Activity of Oxovanadium(V) Thiobisphenolates
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Discrete spherical hexadecavanadates incorporating a bromide with oxidative bromination activity
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Vanadium(V)-Catalyzed Oxidative Bromination of Acid Labile Alkenols and Alkenes in Alkyl Carbonates
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Decarbonylative Halogenation by a Vanadium Complex
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A Doubly Biomimetic Synthetic Transformation: Catalytic Decarbonylation and Halogenation at Room Temperature by Vanadium Pentoxide
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An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts
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Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide
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Vanadium-catalyzed oxidative Strecker reaction: α-C–H cyanation of para-methoxyphenyl (PMP)-protected primary amines
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Asymmetric addition of trimethylsilylcyanide to N-benzylimines catalyzed by recyclable chiral dimeric V(V) salen complex
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Room-temperature synthesis of enantioenriched non-protected cyanohydrins using vanadium(salalen) catalyst
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Regioselective direct oxidative C–H cyanation of quinoline and its derivatives catalyzed by vanadium-containing heteropoly acids
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Direct conversion of benzylamines to imines via atmospheric oxidation in the presence of VO(Hhpic)2 catalyst
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Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands
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Oxidative Addition of a Dinuclear and Divalent Vanadium Hydride to an Olefin C−H Bond, Leading to Catalytic Hydrogenation
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Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques
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Figures / Tables found in this record:

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