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Title: Catalytic Applications of Vanadium: A Mechanistic Perspective

Abstract

The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2];  [1]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1509906
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Volume: 119; Journal Issue: 4; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States: N. p., 2018. Web. doi:10.1021/acs.chemrev.8b00245.
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., & Delferro, Massimiliano. Catalytic Applications of Vanadium: A Mechanistic Perspective. United States. doi:10.1021/acs.chemrev.8b00245.
Langeslay, Ryan R., Kaphan, David M., Marshall, Christopher L., Stair, Peter C., Sattelberger, Alfred P., and Delferro, Massimiliano. Mon . "Catalytic Applications of Vanadium: A Mechanistic Perspective". United States. doi:10.1021/acs.chemrev.8b00245. https://www.osti.gov/servlets/purl/1509906.
@article{osti_1509906,
title = {Catalytic Applications of Vanadium: A Mechanistic Perspective},
author = {Langeslay, Ryan R. and Kaphan, David M. and Marshall, Christopher L. and Stair, Peter C. and Sattelberger, Alfred P. and Delferro, Massimiliano},
abstractNote = {The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.},
doi = {10.1021/acs.chemrev.8b00245},
journal = {Chemical Reviews},
number = 4,
volume = 119,
place = {United States},
year = {2018},
month = {10}
}

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Cited by: 38 works
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Figures / Tables:

Figure 1 Figure 1: (a) FeV cofactor in the turnover state and (b) FeV cofactor in the resting state (Protein Data Bank ID, 5N6Y). Bond distances are in Angstroms (Å). Adapted with permission from ref 13. Copyright 2018 by American Association for the Advancement of Science. Color legend: V (green), N (blue),more » S (yellow), Fe (gray), C (black), and O (red).« less

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