Catalysis Enabled by Plasma Activation of Strong Chemical Bonds: A Review

Mehta, Prateek; Barboun, Patrick; Go, David B.; Hicks, Jason C.; Schneider, William F.

doi:10.1021/acsenergylett.9b00263

Title: Catalysis Enabled by Plasma Activation of Strong Chemical Bonds: A Review

Journal Article · 05 April 2019 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.9b00263 · OSTI ID:1509775

^[1]; Barboun, Patrick ^[1];

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Univ. of Notre Dame, IN (United States). Dept. of Chemical and Biomolecular Engineering
Univ. of Notre Dame, IN (United States). Dept. of Aerospace and Mechanical Engineering, Dept. of Chemical and Biomolecular Engineering

Nonthermal plasma-driven catalysis is an emerging subfield of heterogeneous catalysis that is particularly promising for the chemical transformation of hard-to-activate molecules (e.g., N₂, CO₂, CH₄). In this Review, we illustrate this promise of plasma-enhanced catalysis, focusing on the ammonia synthesis and methane dry reforming reactions, two reactions that have received wide attention and that illustrate the potential for plasma excitations to mitigate kinetic and thermodynamic obstacles to chemical conversions. We highlight how plasma activation of reactants can provide access to overall reaction rates, conversions, product yields, and/or product distributions unattainable by thermal catalysis at similar temperatures and pressures. Particular emphasis is given to efforts aimed at discerning the underlying mechanisms at play in these systems. We discuss opportunities for and challenges to the advancement of the field.

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Research Organization:: University of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016543

OSTI ID:: 1509775

Alternate ID(s):: OSTI ID: 1512270

Journal Information:: ACS Energy Letters, Vol. 4, Issue 5; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 181 works

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