Title: Rare-earth high entropy alloys with hexagonal close-packed structure

Journal Article · · Journal of Applied Physics
DOI: https://doi.org/10.1063/1.5051514 · OSTI ID:1509712
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [2];  [3];  [4]
  1. Taiyuan Univ. of Technology, Taiyuan (China)
  2. Univ. of Science and Technology Beijing, Beijing (China)
  3. National Energy Technology Lab. (NETL), Albany, OR (United States)
  4. National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, South Park, PA (United States)

The formation of octonary DyErGdHoLuScTbY and senary DyGdHoLaTbY and ErGdHoLaTbY high-entropy alloys (HEAs) with the hexagonal close-packed (HCP) structure was reported in this study. Experiments using scanning electron microscopy and x-ray diffraction confirmed the single HCP solid solution in the as-cast state for these three HEAs if the presence of minor rare-earth oxides due to contamination from processing is ignored. The measured compressive yield stress values for these HEAs at room temperature are 245, 205, and 360 MPa for the ErGdHoLaTbY, DyGdHoLaTbY, and DyErGdHoLuScTbY HEAs, respectively. As a result, the corresponding solid solution strengthening contributions for these HEAs were estimated using a simple elastic model, and the resulting contributions were 28 MPa, 27 MPa, and 42 MPa for the three aforementioned HEAs.

Research Organization:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
Sponsoring Organization:
FE; USDOE
Grant/Contract Number:
FE0004000
OSTI ID:
1509712
Report Number(s):
NETL-PUB-22339
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 19 Vol. 124; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (53)

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes journal May 2004
Solid-Solution Phase Formation Rules for Multi-component Alloys journal June 2008
Solid solution hardening in MgCd single crystals journal June 1992
A Statistical Theory of Solid Solution Hardening journal January 1970
High-Entropy Alloys book January 2016
Multi-component solid solution hardening: Part 1 Proposed model journal May 1977
Multi-component solid solution hardening: Part 2 Agreement with experimental results journal May 1977
Microstructure and elevated temperature properties of a refractory TaNbHfZrTi alloy journal January 2012
High-Entropy Alloys in Hexagonal Close-Packed Structure journal August 2015
Senary Refractory High-Entropy Alloy HfNbTaTiVZr journal September 2015
High-Entropy Alloys with a Hexagonal Close-Packed Structure Designed by Equi-Atomic Alloy Strategy and Binary Phase Diagrams journal July 2014
Substitutional solution hardening journal March 1963
Substitutional solution hardening journal March 1963
Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase journal December 2011
High-Entropy Alloys book June 2014
Fatigue behavior of Al0.5CoCrCuFeNi high entropy alloys journal September 2012
Electronic and thermodynamic criteria for the occurrence of high entropy alloys in metallic systems journal August 2014
Modelling solid solution hardening in high entropy alloys journal February 2015
Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range journal February 2017
Rare-earth high-entropy alloys with giant magnetocaloric effect journal February 2017
Senary refractory high-entropy alloy Cr MoNbTaVW journal December 2015
Thermodynamics of concentrated solid solution alloys journal October 2017
Refractory high-entropy alloys journal September 2010
The generalized thermodynamic rule for phase selection in multicomponent alloys journal April 2015
Dual HCP structures formed in senary ScYLaTiZrHf multi-principal-element alloy journal February 2016
Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy journal May 2011
Microstructures and mechanical properties of Al CrFeNiTi0.25 alloys journal January 2015
Disordered ferromagnetic state in the Ce-Gd-Tb-Dy-Ho hexagonal high-entropy alloy journal April 2018
Alloying behavior, microstructure and mechanical properties in a FeNiCrCo0.3Al0.7 high entropy alloy journal October 2013
A hexagonal close-packed high-entropy alloy: The effect of entropy journal April 2016
High-entropy alloy: challenges and prospects journal July 2016
Microstructural development in equiatomic multicomponent alloys journal July 2004
Microstructures and compressive properties of multicomponent AlCoCrFeNiMox alloys journal October 2010
Effect of Nb addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy journal January 2012
Microstructures and properties of high-entropy alloys journal April 2014
Design of high entropy alloys: A single-parameter thermodynamic rule journal July 2015
Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase journal December 2011
Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres journal February 1971
Solid solution alloys of AlCoCrFeNiTix with excellent room-temperature mechanical properties journal April 2007
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys journal May 2011
Substitutional solution hardening of magnesium single crystals journal April 1972
Hexagonal High-entropy Alloys journal August 2014
Multicomponent equiatomic rare earth oxides journal August 2016
Complex magnetism of Ho-Dy-Y-Gd-Tb hexagonal high-entropy alloy journal December 2015
Complex magnetism of Ho-Dy-Y-Gd-Tb hexagonal high-entropy alloy journal December 2015
A fracture-resistant high-entropy alloy for cryogenic applications journal September 2014
On the Studies of Solid Solution Hardening journal March 1981
On the Studies of Solid Solution Hardening journal March 1981
Senary refractory high entropy alloy MoNbTaTiVW journal March 2015
Senary refractory high entropy alloy MoNbTaTiVW journal March 2015
Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element journal January 2005
Multicomponent equiatomic rare earth oxides text January 2017
Multicomponent equiatomic rare earth oxides text January 2016

Cited By (6)

Superconductivity in a uranium containing high entropy alloy journal March 2020
Microstructure and Mechanical Properties of CoCrFeMnNiSnx High-Entropy Alloys journal June 2019
High-Entropy Alloys book June 2014
High-entropy alloys journal June 2019
Creep resistance and strain-rate sensitivity of a CoCrFeNiAl 0.3 high-entropy alloy by nanoindentation journal November 2019
High-Pressure Induced Phase Transitions in High-Entropy Alloys: A Review journal March 2019

Similar Records

A hexagonal close-packed high-entropy alloy: The effect of entropy
Journal Article · 2016 · Materials & Design · OSTI ID:1482333

High-entropy alloys in hexagonal close-packed structure
Journal Article · 2015 · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science · OSTI ID:1338297

Senary refractory high-entropy alloy HfNbTaTiVZr
Journal Article · 2015 · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science · OSTI ID:1338299