Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations

Yang, Yi; Zhou, Qinghai; Cai, Junjie; Xue, Teng; Liu, Yingle; Jiang, Yan; Su, Yumei; Chung, Lungwa; Vicic, David A.

doi:10.1039/C9SC00554D

Title: Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations

Journal Article · 22 May 2019 · Chemical Science

DOI: https://doi.org/10.1039/C9SC00554D · OSTI ID:1509518

^[1]; Zhou, Qinghai ^[2]; Cai, Junjie ^[1]; Xue, Teng ^[3]; Liu, Yingle ^[1]; Jiang, Yan ^[1]; Su, Yumei ^[1];

^[2]; Vicic, David A. ^[3]

Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, School of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, China
Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China
Department of Chemistry, Lehigh University, Bethlehem, USA

A bis-trifluoroethyl coordinated nickel/bipyridine complex has been developed as efficient precatalyst for diverse Suzuki-type alkylations which features unconventional precatalyst initiation mode.

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Research Organization:: Lehigh Univ., Bethlehem, PA (United States)

Sponsoring Organization:: Key Laboratory of Vanadium and Titanium of Sichuan Province; National Natural Science Foundation of China (NNSFC); Science & Technology Department of Sichuan Province; Sichuan University of Science and Engineering; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0009363

OSTI ID:: 1509518

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 20 Vol. 10; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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