Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell
Abstract
This work introduces the first practical platinum group metal-free (PGM-free) electrocatalyst for hydrogen oxidation reaction (HOR) in alkaline membrane fuel cells (AMFC), based on nickel-rich Ni95Cu5-alloy nanoparticles supported on Ketjenblack (KB) family carbon blacks. The catalyst synthesis is scalable and results in expected true alloy of NiCu, which is thoroughly characterized by XRD, microscopy and XPS. Reactivity of the catalyst towards HOR is studied by cyclic voltammetry and explained in view of its composition and structure. This catalyst showed highest specific activity compared to previously reported NiCu electrocatalysts and was successfully integrated into an AMFC membrane electrode assembly (MEA) using commercially available state-of-the-art membrane and ionomer. Single MEA fuel cell tests have demonstrated power density of 350 mWcm-2 at 80°C, which sets a technical record for a PGM-free anode in realistic operating conditions. The MEA with NiCu/KB anode catalysts layer were evaluated by in situ nano- and operando micro-X-ray computed tomography (CT) and results suggest that the nickel state in NiCu is hydrophobic in nature, where the NiCu surface may be isostructural with β-Ni(OH)2. The hydrophobic nature of electrocatalyst allows for improved water distribution in MEA and overall fuel cell as observed with operando micro X-ray CT.
- Authors:
-
- Univ. of New Mexico, Albuquerque, NM (United States)
- Tufts Univ., Medford, MA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1508978
- Alternate Identifier(s):
- OSTI ID: 1463749
- Grant/Contract Number:
- AC02-06CH11357; EE0006962
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Sustainable Energy & Fuels
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 10; Journal ID: ISSN 2398-4902
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Roy, Aaron, Talarposhti, Morteza R., Normile, Stanley J., Zenyuk, Iryna V., De Andrade, Vincent, Artyushkova, Kateryna, Serov, Alexey, and Atanassov, Plamen. Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell. United States: N. p., 2018.
Web. doi:10.1039/c8se00261d.
Roy, Aaron, Talarposhti, Morteza R., Normile, Stanley J., Zenyuk, Iryna V., De Andrade, Vincent, Artyushkova, Kateryna, Serov, Alexey, & Atanassov, Plamen. Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell. United States. https://doi.org/10.1039/c8se00261d
Roy, Aaron, Talarposhti, Morteza R., Normile, Stanley J., Zenyuk, Iryna V., De Andrade, Vincent, Artyushkova, Kateryna, Serov, Alexey, and Atanassov, Plamen. Fri .
"Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell". United States. https://doi.org/10.1039/c8se00261d. https://www.osti.gov/servlets/purl/1508978.
@article{osti_1508978,
title = {Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell},
author = {Roy, Aaron and Talarposhti, Morteza R. and Normile, Stanley J. and Zenyuk, Iryna V. and De Andrade, Vincent and Artyushkova, Kateryna and Serov, Alexey and Atanassov, Plamen},
abstractNote = {This work introduces the first practical platinum group metal-free (PGM-free) electrocatalyst for hydrogen oxidation reaction (HOR) in alkaline membrane fuel cells (AMFC), based on nickel-rich Ni95Cu5-alloy nanoparticles supported on Ketjenblack (KB) family carbon blacks. The catalyst synthesis is scalable and results in expected true alloy of NiCu, which is thoroughly characterized by XRD, microscopy and XPS. Reactivity of the catalyst towards HOR is studied by cyclic voltammetry and explained in view of its composition and structure. This catalyst showed highest specific activity compared to previously reported NiCu electrocatalysts and was successfully integrated into an AMFC membrane electrode assembly (MEA) using commercially available state-of-the-art membrane and ionomer. Single MEA fuel cell tests have demonstrated power density of 350 mWcm-2 at 80°C, which sets a technical record for a PGM-free anode in realistic operating conditions. The MEA with NiCu/KB anode catalysts layer were evaluated by in situ nano- and operando micro-X-ray computed tomography (CT) and results suggest that the nickel state in NiCu is hydrophobic in nature, where the NiCu surface may be isostructural with β-Ni(OH)2. The hydrophobic nature of electrocatalyst allows for improved water distribution in MEA and overall fuel cell as observed with operando micro X-ray CT.},
doi = {10.1039/c8se00261d},
journal = {Sustainable Energy & Fuels},
number = 10,
volume = 2,
place = {United States},
year = {2018},
month = {7}
}
Web of Science
Works referenced in this record:
Pt–Ru catalyzed hydrogen oxidation in alkaline media: oxophilic effect or electronic effect?
journal, January 2015
- Wang, Ying; Wang, Gongwei; Li, Guangwei
- Energy & Environmental Science, Vol. 8, Issue 1
TomoPy: a framework for the analysis of synchrotron tomographic data
journal, August 2014
- Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui
- Journal of Synchrotron Radiation, Vol. 21, Issue 5
Review of cell performance in anion exchange membrane fuel cells
journal, January 2018
- Dekel, Dario R.
- Journal of Power Sources, Vol. 375
A review on recent developments of anion exchange membranes for fuel cells and redox flow batteries
journal, January 2015
- Maurya, Sandip; Shin, Sung-Hee; Kim, Yekyung
- RSC Advances, Vol. 5, Issue 47
Structure of Fe–N x –C Defects in Oxygen Reduction Reaction Catalysts from First-Principles Modeling
journal, June 2014
- Holby, Edward F.; Wu, Gang; Zelenay, Piotr
- The Journal of Physical Chemistry C, Vol. 118, Issue 26
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism
journal, January 2014
- Durst, J.; Siebel, A.; Simon, C.
- Energy Environ. Sci., Vol. 7, Issue 7
Gas-diffusion-layer structural properties under compression via X-ray tomography
journal, October 2016
- Zenyuk, Iryna V.; Parkinson, Dilworth Y.; Connolly, Liam G.
- Journal of Power Sources, Vol. 328
Anion exchange membranes for alkaline fuel cells: A review
journal, July 2011
- Merle, Géraldine; Wessling, Matthias; Nijmeijer, Kitty
- Journal of Membrane Science, Vol. 377, Issue 1-2, p. 1-35
Palladium Supported on 3D Graphene as an Active Catalyst for Alcohols Electrooxidation
journal, January 2015
- Serov, Alexey; Andersen, Nalin I.; Kabir, Sadia A.
- Journal of The Electrochemical Society, Vol. 162, Issue 12
Nickel–silver alloy electrocatalysts for hydrogen evolution and oxidation in an alkaline electrolyte
journal, January 2014
- Tang, Maureen H.; Hahn, Christopher; Klobuchar, Aidan J.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 36
A short-range ordered–disordered transition of a NiOOH/Ni(OH) 2 pair induces switchable wettability
journal, January 2014
- Chang, Ya-Huei; Hau, Nga Yu; Liu, Chang
- Nanoscale, Vol. 6, Issue 24
Scientific data exchange: a schema for HDF5-based storage of raw and analyzed data
journal, October 2014
- De Carlo, Francesco; Gürsoy, Dogˇa; Marone, Federica
- Journal of Synchrotron Radiation, Vol. 21, Issue 6
Palladium/nickel bifunctional electrocatalyst for hydrogen oxidation reaction in alkaline membrane fuel cell
journal, February 2016
- Alesker, Maria; Page, Miles; Shviro, Meital
- Journal of Power Sources, Vol. 304
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media
journal, November 2017
- Li, Jingkun; Ghoshal, Shraboni; Bates, Michael K.
- Angewandte Chemie International Edition, Vol. 56, Issue 49
Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015
- Strickland, Kara; Miner, Elise; Jia, Qingying
- Nature Communications, Vol. 6, Issue 1
Hydrogen oxidation reaction in alkaline media: Relationship between electrocatalysis and electrochemical double-layer structure
journal, November 2017
- Ramaswamy, Nagappan; Ghoshal, Shraboni; Bates, Michael K.
- Nano Energy, Vol. 41
Investigating Phase‐Change‐Induced Flow in Gas Diffusion Layers in Fuel Cells with X‐ray Computed Tomography
journal, December 2017
- Shum, Andrew D.; Parkinson, Dilworth Y.; Xiao, Xianghui
- Electrochimica Acta, Vol. 256
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems
journal, April 2009
- Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M.
- Surface and Interface Analysis, Vol. 41, Issue 4
Nickel supported on nitrogen-doped carbon nanotubes as hydrogen oxidation reaction catalyst in alkaline electrolyte
journal, January 2016
- Zhuang, Zhongbin; Giles, Stephen A.; Zheng, Jie
- Nature Communications, Vol. 7, Issue 1
Anion-exchange membranes in electrochemical energy systems
journal, January 2014
- Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R.
- Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191
Highly active nanostructured palladium-ceria electrocatalysts for the hydrogen oxidation reaction in alkaline medium
journal, March 2017
- Miller, Hamish A.; Vizza, Francesco; Marelli, Marcello
- Nano Energy, Vol. 33
Platinum group metal-free NiMo hydrogen oxidation catalysts: high performance and durability in alkaline exchange membrane fuel cells
journal, January 2017
- Kabir, Sadia; Lemire, Kenneth; Artyushkova, Kateryna
- Journal of Materials Chemistry A, Vol. 5, Issue 46
Manipulating Water in High-Performance Hydroxide Exchange Membrane Fuel Cells through Asymmetric Humidification and Wetproofing
journal, January 2015
- Kaspar, Robert B.; Letterio, Michael P.; Wittkopf, Jarrid A.
- Journal of The Electrochemical Society, Vol. 162, Issue 6
On the Effect of Cu on the Activity of Carbon Supported Ni Nanoparticles for Hydrogen Electrode Reactions in Alkaline Medium
journal, September 2015
- Oshchepkov, Alexandr G.; Simonov, Pavel A.; Cherstiouk, Olga V.
- Topics in Catalysis, Vol. 58, Issue 18-20
Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H
journal, August 2002
- Conway, B. E.; Tilak, B. V.
- Electrochimica Acta, Vol. 47, Issue 22-23, p. 3571-3594
Surface configuration and wettability of nickel(oxy)hydroxides: a first-principles investigation
journal, January 2017
- Eslamibidgoli, Mohammad Javad; Groß, Axel; Eikerling, Michael
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Nanoscale 3D imaging at the Advanced Photon Source
journal, May 2016
- De Andrade, Vincent; Deriy, Alex; Wojcik, Michael J.
- SPIE Newsroom
Highly active and selective nickel molybdenum catalysts for direct hydrazine fuel cell
journal, October 2016
- Asset, Tristan; Roy, Aaron; Sakamoto, Tomokazu
- Electrochimica Acta, Vol. 215
Metal organic frameworks for electrochemical applications
journal, January 2012
- Morozan, Adina; Jaouen, Frédéric
- Energy & Environmental Science, Vol. 5, Issue 11
Integration of TomoPy and the ASTRA toolbox for advanced processing and reconstruction of tomographic synchrotron data
journal, April 2016
- Pelt, Daniël M.; Gürsoy, Dogˇa; Palenstijn, Willem Jan
- Journal of Synchrotron Radiation, Vol. 23, Issue 3
Hot topics in alkaline exchange membrane fuel cells
journal, January 2018
- Serov, Alexey; Zenyuk, Iryna V.; Arges, Christopher G.
- Journal of Power Sources, Vol. 375
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media
journal, November 2017
- Li, Jingkun; Ghoshal, Shraboni; Bates, Michael K.
- Angewandte Chemie, Vol. 129, Issue 49
TomoPy: A framework for the analysis of synchrotron tomographic data
conference, September 2014
- Gürsoy, Doğa; De Carlo, Francesco; Xiao, Xianghui
- SPIE Optical Engineering + Applications, SPIE Proceedings
Works referencing / citing this record:
Nitrogen‐doped Carbon–CoO x Nanohybrids: A Precious Metal Free Cathode that Exceeds 1.0 W cm −2 Peak Power and 100 h Life in Anion‐Exchange Membrane Fuel Cells
journal, November 2018
- Peng, Xiong; Omasta, Travis J.; Magliocca, Emanuele
- Angewandte Chemie, Vol. 131, Issue 4
Nitrogen-doped Carbon-CoO x Nanohybrids: A Precious Metal Free Cathode that Exceeds 1.0 W cm −2 Peak Power and 100 h Life in Anion-Exchange Membrane Fuel Cells
journal, November 2018
- Peng, Xiong; Omasta, Travis J.; Magliocca, Emanuele
- Angewandte Chemie International Edition, Vol. 58, Issue 4
Investigation of Perovskite Oxide SrCo 0.8 Cu 0.1 Nb 0.1 O 3– δ as a Cathode Material for Room Temperature Direct Ammonia Fuel Cells
journal, May 2019
- Zou, Peimiao; Chen, Shigang; Lan, Rong
- ChemSusChem, Vol. 12, Issue 12
Pd‐Decorated Tungsten as Pt‐Free Bimetallic Catalysts for Hydrogen Oxidation Reaction in Alkaline Electrolyte
journal, December 2019
- Arulrajan, Antony Cyril; Subramanian, Palaniappan; Singh, Ramesh Kumar
- Israel Journal of Chemistry, Vol. 60, Issue 5-6
Ultrathin IrRu nanowire networks with high performance and durability for the hydrogen oxidation reaction in alkaline anion exchange membrane fuel cells
journal, January 2018
- Qin, Bowen; Yu, Hongmei; Gao, Xueqiang
- Journal of Materials Chemistry A, Vol. 6, Issue 41
Weakening hydrogen adsorption on nickel via interstitial nitrogen doping promotes bifunctional hydrogen electrocatalysis in alkaline solution
journal, January 2019
- Wang, Tingting; Wang, Miao; Yang, Hao
- Energy & Environmental Science, Vol. 12, Issue 12
Ultrafine Pt cluster and RuO 2 heterojunction anode catalysts designed for ultra-low Pt-loading anion exchange membrane fuel cells
journal, January 2020
- Wang, Rongyue; Li, Dongguo; Maurya, Sandip
- Nanoscale Horizons, Vol. 5, Issue 2
Pt-rare earth metal alloy/metal oxide catalysts for oxygen reduction and alcohol oxidation reactions: an overview
journal, January 2019
- Peera, Shaik Gouse; Lee, Tae Gwan; Sahu, Akhila Kumar
- Sustainable Energy & Fuels, Vol. 3, Issue 8
Analysis of the effect of catalyst layer thickness on the performance and durability of platinum group metal-free catalysts for polymer electrolyte membrane fuel cells
journal, January 2019
- Baricci, Andrea; Bisello, Andrea; Serov, Alexey
- Sustainable Energy & Fuels, Vol. 3, Issue 12
Hydrogen Oxidation on Ni-Based Electrocatalysts: The Effect of Metal Doping
journal, October 2018
- Davydova, Elena; Zaffran, Jérémie; Dhaka, Kapil
- Catalysts, Vol. 8, Issue 10
Platinum and Platinum Group Metal-Free Catalysts for Anion Exchange Membrane Fuel Cells
journal, January 2020
- Men Truong, Van; Richard Tolchard, Julian; Svendby, Jørgen
- Energies, Vol. 13, Issue 3