Light harvesting and energy transfer in a porphyrin-based metal organic framework

Shaikh, Shaunak M.; Chakraborty, Arnab; Alatis, James; Cai, Meng; Danilov, Evgeny; Morris, Amanda J.

doi:10.1039/C8FD00194D

Title: Light harvesting and energy transfer in a porphyrin-based metal organic framework

Abstract

We present the synthesis and photophysical characterization of a water stable PCN-223(freebase) metal organic framework (MOF) constructed from meso -tetrakis(4-carboxyphenyl)porphyrin (TCPP).

Authors:

Shaikh, Shaunak M. ^[1]; Chakraborty, Arnab ^[1]; Alatis, James ^[1]; Cai, Meng ^[1];

^[2];

^[1]

Department of Chemistry, Virginia Tech, Blacksburg, USA
Department of Chemistry, North Carolina State University, Raleigh, USA

Publication Date:: 2019-07-11

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1508663

Grant/Contract Number:: SC0012445

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Faraday Discussions

Additional Journal Information:: Journal Name: Faraday Discussions Journal Volume: 216; Journal ID: ISSN 1359-6640

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Shaikh, Shaunak M., Chakraborty, Arnab, Alatis, James, Cai, Meng, Danilov, Evgeny, and Morris, Amanda J. Light harvesting and energy transfer in a porphyrin-based metal organic framework.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C8FD00194D.

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                    Shaikh, Shaunak M., Chakraborty, Arnab, Alatis, James, Cai, Meng, Danilov, Evgeny, & Morris, Amanda J. Light harvesting and energy transfer in a porphyrin-based metal organic framework.  United Kingdom.  https://doi.org/10.1039/C8FD00194D

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                    Shaikh, Shaunak M., Chakraborty, Arnab, Alatis, James, Cai, Meng, Danilov, Evgeny, and Morris, Amanda J. Thu .  
"Light harvesting and energy transfer in a porphyrin-based metal organic framework".  United Kingdom.  https://doi.org/10.1039/C8FD00194D.

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@article{osti_1508663,

  title        = {Light harvesting and energy transfer in a porphyrin-based metal organic framework},

  author       = {Shaikh, Shaunak M. and Chakraborty, Arnab and Alatis, James and Cai, Meng and Danilov, Evgeny and Morris, Amanda J.},

  abstractNote = {We present the synthesis and photophysical characterization of a water stable PCN-223(freebase) metal organic framework (MOF) constructed from meso -tetrakis(4-carboxyphenyl)porphyrin (TCPP).},

  doi          = {10.1039/C8FD00194D},

  journal      = {Faraday Discussions},

  number       = ,

  volume       = 216,

  place        = {United Kingdom},

  year         = {2019},

  month        = {7}

}

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https://doi.org/10.1039/C8FD00194D

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Light harvesting and energy transfer in a porphyrin-based metal organic framework

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Title: Light harvesting and energy transfer in a porphyrin-based metal organic framework

Abstract

Citation Formats

Microsecond 3 MLCT excited state lifetimes in bis-tridentate Ru( ii )-complexes: significant reductions of non-radiative rate constants journal, January 2017

Effects of molecular organization on exciton diffusion in thin films of bioinspired light-harvesting molecules journal, January 2009

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A unified theory of radiative and radiationless molecular energy transfer journal, August 1989

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Protonation–deprotonation equilibria in tetrapyrroles. Part 1. Protonation titrations of 13 2 -(demethoxycarbonyl)pheophytin a in methanolic hydrochloric acid by electronic absorption spectroscopy journal, January 1991

Theory of excitation energy transfer: from structure to function journal, August 2009

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Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks journal, December 2012

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Excitation energy transfer in multiporphyrin arrays with cyclic architectures: towards artificial light-harvesting antenna complexes journal, January 2012

A Theory of Sensitized Luminescence in Solids journal, May 1953

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Ultrafast Singlet−Singlet Energy Transfer in Self-Assembled via Metal−Ligand Axial Coordination of Free-Base Porphyrin−Zinc Phthalocyanine and Free-Base Porphyrin−Zinc Naphthalocyanine Dyads journal, January 2010

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Microsecond ³ MLCT excited state lifetimes in bis-tridentate Ru( ii )-complexes: significant reductions of non-radiative rate constants
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A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
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journal, January 2015

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journal, December 2017

A unified theory of radiative and radiationless molecular energy transfer
journal, August 1989

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

Protonation–deprotonation equilibria in tetrapyrroles. Part 1. Protonation titrations of 13 ² -(demethoxycarbonyl)pheophytin a in methanolic hydrochloric acid by electronic absorption spectroscopy
journal, January 1991

Theory of excitation energy transfer: from structure to function
journal, August 2009

Triplet Excitation Energy Dynamics in Metal–Organic Frameworks
journal, June 2013

Ultrafast Dynamics of Porphyrins in the Condensed Phase: II. Zinc Tetraphenylporphyrin ^†
journal, October 2002

Metal–Organic Frameworks Based on Previously Unknown Zr ₈ /Hf ₈ Cubic Clusters
journal, October 2013

Metal−Organic Frameworks: Structural, Energetic, Electronic, and Mechanical Properties
journal, July 2007

Influence of Macrocycle Protonation on the Photophysical Properties of Porphyrins
journal, January 2011

Exciton diffusion in organic semiconductors
journal, January 2015

Framework-Topology-Dependent Catalytic Activity of Zirconium-Based (Porphinato)zinc(II) MOFs
journal, October 2016

Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks
journal, December 2012

Ultrafast Dynamics of Highly Conjugated Porphyrin Arrays
journal, November 1998

Electron transfer dynamics from the singlet and triplet excited states of meso-tetrakis(p-carboxyphenyl)porphyrin into colloidal TiO2 and AuTiO2 nanoparticles
journal, August 2010

Concentration Dependent Dimensionality of Resonance Energy Transfer in a Postsynthetically Doped Morphologically Homologous Analogue of UiO-67 MOF with a Ruthenium(II) Polypyridyl Complex
journal, June 2015

An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence
journal, September 2013

Ultrafast Energy Migration in Porphyrin-based Metal Organic Frameworks (MOFs)
journal, January 2013

Ruthenium( ii )-polypyridyl zirconium( iv ) metal–organic frameworks as a new class of sensitized solar cells
journal, January 2016

Hetero-arrays of porphyrins and phthalocyanines
journal, September 2007

Förster Energy Transport in Metal–Organic Frameworks Is Beyond Step-by-Step Hopping
journal, January 2016

Excitation energy transfer in multiporphyrin arrays with cyclic architectures: towards artificial light-harvesting antenna complexes
journal, January 2012

A Theory of Sensitized Luminescence in Solids
journal, May 1953

Topology-dependent emissive properties of zirconium-based porphyrin MOFs
journal, January 2016

Ultrafast Singlet−Singlet Energy Transfer in Self-Assembled via Metal−Ligand Axial Coordination of Free-Base Porphyrin−Zinc Phthalocyanine and Free-Base Porphyrin−Zinc Naphthalocyanine Dyads
journal, January 2010

Photophysical Characterization of a Ruthenium(II) Tris(2,2′-bipyridine)-Doped Zirconium UiO-67 Metal–Organic Framework
journal, April 2014

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

Enhancement of exciton transport in porphyrin aggregate nanostructures by controlling the hierarchical self-assembly
journal, January 2018

Enhancing exciton diffusion in porphyrin thin films using peripheral carboalkoxy groups to influence molecular assembly
journal, January 2016

Porphyrins in analytical chemistry. A review
journal, February 2000

Evidence for incoherent energy transfer processes in J-aggregates with Davydov splitting
journal, May 1998

Six-Membered Ring Chelate Complexes of Ru(II): Structural and Photophysical Effects
journal, November 2007

Spectroscopy of Protonated Tetraphenylporphyrins with Amino/Carbomethoxy Substituents: Hyperporphyrin Effects and Evidence for a Monoprotonated Porphyrin
journal, May 2013

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

Energy Transfer Dynamics in Metal−Organic Frameworks
journal, September 2010

Ultrafast Dynamics of Porphyrins in the Condensed Phase: I. Free Base Tetraphenylporphyrin ^†
journal, October 2002

Porphyrins
journal, January 1969

Time‐resolved and static optical properties of vibrationally excited porphyrins
journal, May 1991

Femtosecond electronic relaxation of excited metalloporphyrins in the gas phase
journal, March 2006