skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates

Abstract

Perturbation of molecular packing and dielectric environment at a quantum dot surface can promote singlet fission in diphenylpentacene aggregates.

Authors:
ORCiD logo [1];  [2];  [2]; ORCiD logo [2]
  1. Department of Chemistry and Biochemistry, City University of New York, Queens College, Flushing, USA
  2. Department of Chemistry, Northwestern University, Evanston, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1508423
Grant/Contract Number:  
SC0000989
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Faraday Discussions
Additional Journal Information:
Journal Name: Faraday Discussions Journal Volume: 216; Journal ID: ISSN 1359-6640
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Wang, Chen, Kodaimati, Mohamad S., Lian, Shichen, and Weiss, Emily A. Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates. United Kingdom: N. p., 2019. Web. doi:10.1039/C8FD00157J.
Wang, Chen, Kodaimati, Mohamad S., Lian, Shichen, & Weiss, Emily A. Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates. United Kingdom. doi:10.1039/C8FD00157J.
Wang, Chen, Kodaimati, Mohamad S., Lian, Shichen, and Weiss, Emily A. Thu . "Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates". United Kingdom. doi:10.1039/C8FD00157J.
@article{osti_1508423,
title = {Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates},
author = {Wang, Chen and Kodaimati, Mohamad S. and Lian, Shichen and Weiss, Emily A.},
abstractNote = {Perturbation of molecular packing and dielectric environment at a quantum dot surface can promote singlet fission in diphenylpentacene aggregates.},
doi = {10.1039/C8FD00157J},
journal = {Faraday Discussions},
number = ,
volume = 216,
place = {United Kingdom},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8FD00157J

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Solar conversion efficiency of photovoltaic and photoelectrolysis cells with carrier multiplication absorbers
journal, October 2006

  • Hanna, M. C.; Nozik, A. J.
  • Journal of Applied Physics, Vol. 100, Issue 7
  • DOI: 10.1063/1.2356795

Evidence for Charge-Transfer Mediation in the Primary Events of Singlet Fission in a Weakly Coupled Pentacene Dimer
journal, May 2018


Delayed Molecular Triplet Generation from Energized Lead Sulfide Quantum Dots
journal, March 2017

  • Garakyaraghi, Sofia; Mongin, Cédric; Granger, Devin B.
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 7
  • DOI: 10.1021/acs.jpclett.7b00546

Thermodynamic Limit of Exciton Fission Solar Cell Efficiency
journal, September 2012

  • Tayebjee, Murad J. Y.; Gray-Weale, Angus A.; Schmidt, Timothy W.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 19
  • DOI: 10.1021/jz301069u

Mechanism for Singlet Fission in Pentacene and Tetracene: From Single Exciton to Two Triplets
journal, December 2011

  • Zimmerman, Paul M.; Bell, Franziska; Casanova, David
  • Journal of the American Chemical Society, Vol. 133, Issue 49
  • DOI: 10.1021/ja208431r

Narrow-Band Absorption-Enhanced Quantum Dot/J-Aggregate Conjugates
journal, July 2009

  • Walker, Brian J.; Nair, Gautham P.; Marshall, Lisa F.
  • Journal of the American Chemical Society, Vol. 131, Issue 28
  • DOI: 10.1021/ja902813q

Efficient Singlet Fission Discovered in a Disordered Acene Film
journal, March 2012

  • Roberts, Sean T.; McAnally, R. Eric; Mastron, Joseph N.
  • Journal of the American Chemical Society, Vol. 134, Issue 14
  • DOI: 10.1021/ja300504t

Striking the right balance of intermolecular coupling for high-efficiency singlet fission
journal, January 2018

  • Pensack, Ryan D.; Tilley, Andrew J.; Grieco, Christopher
  • Chemical Science, Vol. 9, Issue 29
  • DOI: 10.1039/C8SC00293B

Singlet Fission
journal, November 2010

  • Smith, Millicent B.; Michl, Josef
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr1002613

Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy
journal, October 2015

  • Bakulin, Artem A.; Morgan, Sarah E.; Kehoe, Tom B.
  • Nature Chemistry, Vol. 8, Issue 1
  • DOI: 10.1038/nchem.2371

High-Yield Excited Triplet States in Pentacene Self-Assembled Monolayers on Gold Nanoparticles through Singlet Exciton Fission
journal, March 2016

  • Kato, Daiki; Sakai, Hayato; Tkachenko, Nikolai V.
  • Angewandte Chemie, Vol. 128, Issue 17
  • DOI: 10.1002/ange.201601421

Colloidal PbS Nanocrystals with Size-Tunable Near-Infrared Emission: Observation of Post-Synthesis Self-Narrowing of the Particle Size Distribution
journal, November 2003

  • Hines, M. A.; Scholes, G. D.
  • Advanced Materials, Vol. 15, Issue 21, p. 1844-1849
  • DOI: 10.1002/adma.200305395

Quantum Beats in Crystalline Tetracene Delayed Fluorescence Due to Triplet Pair Coherences Produced by Direct Singlet Fission
journal, May 2012

  • Burdett, Jonathan J.; Bardeen, Christopher J.
  • Journal of the American Chemical Society, Vol. 134, Issue 20
  • DOI: 10.1021/ja301683w

Dynamics of the triplet-pair state reveals the likely coexistence of coherent and incoherent singlet fission in crystalline hexacene
journal, December 2016

  • Monahan, Nicholas R.; Sun, Dezheng; Tamura, Hiroyuki
  • Nature Chemistry, Vol. 9, Issue 4
  • DOI: 10.1038/nchem.2665

Long-Lived Correlated Triplet Pairs in a π-Stacked Crystalline Pentacene Derivative
journal, February 2018

  • Folie, Brendan D.; Haber, Jonah B.; Refaely-Abramson, Sivan
  • Journal of the American Chemical Society, Vol. 140, Issue 6
  • DOI: 10.1021/jacs.7b12662

Singlet fission in pentacene through multi-exciton quantum states
journal, June 2010

  • Zimmerman, Paul M.; Zhang, Zhiyong; Musgrave, Charles B.
  • Nature Chemistry, Vol. 2, Issue 8
  • DOI: 10.1038/nchem.694

Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals
journal, October 2014

  • Tabachnyk, Maxim; Ehrler, Bruno; Gélinas, Simon
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4093

Femtosecond stimulated Raman evidence for charge-transfer character in pentacene singlet fission
journal, January 2018

  • Hart, Stephanie M.; Silva, W. Ruchira; Frontiera, Renee R.
  • Chemical Science, Vol. 9, Issue 5
  • DOI: 10.1039/C7SC03496B

Exceeding the Shockley–Queisser limit in solar energy conversion
journal, January 2013

  • Nelson, Cory A.; Monahan, Nicholas R.; Zhu, X. -Y.
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42098a

The Dynamics of Singlet Fission in Crystalline Tetracene and Covalent Analogs
journal, January 2013

  • Burdett, Jonathan J.; Bardeen, Christopher J.
  • Accounts of Chemical Research, Vol. 46, Issue 6
  • DOI: 10.1021/ar300191w

Sub-Nanosecond Resonance Energy Transfer in the Near-Infrared within Self-Assembled Conjugates of PbS Quantum Dots and Cyanine Dye J-Aggregates
journal, July 2016

  • Wang, Chen; Weiss, Emily A.
  • Journal of the American Chemical Society, Vol. 138, Issue 30
  • DOI: 10.1021/jacs.6b04087

Singlet Exciton Fission for Solar Cell Applications: Energy Aspects of Interchromophore Coupling
journal, November 2010

  • Greyson, Eric C.; Stepp, Brian R.; Chen, Xudong
  • The Journal of Physical Chemistry B, Vol. 114, Issue 45
  • DOI: 10.1021/jp909002d

Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals
journal, October 2014

  • Thompson, Nicholas J.; Wilson, Mark W. B.; Congreve, Daniel N.
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4097

Exciton Delocalization Drives Rapid Singlet Fission in Nanoparticles of Acene Derivatives
journal, May 2015

  • Pensack, Ryan D.; Tilley, Andrew J.; Parkin, Sean R.
  • Journal of the American Chemical Society, Vol. 137, Issue 21
  • DOI: 10.1021/ja512668r

The Spectral Signatures of Frenkel Polarons in H- and J-Aggregates
journal, March 2010

  • Spano, Frank C.
  • Accounts of Chemical Research, Vol. 43, Issue 3
  • DOI: 10.1021/ar900233v

Unified model for singlet fission within a non-conjugated covalent pentacene dimer
journal, May 2017

  • Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15171

Surface States Mediate Triplet Energy Transfer in Nanocrystal–Acene Composite Systems
journal, May 2018

  • Bender, Jon A.; Raulerson, Emily K.; Li, Xin
  • Journal of the American Chemical Society, Vol. 140, Issue 24
  • DOI: 10.1021/jacs.8b01966

Hybrid organic/inorganic semiconductor nanostructures with highly efficient energy transfer
journal, January 2012

  • Savateeva, Diana; Melnikau, Dzmitry; Lesnyak, Vladimir
  • Journal of Materials Chemistry, Vol. 22, Issue 21
  • DOI: 10.1039/c2jm30917c

Competition between Singlet Fission and Charge Separation in Solution-Processed Blend Films of 6,13-Bis(triisopropylsilylethynyl)pentacene with Sterically-Encumbered Perylene-3,4:9,10-bis(dicarboximide)s
journal, December 2011

  • Ramanan, Charusheela; Smeigh, Amanda L.; Anthony, John E.
  • Journal of the American Chemical Society, Vol. 134, Issue 1
  • DOI: 10.1021/ja2080482

Singlet Fission within Diketopyrrolopyrrole Nanoparticles in Water
journal, August 2017


Ultrafast Dynamics of Exciton Fission in Polycrystalline Pentacene
journal, August 2011

  • Wilson, Mark W. B.; Rao, Akshay; Clark, Jenny
  • Journal of the American Chemical Society, Vol. 133, Issue 31
  • DOI: 10.1021/ja201688h

Aqueous Colloidal Acene Nanoparticles: A New Platform for Studying Singlet Fission
journal, July 2013

  • Mastron, Joseph N.; Roberts, Sean T.; McAnally, R. Eric
  • The Journal of Physical Chemistry B, Vol. 117, Issue 49
  • DOI: 10.1021/jp4057972

Singlet fission in rubrene single crystal: direct observation by femtosecond pump–probe spectroscopy
journal, January 2012

  • Ma, Lin; Zhang, Keke; Kloc, Christian
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 23
  • DOI: 10.1039/c2cp40449d

Observation of Two Triplet-Pair Intermediates in Singlet Exciton Fission
journal, June 2016

  • Pensack, Ryan D.; Ostroumov, Evgeny E.; Tilley, Andrew J.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
  • DOI: 10.1021/acs.jpclett.6b00947

Solution-processable, crystalline material for quantitative singlet fission
journal, January 2017

  • Pensack, Ryan D.; Grieco, Christopher; Purdum, Geoffrey E.
  • Materials Horizons, Vol. 4, Issue 5
  • DOI: 10.1039/C7MH00303J

Triplet Exciton Dissociation in Singlet Exciton Fission Photovoltaics
journal, September 2012

  • Jadhav, Priya J.; Brown, Patrick R.; Thompson, Nicholas
  • Advanced Materials, Vol. 24, Issue 46
  • DOI: 10.1002/adma.201202397

Steric-Hindrance-Driven Shape Transition in PbS Quantum Dots: Understanding Size-Dependent Stability
journal, March 2013

  • Choi, Hyekyoung; Ko, Jae-Hyeon; Kim, Yong-Hyun
  • Journal of the American Chemical Society, Vol. 135, Issue 14
  • DOI: 10.1021/ja400948t

Singlet Exciton Fission-Sensitized Infrared Quantum Dot Solar Cells
journal, January 2012

  • Ehrler, Bruno; Wilson, Mark W. B.; Rao, Akshay
  • Nano Letters, Vol. 12, Issue 2
  • DOI: 10.1021/nl204297u

Observing the Multiexciton State in Singlet Fission and Ensuing Ultrafast Multielectron Transfer
journal, December 2011


Maximizing Singlet Fission in Organic Dimers: Theoretical Investigation of Triplet Yield in the Regime of Localized Excitation and Fast Coherent Electron Transfer
journal, November 2010

  • Greyson, Eric C.; Vura-Weis, Josh; Michl, Josef
  • The Journal of Physical Chemistry B, Vol. 114, Issue 45
  • DOI: 10.1021/jp907392q

Singlet Fission for Dye-Sensitized Solar Cells:  Can a Suitable Sensitizer Be Found?
journal, December 2006

  • Paci, Irina; Johnson, Justin C.; Chen, Xudong
  • Journal of the American Chemical Society, Vol. 128, Issue 51
  • DOI: 10.1021/ja063980h

A transferable model for singlet-fission kinetics
journal, May 2014

  • Yost, Shane R.; Lee, Jiye; Wilson, Mark W. B.
  • Nature Chemistry, Vol. 6, Issue 6
  • DOI: 10.1038/nchem.1945

Evidence for conical intersection dynamics mediating ultrafast singlet exciton fission
journal, March 2015

  • Musser, Andrew J.; Liebel, Matz; Schnedermann, Christoph
  • Nature Physics, Vol. 11, Issue 4
  • DOI: 10.1038/nphys3241

Charge Carrier Resolved Relaxation of the First Excitonic State in CdSe Quantum Dots Probed with Near-Infrared Transient Absorption Spectroscopy
journal, November 2010

  • McArthur, Eric A.; Morris-Cohen, Adam J.; Knowles, Kathryn E.
  • The Journal of Physical Chemistry B, Vol. 114, Issue 45
  • DOI: 10.1021/jp102101f