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Title: Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy

Abstract

A time-resolved operando X-ray absorption spectroscopy experiment was successfully designed to explore the sulfur reaction dynamics in lithium–sulfur (Li–S) batteries. It presents direct real-time experimental evidence for the distinct sulfur dynamics at different discharge rates, deepening the understanding of reaction mechanisms in Li–S batteries.

Authors:
 [1]; ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [1];  [1]; ORCiD logo [1]
  1. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics, Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China); Songshan Lake Materials Lab., Dongguan, Guangdong (China)
  2. Chinese Academy of Sciences (CAS), Shenyang (China). Advanced Carbon Division, Shenyang National Lab. for Materials Science, Inst. of Metal Research
  3. Chinese Academy of Sciences, Shanghai (China). Shanghai Synchrotron Radiation Facility, Shanghai Inst. of Applied Physics
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
OSTI Identifier:
1507701
Alternate Identifier(s):
OSTI ID: 1506138
Report Number(s):
BNL-211559-2019-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC0012704; 11675255; 51502334; 51822211
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 34; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Li-Sulfur cathode; Li batteries

Citation Formats

Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, and Yu, Xiqian. Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy. United States: N. p., 2019. Web. doi:10.1039/C9CC00485H.
Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, & Yu, Xiqian. Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy. United States. doi:10.1039/C9CC00485H.
Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, and Yu, Xiqian. Mon . "Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy". United States. doi:10.1039/C9CC00485H. https://www.osti.gov/servlets/purl/1507701.
@article{osti_1507701,
title = {Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy},
author = {Zhao, Enyue and Wang, Junyang and Li, Feng and Jiang, Zheng and Yang, Xiao-Qing and Wang, Fangwei and Li, Hong and Yu, Xiqian},
abstractNote = {A time-resolved operando X-ray absorption spectroscopy experiment was successfully designed to explore the sulfur reaction dynamics in lithium–sulfur (Li–S) batteries. It presents direct real-time experimental evidence for the distinct sulfur dynamics at different discharge rates, deepening the understanding of reaction mechanisms in Li–S batteries.},
doi = {10.1039/C9CC00485H},
journal = {ChemComm},
number = 34,
volume = 55,
place = {United States},
year = {2019},
month = {4}
}

Journal Article:
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