Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis

Luo, Qun-Xing; Guo, Li-Peng; Yao, Si-Yu; Bao, Jun; Liu, Zhao-Tie; Liu, Zhong-Wen

doi:10.1016/j.jcat.2018.11.002

Title: Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis

Journal Article · 16 November 2018 · Journal of Catalysis

DOI: https://doi.org/10.1016/j.jcat.2018.11.002 · OSTI ID:1507698

^[1]; Guo, Li-Peng ^[1]; Yao, Si-Yu ^[2]; Bao, Jun ^[3];

^[1]; Liu, Zhong-Wen ^[1]

Shaanxi Normal Univ., Xi’an (China). Key Lab. of Applied Surface and Colloid Chemistry (MOE), School of Chemistry and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
Univ. of Science and Technology of China, Hefei (China). National Synchrotron Radiation Lab.

The size effect of the metallic Co (Co⁰) over supported catalysts for Fischer-Tropsch synthesis (FTS) has imposed great importance for developing a high-performance catalyst. However, the lack of well-structured catalysts makes the clarification of the intrinsic size-dependence of Co⁰ still a challenge. In this work, the Co/C catalysts with Co⁰ particles from 8.4 ± 1.9 to 74.8 ± 11.6 nm were synthesized by well-controlled pyrolysis of ZIF-67. Based on different characterizations, Co/C catalysts via pyrolyzing ZIF-67 above 450 °C were confirmed as Co0 entrapped in partially graphitized carbon matrix polished by a certain amount of pyridinic and graphitic N and a small portion of adsorbed oxygen. Without the limitation of high-temperature reduction and the dispersion-reducibility dependence, the intrinsic size effect of Co⁰ on the activity and product selectivity of FTS was rigorously revealed, and the critical size was determined to be 10.5 ± 1.9 nm.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1507698

Report Number(s):: BNL-211560-2019-JAAM

Journal Information:: Journal of Catalysis, Vol. 369, Issue C; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC
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PHYSICAL AND ANALYTICAL CHEMISTRY
Fischer-Tropsch synthesis
Synthesis gas
Product distribution
Cobalt
Size effect
Porous carbon

Title: Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis

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