Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis
Abstract
The size effect of the metallic Co (Co0) over supported catalysts for Fischer-Tropsch synthesis (FTS) has imposed great importance for developing a high-performance catalyst. However, the lack of well-structured catalysts makes the clarification of the intrinsic size-dependence of Co0 still a challenge. In this work, the Co/C catalysts with Co0 particles from 8.4 ± 1.9 to 74.8 ± 11.6 nm were synthesized by well-controlled pyrolysis of ZIF-67. Based on different characterizations, Co/C catalysts via pyrolyzing ZIF-67 above 450 °C were confirmed as Co0 entrapped in partially graphitized carbon matrix polished by a certain amount of pyridinic and graphitic N and a small portion of adsorbed oxygen. Without the limitation of high-temperature reduction and the dispersion-reducibility dependence, the intrinsic size effect of Co0 on the activity and product selectivity of FTS was rigorously revealed, and the critical size was determined to be 10.5 ± 1.9 nm.
- Authors:
-
[1];
[1];
- Shaanxi Normal Univ., Xi’an (China). Key Lab. of Applied Surface and Colloid Chemistry (MOE), School of Chemistry and Chemical Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- Univ. of Science and Technology of China, Hefei (China). National Synchrotron Radiation Lab.
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1507698
- Report Number(s):
- BNL-211560-2019-JAAM
Journal ID: ISSN 0021-9517
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Catalysis
- Additional Journal Information:
- Journal Volume: 369; Journal Issue: C; Journal ID: ISSN 0021-9517
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; Fischer-Tropsch synthesis; Synthesis gas; Product distribution; Cobalt; Size effect; Porous carbon
Citation Formats
Luo, Qun-Xing, Guo, Li-Peng, Yao, Si-Yu, Bao, Jun, Liu, Zhao-Tie, and Liu, Zhong-Wen. Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis. United States: N. p., 2018.
Web. doi:10.1016/j.jcat.2018.11.002.
Luo, Qun-Xing, Guo, Li-Peng, Yao, Si-Yu, Bao, Jun, Liu, Zhao-Tie, & Liu, Zhong-Wen. Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis. United States. https://doi.org/10.1016/j.jcat.2018.11.002
Luo, Qun-Xing, Guo, Li-Peng, Yao, Si-Yu, Bao, Jun, Liu, Zhao-Tie, and Liu, Zhong-Wen. Fri .
"Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis". United States. https://doi.org/10.1016/j.jcat.2018.11.002. https://www.osti.gov/servlets/purl/1507698.
@article{osti_1507698,
title = {Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis},
author = {Luo, Qun-Xing and Guo, Li-Peng and Yao, Si-Yu and Bao, Jun and Liu, Zhao-Tie and Liu, Zhong-Wen},
abstractNote = {The size effect of the metallic Co (Co0) over supported catalysts for Fischer-Tropsch synthesis (FTS) has imposed great importance for developing a high-performance catalyst. However, the lack of well-structured catalysts makes the clarification of the intrinsic size-dependence of Co0 still a challenge. In this work, the Co/C catalysts with Co0 particles from 8.4 ± 1.9 to 74.8 ± 11.6 nm were synthesized by well-controlled pyrolysis of ZIF-67. Based on different characterizations, Co/C catalysts via pyrolyzing ZIF-67 above 450 °C were confirmed as Co0 entrapped in partially graphitized carbon matrix polished by a certain amount of pyridinic and graphitic N and a small portion of adsorbed oxygen. Without the limitation of high-temperature reduction and the dispersion-reducibility dependence, the intrinsic size effect of Co0 on the activity and product selectivity of FTS was rigorously revealed, and the critical size was determined to be 10.5 ± 1.9 nm.},
doi = {10.1016/j.jcat.2018.11.002},
journal = {Journal of Catalysis},
number = C,
volume = 369,
place = {United States},
year = {Fri Nov 16 00:00:00 EST 2018},
month = {Fri Nov 16 00:00:00 EST 2018}
}
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