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Title: Catalytic hydrazine disproportionation mediated by a thiolate-bridged VFe complex

Abstract

A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields of up to 1073 equivalents of NH 3 per catalyst, comparable to the highest turnover known for any molecular catalyst.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
  2. Department of Chemistry, University of Connecticut, Storrs, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1507455
Grant/Contract Number:  
DOE-0235032
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 37; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Gu, Nina X., Ung, Gaël, and Peters, Jonas C. Catalytic hydrazine disproportionation mediated by a thiolate-bridged VFe complex. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC00345B.
Gu, Nina X., Ung, Gaël, & Peters, Jonas C. Catalytic hydrazine disproportionation mediated by a thiolate-bridged VFe complex. United Kingdom. doi:10.1039/C9CC00345B.
Gu, Nina X., Ung, Gaël, and Peters, Jonas C. Thu . "Catalytic hydrazine disproportionation mediated by a thiolate-bridged VFe complex". United Kingdom. doi:10.1039/C9CC00345B.
@article{osti_1507455,
title = {Catalytic hydrazine disproportionation mediated by a thiolate-bridged VFe complex},
author = {Gu, Nina X. and Ung, Gaël and Peters, Jonas C.},
abstractNote = {A heterobimetallic VFe complex is demonstrated to catalyse hydrazine disproportionation with yields of up to 1073 equivalents of NH 3 per catalyst, comparable to the highest turnover known for any molecular catalyst.},
doi = {10.1039/C9CC00345B},
journal = {Chemical Communications},
number = 37,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on April 9, 2020
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