skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A surface with stress, extensional elasticity, and bending stiffness

Abstract

We demonstrate that the surface of a commonly used polydimethylsiloxane formulation (PDMS, Sylgard 184) treated by ultraviolet ozonolysis (UVO) has significant surface stress, considerable extensional elasticity (the “Shuttleworth Effect”), and surface bending elasticity.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [4]
  1. Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, USA
  2. Department of Mechanical & Aerospace Engineering, Cornell University, Ithaca, New York, USA
  3. Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, USA
  4. Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, USA, Department of Bioengineering
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1507446
Grant/Contract Number:  
DEFG02-07ER46463
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Soft Matter
Additional Journal Information:
Journal Name: Soft Matter Journal Volume: 15 Journal Issue: 18; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lapinski, Nicole, Liu, Zezhou, Yang, Shu, Hui, Chung-Yuen, and Jagota, Anand. A surface with stress, extensional elasticity, and bending stiffness. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SM00075E.
Lapinski, Nicole, Liu, Zezhou, Yang, Shu, Hui, Chung-Yuen, & Jagota, Anand. A surface with stress, extensional elasticity, and bending stiffness. United Kingdom. doi:10.1039/C9SM00075E.
Lapinski, Nicole, Liu, Zezhou, Yang, Shu, Hui, Chung-Yuen, and Jagota, Anand. Wed . "A surface with stress, extensional elasticity, and bending stiffness". United Kingdom. doi:10.1039/C9SM00075E.
@article{osti_1507446,
title = {A surface with stress, extensional elasticity, and bending stiffness},
author = {Lapinski, Nicole and Liu, Zezhou and Yang, Shu and Hui, Chung-Yuen and Jagota, Anand},
abstractNote = {We demonstrate that the surface of a commonly used polydimethylsiloxane formulation (PDMS, Sylgard 184) treated by ultraviolet ozonolysis (UVO) has significant surface stress, considerable extensional elasticity (the “Shuttleworth Effect”), and surface bending elasticity.},
doi = {10.1039/C9SM00075E},
journal = {Soft Matter},
number = 18,
volume = 15,
place = {United Kingdom},
year = {2019},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SM00075E

Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

From adhesion to wetting of a soft particle
journal, January 2013

  • Salez, Thomas; Benzaquen, Michael; Raphaël, Élie
  • Soft Matter, Vol. 9, Issue 45
  • DOI: 10.1039/c3sm51780b

Intrinsic Contact Angle of Aqueous Phases at Membranes and Vesicles
journal, December 2009


Biologically inspired crack trapping for enhanced adhesion
journal, June 2007

  • Glassmaker, N. J.; Jagota, A.; Hui, C. -Y.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 26
  • DOI: 10.1073/pnas.0703762104

Polymeric Droplets on Soft Surfaces: From Neumann’s Triangle to Young’s Law
journal, January 2015

  • Cao, Zhen; Dobrynin, Andrey V.
  • Macromolecules, Vol. 48, Issue 2
  • DOI: 10.1021/ma501672p

Surface stress in solids
journal, January 1978


Constraints on Microcontact Printing Imposed by Stamp Deformation
journal, February 2002

  • Hui, C. Y.; Jagota, A.; Lin, Y. Y.
  • Langmuir, Vol. 18, Issue 4
  • DOI: 10.1021/la0113567

Role of uncrosslinked chains in droplets dynamics on silicone elastomers
journal, January 2017

  • Hourlier-Fargette, Aurélie; Antkowiak, Arnaud; Chateauminois, Antoine
  • Soft Matter, Vol. 13, Issue 19
  • DOI: 10.1039/C7SM00447H

Solid Drops: Large Capillary Deformations of Immersed Elastic Rods
journal, September 2013


Contact Angles on a Soft Solid: From Young’s Law to Neumann’s Law
journal, December 2012


Effects of surface stress on the elastic moduli of thin films and superlattices
journal, April 1989


Surface Stress in the Self-Assembly of Alkanethiols on Gold
journal, June 1997


Buckling of Langmuir Monolayers
journal, July 1989


A general theory of a Cosserat surface
journal, January 1965

  • Green, A. E.; Naghdi, P. M.; Wainwright, W. L.
  • Archive for Rational Mechanics and Analysis, Vol. 20, Issue 4
  • DOI: 10.1007/BF00253138

Deformation of an Elastic Substrate by a Three-Phase Contact Line
journal, May 2011


Indentation of a rigid sphere into an elastic substrate with surface tension and adhesion
journal, March 2015

  • Hui, Chung-Yuen; Liu, Tianshu; Salez, Thomas
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 471, Issue 2175
  • DOI: 10.1098/rspa.2014.0727

Estimation of solid–liquid interfacial tension using curved surface of a soft solid
journal, September 2015

  • Mondal, Subrata; Phukan, Monmee; Ghatak, Animangsu
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 41
  • DOI: 10.1073/pnas.1502642112

Surface and Interface Stresses
journal, August 1994


The mechanical properties of a surface-modified layer on polydimethylsiloxane
journal, January 2008

  • Mills, K. L.; Zhu, Xiaoyue; Takayama, Shuichi
  • Journal of Materials Research, Vol. 23, Issue 1
  • DOI: 10.1557/JMR.2008.0029

Effects of surface tension on the adhesive contact of a rigid sphere to a compliant substrate
journal, January 2014

  • Xu, Xuejuan; Jagota, Anand; Hui, Chung-Yuen
  • Soft Matter, Vol. 10, Issue 26
  • DOI: 10.1039/C4SM00216D

Solid surface tension measured by a liquid drop under a solid film
journal, June 2013

  • Nadermann, N.; Hui, C. -Y.; Jagota, A.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 26
  • DOI: 10.1073/pnas.1304587110

Contact Mechanics of Nanoparticles
journal, July 2012

  • Carrillo, Jan-Michael Y.; Dobrynin, Andrey V.
  • Langmuir, Vol. 28, Issue 29
  • DOI: 10.1021/la301657c

Nanoscale Hydrophobic Recovery: A Chemical Force Microscopy Study of UV/Ozone-Treated Cross-Linked Poly(dimethylsiloxane)
journal, February 2004

  • Hillborg, Henrik; Tomczak, Nikodem; Olàh, Attila
  • Langmuir, Vol. 20, Issue 3, p. 785-794
  • DOI: 10.1021/la035552k

Capillary wrinkling of elastic membranes
journal, January 2010

  • Vella, D.; Adda-Bedia, M.; Cerda, E.
  • Soft Matter, Vol. 6, Issue 22
  • DOI: 10.1039/c0sm00432d

Interfacial properties of elastically strained materials: I. Thermodynamics of a planar interface
journal, September 1988

  • Nozi�res, P.; Wolf, D. E.
  • Zeitschrift f�r Physik B Condensed Matter, Vol. 70, Issue 3
  • DOI: 10.1007/BF01317248

Mechanically tunable dry adhesive from wrinkled elastomers
journal, January 2008

  • Lin, Pei-Chun; Vajpayee, Shilpi; Jagota, Anand
  • Soft Matter, Vol. 4, Issue 9
  • DOI: 10.1039/b802848f

Planar equilibrium shapes of a liquid drop on a membrane
journal, January 2015


Complex Fluid-Fluid Interfaces: Rheology and Structure
journal, July 2012


The Surface Tension of Solids
journal, May 1950


Liquid Droplets on a Highly Deformable Membrane
journal, November 2015


Surface tension and contact with soft elastic solids
journal, November 2013

  • Style, Robert W.; Hyland, Callen; Boltyanskiy, Rostislav
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3728

A curvature-dependent interfacial energy-based interface stress theory and its applications to nano-structured materials: (I) General theory
journal, May 2014


Surface Modification of Sylgard-184 Poly(dimethyl siloxane) Networks by Ultraviolet and Ultraviolet/Ozone Treatment
journal, October 2002

  • Efimenko, Kirill; Wallace, William E.; Genzer, Jan
  • Journal of Colloid and Interface Science, Vol. 254, Issue 2, p. 306-315
  • DOI: 10.1006/jcis.2002.8594

Elastocapillarity: Surface Tension and the Mechanics of Soft Solids
journal, March 2017


Flattening of a patterned compliant solid by surface stress
journal, January 2014

  • Paretkar, Dadhichi; Xu, Xuejuan; Hui, Chung-Yuen
  • Soft Matter, Vol. 10, Issue 23
  • DOI: 10.1039/C3SM52891J

On a stress resultant geometrically exact shell model. Part III: Computational aspects of the nonlinear theory
journal, March 1990

  • Simo, J. C.; Fox, D. D.; Rifai, M. S.
  • Computer Methods in Applied Mechanics and Engineering, Vol. 79, Issue 1
  • DOI: 10.1016/0045-7825(90)90094-3

A buckling-based metrology for measuring the elastic moduli of polymeric thin films
journal, July 2004

  • Stafford, Christopher M.; Harrison, Christopher; Beers, Kathryn L.
  • Nature Materials, Vol. 3, Issue 8, p. 545-550
  • DOI: 10.1038/nmat1175

Elastic Properties of Lipid Bilayers: Theory and Possible Experiments
journal, December 1973


Determination of the interfacial tension by zero creep experiments on multilayers—II. Experiment
journal, October 1993


Capillarity Driven Instability of a Soft Solid
journal, November 2010