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Title: Chemical control of the electrical surface properties in donor-doped transition metal oxides

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Publisher's Accepted Manuscript
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Physical Review Materials
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Journal Name: Physical Review Materials Journal Volume: 3 Journal Issue: 4; Journal ID: ISSN 2475-9953
American Physical Society
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United States

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Andrä, M., Bluhm, H., Dittmann, R., Schneider, C. M., Waser, R., Mueller, D. N., and Gunkel, F. Chemical control of the electrical surface properties in donor-doped transition metal oxides. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.044604.
Andrä, M., Bluhm, H., Dittmann, R., Schneider, C. M., Waser, R., Mueller, D. N., & Gunkel, F. Chemical control of the electrical surface properties in donor-doped transition metal oxides. United States.
Andrä, M., Bluhm, H., Dittmann, R., Schneider, C. M., Waser, R., Mueller, D. N., and Gunkel, F. Mon . "Chemical control of the electrical surface properties in donor-doped transition metal oxides". United States.
title = {Chemical control of the electrical surface properties in donor-doped transition metal oxides},
author = {Andrä, M. and Bluhm, H. and Dittmann, R. and Schneider, C. M. and Waser, R. and Mueller, D. N. and Gunkel, F.},
abstractNote = {},
doi = {10.1103/PhysRevMaterials.3.044604},
journal = {Physical Review Materials},
number = 4,
volume = 3,
place = {United States},
year = {2019},
month = {4}

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Works referenced in this record:

Transport limits in defect-engineered LaAlO 3 /SrTiO 3 bilayers
journal, January 2015

  • Gunkel, Felix; Wicklein, Sebastian; Hoffmann-Eifert, Susanne
  • Nanoscale, Vol. 7, Issue 3
  • DOI: 10.1039/C4NR06272H

Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009

  • Frank Ogletree, D.; Bluhm, Hendrik; Hebenstreit, Eleonore D.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 601, Issue 1-2
  • DOI: 10.1016/j.nima.2008.12.155

Interface takes charge over Si Oxide electronics
journal, March 2011

  • Schlom, Darrell G.; Mannhart, Jochen
  • Nature Materials, Vol. 10, Issue 3, p. 168-169
  • DOI: 10.1038/nmat2965

Optical and Chemi-Resistive Sensing in Extreme Environments: La-Doped SrTiO 3 Films for Hydrogen Sensing at High Temperatures
journal, March 2015

  • Schultz, Andrew M.; Brown, Thomas D.; Ohodnicki, Paul R.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 11
  • DOI: 10.1021/jp512391f

Polaronic behavior in a weak-coupling superconductor
journal, January 2018

  • Swartz, Adrian G.; Inoue, Hisashi; Merz, Tyler A.
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 7
  • DOI: 10.1073/pnas.1713916115

Tailoring resistive switching in Pt/SrTiO3 junctions by stoichiometry control
journal, June 2015

  • Mikheev, Evgeny; Hwang, Jinwoo; Kajdos, Adam P.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep11079

Surface termination and subsurface restructuring of perovskite-based solid oxide electrode materials
journal, January 2014

  • Druce, J.; Téllez, H.; Burriel, M.
  • Energy Environ. Sci., Vol. 7, Issue 11
  • DOI: 10.1039/C4EE01497A

Verification of redox-processes as switching and retention failure mechanisms in Nb:SrTiO 3 /metal devices
journal, January 2016

Annealing Effects on Sensitivity of Atomic-Layer-Deposited SrTiO 3 -Based Oxygen Sensors
journal, September 2010

  • Hara, Toru; Ishiguro, Takashi; Shinozaki, Kazuo
  • Japanese Journal of Applied Physics, Vol. 49, Issue 9
  • DOI: 10.1143/JJAP.49.09MA15

Double Perovskites as Anode Materials for Solid-Oxide Fuel Cells
journal, April 2006

A differentially pumped electrostatic lens system for photoemission studies in the millibar range
journal, November 2002

  • Ogletree, D. Frank; Bluhm, Hendrik; Lebedev, Gennadi
  • Review of Scientific Instruments, Vol. 73, Issue 11
  • DOI: 10.1063/1.1512336

Calibration of electron spectra
journal, January 1973

  • Johansson, G.; Hedman, J.; Berndtsson, A.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 2, Issue 3
  • DOI: 10.1016/0368-2048(73)80022-2

Designing strontium titanate-based thermoelectrics: insight into defect chemistry mechanisms
journal, January 2017

  • Kovalevsky, Andrei V.; Aguirre, Myriam H.; Populoh, Sascha
  • Journal of Materials Chemistry A, Vol. 5, Issue 8
  • DOI: 10.1039/C6TA09860F

Band Edge Engineering of Oxide Photoanodes for Photoelectrochemical Water Splitting: Integration of Subsurface Dipoles with Atomic-Scale Control
journal, January 2016

  • Hikita, Yasuyuki; Nishio, Kazunori; Seitz, Linsey C.
  • Advanced Energy Materials, Vol. 6, Issue 7
  • DOI: 10.1002/aenm.201502154

Surface segregation and restructuring of colossal-magnetoresistant manganese perovskites La 0.65 Sr 0.35 MnO 3
journal, December 2000

Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3
journal, November 2014

  • Ge, Jian-Feng; Liu, Zhi-Long; Liu, Canhua
  • Nature Materials, Vol. 14, Issue 3
  • DOI: 10.1038/nmat4153

Surface Termination Conversion during SrTiO3 Thin Film Growth Revealed by X-ray Photoelectron Spectroscopy
journal, July 2015

  • Baeumer, Christoph; Xu, Chencheng; Gunkel, Felix
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep11829

Atomically precise interfaces from non-stoichiometric deposition
journal, August 2014

  • Nie, Y. F.; Zhu, Y.; Lee, C. -H.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5530

Transition Metal Oxides
journal, October 1989

Coexistence of Filamentary and Homogeneous Resistive Switching in Fe-Doped SrTiO3 Thin-Film Memristive Devices
journal, August 2010

  • Muenstermann, Ruth; Menke, Tobias; Dittmann, Regina
  • Advanced Materials, Vol. 22, Issue 43, p. 4819-4822
  • DOI: 10.1002/adma.201001872

Resistive donor-doped SrTiO3 sensors: I, basic model for a fast sensor response
journal, July 2004

Chemical Heterogeneities on La 0.6 Sr 0.4 CoO 3−δ Thin Films—Correlations to Cathode Surface Activity and Stability
journal, March 2012

  • Cai, Zhuhua; Kubicek, Markus; Fleig, Jürgen
  • Chemistry of Materials, Vol. 24, Issue 6
  • DOI: 10.1021/cm203501u

Epitaxial SrTiO3 films with electron mobilities exceeding 30,000 cm2 V-1 s-1
journal, April 2010

  • Son, Junwoo; Moetakef, Pouya; Jalan, Bharat
  • Nature Materials, Vol. 9, Issue 6, p. 482-484
  • DOI: 10.1038/nmat2750

The effects of core-level broadening in determining band alignment at the epitaxial SrTiO 3 (001)/ p -Ge(001) heterojunction
journal, February 2017

  • Chambers, Scott A.; Du, Yingge; Comes, Ryan B.
  • Applied Physics Letters, Vol. 110, Issue 8
  • DOI: 10.1063/1.4977422

Solid-state memories based on ferroelectric tunnel junctions
journal, December 2011

  • Chanthbouala, André; Crassous, Arnaud; Garcia, Vincent
  • Nature Nanotechnology, Vol. 7, Issue 2
  • DOI: 10.1038/nnano.2011.213

Unraveling the enhanced Oxygen Vacancy Formation in Complex Oxides during Annealing and Growth
journal, January 2017

  • Hensling, Felix V. E.; Xu, Chencheng; Gunkel, Felix
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep39953

Stoichiometry-driven switching between surface reconstructions on SrTiO3(001)
journal, March 2014

Surface preparation of TiO2 anatase (101): Pitfalls and how to avoid them
journal, August 2014

Insulator-to-metal transition of SrTiO 3 :Nb single crystal surfaces induced by Ar + bombardment
journal, March 2013

  • Rodenbücher, C.; Wicklein, S.; Waser, R.
  • Applied Physics Letters, Vol. 102, Issue 10
  • DOI: 10.1063/1.4795611

Reaction of O2 with Subsurface Oxygen Vacancies on TiO2 Anatase (101)
journal, August 2013

c(4 × 2) and related structural units on the SrTiO 3 (001) surface: Scanning tunneling microscopy, density functional theory, and atomic structure
journal, June 2012

  • Becerra-Toledo, A. E.; Marshall, M. S. J.; Castell, M. R.
  • The Journal of Chemical Physics, Vol. 136, Issue 21
  • DOI: 10.1063/1.4719212

Enhancement of Ionic Conductivity in Sm-Doped Ceria/Yttria-Stabilized Zirconia Heteroepitaxial Structures
journal, August 2010

Determination of the electrostatic potential distribution in Pt/Fe:SrTiO3/Nb:SrTiO3 thin-film structures by electron holography
journal, November 2014

  • Marchewka, Astrid; Cooper, David; Lenser, Christian
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06975

Formation of micro-crystals on the (100) surface of SrTiO3 at elevated temperatures
journal, July 2000

Perovskite-Based Solar Cells
journal, October 2013

Enhancement of the chemical stability in confined δ-Bi2O3
journal, April 2015

  • Sanna, Simone; Esposito, Vincenzo; Andreasen, Jens Wenzel
  • Nature Materials, Vol. 14, Issue 5
  • DOI: 10.1038/nmat4266

Thickness-Dependent Photoelectrochemical Water Splitting on Ultrathin LaFeO 3 Films Grown on Nb:SrTiO 3
journal, March 2015

  • May, Kevin J.; Fenning, David P.; Ming, Tian
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 6
  • DOI: 10.1021/acs.jpclett.5b00169

Calculations of electron inelastic mean free paths. V. Data for 14 organic compounds over the 50-2000 eV range
journal, March 1994

  • Tanuma, S.; Powell, C. J.; Penn, D. R.
  • Surface and Interface Analysis, Vol. 21, Issue 3
  • DOI: 10.1002/sia.740210302

Memristive behaviors in Pt/BaTiO 3 /Nb:SrTiO 3 ferroelectric tunnel junctions
journal, August 2014

  • Wen, Zheng; Wu, Di; Li, Aidong
  • Applied Physics Letters, Vol. 105, Issue 5
  • DOI: 10.1063/1.4892846

Direct Mapping of Band Positions in Doped and Undoped Hematite during Photoelectrochemical Water Splitting
journal, November 2017

  • Shavorskiy, Andrey; Ye, Xiaofei; Karslıoğlu, Osman
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 22
  • DOI: 10.1021/acs.jpclett.7b02548

Oxidation of reduced polycrystalline Nb-doped SrTiO3: Characterization of surface islands
journal, December 2005

Nanoionics-based resistive switching memories
journal, November 2007

  • Waser, Rainer; Aono, Masakazu
  • Nature Materials, Vol. 6, Issue 11, p. 833-840
  • DOI: 10.1038/nmat2023

Surface depletion in doped SrTiO3 thin films
journal, March 2004

  • Ohtomo, A.; Hwang, H. Y.
  • Applied Physics Letters, Vol. 84, Issue 10
  • DOI: 10.1063/1.1668329

Transport at the Epitaxial Interface between Germanium and Functional Oxides
journal, October 2015

  • Kornblum, Lior; Morales-Acosta, Mayra D.; Jin, Eric N.
  • Advanced Materials Interfaces, Vol. 2, Issue 18
  • DOI: 10.1002/admi.201500193

More Is Different
journal, August 1972

Electronic structure of p -type SrTiO 3 by photoemission spectroscopy
journal, March 1998

Oxygen partial pressure dependence of surface space charge formation in donor-doped SrTiO 3
journal, May 2017

  • Andrä, Michael; Dvořák, Filip; Vorokhta, Mykhailo
  • APL Materials, Vol. 5, Issue 5
  • DOI: 10.1063/1.4983618

Giant tunnel electroresistance for non-destructive readout of ferroelectric states
journal, May 2009

  • Garcia, V.; Fusil, S.; Bouzehouane, K.
  • Nature, Vol. 460, Issue 7251, p. 81-84
  • DOI: 10.1038/nature08128

Dramatic mobility enhancements in doped SrTiO3 thin films by defect management
journal, July 2010

  • Kozuka, Y.; Hikita, Y.; Bell, C.
  • Applied Physics Letters, Vol. 97, Issue 1
  • DOI: 10.1063/1.3457994

Space charges and defect concentration profiles at complex oxide interfaces
journal, June 2016

Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges
journal, July 2009

  • Waser, Rainer; Dittmann, Regina; Staikov, Georgi
  • Advanced Materials, Vol. 21, Issue 25-26, p. 2632-2663
  • DOI: 10.1002/adma.200900375

Spectromicroscopic insights for rational design of redox-based memristive devices
journal, October 2015

  • Baeumer, Christoph; Schmitz, Christoph; Ramadan, Amr H. H.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9610

Tunable Oxygen Diffusion and Electronic Conduction in SrTiO 3 by Dislocation-Induced Space Charge Fields
journal, April 2017

  • Adepalli, Kiran K.; Yang, Jing; Maier, Joachim
  • Advanced Functional Materials, Vol. 27, Issue 22
  • DOI: 10.1002/adfm.201700243

Intrinsic Mobility Limiting Mechanisms in Lanthanum-Doped Strontium Titanate
journal, May 2014

Dynamic layer rearrangement during growth of layered oxide films by molecular beam epitaxy
journal, August 2014

  • Lee, J. H.; Luo, G.; Tung, I. C.
  • Nature Materials, Vol. 13, Issue 9
  • DOI: 10.1038/nmat4039

A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface
journal, January 2004

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations
journal, January 2011

  • Chroneos, Alexander; Yildiz, Bilge; Tarancón, Albert
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c0ee00717j

A comparison of different spectrometers and charge corrections used in X-ray photoelectron spectroscopy
journal, January 1977

  • Nefedov, V. I.; Salyn, Ya. V.; Leonhardt, G.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 10, Issue 2
  • DOI: 10.1016/0368-2048(77)85010-X

Defect Chemistry of Donor-Doped and Undoped Strontium Titanate Ceramics between 1000° and 1400°C
journal, October 1997

Defect and electrical transport properties of Nb-doped SrTiO3
journal, October 2008

Inhomogeneity of donor doping in SrTiO 3 substrates studied by fluorescence-lifetime imaging microscopy
journal, October 2013

  • Rodenbücher, C.; Gensch, T.; Speier, W.
  • Applied Physics Letters, Vol. 103, Issue 16
  • DOI: 10.1063/1.4825367

Dynamics of the metal-insulator transition of donor-doped SrTi O 3
journal, September 2016

Recent advances in pulsed-laser deposition of complex oxides
journal, June 2008

Scaling Potential of Local Redox Processes in Memristive SrTiO $_{3}$ Thin-Film Devices
journal, June 2012

Tunable coupling of two-dimensional superconductors in bilayer SrTiO 3 heterostructures
journal, December 2013

Finite-size versus interface-proximity effects in thin-film epitaxial SrTiO 3
journal, June 2014

Surface and Defect Structure of Oxide Nanowires on SrTiO 3
journal, August 2011

  • Marshall, Matthew S. J.; Becerra-Toledo, Andres E.; Marks, Laurence D.
  • Physical Review Letters, Vol. 107, Issue 8
  • DOI: 10.1103/PhysRevLett.107.086102