The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze
Abstract
Here, we describe the previously unreported oxygen excess hexagonal antimony tungsten bronze with composition Sb0.5W3O10, in the following denoted as h–SbxWO3+2x with x = 0.167, to demonstrate its analogy to classical AxWO3 tungsten bronzes. This compound forms in a relatively narrow temperature range between 580 °C < T < 620 °C. It was obtained as a dark–blue polycrystalline powder, and as thin, needle–shaped, blue single crystals. h–SbxWO3+2x crystallizes in the hexagonal space group P6/mmm with the cell parameters a=7.4369(4) Å and c=3.7800(2) Å. The antimony and excess oxygen occupy the hexagonal channels within the network of corner–sharing WO6 octahedra. h–SbxWO3+2x has a resistivity of ρ300 K≈1.28 mΩ cm at room temperature, with little if any temperature–dependence on cooling. DFT calculations on a simplified model for this compound find a metallic–like electronic structure with the Fermi level falling within rather flat bands, especially around the Γ point.
- Authors:
-
- Univ. of Zurich, Zurich (Switzerland)
- Princeton Univ., Princeton, NJ (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Princeton Univ., NJ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1507113
- Alternate Identifier(s):
- OSTI ID: 1490115; OSTI ID: 1595066
- Report Number(s):
- BNL-211545-2019-JAAM
Journal ID: ISSN 0947-6539
- Grant/Contract Number:
- SC0012704; FG02-98ER45706
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: 8; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; antimony; bronze; hexagonal bipyramids; metallic oxide; tungsten
Citation Formats
von Rohr, Fabian O., Ryser, Alice, Ji, Huiwen, Stolze, Karoline, Tao, Jing, Frick, Jessica J., Patzke, Greta R., and Cava, Robert J. The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze. United States: N. p., 2019.
Web. doi:10.1002/chem.201805251.
von Rohr, Fabian O., Ryser, Alice, Ji, Huiwen, Stolze, Karoline, Tao, Jing, Frick, Jessica J., Patzke, Greta R., & Cava, Robert J. The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze. United States. https://doi.org/10.1002/chem.201805251
von Rohr, Fabian O., Ryser, Alice, Ji, Huiwen, Stolze, Karoline, Tao, Jing, Frick, Jessica J., Patzke, Greta R., and Cava, Robert J. Wed .
"The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze". United States. https://doi.org/10.1002/chem.201805251. https://www.osti.gov/servlets/purl/1507113.
@article{osti_1507113,
title = {The h–SbxWO3+2x Oxygen Excess Antimony Tungsten Bronze},
author = {von Rohr, Fabian O. and Ryser, Alice and Ji, Huiwen and Stolze, Karoline and Tao, Jing and Frick, Jessica J. and Patzke, Greta R. and Cava, Robert J.},
abstractNote = {Here, we describe the previously unreported oxygen excess hexagonal antimony tungsten bronze with composition Sb0.5W3O10, in the following denoted as h–SbxWO3+2x with x = 0.167, to demonstrate its analogy to classical AxWO3 tungsten bronzes. This compound forms in a relatively narrow temperature range between 580 °C < T < 620 °C. It was obtained as a dark–blue polycrystalline powder, and as thin, needle–shaped, blue single crystals. h–SbxWO3+2x crystallizes in the hexagonal space group P6/mmm with the cell parameters a=7.4369(4) Å and c=3.7800(2) Å. The antimony and excess oxygen occupy the hexagonal channels within the network of corner–sharing WO6 octahedra. h–SbxWO3+2x has a resistivity of ρ300 K≈1.28 mΩ cm at room temperature, with little if any temperature–dependence on cooling. DFT calculations on a simplified model for this compound find a metallic–like electronic structure with the Fermi level falling within rather flat bands, especially around the Γ point.},
doi = {10.1002/chem.201805251},
journal = {Chemistry - A European Journal},
number = 8,
volume = 25,
place = {United States},
year = {Wed Jan 09 00:00:00 EST 2019},
month = {Wed Jan 09 00:00:00 EST 2019}
}
Web of Science
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