Environmentally friendly preparation of nanoparticles for organic photovoltaics
Abstract
Aqueous nanoparticle dispersions were prepared from a conjugated polymer poly[thiophene-2,5-diyl-alt-5,10-bis((2-hexyldecyl)oxy)dithieno[3,2-c:3',2'-h][1,5]naphthyridine-2,7-diyl] (PTNT) and fullerene blend utilizing chloroform as well as a non-chlorinated and environmentally benign solvent, o-xylene, as the miniemulsion dispersed phase solvent. The nanoparticles (NPs) in the solid-state film were found to coalesce and offered a smooth surface topography upon thermal annealing. Organic photovoltaics (OPVs) with photoactive layer processed from the nanoparticle dispersions prepared using chloroform as the miniemulsion dispersed phase solvent were found to have a power conversion efficiency (PCE) of 1.04%, which increased to 1.65% for devices utilizing NPs prepared from o-xylene. Physical, thermal and optical properties of NPs prepared using both chloroform and o-xylene were systematically studied using dynamic mechanical thermal analysis (DMTA) and photoluminescence (PL) spectroscopy and correlated to their photovoltaic properties. The PL results indicate different morphology of NPs in the solid state were achieved by varying miniemulsion dispersed phase solvent.
- Authors:
-
- Flinders Univ., Bedford Park, SA (Australia)
- Flinders Univ., Bedford Park, SA (Australia); Univ. of Bordeaux (France)
- The Univ. of South Pacific, Suva (Fiji)
- Chalmers Univ. of Technology, Goteborg (Sweden)
- Univ. of Newcastle, Callaghan, NSW (Australia)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1506340
- Alternate Identifier(s):
- OSTI ID: 1566238
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Organic Electronics
- Additional Journal Information:
- Journal Volume: 59; Journal Issue: C; Journal ID: ISSN 1566-1199
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY
Citation Formats
Pan, Xun, Sharma, Anirudh, Gedefaw, Desta, Kroon, Renee, Diaz de Zerio, Amaia, Holmes, Natalie P., Kilcoyne, A. L. David, Barr, Matthew G., Fahy, Adam, Marks, Melissa, Zhou, Xiaojing, Belcher, Warwick, Dastoor, Paul C., and Andersson, Mats R. Environmentally friendly preparation of nanoparticles for organic photovoltaics. United States: N. p., 2018.
Web. doi:10.1016/j.orgel.2018.05.040.
Pan, Xun, Sharma, Anirudh, Gedefaw, Desta, Kroon, Renee, Diaz de Zerio, Amaia, Holmes, Natalie P., Kilcoyne, A. L. David, Barr, Matthew G., Fahy, Adam, Marks, Melissa, Zhou, Xiaojing, Belcher, Warwick, Dastoor, Paul C., & Andersson, Mats R. Environmentally friendly preparation of nanoparticles for organic photovoltaics. United States. https://doi.org/10.1016/j.orgel.2018.05.040
Pan, Xun, Sharma, Anirudh, Gedefaw, Desta, Kroon, Renee, Diaz de Zerio, Amaia, Holmes, Natalie P., Kilcoyne, A. L. David, Barr, Matthew G., Fahy, Adam, Marks, Melissa, Zhou, Xiaojing, Belcher, Warwick, Dastoor, Paul C., and Andersson, Mats R. Tue .
"Environmentally friendly preparation of nanoparticles for organic photovoltaics". United States. https://doi.org/10.1016/j.orgel.2018.05.040. https://www.osti.gov/servlets/purl/1506340.
@article{osti_1506340,
title = {Environmentally friendly preparation of nanoparticles for organic photovoltaics},
author = {Pan, Xun and Sharma, Anirudh and Gedefaw, Desta and Kroon, Renee and Diaz de Zerio, Amaia and Holmes, Natalie P. and Kilcoyne, A. L. David and Barr, Matthew G. and Fahy, Adam and Marks, Melissa and Zhou, Xiaojing and Belcher, Warwick and Dastoor, Paul C. and Andersson, Mats R.},
abstractNote = {Aqueous nanoparticle dispersions were prepared from a conjugated polymer poly[thiophene-2,5-diyl-alt-5,10-bis((2-hexyldecyl)oxy)dithieno[3,2-c:3',2'-h][1,5]naphthyridine-2,7-diyl] (PTNT) and fullerene blend utilizing chloroform as well as a non-chlorinated and environmentally benign solvent, o-xylene, as the miniemulsion dispersed phase solvent. The nanoparticles (NPs) in the solid-state film were found to coalesce and offered a smooth surface topography upon thermal annealing. Organic photovoltaics (OPVs) with photoactive layer processed from the nanoparticle dispersions prepared using chloroform as the miniemulsion dispersed phase solvent were found to have a power conversion efficiency (PCE) of 1.04%, which increased to 1.65% for devices utilizing NPs prepared from o-xylene. Physical, thermal and optical properties of NPs prepared using both chloroform and o-xylene were systematically studied using dynamic mechanical thermal analysis (DMTA) and photoluminescence (PL) spectroscopy and correlated to their photovoltaic properties. The PL results indicate different morphology of NPs in the solid state were achieved by varying miniemulsion dispersed phase solvent.},
doi = {10.1016/j.orgel.2018.05.040},
journal = {Organic Electronics},
number = C,
volume = 59,
place = {United States},
year = {Tue May 29 00:00:00 EDT 2018},
month = {Tue May 29 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
A global review of energy consumption, CO 2 emissions and policy in the residential sector (with an overview of the top ten CO 2 emitting countries)
journal, March 2015
- Nejat, Payam; Jomehzadeh, Fatemeh; Taheri, Mohammad Mahdi
- Renewable and Sustainable Energy Reviews, Vol. 43
The role of renewable energy in climate stabilization: results from the EMF27 scenarios
journal, October 2013
- Luderer, Gunnar; Krey, Volker; Calvin, Katherine
- Climatic Change, Vol. 123, Issue 3-4
Preface: Overview of the Forum on Solar and Renewable Energy
journal, October 2005
- Eisenberg, Richard; Nocera, Daniel G.
- Inorganic Chemistry, Vol. 44, Issue 20
[6,6]-Phenyl-C61-Butyric Acid Dimethylamino Ester as a Cathode Buffer Layer for High-Performance Polymer Solar Cells
journal, July 2013
- Li, Shusheng; Lei, Ming; Lv, Menglan
- Advanced Energy Materials, Vol. 3, Issue 12, p. 1569-1574
Solution-processed cathode interfacial layer materials for high-efficiency polymer solar cells
journal, September 2015
- Xiao, Biao; Wu, Hongbin; Cao, Yong
- Materials Today, Vol. 18, Issue 7
Solubility Based Identification of Green Solvents for Small Molecule Organic Solar Cells
journal, November 2013
- Burgués-Ceballos, Ignasi; Machui, Florian; Min, Jie
- Advanced Functional Materials, Vol. 24, Issue 10
Roll-to-Roll Inkjet Printing and Photonic Sintering of Electrodes for ITO Free Polymer Solar Cell Modules and Facile Product Integration
journal, September 2012
- Angmo, Dechan; Larsen-Olsen, Thue T.; Jørgensen, Mikkel
- Advanced Energy Materials, Vol. 3, Issue 2
Ultrafast formation of air-processable and high-quality polymer films on an aqueous substrate
journal, August 2016
- Noh, Jonghyeon; Jeong, Seonju; Lee, Jung-Yong
- Nature Communications, Vol. 7, Issue 1
Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells
journal, May 2017
- Zhao, Wenchao; Li, Sunsun; Yao, Huifeng
- Journal of the American Chemical Society, Vol. 139, Issue 21
Optimization of the power conversion efficiency in high bandgap pyridopyridinedithiophene-based conjugated polymers for organic photovoltaics by the random terpolymer approach
journal, June 2017
- Gedefaw, Desta; Sharma, Anirudh; Pan, Xun
- European Polymer Journal, Vol. 91
A multilayered approach to polyfluorene water-based organic photovoltaics
journal, July 2012
- Stapleton, Andrew; Vaughan, Ben; Xue, Bofei
- Solar Energy Materials and Solar Cells, Vol. 102
Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methods
journal, April 2011
- Andersen, Thomas R.; Larsen-Olsen, Thue T.; Andreasen, Birgitta
- ACS Nano, Vol. 5, Issue 5
Fabrication and processing of polymer solar cells: A review of printing and coating techniques
journal, April 2009
- Krebs, Frederik C.
- Solar Energy Materials and Solar Cells, Vol. 93, Issue 4, p. 394-412
Upscaling of polymer solar cell fabrication using full roll-to-roll processing
journal, January 2010
- Krebs, Frederik C.; Tromholt, Thomas; Jørgensen, Mikkel
- Nanoscale, Vol. 2, Issue 6
Industrial solvents and liver toxicity: Risk assessment, risk factors and mechanisms
journal, January 2002
- Brautbar, Nachman; Williams, John
- International Journal of Hygiene and Environmental Health, Vol. 205, Issue 6
Chlorinated Solvents in Groundwater of the United States
journal, January 2007
- Moran, Michael J.; Zogorski, John S.; Squillace, Paul J.
- Environmental Science & Technology, Vol. 41, Issue 1
Green-Solvent-Processed Molecular Solar Cells
journal, November 2014
- Chen, Xiaofen; Liu, Xiaofeng; Burgers, Mark A.
- Angewandte Chemie International Edition, Vol. 53, Issue 52
Green-solvent-processable organic solar cells
journal, November 2016
- Zhang, Shaoqing; Ye, Long; Zhang, Hao
- Materials Today, Vol. 19, Issue 9
Optimisation of processing solvent and molecular weight for the production of green-solvent-processed all-polymer solar cells with a power conversion efficiency over 9%
journal, January 2017
- Fan, Baobing; Ying, Lei; Wang, Zhenfeng
- Energy & Environmental Science, Vol. 10, Issue 5
Charge generation and morphology in P3HT : PCBM nanoparticles prepared by mini-emulsion and reprecipitation methods
journal, January 2015
- Schwarz, Kyra N.; Farley, Sam B.; Smith, Trevor A.
- Nanoscale, Vol. 7, Issue 47
Surfactant-free nanoparticulate organic photovoltaics
journal, February 2014
- Darwis, Darmawati; Holmes, Natalie; Elkington, Daniel
- Solar Energy Materials and Solar Cells, Vol. 121
Eco-Friendly Fabrication of 4% Efficient Organic Solar Cells from Surfactant-Free P3HT:ICBA Nanoparticle Dispersions
journal, September 2014
- Gärtner, Stefan; Christmann, Marco; Sankaran, Sivaramakrishnan
- Advanced Materials, Vol. 26, Issue 38
Semiconducting Polymer Nanospheres in Aqueous Dispersion Prepared by a Miniemulsion Process
journal, May 2002
- Landfester, K.; Montenegro, R.; Scherf, U.
- Advanced Materials, Vol. 14, Issue 9
Nano-domain behaviour in P3HT:PCBM nanoparticles, relating material properties to morphological changes
journal, October 2013
- Holmes, Natalie P.; Burke, Kerry B.; Sista, Prakash
- Solar Energy Materials and Solar Cells, Vol. 117
Tuning of PCDTBT:PC71BM blend nanoparticles for eco-friendly processing of polymer solar cells
journal, January 2017
- D’Olieslaeger, Lien; Pfannmöller, Martin; Fron, Eduard
- Solar Energy Materials and Solar Cells, Vol. 159
Aqueous Nanoparticle Polymer Solar Cells: Effects of Surfactant Concentration and Processing on Device Performance
journal, April 2017
- Colberts, Fallon J. M.; Wienk, Martijn M.; Janssen, René A. J.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 15
Photoactive Donor–Acceptor Composite Nanoparticles Dispersed in Water
journal, January 2017
- Parrenin, Laurie; Laurans, Gildas; Pavlopoulou, Eleni
- Langmuir, Vol. 33, Issue 6
Aqueous PCDTBT:PC 71 BM Photovoltaic Inks Made by Nanoprecipitation
journal, October 2017
- Prunet, Geoffrey; Parrenin, Laurie; Pavlopoulou, Eleni
- Macromolecular Rapid Communications, Vol. 39, Issue 2
Monodisperse conjugated polymer particles by Suzuki–Miyaura dispersion polymerization
journal, January 2012
- Kuehne, Alexander J. C.; Gather, Malte C.; Sprakel, Joris
- Nature Communications, Vol. 3, Issue 1
Light-Switchable and Monodisperse Conjugated Polymer Particles
journal, August 2013
- Anwar, Naveed; Willms, Thomas; Grimme, Benjamin
- ACS Macro Letters, Vol. 2, Issue 9
Low Bandgap Semiconducting Copolymer Nanoparticles by Suzuki Cross-Coupling Polymerization in Alcoholic Dispersed Media
journal, August 2015
- Parrenin, Laurie; Brochon, Cyril; Hadziioannou, Georges
- Macromolecular Rapid Communications, Vol. 36, Issue 20
Determining the structural motif of P3HT:PCBM nanoparticulate organic photovoltaic devices
journal, March 2013
- Ulum, Syahrul; Holmes, Natalie; Darwis, Darmawati
- Solar Energy Materials and Solar Cells, Vol. 110
Eco-friendly fabrication of PBDTTPD:PC71BM solar cells reaching a PCE of 3.8% using water-based nanoparticle dispersions
journal, March 2017
- D'Olieslaeger, Lien; Pirotte, Geert; Cardinaletti, Ilaria
- Organic Electronics, Vol. 42
A New Tetracyclic Lactam Building Block for Thick, Broad-Bandgap Photovoltaics
journal, August 2014
- Kroon, Renee; Diaz de Zerio Mendaza, Amaia; Himmelberger, Scott
- Journal of the American Chemical Society, Vol. 136, Issue 33
Poly(4-vinylpyridine): A New Interface Layer for Organic Solar Cells
journal, March 2017
- Sharma, Anirudh; Kroon, Renee; Lewis, David A.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 12
Nano-pathways: Bridging the divide between water-processable nanoparticulate and bulk heterojunction organic photovoltaics
journal, January 2016
- Holmes, Natalie P.; Marks, Melissa; Kumar, Pankaj
- Nano Energy, Vol. 19
Application of gradient-based Hough transform to the detection of corrosion pits in optical images
journal, March 2016
- Wang, Yafei; Cheng, Guangxu
- Applied Surface Science, Vol. 366
Unravelling the Thermomechanical Properties of Bulk Heterojunction Blends in Polymer Solar Cells
journal, April 2017
- Sharma, Anirudh; Pan, Xun; Campbell, Jonathan A.
- Macromolecules, Vol. 50, Issue 8
Inverted Polymer Solar Cells Integrated with a Low-Temperature-Annealed Sol-Gel-Derived ZnO Film as an Electron Transport Layer
journal, February 2011
- Sun, Yanming; Seo, Jung Hwa; Takacs, Christopher J.
- Advanced Materials, Vol. 23, Issue 14, p. 1679-1683
PCBM concentration dependent morphology of P3HT in composite P3HT/PCBM nanoparticles
journal, July 2009
- Hu, Zhongjian; Gesquiere, Andre J.
- Chemical Physics Letters, Vol. 476, Issue 1-3
Correlation between spectroscopic and morphological properties of composite P3HT/PCBM nanoparticles studied by single particle spectroscopy
journal, May 2010
- Hu, Zhongjian; Tenery, Daeri; Bonner, Maxwell S.
- Journal of Luminescence, Vol. 130, Issue 5
Water-based nanoparticulate solar cells using a diketopyrrolopyrrole donor polymer
journal, January 2014
- Vaughan, Ben; Williams, Evan L.; Holmes, Natalie P.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 6
Organic Solar Cells: An Overview Focusing on Active Layer Morphology
journal, January 2006
- Benanti, Travis L.; Venkataraman, D.
- Photosynthesis Research, Vol. 87, Issue 1, p. 73-81
Phase Separation in Bulk Heterojunctions of Semiconducting Polymers and Fullerenes for Photovoltaics
journal, April 2014
- Treat, Neil D.; Chabinyc, Michael L.
- Annual Review of Physical Chemistry, Vol. 65, Issue 1
The role of miscibility in polymer:fullerene nanoparticulate organic photovoltaic devices
journal, September 2013
- Ulum, Syahrul; Holmes, Natalie; Barr, Matthew
- Nano Energy, Vol. 2, Issue 5
The effect of mesomorphology upon the performance of nanoparticulate organic photovoltaic devices
journal, July 2015
- Dam, Henrik F.; Holmes, Natalie P.; Andersen, Thomas R.
- Solar Energy Materials and Solar Cells, Vol. 138
Inverted all-polymer solar cells based on a quinoxaline–thiophene/naphthalene-diimide polymer blend improved by annealing
journal, January 2016
- Xia, Yuxin; Musumeci, Chiara; Bergqvist, Jonas
- Journal of Materials Chemistry A, Vol. 4, Issue 10
In Situ Characterization of Polymer–Fullerene Bilayer Stability
journal, January 2015
- Leman, Deborah; Kelly, Mary Allison; Ness, Stuart
- Macromolecules, Vol. 48, Issue 2
The effect of polymer molecular weight on P3HT:PCBM nanoparticulate organic photovoltaic device performance
journal, September 2014
- Holmes, Natalie P.; Ulum, Syahrul; Sista, Prakash
- Solar Energy Materials and Solar Cells, Vol. 128
Structure and crystallinity of water dispersible photoactive nanoparticles for organic solar cells
journal, January 2015
- Pedersen, E. B. L.; Pedersen, M. C.; Simonsen, S. B.
- Journal of Materials Chemistry A, Vol. 3, Issue 33
DMTA and FTIR Investigation of the Phase Behavior of Poly(methyl methacrylate)−Poly(4-vinylphenol) Blends
journal, January 1996
- Li, Dean; Brisson, Josée
- Macromolecules, Vol. 29, Issue 3
Dynamic mechanical analysis of carbon/epoxy composites for structural pipeline repair
journal, January 2007
- Goertzen, W. K.; Kessler, M. R.
- Composites Part B: Engineering, Vol. 38, Issue 1
Study of crystallinity and thermomechanical analysis of annealed poly(ethylene terephthalate) films
journal, May 2008
- Karagiannidis, Panagiotis G.; Stergiou, Anagnostis C.; Karayannidis, George P.
- European Polymer Journal, Vol. 44, Issue 5
Structural Hierarchy in Melt-Processed Poly(3-hexyl thiophene)−Montmorillonite Clay Nanocomposites: Novel Physical, Mechanical, Optical, and Conductivity Properties
journal, February 2006
- Kuila, Biplab K.; Nandi, Arun K.
- The Journal of Physical Chemistry B, Vol. 110, Issue 4
Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics
journal, April 2007
- Kim, Kyungkon; Liu, Jiwen; Namboothiry, Manoj A. G.
- Applied Physics Letters, Vol. 90, Issue 16
A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells
journal, February 2006
- Kim, Youngkyoo; Cook, Steffan; Tuladhar, Sachetan M.
- Nature Materials, Vol. 5, Issue 3
P3HT/PCBM Bulk Heterojunction Solar Cells: Impact of Blend Composition and 3D Morphology on Device Performance
journal, April 2010
- van Bavel, Svetlana S.; Bärenklau, Maik; de With, Gijsbertus
- Advanced Functional Materials, Vol. 20, Issue 9
Dynamic quenching of 5-(2?-ethyl-hexyloxy)-p-phenylene vinylene (MEH-PPV) by charge transfer to a C60 derivative in solution
journal, January 2001
- Wang, Jian; Wang, Deli; Moses, Daniel
- Journal of Applied Polymer Science, Vol. 82, Issue 10
Fabrication conditions for efficient organic photovoltaic cells from aqueous dispersions of nanoparticles
journal, January 2014
- Bag, Monojit; Gehan, Timothy S.; Renna, Lawrence A.
- RSC Adv., Vol. 4, Issue 85
The origin of performance limitations in miniemulsion nanoparticulate organic photovoltaic devices
journal, February 2018
- Al-Mudhaffer, Mohammed F.; Griffith, Matthew J.; Feron, Krishna
- Solar Energy Materials and Solar Cells, Vol. 175
Overcoming Microstructural Limitations in Water Processed Organic Solar Cells by Engineering Customized Nanoparticulate Inks
journal, January 2018
- Xie, Chen; Classen, Andrej; Späth, Andreas
- Advanced Energy Materials, Vol. 8, Issue 13
Domain Compositions and Fullerene Aggregation Govern Charge Photogeneration in Polymer/Fullerene Solar Cells
journal, March 2014
- Kesava, Sameer Vajjala; Fei, Zhuping; Rimshaw, Adam D.
- Advanced Energy Materials, Vol. 4, Issue 11
Works referencing / citing this record:
Manipulating nanoscale structure to control functionality in printed organic photovoltaic, transistor and bioelectronic devices
journal, December 2019
- Griffith, Matthew J.; Holmes, Natalie P.; Elkington, Daniel C.
- Nanotechnology, Vol. 31, Issue 9
Green-solvent-processable strategies for achieving large-scale manufacture of organic photovoltaics
journal, January 2019
- Ma, Zongwen; Zhao, Biao; Gong, Yongshuai
- Journal of Materials Chemistry A, Vol. 7, Issue 40
Optimizing Polymer Solar Cells Using Non-Halogenated Solvent Blends
journal, March 2019
- Kocak, Guler; Gedefaw, Desta; Andersson, Mats
- Polymers, Vol. 11, Issue 3
Figures / Tables found in this record: