skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers

Authors:
ORCiD logo [1];  [1];  [1];  [1]
  1. Department of Polymer Science and EngineeringUniversity of Massachusetts Amherst 120 Governors Drive, Amherst Massachusetts, 01003
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1506159
Grant/Contract Number:  
DE‐SC0012704
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part B, Polymer Physics
Additional Journal Information:
Journal Name: Journal of Polymer Science. Part B, Polymer Physics Journal Volume: 57 Journal Issue: 11; Journal ID: ISSN 0887-6266
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, and Watkins, James J. Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers. United States: N. p., 2019. Web. doi:10.1002/polb.24824.
Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, & Watkins, James J. Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers. United States. doi:10.1002/polb.24824.
Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, and Watkins, James J. Sat . "Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers". United States. doi:10.1002/polb.24824.
@article{osti_1506159,
title = {Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers},
author = {Fei, Huafeng and Yavitt, Benjamin M. and Kopanati, Gayathri and Watkins, James J.},
abstractNote = {},
doi = {10.1002/polb.24824},
journal = {Journal of Polymer Science. Part B, Polymer Physics},
number = 11,
volume = 57,
place = {United States},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/polb.24824

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Large-Volume Self-Organization of Polymer/Nanoparticle Hybrids with Millimeter-Scale Grain Sizes Using Brush Block Copolymers
journal, September 2015

  • Song, Dong-Po; Li, Cheng; Colella, Nicholas S.
  • Journal of the American Chemical Society, Vol. 137, Issue 39
  • DOI: 10.1021/jacs.5b08632

Self-Assembly of Symmetric Brush Diblock Copolymers
journal, February 2013

  • Gu, Weiyin; Huh, June; Hong, Sung Woo
  • ACS Nano, Vol. 7, Issue 3
  • DOI: 10.1021/nn305867d

Synthesis of Poly(styrene−dimethylsiloxane) Block Copolymers:  Influence of the Phase-Separated Morphologies on the Thermal Behaviors
journal, June 1998

  • Rosati, David; Perrin, Michel; Navard, Patrick
  • Macromolecules, Vol. 31, Issue 13
  • DOI: 10.1021/ma971577c

On the Self-Assembly of Brush Block Copolymers in Thin Films
journal, October 2013

  • Hong, Sung Woo; Gu, Weiyin; Huh, June
  • ACS Nano, Vol. 7, Issue 11
  • DOI: 10.1021/nn402639g

Templated Self-Assembly of a PS- Branch -PDMS Bottlebrush Copolymer
journal, June 2018


50th Anniversary Perspective : Block Polymers—Pure Potential
journal, December 2016


Thermally Tunable Metallodielectric Photonic Crystals from the Self-Assembly of Brush Block Copolymers and Gold Nanoparticles
journal, April 2015

  • Song, Dong-Po; Li, Cheng; Colella, Nicholas S.
  • Advanced Optical Materials, Vol. 3, Issue 9
  • DOI: 10.1002/adom.201500116

Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties
journal, August 1994

  • Fetters, L. J.; Lohse, D. J.; Richter, D.
  • Macromolecules, Vol. 27, Issue 17
  • DOI: 10.1021/ma00095a001

Photonic Resins: Designing Optical Appearance via Block Copolymer Self-Assembly
journal, March 2018


Synthesis and morphology of model PS-b-PDMS copolymers
journal, June 2010

  • Ninago, Mario D.; Satti, Angel J.; Ciolino, Andrés E.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 48, Issue 14
  • DOI: 10.1002/pola.24093

Bottlebrush Block Polymers: Quantitative Theory and Experiments
journal, October 2015

  • Dalsin, Samuel J.; Rions-Maehren, Thomas G.; Beam, Marissa D.
  • ACS Nano, Vol. 9, Issue 12
  • DOI: 10.1021/acsnano.5b05473

Packing Length Influence in Linear Polymer Melts on the Entanglement, Critical, and Reptation Molecular Weights
journal, October 1999

  • Fetters, Lewis J.; Lohse, David J.; Milner, Scott T.
  • Macromolecules, Vol. 32, Issue 20
  • DOI: 10.1021/ma990620o

Coexistence curves of polystyrene/ poly(dimethylsiloxane) blends
journal, January 1995


Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement
journal, December 2009

  • Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A.
  • Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532
  • DOI: 10.1021/ja908379q

Rheology of strongly segregated poly(styrene–dimethylsiloxane) block copolymers
journal, January 2000


Block Copolymer Nanocomposites with High Refractive Index Contrast for One-Step Photonics
journal, December 2015


Design, Synthesis, and Self-Assembly of Polymers with Tailored Graft Distributions
journal, November 2017

  • Chang, Alice B.; Lin, Tzu-Pin; Thompson, Niklas B.
  • Journal of the American Chemical Society, Vol. 139, Issue 48
  • DOI: 10.1021/jacs.7b10525

Multilayer block copolymer meshes by orthogonal self-assembly
journal, January 2016

  • Tavakkoli K. G., Amir; Nicaise, Samuel M.; Gadelrab, Karim R.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10518

The glass temperature and related properties of polystyrene. Influence of molecular weight
journal, September 1954


Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers
journal, September 2016

  • Kawamoto, Ken; Zhong, Mingjiang; Gadelrab, Karim R.
  • Journal of the American Chemical Society, Vol. 138, Issue 36
  • DOI: 10.1021/jacs.6b07670

About the Experimental Determination of the Persistence Length of Wormlike Chains of Polystyrene
journal, June 1996

  • Brûlet, A.; Boué, F.; Cotton, J. P.
  • Journal de Physique II, Vol. 6, Issue 6
  • DOI: 10.1051/jp2:1996217

Controlled Supramolecular Self-Assembly of Large Nanoparticles in Amphiphilic Brush Block Copolymers
journal, March 2015

  • Song, Dong-Po; Lin, Ying; Gai, Yue
  • Journal of the American Chemical Society, Vol. 137, Issue 11
  • DOI: 10.1021/jacs.5b01050

Role of Grain Boundary Defects During Grain Coarsening of Lamellar Block Copolymers
journal, December 2012

  • Ryu, Hyung Ju; Fortner, David B.; Lee, Sukbin
  • Macromolecules, Vol. 46, Issue 1
  • DOI: 10.1021/ma3015382

A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile
journal, November 2002


Application of Bottlebrush Block Copolymers as Photonic Crystals
journal, May 2017

  • Liberman-Martin, Allegra L.; Chu, Crystal K.; Grubbs, Robert H.
  • Macromolecular Rapid Communications, Vol. 38, Issue 13
  • DOI: 10.1002/marc.201700058

Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush
journal, September 2017


Bottlebrush-Guided Polymer Crystallization Resulting in Supersoft and Reversibly Moldable Physical Networks
journal, February 2017

  • Daniel, William F. M.; Xie, Guojun; Vatankhah Varnoosfaderani, Mohammad
  • Macromolecules, Vol. 50, Issue 5
  • DOI: 10.1021/acs.macromol.7b00030

Rapid self-assembly of brush block copolymers to photonic crystals
journal, August 2012

  • Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336
  • DOI: 10.1073/pnas.1213055109

Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers
journal, October 2017


Morphologies of Bottle-Brush Block Copolymers
journal, October 2014

  • Chremos, Alexandros; Theodorakis, Panagiotis E.
  • ACS Macro Letters, Vol. 3, Issue 10
  • DOI: 10.1021/mz500580f

Manipulating the ABCs of self-assembly via low-χ block polymer design
journal, June 2017

  • Chang, Alice B.; Bates, Christopher M.; Lee, Byeongdu
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 25
  • DOI: 10.1073/pnas.1701386114

When Does a Molecule Become a Polymer?
journal, January 2004

  • Ding, Yifu; Kisliuk, A.; Sokolov, A. P.
  • Macromolecules, Vol. 37, Issue 1
  • DOI: 10.1021/ma035618i

Molecular structure of bottlebrush polymers in melts
journal, November 2016

  • Paturej, Jarosław; Sheiko, Sergei S.; Panyukov, Sergey
  • Science Advances, Vol. 2, Issue 11
  • DOI: 10.1126/sciadv.1601478

Block Copolymers—Designer Soft Materials
journal, February 1999

  • Bates, Frank S.; Fredrickson, Glenn H.
  • Physics Today, Vol. 52, Issue 2
  • DOI: 10.1063/1.882522

ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties
journal, July 2015


Conformational rearrangements in interfacial region of polydimethylsiloxane melt films
journal, January 2006


Linear Rheology of Polyolefin-Based Bottlebrush Polymers
journal, June 2015