Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers

doi:10.1002/polb.24824

Title: Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers

Authors:

^[1]; Yavitt, Benjamin M. ^[1]; Kopanati, Gayathri ^[1]; Watkins, James J. ^[1]

Department of Polymer Science and EngineeringUniversity of Massachusetts Amherst 120 Governors Drive, Amherst Massachusetts, 01003

Publication Date:: 2019-03-23

Sponsoring Org.:: USDOE

OSTI Identifier:: 1506159

Grant/Contract Number:: DE‐SC0012704

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Polymer Science. Part B, Polymer Physics

Additional Journal Information:: Journal Name: Journal of Polymer Science. Part B, Polymer Physics Journal Volume: 57 Journal Issue: 11; Journal ID: ISSN 0887-6266

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United States

Language:: English

Citation Formats


                    Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, and Watkins, James J. Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers.  United States: N. p., 2019. 
        Web.  doi:10.1002/polb.24824.

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                    Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, & Watkins, James J. Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers.  United States.  doi:10.1002/polb.24824.

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                    Fei, Huafeng, Yavitt, Benjamin M., Kopanati, Gayathri, and Watkins, James J. Sat .  
        "Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers".  United States.  doi:10.1002/polb.24824.

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@article{osti_1506159,

  title        = {Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers},

  author       = {Fei, Huafeng and Yavitt, Benjamin M. and Kopanati, Gayathri and Watkins, James J.},

  abstractNote = {},

  doi          = {10.1002/polb.24824},

  journal      = {Journal of Polymer Science. Part B, Polymer Physics},

  number       = 11,

  volume       = 57,

  place        = {United States},

  year         = {2019},

  month        = {3}

}

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DOI: 10.1002/polb.24824

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Title: Effect of side chain and backbone length on lamellar spacing in polystyrene‐block‐poly(dimethyl siloxane) brush block copolymers

Citation Formats

Large-Volume Self-Organization of Polymer/Nanoparticle Hybrids with Millimeter-Scale Grain Sizes Using Brush Block Copolymers journal, September 2015

Self-Assembly of Symmetric Brush Diblock Copolymers journal, February 2013

Synthesis of Poly(styrene−dimethylsiloxane) Block Copolymers: Influence of the Phase-Separated Morphologies on the Thermal Behaviors journal, June 1998

On the Self-Assembly of Brush Block Copolymers in Thin Films journal, October 2013

Templated Self-Assembly of a PS- Branch -PDMS Bottlebrush Copolymer journal, June 2018

Morphologies and photonic properties of an asymmetric brush block copolymer with polystyrene and polydimethylsiloxane side chains journal, November 2018

50th Anniversary Perspective : Block Polymers—Pure Potential journal, December 2016

Thermally Tunable Metallodielectric Photonic Crystals from the Self-Assembly of Brush Block Copolymers and Gold Nanoparticles journal, April 2015

Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties journal, August 1994

Photonic Resins: Designing Optical Appearance via Block Copolymer Self-Assembly journal, March 2018

Synthesis and morphology of model PS-b-PDMS copolymers journal, June 2010

Bottlebrush Block Polymers: Quantitative Theory and Experiments journal, October 2015

Packing Length Influence in Linear Polymer Melts on the Entanglement, Critical, and Reptation Molecular Weights journal, October 1999

Coexistence curves of polystyrene/ poly(dimethylsiloxane) blends journal, January 1995

Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement journal, December 2009

Rheology of strongly segregated poly(styrene–dimethylsiloxane) block copolymers journal, January 2000

Block Copolymer Nanocomposites with High Refractive Index Contrast for One-Step Photonics journal, December 2015

Design, Synthesis, and Self-Assembly of Polymers with Tailored Graft Distributions journal, November 2017

Multilayer block copolymer meshes by orthogonal self-assembly journal, January 2016

The glass temperature and related properties of polystyrene. Influence of molecular weight journal, September 1954

Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers journal, September 2016

About the Experimental Determination of the Persistence Length of Wormlike Chains of Polystyrene journal, June 1996

Controlled Supramolecular Self-Assembly of Large Nanoparticles in Amphiphilic Brush Block Copolymers journal, March 2015

Role of Grain Boundary Defects During Grain Coarsening of Lamellar Block Copolymers journal, December 2012

A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile journal, November 2002

Application of Bottlebrush Block Copolymers as Photonic Crystals journal, May 2017

Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush journal, September 2017

Bottlebrush-Guided Polymer Crystallization Resulting in Supersoft and Reversibly Moldable Physical Networks journal, February 2017

Rapid self-assembly of brush block copolymers to photonic crystals journal, August 2012

Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures journal, March 2009

Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers journal, October 2017

Polystyrene- block -poly(ethylene oxide) Bottlebrush Block Copolymer Morphology Transitions: Influence of Side Chain Length and Volume Fraction journal, February 2017

Morphologies of Bottle-Brush Block Copolymers journal, October 2014

Manipulating the ABCs of self-assembly via low-χ block polymer design journal, June 2017

When Does a Molecule Become a Polymer? journal, January 2004

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Block Copolymers—Designer Soft Materials journal, February 1999

ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties journal, July 2015

Conformational rearrangements in interfacial region of polydimethylsiloxane melt films journal, January 2006

Linear Rheology of Polyolefin-Based Bottlebrush Polymers journal, June 2015

Large-Volume Self-Organization of Polymer/Nanoparticle Hybrids with Millimeter-Scale Grain Sizes Using Brush Block Copolymers
journal, September 2015

Self-Assembly of Symmetric Brush Diblock Copolymers
journal, February 2013

Synthesis of Poly(styrene−dimethylsiloxane) Block Copolymers: Influence of the Phase-Separated Morphologies on the Thermal Behaviors
journal, June 1998

On the Self-Assembly of Brush Block Copolymers in Thin Films
journal, October 2013

Templated Self-Assembly of a PS- Branch -PDMS Bottlebrush Copolymer
journal, June 2018

Morphologies and photonic properties of an asymmetric brush block copolymer with polystyrene and polydimethylsiloxane side chains
journal, November 2018

50th Anniversary Perspective : Block Polymers—Pure Potential
journal, December 2016

Thermally Tunable Metallodielectric Photonic Crystals from the Self-Assembly of Brush Block Copolymers and Gold Nanoparticles
journal, April 2015

Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties
journal, August 1994

Photonic Resins: Designing Optical Appearance via Block Copolymer Self-Assembly
journal, March 2018

Synthesis and morphology of model PS-b-PDMS copolymers
journal, June 2010

Bottlebrush Block Polymers: Quantitative Theory and Experiments
journal, October 2015

Packing Length Influence in Linear Polymer Melts on the Entanglement, Critical, and Reptation Molecular Weights
journal, October 1999

Coexistence curves of polystyrene/ poly(dimethylsiloxane) blends
journal, January 1995

Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement
journal, December 2009

Rheology of strongly segregated poly(styrene–dimethylsiloxane) block copolymers
journal, January 2000

Block Copolymer Nanocomposites with High Refractive Index Contrast for One-Step Photonics
journal, December 2015

Design, Synthesis, and Self-Assembly of Polymers with Tailored Graft Distributions
journal, November 2017

Multilayer block copolymer meshes by orthogonal self-assembly
journal, January 2016

The glass temperature and related properties of polystyrene. Influence of molecular weight
journal, September 1954

Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers
journal, September 2016

About the Experimental Determination of the Persistence Length of Wormlike Chains of Polystyrene
journal, June 1996

Controlled Supramolecular Self-Assembly of Large Nanoparticles in Amphiphilic Brush Block Copolymers
journal, March 2015

Role of Grain Boundary Defects During Grain Coarsening of Lamellar Block Copolymers
journal, December 2012

A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile
journal, November 2002

Application of Bottlebrush Block Copolymers as Photonic Crystals
journal, May 2017

Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush
journal, September 2017

Bottlebrush-Guided Polymer Crystallization Resulting in Supersoft and Reversibly Moldable Physical Networks
journal, February 2017

Rapid self-assembly of brush block copolymers to photonic crystals
journal, August 2012

Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures
journal, March 2009

Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers
journal, October 2017

Polystyrene- block -poly(ethylene oxide) Bottlebrush Block Copolymer Morphology Transitions: Influence of Side Chain Length and Volume Fraction
journal, February 2017

Morphologies of Bottle-Brush Block Copolymers
journal, October 2014

Manipulating the ABCs of self-assembly via low-χ block polymer design
journal, June 2017

When Does a Molecule Become a Polymer?
journal, January 2004

Molecular structure of bottlebrush polymers in melts
journal, November 2016

Block Copolymers—Designer Soft Materials
journal, February 1999

ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties
journal, July 2015

Conformational rearrangements in interfacial region of polydimethylsiloxane melt films
journal, January 2006

Linear Rheology of Polyolefin-Based Bottlebrush Polymers
journal, June 2015