skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on April 7, 2020

Title: Ambient‐Pressure Relithiation of Degraded Li x Ni 0.5 Co 0.2 Mn 0.3 O 2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium‐Ion Battery Cathodes

Authors:
 [1];  [1];  [2]; ORCiD logo [3]
  1. Department of NanoEngineeringUniversity of California San Diego La Jolla CA 92093 USA
  2. Department of NanoEngineeringUniversity of California San Diego La Jolla CA 92093 USA, Sustainable Power &, Energy Center (SPEC)University of California San Diego La Jolla CA 92093 USA
  3. Department of NanoEngineeringUniversity of California San Diego La Jolla CA 92093 USA, Sustainable Power &, Energy Center (SPEC)University of California San Diego La Jolla CA 92093 USA, Program of Chemical EngineeringUniversity of California San Diego La Jolla CA 92093 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1505652
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 20; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Shi, Yang, Zhang, Minghao, Meng, Ying Shirley, and Chen, Zheng. Ambient‐Pressure Relithiation of Degraded Li x Ni 0.5 Co 0.2 Mn 0.3 O 2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium‐Ion Battery Cathodes. Germany: N. p., 2019. Web. doi:10.1002/aenm.201900454.
Shi, Yang, Zhang, Minghao, Meng, Ying Shirley, & Chen, Zheng. Ambient‐Pressure Relithiation of Degraded Li x Ni 0.5 Co 0.2 Mn 0.3 O 2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium‐Ion Battery Cathodes. Germany. doi:10.1002/aenm.201900454.
Shi, Yang, Zhang, Minghao, Meng, Ying Shirley, and Chen, Zheng. Mon . "Ambient‐Pressure Relithiation of Degraded Li x Ni 0.5 Co 0.2 Mn 0.3 O 2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium‐Ion Battery Cathodes". Germany. doi:10.1002/aenm.201900454.
@article{osti_1505652,
title = {Ambient‐Pressure Relithiation of Degraded Li x Ni 0.5 Co 0.2 Mn 0.3 O 2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium‐Ion Battery Cathodes},
author = {Shi, Yang and Zhang, Minghao and Meng, Ying Shirley and Chen, Zheng},
abstractNote = {},
doi = {10.1002/aenm.201900454},
journal = {Advanced Energy Materials},
number = 20,
volume = 9,
place = {Germany},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on April 7, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes: I. Nickel-Rich, LiNi
journal, December 2016

  • Schipper, Florian; Erickson, Evan M.; Erk, Christoph
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0351701jes

A Molten Salt Lithium–Oxygen Battery
journal, February 2016

  • Giordani, Vincent; Tozier, Dylan; Tan, Hongjin
  • Journal of the American Chemical Society, Vol. 138, Issue 8
  • DOI: 10.1021/jacs.5b11744

Electrode Side Reactions, Capacity Loss and Mechanical Degradation in Lithium-Ion Batteries
journal, January 2015

  • Xu, Jiagang; Deshpande, Rutooj D.; Pan, Jie
  • Journal of The Electrochemical Society, Vol. 162, Issue 10
  • DOI: 10.1149/2.0291510jes

Running out of lithium? A route to differentiate between capacity losses and active lithium losses in lithium-ion batteries
journal, January 2017

  • Holtstiege, Florian; Wilken, Andrea; Winter, Martin
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 38
  • DOI: 10.1039/C7CP05405J

Assessing the progress toward lower priced long range battery electric vehicles
journal, January 2019


Lithium-ion battery recycling processes: Research towards a sustainable course
journal, September 2018


Structural and Electrochemical Aspects of LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode Materials Doped by Various Cations
journal, January 2019


Remaining capacity estimation of lithium-ion batteries based on the constant voltage charging profile
journal, July 2018


Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

  • Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4529

Effect of Ni 2+ Content on Lithium/Nickel Disorder for Ni-Rich Cathode Materials
journal, April 2015

  • Wu, Feng; Tian, Jun; Su, Yuefeng
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 14
  • DOI: 10.1021/acsami.5b00645

Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency
journal, October 2016


Urea-based hydrothermal synthesis of LiNi0.5Co0.2Mn0.3O2 cathode material for Li-ion battery
journal, August 2018


Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials
journal, April 2018


Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction
journal, May 2013


Synthesis by molten salt and cathodic properties of Li(Ni1/3Co1/3Mn1/3)O2
journal, September 2006


Lithium Molten Salt Battery at Near Room Temperature Using Low-Melting Alkali Metal Melts
journal, August 2016


Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries
journal, July 2016

  • Qiu, Bao; Zhang, Minghao; Wu, Lijun
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12108

Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches
journal, February 2015


Toward sustainable and systematic recycling of spent rechargeable batteries
journal, January 2018

  • Zhang, Xiaoxiao; Li, Li; Fan, Ersha
  • Chemical Society Reviews, Vol. 47, Issue 19
  • DOI: 10.1039/C8CS00297E

Capacity fade analysis of a lithium ion cell
journal, May 2008


Preferred Orientation of Polycrystalline LiCoO[sub 2] Films
journal, January 2000

  • Bates, J. B.; Dudney, N. J.; Neudecker, B. J.
  • Journal of The Electrochemical Society, Vol. 147, Issue 1
  • DOI: 10.1149/1.1393157

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries
journal, March 2015

  • Liu, Wen; Oh, Pilgun; Liu, Xien
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201409262

Zwitterionic-type molten salt-catalyzed syn-selective aza-Henry reaction: solvent-free one-pot synthesis of β-nitroamines
journal, December 2009


An Integrated Probabilistic Approach to Lithium-Ion Battery Remaining Useful Life Estimation
journal, March 2015


Molten-salt thermal energy storage in thermoclines under different environmental boundary conditions
journal, November 2010


Effective regeneration of LiCoO 2 from spent lithium-ion batteries: a direct approach towards high-performance active particles
journal, January 2018

  • Shi, Yang; Chen, Gen; Chen, Zheng
  • Green Chemistry, Vol. 20, Issue 4
  • DOI: 10.1039/C7GC02831H

A Critical Review and Analysis on the Recycling of Spent Lithium-Ion Batteries
journal, December 2017


Current status and challenges for automotive battery production technologies
journal, April 2018


Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density
journal, May 2017

  • Placke, Tobias; Kloepsch, Richard; Dühnen, Simon
  • Journal of Solid State Electrochemistry, Vol. 21, Issue 7
  • DOI: 10.1007/s10008-017-3610-7

The Recycling of Spent Lithium-Ion Batteries: a Review of Current Processes and Technologies
journal, September 2018


Molten salt synthesis of spherical LiNi0.5Mn1.5O4 cathode materials
journal, June 2006


Failure statistics for commercial lithium ion batteries: A study of 24 pouch cells
journal, February 2017


White lines and d -band occupancy for the 3 d transition-metal oxides and lithium transition-metal oxides
journal, June 2004


The Lithium future-resources, recycling, and the environment: The Lithium future
journal, March 2011


Factors that affect Li mobility in layered lithium transition metal oxides
journal, September 2006


Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013

  • Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
  • Advanced Energy Materials, Vol. 4, Issue 1
  • DOI: 10.1002/aenm.201300787

Testing of Thermocline Filler Materials and Molten-Salt Heat Transfer Fluids for Thermal Energy Storage Systems in Parabolic Trough Power Plants
journal, February 2005

  • Brosseau, Doug; Kelton, John W.; Ray, Daniel
  • Journal of Solar Energy Engineering, Vol. 127, Issue 1
  • DOI: 10.1115/1.1824107

Cycle Life of Commercial Lithium-Ion Batteries with Lithium Titanium Oxide Anodes in Electric Vehicles
journal, July 2014

  • Han, Xuebing; Ouyang, Minggao; Lu, Languang
  • Energies, Vol. 7, Issue 8
  • DOI: 10.3390/en7084895

Synthesis of LiNi1/3Co1/3Al1/3O2 cathode material with eutectic molten salt LiOH-LiNO3
journal, February 2011


Burgeoning Prospects of Spent Lithium-Ion Batteries in Multifarious Applications
journal, October 2018

  • Natarajan, Subramanian; Aravindan, Vanchiappan
  • Advanced Energy Materials, Vol. 8, Issue 33
  • DOI: 10.1002/aenm.201802303

Defect Chemistry in Layered Li M O 2 ( M = Co, Ni, Mn, and Li 1/3 Mn 2/3 ) by First-Principles Calculations
journal, October 2012

  • Koyama, Yukinori; Arai, Hajime; Tanaka, Isao
  • Chemistry of Materials, Vol. 24, Issue 20
  • DOI: 10.1021/cm3018314

Room temperature molten salts as lithium battery electrolyte
journal, October 2004


Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014

  • Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 24
  • DOI: 10.1021/am506712c