Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery

doi:10.1002/adfm.201901531

Title: Engineering Fe–Fe ₃ C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H ₂ –O ₂ Fuel Cell and Li–O ₂ Battery

Authors:

^[1];

^[2]; Liu, Ning ^[3]; Kou, Rong‐Hui ^[4]; He, Xiao‐Bo ^[2]; Sun, Cheng‐Jun ^[4]; Chen, Biao‐Hua ^[3];

^[5]; Yin, Hua‐Qiang ^[6]

College of Chemical EngineeringBeijing University of Chemical Technology Beijing 100029 P. R. China, Chemical Sciences and Engineering DivisionArgonne National Laboratory Lemont IL 60439 USA
Jiangsu Key Laboratory of Advanced Catalytic Materials and TechnologySchool of Petrochemical EngineeringChangzhou University Changzhou 213164 P. R. China, Changzhou Institute of Advanced MaterialsBeijing University of Chemical Technology Changzhou 213164 P. R. China
College of Environmental and Energy EngineeringBeijing University of Technology Beijing 100124 P. R. China
X‐ray Science DivisionAdvanced Photon SourceArgonne National Laboratory Lemont IL 60439 USA
Chemical Sciences and Engineering DivisionArgonne National Laboratory Lemont IL 60439 USA
Key Laboratory of Advanced Reactor Engineering and SafetyMinistry of EducationTsinghua University Beijing 100084 P. R. China

Publication Date:: 2019-04-08

Sponsoring Org.:: USDOE

OSTI Identifier:: 1505647

Grant/Contract Number:: DE‐AC02‐06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Name: Advanced Functional Materials Journal Volume: 29 Journal Issue: 23; Journal ID: ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, and Yin, Hua‐Qiang. Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery.  Germany: N. p., 2019. 
        Web.  doi:10.1002/adfm.201901531.

Copy to clipboard


                    Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, & Yin, Hua‐Qiang. Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery.  Germany.  doi:10.1002/adfm.201901531.

Copy to clipboard


                    Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, and Yin, Hua‐Qiang. Mon .  
        "Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery".  Germany.  doi:10.1002/adfm.201901531.

Copy to clipboard


                    
@article{osti_1505647,

  title        = {Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery},

  author       = {Wang, Hao and Yin, Feng‐Xiang and Liu, Ning and Kou, Rong‐Hui and He, Xiao‐Bo and Sun, Cheng‐Jun and Chen, Biao‐Hua and Liu, Di‐Jia and Yin, Hua‐Qiang},

  abstractNote = {},

  doi          = {10.1002/adfm.201901531},

  journal      = {Advanced Functional Materials},

  number       = 23,

  volume       = 29,

  place        = {Germany},

  year         = {2019},

  month        = {4}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1002/adfm.201901531

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 13 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction
journal, November 2014

Zhao, Shenlong; Yin, Huajie; Du, Lei
ACS Nano, Vol. 8, Issue 12
DOI: 10.1021/nn505582e

Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries
journal, June 2017

Tan, Guoqiang; Xu, Rui; Xing, Zhenyu
Nature Energy, Vol. 2, Issue 7
DOI: 10.1038/nenergy.2017.90

Toyota MIRAI Fuel Cell Vehicle and Progress Toward a Future Hydrogen Society
journal, January 2015

Yoshida, T.; Kojima, K.
Interface magazine, Vol. 24, Issue 2
DOI: 10.1149/2.F03152if

Organic dyestuffs as catalysts for fuel cells
book, January 1976

Jahnke, Horst; Schönborn, Manfred; Zimmermann, Georg
Physical and Chemical Applications of Dyestuffs, p. 133-181
DOI: 10.1007/BFb0046059

Fe-Cluster Pushing Electrons to N-Doped Graphitic Layers with Fe ₃ C(Fe) Hybrid Nanostructure to Enhance O ₂ Reduction Catalysis of Zn-Air Batteries
journal, January 2017

Yang, Jie; Hu, Jiangtao; Weng, Mouyi
ACS Applied Materials & Interfaces, Vol. 9, Issue 5
DOI: 10.1021/acsami.6b13166

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

Zhao, Dan; Shui, Jiang-Lan; Chen, Chen
Chemical Science, Vol. 3, Issue 11
DOI: 10.1039/c2sc20657a

Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
journal, February 2017

Zheng, Yao; Jiao, Yan; Zhu, Yihan
Journal of the American Chemical Society, Vol. 139, Issue 9
DOI: 10.1021/jacs.6b13100

Fe/N/C Composite in Li–O ₂ Battery: Studies of Catalytic Structure and Activity toward Oxygen Evolution Reaction
journal, October 2012

Shui, Jiang-Lan; Karan, Naba K.; Balasubramanian, Mahalingam
Journal of the American Chemical Society, Vol. 134, Issue 40
DOI: 10.1021/ja3042993

A General Approach to Preferential Formation of Active Fe–N _x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
journal, November 2016

Sa, Young Jin; Seo, Dong-Jun; Woo, Jinwoo
Journal of the American Chemical Society, Vol. 138, Issue 45
DOI: 10.1021/jacs.6b09470

Range-extending Zinc-air battery for electric vehicle
journal, January 2018

B. Sherman, Steven; P. Cano, Zachary; Fowler, Michael
AIMS Energy, Vol. 6, Issue 1
DOI: 10.3934/energy.2018.1.121

Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016

Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice
Journal of the American Chemical Society, Vol. 139, Issue 1
DOI: 10.1021/jacs.6b11248

Fuel Cells and Precious-Metal Catalysts
journal, October 1999

Berger, D. J.
Science, Vol. 286, Issue 5437
DOI: 10.1126/science.286.5437.49c

Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network
journal, August 2015

Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren
Proceedings of the National Academy of Sciences, Vol. 112, Issue 34
DOI: 10.1073/pnas.1507159112

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011

Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
Chemistry - A European Journal, Vol. 17, Issue 7
DOI: 10.1002/chem.201003080

Roles of Fe−N _x and Fe−Fe ₃ C@C Species in Fe−N/C Electrocatalysts for Oxygen Reduction Reaction
journal, March 2017

Kim, Jae Hyung; Sa, Young Jin; Jeong, Hu Young
ACS Applied Materials & Interfaces, Vol. 9, Issue 11
DOI: 10.1021/acsami.6b13417

The effect of iron catalyzed graphitization on the textural properties of carbonized cellulose: Magnetically separable graphitic carbon bodies for catalysis and remediation
journal, October 2016

Hoekstra, Jacco; Beale, Andrew M.; Soulimani, Fouad
Carbon, Vol. 107
DOI: 10.1016/j.carbon.2016.05.065

Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015

Strickland, Kara; Miner, Elise; Jia, Qingying
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms8343

Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity
journal, March 2014

Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen
Advanced Energy Materials, Vol. 4, Issue 10
DOI: 10.1002/aenm.201301735

An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting
journal, December 2014

Hou, Yang; Wen, Zhenhai; Cui, Shumao
Advanced Functional Materials, Vol. 25, Issue 6
DOI: 10.1002/adfm.201403657

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction
journal, January 2016

Guan, Bu Yuan; Yu, Le; (David) Lou, Xiong Wen
Energy & Environmental Science, Vol. 9, Issue 10
DOI: 10.1039/C6EE02171A

Nitrogen-doped Fe/Fe ₃ C@graphitic layer/carbon nanotube hybrids derived from MOFs: efficient bifunctional electrocatalysts for ORR and OER
journal, January 2015

Li, Ji-Sen; Li, Shun-Li; Tang, Yu-Jia
Chemical Communications, Vol. 51, Issue 13
DOI: 10.1039/C4CC09062D

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode surface
journal, November 1991

Kim, Sunghyun; Bae, In Tae; Sandifer, Marnita
Journal of the American Chemical Society, Vol. 113, Issue 24
DOI: 10.1021/ja00024a006

From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018

Jiao, Long; Wan, Gang; Zhang, Rui
Angewandte Chemie, Vol. 130, Issue 28
DOI: 10.1002/ange.201803262

Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe ₃ C Nanoparticles Boost the Activity of Fe–N _x
journal, March 2016

Jiang, Wen-Jie; Gu, Lin; Li, Li
Journal of the American Chemical Society, Vol. 138, Issue 10
DOI: 10.1021/jacs.6b00757

A New Fuel Cell Cathode Catalyst
journal, March 1964

Jasinski, Raymond
Nature, Vol. 201, Issue 4925, p. 1212-1213
DOI: 10.1038/2011212a0

Fe/Fe ₃ C@C nanoparticles encapsulated in N-doped graphene–CNTs framework as an efficient bifunctional oxygen electrocatalyst for robust rechargeable Zn–air batteries
journal, January 2018

Wang, Qichen; Lei, Yongpeng; Chen, Zhiyan
Journal of Materials Chemistry A, Vol. 6, Issue 2
DOI: 10.1039/C7TA08423D

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
Nature Communications, Vol. 2, Issue 1
DOI: 10.1038/ncomms1427

Nitrogen-Doped Graphene-Rich Catalysts Derived from Heteroatom Polymers for Oxygen Reduction in Nonaqueous Lithium–O ₂ Battery Cathodes
journal, October 2012

Wu, Gang; Mack, Nathan H.; Gao, Wei
ACS Nano, Vol. 6, Issue 11
DOI: 10.1021/nn303275d

Lithium−Air Battery: Promise and Challenges
journal, June 2010

Girishkumar, G.; McCloskey, B.; Luntz, A. C.
The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
DOI: 10.1021/jz1005384

A Versatile Iron-Tannin-Framework Ink Coating Strategy to Fabricate Biomass-Derived Iron Carbide/Fe-N-Carbon Catalysts for Efficient Oxygen Reduction
journal, December 2015

Wei, Jing; Liang, Yan; Hu, Yaoxin
Angewandte Chemie International Edition, Vol. 55, Issue 4
DOI: 10.1002/anie.201509024

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
journal, January 1985

Sing, K. S. W.
Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619
DOI: 10.1351/pac198557040603

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
journal, January 2017

Barkholtz, Heather M.; Liu, Di-Jia
Materials Horizons, Vol. 4, Issue 1
DOI: 10.1039/C6MH00344C

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018

Fei, Huilong; Dong, Juncai; Feng, Yexin
Nature Catalysis, Vol. 1, Issue 1
DOI: 10.1038/s41929-017-0008-y

Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid
journal, July 2016

Wang, Xiaojuan; Zhang, Hanguang; Lin, Honghong
Nano Energy, Vol. 25
DOI: 10.1016/j.nanoen.2016.04.042

Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity
journal, October 2015

Jia, Qingying; Ramaswamy, Nagappan; Hafiz, Hasnain
ACS Nano, Vol. 9, Issue 12
DOI: 10.1021/acsnano.5b05984

High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017

Liu, Jing; Jiao, Menggai; Lu, Lanlu
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms15938

Similar Records in DOE PAGES and OSTI.GOV collections:

Engineering Fe–Fe3C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H2–O2 Fuel Cell and Li–O2 Battery

Journal Article Wang, Hao ; Yin, Feng-Xiang ; Liu, Ning ; ... - Advanced Functional Materials

Dual metal-organic frameworks (MOFs, i.e., MIL-100(Fe) and ZIF-8) are thermally converted into Fe-Fe3C-embedded Fe-N-codoped carbon as platinum group metal (PGM)-free oxygen reduction reaction (ORR) electrocatalysts. Pyrolysis enables imidazolate in ZIF-8 rearranged into highly N-doped carbon, while Fe from MIL-100(Fe) into N-ligated atomic sites concurrently with a few Fe-Fe3C nanoparticles. Upon precise control of MOF compositions, the optimal catalyst is highly active for the ORR in half-cells (0.88 V in base and 0.79 V versus RHE in acid in half-wave potential), a proton exchange membrane fuel cell (0.76 W cm(-2) in peak power density) and an aprotic Li-O-2 battery (8749 mAhmore »« less
DOI: 10.1002/adfm.201901531
Hydrothermal synthesis and crystal structure of the Ni{sub 2}(C{sub 4}H{sub 4}N{sub 2})(V{sub 4}O{sub 12})(H{sub 2}O){sub 2} and Ni{sub 3}(C{sub 4}H{sub 4}N{sub 2}){sub 3}(V{sub 8}O{sub 23}) inorganic-organic hybrid compounds. Thermal, spectroscopic and magnetic studies of the hydrated phase

Journal Article Larrea, Edurne S ; Mesa, Jose L. ; Pizarro, Jose L ; ... - Journal of Solid State Chemistry

Ni{sub 2}(C{sub 4}H{sub 4}N{sub 2})(V{sub 4}O{sub 12})(H{sub 2}O){sub 2}, 1, and Ni{sub 3}(C{sub 4}H{sub 4}N{sub 2}){sub 3}(V{sub 8}O{sub 23}), 2, have been synthesized using mild hydrothermal conditions at 170 deg. C under autogenous pressure. Both phases crystallize in the P-1 triclinic space group, with the unit-cell parameters, a=7.437(7), b=7.571(3), c=7.564(4) A, {alpha}=65.64(4), {beta}=76.09(4), {gamma}=86.25(3){sup o} for 1 and a=8.566(2), b=9.117(2), c=12.619(3) A, {alpha}=71.05(2), {beta}=83.48(4), {gamma}=61.32(3){sup o} for 2, being Z=2 for both compounds. The crystal structure of the three-dimensional 1 is constructed from layers linked between them through the pyrazine molecules. The sheets are formed by edge-shared [Ni{sub 2}O{sub 6}(H{submore »« less
DOI: 10.1016/j.jssc.2006.12.037
Inorganic-organic hybrid structure: Synthesis, structure and magnetic properties of a cobalt phosphite-oxalate, [C{sub 4}N{sub 2}H{sub 12}][Co{sub 4}(HPO{sub 3}){sub 2}(C{sub 2}O{sub 4}){sub 3}]

Journal Article Mandal, Sukhendu ; Natarajan, Srinivasan - Journal of Solid State Chemistry

A hydrothermal reaction of a mixture of cobalt (II) oxalate, phosphorous acid, piperazine and water at 150{sup o}C for 96h followed by heating at 180{sup o}C for 24h gave rise to a new inorganic-organic hybrid solid, [C{sub 4}N{sub 2}H{sub 12}][Co{sub 4}(HPO{sub 3}){sub 2}(C{sub 2}O{sub 4}){sub 3}], I. The structure consists of edge-shared CoO{sub 6} octahedra forming a [Co{sub 2}O{sub 10}] dimers that are connected by HPO{sub 3} and C{sub 2}O{sub 4} units forming a three-dimensional structure with one-dimensional channels. The amine molecules are positioned within these channels. The oxalate units have a dual role of connecting within the plane ofmore »« less
DOI: 10.1016/j.jssc.2005.05.020
Synthesis, molecular structure, and characterization of a new 3D-layered inorganic-organic hybrid material: [D/L-C{sub 6}H{sub 13}O{sub 2}N-H]{sub 3}[(PO{sub 4})W{sub 12}O{sub 36}].4.5H{sub 2}O

Journal Article Alizadeh, Mohammad H., E-mail: mhalizadehg@yahoo.com ; Mirzaei, Masoud ; Salimi, Ali R ; ... - Materials Research Bulletin

A new 3D-layered inorganic-organic hybrid [D/L-C{sub 6}H{sub 13}O{sub 2}N-H]{sub 3}[(PO{sub 4})W{sub 12}O{sub 36}].4.5H{sub 2}O (1), as racemic material in the solid phase, has been synthesized and fully characterized by elemental microanalysis, single crystal X-ray diffraction, and infrared, Raman, and proton nuclear magnetic resonance spectroscopes. The most unique structural feature of 1 is its three-dimensional inorganic infinite tunnel-like framework that results in weak van der Waals interactions along the a-axis. A weak interlayer interaction between the titled layers provides a desirable condition to explore its potential as a host in a host-guest complex. The racemization has been observed in the crystalmore »« less
DOI: 10.1016/J.MATERRESBULL.2009.02.008
Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid

Journal Article Wang, Xiaojuan ; Zhang, Hanguang ; Lin, Honghong ; ... - Nano Energy
Cited by 77
DOI: 10.1016/j.nanoen.2016.04.042

Similar Records

Title: Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery

Citation Formats

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction journal, November 2014

Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries journal, June 2017

Toyota MIRAI Fuel Cell Vehicle and Progress Toward a Future Hydrogen Society journal, January 2015

Organic dyestuffs as catalysts for fuel cells book, January 1976

Fe-Cluster Pushing Electrons to N-Doped Graphitic Layers with Fe 3 C(Fe) Hybrid Nanostructure to Enhance O 2 Reduction Catalysis of Zn-Air Batteries journal, January 2017

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells journal, January 2012

Molecule-Level g-C 3 N 4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions journal, February 2017

Fe/N/C Composite in Li–O 2 Battery: Studies of Catalytic Structure and Activity toward Oxygen Evolution Reaction journal, October 2012

A General Approach to Preferential Formation of Active Fe–N x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction journal, November 2016

Range-extending Zinc-air battery for electric vehicle journal, January 2018

Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts journal, December 2016

Fuel Cells and Precious-Metal Catalysts journal, October 1999

Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network journal, August 2015

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts journal, January 2011

Roles of Fe−N x and Fe−Fe 3 C@C Species in Fe−N/C Electrocatalysts for Oxygen Reduction Reaction journal, March 2017

The effect of iron catalyzed graphitization on the textural properties of carbonized cellulose: Magnetically separable graphitic carbon bodies for catalysis and remediation journal, October 2016

Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination journal, June 2015

Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity journal, March 2014

An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting journal, December 2014

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction journal, January 2016

Nitrogen-doped Fe/Fe 3 C@graphitic layer/carbon nanotube hybrids derived from MOFs: efficient bifunctional electrocatalysts for ORR and OER journal, January 2015

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode surface journal, November 1991

From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media journal, June 2018

Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe 3 C Nanoparticles Boost the Activity of Fe–N x journal, March 2016

A New Fuel Cell Cathode Catalyst journal, March 1964

Fe/Fe 3 C@C nanoparticles encapsulated in N-doped graphene–CNTs framework as an efficient bifunctional oxygen electrocatalyst for robust rechargeable Zn–air batteries journal, January 2018

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells journal, August 2011

Nitrogen-Doped Graphene-Rich Catalysts Derived from Heteroatom Polymers for Oxygen Reduction in Nonaqueous Lithium–O 2 Battery Cathodes journal, October 2012

Lithium−Air Battery: Promise and Challenges journal, June 2010

A Versatile Iron-Tannin-Framework Ink Coating Strategy to Fabricate Biomass-Derived Iron Carbide/Fe-N-Carbon Catalysts for Efficient Oxygen Reduction journal, December 2015

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) journal, January 1985

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks journal, January 2017

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities journal, January 2018

Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid journal, July 2016

Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity journal, October 2015

High performance platinum single atom electrocatalyst for oxygen reduction reaction journal, July 2017

Title: Engineering Fe–Fe ₃ C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H ₂ –O ₂ Fuel Cell and Li–O ₂ Battery

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction
journal, November 2014

Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries
journal, June 2017

Toyota MIRAI Fuel Cell Vehicle and Progress Toward a Future Hydrogen Society
journal, January 2015

Organic dyestuffs as catalysts for fuel cells
book, January 1976

Fe-Cluster Pushing Electrons to N-Doped Graphitic Layers with Fe ₃ C(Fe) Hybrid Nanostructure to Enhance O ₂ Reduction Catalysis of Zn-Air Batteries
journal, January 2017

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
journal, February 2017

Fe/N/C Composite in Li–O ₂ Battery: Studies of Catalytic Structure and Activity toward Oxygen Evolution Reaction
journal, October 2012

A General Approach to Preferential Formation of Active Fe–N _x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
journal, November 2016

Range-extending Zinc-air battery for electric vehicle
journal, January 2018

Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016

Fuel Cells and Precious-Metal Catalysts
journal, October 1999

Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network
journal, August 2015

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011

Roles of Fe−N _x and Fe−Fe ₃ C@C Species in Fe−N/C Electrocatalysts for Oxygen Reduction Reaction
journal, March 2017

The effect of iron catalyzed graphitization on the textural properties of carbonized cellulose: Magnetically separable graphitic carbon bodies for catalysis and remediation
journal, October 2016

Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015

Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity
journal, March 2014

An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting
journal, December 2014

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction
journal, January 2016

Nitrogen-doped Fe/Fe ₃ C@graphitic layer/carbon nanotube hybrids derived from MOFs: efficient bifunctional electrocatalysts for ORR and OER
journal, January 2015

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode surface
journal, November 1991

From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018

Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe ₃ C Nanoparticles Boost the Activity of Fe–N _x
journal, March 2016

A New Fuel Cell Cathode Catalyst
journal, March 1964

Fe/Fe ₃ C@C nanoparticles encapsulated in N-doped graphene–CNTs framework as an efficient bifunctional oxygen electrocatalyst for robust rechargeable Zn–air batteries
journal, January 2018

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

Nitrogen-Doped Graphene-Rich Catalysts Derived from Heteroatom Polymers for Oxygen Reduction in Nonaqueous Lithium–O ₂ Battery Cathodes
journal, October 2012

Lithium−Air Battery: Promise and Challenges
journal, June 2010

A Versatile Iron-Tannin-Framework Ink Coating Strategy to Fabricate Biomass-Derived Iron Carbide/Fe-N-Carbon Catalysts for Efficient Oxygen Reduction
journal, December 2015

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
journal, January 1985

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
journal, January 2017

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018

Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid
journal, July 2016

Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity
journal, October 2015

High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017