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Title: Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [2];  [4];  [3]; ORCiD logo [5];  [6]
  1. College of Chemical EngineeringBeijing University of Chemical Technology Beijing 100029 P. R. China, Chemical Sciences and Engineering DivisionArgonne National Laboratory Lemont IL 60439 USA
  2. Jiangsu Key Laboratory of Advanced Catalytic Materials and TechnologySchool of Petrochemical EngineeringChangzhou University Changzhou 213164 P. R. China, Changzhou Institute of Advanced MaterialsBeijing University of Chemical Technology Changzhou 213164 P. R. China
  3. College of Environmental and Energy EngineeringBeijing University of Technology Beijing 100124 P. R. China
  4. X‐ray Science DivisionAdvanced Photon SourceArgonne National Laboratory Lemont IL 60439 USA
  5. Chemical Sciences and Engineering DivisionArgonne National Laboratory Lemont IL 60439 USA
  6. Key Laboratory of Advanced Reactor Engineering and SafetyMinistry of EducationTsinghua University Beijing 100084 P. R. China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1505647
Grant/Contract Number:  
DE‐AC02‐06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 29 Journal Issue: 23; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, and Yin, Hua‐Qiang. Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery. Germany: N. p., 2019. Web. doi:10.1002/adfm.201901531.
Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, & Yin, Hua‐Qiang. Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery. Germany. doi:10.1002/adfm.201901531.
Wang, Hao, Yin, Feng‐Xiang, Liu, Ning, Kou, Rong‐Hui, He, Xiao‐Bo, Sun, Cheng‐Jun, Chen, Biao‐Hua, Liu, Di‐Jia, and Yin, Hua‐Qiang. Mon . "Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery". Germany. doi:10.1002/adfm.201901531.
@article{osti_1505647,
title = {Engineering Fe–Fe 3 C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H 2 –O 2 Fuel Cell and Li–O 2 Battery},
author = {Wang, Hao and Yin, Feng‐Xiang and Liu, Ning and Kou, Rong‐Hui and He, Xiao‐Bo and Sun, Cheng‐Jun and Chen, Biao‐Hua and Liu, Di‐Jia and Yin, Hua‐Qiang},
abstractNote = {},
doi = {10.1002/adfm.201901531},
journal = {Advanced Functional Materials},
number = 23,
volume = 29,
place = {Germany},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adfm.201901531

Citation Metrics:
Cited by: 13 works
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Works referenced in this record:

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction
journal, November 2014

  • Zhao, Shenlong; Yin, Huajie; Du, Lei
  • ACS Nano, Vol. 8, Issue 12
  • DOI: 10.1021/nn505582e

Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries
journal, June 2017


Toyota MIRAI Fuel Cell Vehicle and Progress Toward a Future Hydrogen Society
journal, January 2015


Organic dyestuffs as catalysts for fuel cells
book, January 1976

  • Jahnke, Horst; Schönborn, Manfred; Zimmermann, Georg
  • Physical and Chemical Applications of Dyestuffs, p. 133-181
  • DOI: 10.1007/BFb0046059

Fe-Cluster Pushing Electrons to N-Doped Graphitic Layers with Fe 3 C(Fe) Hybrid Nanostructure to Enhance O 2 Reduction Catalysis of Zn-Air Batteries
journal, January 2017

  • Yang, Jie; Hu, Jiangtao; Weng, Mouyi
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 5
  • DOI: 10.1021/acsami.6b13166

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

  • Zhao, Dan; Shui, Jiang-Lan; Chen, Chen
  • Chemical Science, Vol. 3, Issue 11
  • DOI: 10.1039/c2sc20657a

Molecule-Level g-C 3 N 4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
journal, February 2017

  • Zheng, Yao; Jiao, Yan; Zhu, Yihan
  • Journal of the American Chemical Society, Vol. 139, Issue 9
  • DOI: 10.1021/jacs.6b13100

Fe/N/C Composite in Li–O 2 Battery: Studies of Catalytic Structure and Activity toward Oxygen Evolution Reaction
journal, October 2012

  • Shui, Jiang-Lan; Karan, Naba K.; Balasubramanian, Mahalingam
  • Journal of the American Chemical Society, Vol. 134, Issue 40
  • DOI: 10.1021/ja3042993

A General Approach to Preferential Formation of Active Fe–N x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
journal, November 2016

  • Sa, Young Jin; Seo, Dong-Jun; Woo, Jinwoo
  • Journal of the American Chemical Society, Vol. 138, Issue 45
  • DOI: 10.1021/jacs.6b09470

Range-extending Zinc-air battery for electric vehicle
journal, January 2018


Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016

  • Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b11248

Fuel Cells and Precious-Metal Catalysts
journal, October 1999


Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network
journal, August 2015

  • Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 34
  • DOI: 10.1073/pnas.1507159112

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011

  • Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
  • Chemistry - A European Journal, Vol. 17, Issue 7
  • DOI: 10.1002/chem.201003080

Roles of Fe−N x and Fe−Fe 3 C@C Species in Fe−N/C Electrocatalysts for Oxygen Reduction Reaction
journal, March 2017

  • Kim, Jae Hyung; Sa, Young Jin; Jeong, Hu Young
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 11
  • DOI: 10.1021/acsami.6b13417

Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015

  • Strickland, Kara; Miner, Elise; Jia, Qingying
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8343

Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity
journal, March 2014

  • Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen
  • Advanced Energy Materials, Vol. 4, Issue 10
  • DOI: 10.1002/aenm.201301735

An Advanced Nitrogen-Doped Graphene/Cobalt-Embedded Porous Carbon Polyhedron Hybrid for Efficient Catalysis of Oxygen Reduction and Water Splitting
journal, December 2014

  • Hou, Yang; Wen, Zhenhai; Cui, Shumao
  • Advanced Functional Materials, Vol. 25, Issue 6
  • DOI: 10.1002/adfm.201403657

A dual-metal–organic-framework derived electrocatalyst for oxygen reduction
journal, January 2016

  • Guan, Bu Yuan; Yu, Le; (David) Lou, Xiong Wen
  • Energy & Environmental Science, Vol. 9, Issue 10
  • DOI: 10.1039/C6EE02171A

Nitrogen-doped Fe/Fe 3 C@graphitic layer/carbon nanotube hybrids derived from MOFs: efficient bifunctional electrocatalysts for ORR and OER
journal, January 2015

  • Li, Ji-Sen; Li, Shun-Li; Tang, Yu-Jia
  • Chemical Communications, Vol. 51, Issue 13
  • DOI: 10.1039/C4CC09062D

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode surface
journal, November 1991

  • Kim, Sunghyun; Bae, In Tae; Sandifer, Marnita
  • Journal of the American Chemical Society, Vol. 113, Issue 24
  • DOI: 10.1021/ja00024a006

Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe 3 C Nanoparticles Boost the Activity of Fe–N x
journal, March 2016

  • Jiang, Wen-Jie; Gu, Lin; Li, Li
  • Journal of the American Chemical Society, Vol. 138, Issue 10
  • DOI: 10.1021/jacs.6b00757

A New Fuel Cell Cathode Catalyst
journal, March 1964

  • Jasinski, Raymond
  • Nature, Vol. 201, Issue 4925, p. 1212-1213
  • DOI: 10.1038/2011212a0

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1427

Lithium−Air Battery: Promise and Challenges
journal, June 2010

  • Girishkumar, G.; McCloskey, B.; Luntz, A. C.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
  • DOI: 10.1021/jz1005384

A Versatile Iron-Tannin-Framework Ink Coating Strategy to Fabricate Biomass-Derived Iron Carbide/Fe-N-Carbon Catalysts for Efficient Oxygen Reduction
journal, December 2015

  • Wei, Jing; Liang, Yan; Hu, Yaoxin
  • Angewandte Chemie International Edition, Vol. 55, Issue 4
  • DOI: 10.1002/anie.201509024

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
journal, January 2017

  • Barkholtz, Heather M.; Liu, Di-Jia
  • Materials Horizons, Vol. 4, Issue 1
  • DOI: 10.1039/C6MH00344C

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018


Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity
journal, October 2015


High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017

  • Liu, Jing; Jiao, Menggai; Lu, Lanlu
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15938