Homoleptic U(III) and U(IV) amidate complexes
Abstract
The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described here. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.
- Authors:
-
[1];
[1];
[2];
[1]
- Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation; National Inst. of Health (NIH) (United States)
- OSTI Identifier:
- 1505517
- Grant/Contract Number:
- AC02-05CH11231; NA0003180; NA0000979; S10-RR027172
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 47; Journal Issue: 6; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Straub, M. D., Hohloch, S., Minasian, S. G., and Arnold, J. Homoleptic U(III) and U(IV) amidate complexes. United States: N. p., 2018.
Web. doi:10.1039/c7dt04813k.
Straub, M. D., Hohloch, S., Minasian, S. G., & Arnold, J. Homoleptic U(III) and U(IV) amidate complexes. United States. https://doi.org/10.1039/c7dt04813k
Straub, M. D., Hohloch, S., Minasian, S. G., and Arnold, J. Thu .
"Homoleptic U(III) and U(IV) amidate complexes". United States. https://doi.org/10.1039/c7dt04813k. https://www.osti.gov/servlets/purl/1505517.
@article{osti_1505517,
title = {Homoleptic U(III) and U(IV) amidate complexes},
author = {Straub, M. D. and Hohloch, S. and Minasian, S. G. and Arnold, J.},
abstractNote = {The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described here. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.},
doi = {10.1039/c7dt04813k},
journal = {Dalton Transactions},
number = 6,
volume = 47,
place = {United States},
year = {Thu Jan 18 00:00:00 EST 2018},
month = {Thu Jan 18 00:00:00 EST 2018}
}
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Cited by: 6 works
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Figures / Tables:
Figure 1: Binding modes of amidates to metal centers.
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Works referencing / citing this record:
Chemical Vapor Deposition of Phase‐Pure Uranium Dioxide Thin Films from Uranium(IV) Amidate Precursors
journal, March 2019
- Straub, Mark D.; Leduc, Jennifer; Frank, Michael
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Chemical Vapor Deposition of Phase-Pure Uranium Dioxide Thin Films from Uranium(IV) Amidate Precursors
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Structure and magnetism of a tetrahedral uranium( iii ) β-diketiminate complex
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