SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose
Abstract
SAPO-34 zeolite crystals were grown on zeolite 5A beads, characterized, and then utilized to produce furfural from xylose and 5-hydroxymethylfurfural (HMF) from glucose. The SAPO-34/5A bead catalysts resulted in moderate furfural and HMF yields of 45% from xylose and 20% from glucose (463 K; 3 h) and were easier to recover than the SAPO-34 powder catalyst. At 463 K, the SAPO-34/5A beads were more selective than 0.02 M sulfuric acid for producing HMF and, unlike the sulfuric acid system, no levulinic acid was formed. The SAPO-34/5A bead catalysts had no significant loss in activity after three rounds of recycle when water washed or heated overnight between reactions; however, the heat-treated beads did show signs of thermal stress after the second reuse. The SAPO-34/5A bead catalysts show promise for dehydration reactions to produce furfural and HMF from xylose and glucose, respectively, and adapting the catalyst and the support bead could lead to even higher selectivities and yields.
- Authors:
-
- Montana State Univ., Bozeman, MT (United States)
- Colorado School of Mines, Golden, CO (United States)
- Syracuse Univ., Syracuse, NY (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- National Science Foundation (NSF), Chemical, Bioengineering, Environmental and Transport Systems (CBET); USDOE
- OSTI Identifier:
- 1505295
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Omega
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2470-1343
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., and Wettstein, Stephanie G. SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose. United States: N. p., 2018.
Web. doi:10.1021/acsomega.8b02461.
Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., & Wettstein, Stephanie G. SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose. United States. https://doi.org/10.1021/acsomega.8b02461
Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., and Wettstein, Stephanie G. Thu .
"SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose". United States. https://doi.org/10.1021/acsomega.8b02461. https://www.osti.gov/servlets/purl/1505295.
@article{osti_1505295,
title = {SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose},
author = {Romo, Joelle E. and Wu, Ting and Huang, Xinlei and Lucero, Jolie and Irwin, Jennifer L. and Bond, Jesse Q. and Carreon, Moises A. and Wettstein, Stephanie G.},
abstractNote = {SAPO-34 zeolite crystals were grown on zeolite 5A beads, characterized, and then utilized to produce furfural from xylose and 5-hydroxymethylfurfural (HMF) from glucose. The SAPO-34/5A bead catalysts resulted in moderate furfural and HMF yields of 45% from xylose and 20% from glucose (463 K; 3 h) and were easier to recover than the SAPO-34 powder catalyst. At 463 K, the SAPO-34/5A beads were more selective than 0.02 M sulfuric acid for producing HMF and, unlike the sulfuric acid system, no levulinic acid was formed. The SAPO-34/5A bead catalysts had no significant loss in activity after three rounds of recycle when water washed or heated overnight between reactions; however, the heat-treated beads did show signs of thermal stress after the second reuse. The SAPO-34/5A bead catalysts show promise for dehydration reactions to produce furfural and HMF from xylose and glucose, respectively, and adapting the catalyst and the support bead could lead to even higher selectivities and yields.},
doi = {10.1021/acsomega.8b02461},
journal = {ACS Omega},
number = 11,
volume = 3,
place = {United States},
year = {Thu Nov 29 00:00:00 EST 2018},
month = {Thu Nov 29 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
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Fructose Dehydration to 5-Hydroxymethylfurfural over Solid Acid Catalysts in a Biphasic System
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Beneficial effects of calcium chloride on glucose dehydration to 5-hydroxymethylfurfural in the presence of alumina as catalyst
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Production of furfural from waste aqueous hemicellulose solution of hardwood over ZSM-5 zeolite
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An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery
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Effects of careful designing of SAPO-44 catalysts on the efficient synthesis of furfural
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Zeolite H-USY for the production of lactic acid and methyl lactate from C3-sugars
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Investigation into the shape selectivity of zeolite catalysts for biomass conversion
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The effect of solvent addition on fructose dehydration to 5-hydroxymethylfurfural in biphasic system over zeolites
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A microwave-assisted process for the in-situ production of 5-hydroxymethylfurfural and furfural from lignocellulosic polysaccharides in a biphasic reaction system
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Application of sulfonated carbon-based catalyst for the furfural production from d -xylose and xylan in a microwave-assisted biphasic reaction
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Separation of xylose from glucose by nanofiltration from concentrated monosaccharide solutions
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Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis
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- Moliner, Manuel; Martínez, Cristina; Corma, Avelino
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Efficient, Stable, and Reusable Silicoaluminophosphate for the One-Pot Production of Furfural from Hemicellulose
journal, September 2013
- Bhaumik, Prasenjit; Dhepe, Paresh L.
- ACS Catalysis, Vol. 3, Issue 10
Kr/Xe Separation over a Chabazite Zeolite Membrane
journal, August 2016
- Feng, Xuhui; Zong, Zhaowang; Elsaidi, Sameh K.
- Journal of the American Chemical Society, Vol. 138, Issue 31
Exceptionally high yields of furfural from assorted raw biomass over solid acids
journal, January 2014
- Bhaumik, Prasenjit; Dhepe, Paresh Laxmikant
- RSC Advances, Vol. 4, Issue 50
Potential and challenges of zeolite chemistry in the catalytic conversion of biomass
journal, January 2016
- Ennaert, Thijs; Van Aelst, Joost; Dijkmans, Jan
- Chemical Society Reviews, Vol. 45, Issue 3
Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010
- Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
Works referencing / citing this record:
Production of 5-Hydroxymethylfurfural from Glucose in Water by Using Transition Metal-Oxide Nanosheet Aggregates
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