SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose

Romo, Joelle E.; Wu, Ting; Huang, Xinlei; Lucero, Jolie; Irwin, Jennifer L.; Bond, Jesse Q.; Carreon, Moises A.; Wettstein, Stephanie G.

doi:10.1021/acsomega.8b02461

Title: SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose

Abstract

SAPO-34 zeolite crystals were grown on zeolite 5A beads, characterized, and then utilized to produce furfural from xylose and 5-hydroxymethylfurfural (HMF) from glucose. The SAPO-34/5A bead catalysts resulted in moderate furfural and HMF yields of 45% from xylose and 20% from glucose (463 K; 3 h) and were easier to recover than the SAPO-34 powder catalyst. At 463 K, the SAPO-34/5A beads were more selective than 0.02 M sulfuric acid for producing HMF and, unlike the sulfuric acid system, no levulinic acid was formed. The SAPO-34/5A bead catalysts had no significant loss in activity after three rounds of recycle when water washed or heated overnight between reactions; however, the heat-treated beads did show signs of thermal stress after the second reuse. The SAPO-34/5A bead catalysts show promise for dehydration reactions to produce furfural and HMF from xylose and glucose, respectively, and adapting the catalyst and the support bead could lead to even higher selectivities and yields.

Authors:

Romo, Joelle E. ^[1]; Wu, Ting ^[2]; Huang, Xinlei ^[3]; Lucero, Jolie ^[2]; Irwin, Jennifer L. ^[1]; Bond, Jesse Q. ^[3];

^[2];

^[1]

Montana State Univ., Bozeman, MT (United States)
Colorado School of Mines, Golden, CO (United States)
Syracuse Univ., Syracuse, NY (United States)

Publication Date:: 2018-11-29

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: National Science Foundation (NSF), Chemical, Bioengineering, Environmental and Transport Systems (CBET); USDOE

OSTI Identifier:: 1505295

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: ACS Omega

Additional Journal Information:: Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2470-1343

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., and Wettstein, Stephanie G. SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose.  United States: N. p., 2018. 
Web.  doi:10.1021/acsomega.8b02461.

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                    Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., & Wettstein, Stephanie G. SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose.  United States.  https://doi.org/10.1021/acsomega.8b02461

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                    Romo, Joelle E., Wu, Ting, Huang, Xinlei, Lucero, Jolie, Irwin, Jennifer L., Bond, Jesse Q., Carreon, Moises A., and Wettstein, Stephanie G. Thu .  
"SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose".  United States.  https://doi.org/10.1021/acsomega.8b02461.  https://www.osti.gov/servlets/purl/1505295.

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@article{osti_1505295,

  title        = {SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose},

  author       = {Romo, Joelle E. and Wu, Ting and Huang, Xinlei and Lucero, Jolie and Irwin, Jennifer L. and Bond, Jesse Q. and Carreon, Moises A. and Wettstein, Stephanie G.},

  abstractNote = {SAPO-34 zeolite crystals were grown on zeolite 5A beads, characterized, and then utilized to produce furfural from xylose and 5-hydroxymethylfurfural (HMF) from glucose. The SAPO-34/5A bead catalysts resulted in moderate furfural and HMF yields of 45% from xylose and 20% from glucose (463 K; 3 h) and were easier to recover than the SAPO-34 powder catalyst. At 463 K, the SAPO-34/5A beads were more selective than 0.02 M sulfuric acid for producing HMF and, unlike the sulfuric acid system, no levulinic acid was formed. The SAPO-34/5A bead catalysts had no significant loss in activity after three rounds of recycle when water washed or heated overnight between reactions; however, the heat-treated beads did show signs of thermal stress after the second reuse. The SAPO-34/5A bead catalysts show promise for dehydration reactions to produce furfural and HMF from xylose and glucose, respectively, and adapting the catalyst and the support bead could lead to even higher selectivities and yields.},

  doi          = {10.1021/acsomega.8b02461},

  journal      = {ACS Omega},

  number       = 11,

  volume       = 3,

  place        = {United States},

  year         = {2018},

  month        = {11}

}

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https://doi.org/10.1021/acsomega.8b02461

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Cited by: 2 works

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Figures / Tables:

Figure 1: Representative SEM images of SAPO-34/5A beads: (a) single SAPO-34 covered 5A bead and (b) cross-sectional view.

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Works referencing / citing this record:

Production of 5-Hydroxymethylfurfural from Glucose in Water by Using Transition Metal-Oxide Nanosheet Aggregates
journal, September 2019

Takagaki, Atsushi
Catalysts, Vol. 9, Issue 10
DOI: 10.3390/catal9100818

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

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Title: SAPO-34/5A Zeolite Bead Catalysts for Furan Production from Xylose and Glucose

Abstract

Citation Formats

Figures / Tables:

A roadmap for conversion of lignocellulosic biomass to chemicals and fuels journal, August 2012

Furfural-A Promising Platform for Lignocellulosic Biofuels journal, December 2011

Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review journal, February 2018

Kinetics of levulinic acid and furfural production from Miscanthus×giganteus journal, December 2013

Levulinic Acid as a Catalyst for the Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulose Biomass journal, December 2015

A microwave-assisted process for the in-situ production of 5-hydroxymethylfurfural and furfural from lignocellulosic polysaccharides in a biphasic reaction system journal, June 2018

An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery journal, January 2006

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water journal, March 2010

Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions journal, May 2010

Zeolite H-USY for the production of lactic acid and methyl lactate from C3-sugars journal, January 2010

Production of Furfural from Process-Relevant Biomass-Derived Pentoses in a Biphasic Reaction System journal, June 2017

From Lignocellulosic Biomass to Furfural: Insight into the Active Species of a Silica-Supported Tungsten Oxide Catalyst journal, September 2016

Application of sulfonated carbon-based catalyst for the furfural production from d -xylose and xylan in a microwave-assisted biphasic reaction journal, September 2017

Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals journal, May 2014

Beneficial effects of calcium chloride on glucose dehydration to 5-hydroxymethylfurfural in the presence of alumina as catalyst journal, June 2017

Fructose Dehydration to 5-Hydroxymethylfurfural over Solid Acid Catalysts in a Biphasic System journal, July 2012

Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry journal, December 2017

Conversion of glucose to lactic acid derivatives with mesoporous Sn-MCM-41 and microporous titanosilicates journal, October 2013

Potential and challenges of zeolite chemistry in the catalytic conversion of biomass journal, January 2016

Small pore zeolite catalysts for furfural synthesis from xylose and switchgrass in a γ-valerolactone/water solvent journal, October 2016

Production of furfural from waste aqueous hemicellulose solution of hardwood over ZSM-5 zeolite journal, November 2014

The effect of solvent addition on fructose dehydration to 5-hydroxymethylfurfural in biphasic system over zeolites journal, March 2012

Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids journal, October 1984

Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis journal, July 2013

Efficient, Stable, and Reusable Silicoaluminophosphate for the One-Pot Production of Furfural from Hemicellulose journal, September 2013

Effects of careful designing of SAPO-44 catalysts on the efficient synthesis of furfural journal, August 2015

Dehydration of Xylose into Furfural in the Presence of Crystalline Microporous Silicoaluminophosphates journal, January 2010

Exceptionally high yields of furfural from assorted raw biomass over solid acids journal, January 2014

Decarboxylation of Oleic Acid to Heptadecane over Pt Supported on Zeolite 5A Beads journal, October 2015

Separation of C 6 Paraffins Using Zeolitic Imidazolate Frameworks: Comparison with Zeolite 5A journal, March 2012

Investigation into the shape selectivity of zeolite catalysts for biomass conversion journal, April 2011

Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts journal, February 2012

Separation of xylose from glucose by nanofiltration from concentrated monosaccharide solutions journal, April 2007

Acid Modified H-USY Zeolite for Efficient Catalytic Transformation of Fructose to 5-Hydroxymethyl Furfural (Biofuel Precursor) in Methyl Isobutyl Ketone–Water Biphasic System journal, February 2018

Catalytic evaluation of small-pore molecular sieves with different framework topologies for the synthesis of methylamines journal, May 2006

Acidic catalysts for the dehydration of glycerol: Activity and deactivation journal, August 2009

Kr/Xe Separation over a Chabazite Zeolite Membrane journal, August 2016

Effect of reaction parameters on the decarboxylation of oleic acid over Pt/ZIF-67membrane/zeolite 5A bead catalysts: Effect of reaction parameters on the decarboxylation of oleic acid journal, October 2016

Production of 5-Hydroxymethylfurfural from Glucose in Water by Using Transition Metal-Oxide Nanosheet Aggregates journal, September 2019

A roadmap for conversion of lignocellulosic biomass to chemicals and fuels
journal, August 2012

Furfural-A Promising Platform for Lignocellulosic Biofuels
journal, December 2011

Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review
journal, February 2018

Kinetics of levulinic acid and furfural production from Miscanthus×giganteus
journal, December 2013

Levulinic Acid as a Catalyst for the Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulose Biomass
journal, December 2015

A microwave-assisted process for the in-situ production of 5-hydroxymethylfurfural and furfural from lignocellulosic polysaccharides in a biphasic reaction system
journal, June 2018

An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery
journal, January 2006

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions
journal, May 2010

Zeolite H-USY for the production of lactic acid and methyl lactate from C3-sugars
journal, January 2010

Production of Furfural from Process-Relevant Biomass-Derived Pentoses in a Biphasic Reaction System
journal, June 2017

From Lignocellulosic Biomass to Furfural: Insight into the Active Species of a Silica-Supported Tungsten Oxide Catalyst
journal, September 2016

Application of sulfonated carbon-based catalyst for the furfural production from d -xylose and xylan in a microwave-assisted biphasic reaction
journal, September 2017

Efficient Solid Acid Catalyst Containing Lewis and Brønsted Acid Sites for the Production of Furfurals
journal, May 2014

Beneficial effects of calcium chloride on glucose dehydration to 5-hydroxymethylfurfural in the presence of alumina as catalyst
journal, June 2017

Fructose Dehydration to 5-Hydroxymethylfurfural over Solid Acid Catalysts in a Biphasic System
journal, July 2012

Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry
journal, December 2017

Conversion of glucose to lactic acid derivatives with mesoporous Sn-MCM-41 and microporous titanosilicates
journal, October 2013

Potential and challenges of zeolite chemistry in the catalytic conversion of biomass
journal, January 2016

Small pore zeolite catalysts for furfural synthesis from xylose and switchgrass in a γ-valerolactone/water solvent
journal, October 2016

Production of furfural from waste aqueous hemicellulose solution of hardwood over ZSM-5 zeolite
journal, November 2014

The effect of solvent addition on fructose dehydration to 5-hydroxymethylfurfural in biphasic system over zeolites
journal, March 2012

Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids
journal, October 1984

Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis
journal, July 2013

Efficient, Stable, and Reusable Silicoaluminophosphate for the One-Pot Production of Furfural from Hemicellulose
journal, September 2013

Effects of careful designing of SAPO-44 catalysts on the efficient synthesis of furfural
journal, August 2015

Dehydration of Xylose into Furfural in the Presence of Crystalline Microporous Silicoaluminophosphates
journal, January 2010

Exceptionally high yields of furfural from assorted raw biomass over solid acids
journal, January 2014

Decarboxylation of Oleic Acid to Heptadecane over Pt Supported on Zeolite 5A Beads
journal, October 2015

Separation of C ₆ Paraffins Using Zeolitic Imidazolate Frameworks: Comparison with Zeolite 5A
journal, March 2012

Investigation into the shape selectivity of zeolite catalysts for biomass conversion
journal, April 2011

Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts
journal, February 2012

Separation of xylose from glucose by nanofiltration from concentrated monosaccharide solutions
journal, April 2007

Acid Modified H-USY Zeolite for Efficient Catalytic Transformation of Fructose to 5-Hydroxymethyl Furfural (Biofuel Precursor) in Methyl Isobutyl Ketone–Water Biphasic System
journal, February 2018

Catalytic evaluation of small-pore molecular sieves with different framework topologies for the synthesis of methylamines
journal, May 2006

Acidic catalysts for the dehydration of glycerol: Activity and deactivation
journal, August 2009

Kr/Xe Separation over a Chabazite Zeolite Membrane
journal, August 2016

Effect of reaction parameters on the decarboxylation of oleic acid over Pt/ZIF-67membrane/zeolite 5A bead catalysts: Effect of reaction parameters on the decarboxylation of oleic acid
journal, October 2016

Production of 5-Hydroxymethylfurfural from Glucose in Water by Using Transition Metal-Oxide Nanosheet Aggregates
journal, September 2019