Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives
Abstract
Metal–organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters, connected by multidentate organic ligands. Herein, we describe the synthesis and photophysical properties of two Zr-based, anthracene-containing MOFs, assembled from 2,6-anthracenedicarboxylic acid (2,6-ADCA and 2,6-MOF) and 1,4-anthracenedicarboxylic acid (1,4-ADCA and 1,4-MOF). The 2,6-ADCA analogue formed a highly crystalline octahedral structure that is isostructural with the well-known UiO-67 frameworks. Incorporation of the 1,4-ADCA ligand, on the other hand, resulted in large rod-shaped crystals. Both MOFs exhibit linker-based luminescence. The excited-state properties of the 2,6-MOF and 1,4-MOF were examined using stead-state diffuse reflectance and emission spectroscopies and time-correlated single photon counting (TCSPC) spectroscopy. The photophysical properties of the MOFs are compared with those of the corresponding ligand in solution.
- Authors:
-
- Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
- Publication Date:
- Research Org.:
- Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1504920
- Grant/Contract Number:
- SC0012446
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Canadian Journal of Chemistry
- Additional Journal Information:
- Journal Volume: 96; Journal Issue: 9; Journal ID: ISSN 0008-4042
- Publisher:
- NRC Research Press
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; metal-organic framework; anthracene; luminescence; photophysics
Citation Formats
Rowe, Jennifer M., Soderstrom, Erin M., Zhu, Jie, Usov, Pavel M., and Morris, Amanda J. Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives. United States: N. p., 2018.
Web. doi:10.1139/cjc-2017-0445.
Rowe, Jennifer M., Soderstrom, Erin M., Zhu, Jie, Usov, Pavel M., & Morris, Amanda J. Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives. United States. https://doi.org/10.1139/cjc-2017-0445
Rowe, Jennifer M., Soderstrom, Erin M., Zhu, Jie, Usov, Pavel M., and Morris, Amanda J. Thu .
"Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives". United States. https://doi.org/10.1139/cjc-2017-0445. https://www.osti.gov/servlets/purl/1504920.
@article{osti_1504920,
title = {Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives},
author = {Rowe, Jennifer M. and Soderstrom, Erin M. and Zhu, Jie and Usov, Pavel M. and Morris, Amanda J.},
abstractNote = {Metal–organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters, connected by multidentate organic ligands. Herein, we describe the synthesis and photophysical properties of two Zr-based, anthracene-containing MOFs, assembled from 2,6-anthracenedicarboxylic acid (2,6-ADCA and 2,6-MOF) and 1,4-anthracenedicarboxylic acid (1,4-ADCA and 1,4-MOF). The 2,6-ADCA analogue formed a highly crystalline octahedral structure that is isostructural with the well-known UiO-67 frameworks. Incorporation of the 1,4-ADCA ligand, on the other hand, resulted in large rod-shaped crystals. Both MOFs exhibit linker-based luminescence. The excited-state properties of the 2,6-MOF and 1,4-MOF were examined using stead-state diffuse reflectance and emission spectroscopies and time-correlated single photon counting (TCSPC) spectroscopy. The photophysical properties of the MOFs are compared with those of the corresponding ligand in solution.},
doi = {10.1139/cjc-2017-0445},
journal = {Canadian Journal of Chemistry},
number = 9,
volume = 96,
place = {United States},
year = {Thu Nov 08 00:00:00 EST 2018},
month = {Thu Nov 08 00:00:00 EST 2018}
}
Web of Science
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