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Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd 3Bi 7 and Sm 3Bi 7

Abstract

The binary bismuthides Nd 3Bi 7 and Sm 3Bi 7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Univ. of Delaware, Newark, DE (United States)
Publication Date:
Research Org.:
Univ. of Delaware, Newark, DE (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1504902
Alternate Identifier(s):
OSTI ID: 1441062
Grant/Contract Number:  
SC0008885
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 51; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States: N. p., 2018. Web. doi:10.1039/c8cc02563k.
Ovchinnikov, Alexander, Makongo, Julien P. A., & Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States. doi:10.1039/c8cc02563k.
Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Mon . "Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7". United States. doi:10.1039/c8cc02563k. https://www.osti.gov/servlets/purl/1504902.
@article{osti_1504902,
title = {Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7},
author = {Ovchinnikov, Alexander and Makongo, Julien P. A. and Bobev, Svilen},
abstractNote = {The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.},
doi = {10.1039/c8cc02563k},
journal = {ChemComm},
number = 51,
volume = 54,
place = {United States},
year = {2018},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 2 works
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