Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Ovchinnikov, Alexander; Makongo, Julien P.  A.; Bobev, Svilen

doi:10.1039/c8cc02563k

Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd₃Bi₇ and Sm₃Bi₇

Abstract

The binary bismuthides Nd₃Bi₇ and Sm₃Bi₇ were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.

Authors:

^[1]; Makongo, Julien P. A. ^[1];

^[1]

Univ. of Delaware, Newark, DE (United States)

Publication Date:: Mon Jun 04 00:00:00 EDT 2018

Research Org.:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1504902

Alternate Identifier(s):: OSTI ID: 1441062

Grant/Contract Number:: SC0008885

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 51; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Ovchinnikov, Alexander, Makongo, Julien P.  A., and Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7.  United States: N. p., 2018. 
Web.  doi:10.1039/c8cc02563k.

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                    Ovchinnikov, Alexander, Makongo, Julien P.  A., & Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7.  United States.  https://doi.org/10.1039/c8cc02563k

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                    Ovchinnikov, Alexander, Makongo, Julien P.  A., and Bobev, Svilen. Mon .  
"Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7".  United States.  https://doi.org/10.1039/c8cc02563k.  https://www.osti.gov/servlets/purl/1504902.

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@article{osti_1504902,

  title        = {Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7},

  author       = {Ovchinnikov, Alexander and Makongo, Julien P.  A. and Bobev, Svilen},

  abstractNote = {The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.},

  doi          = {10.1039/c8cc02563k},

  journal      = {ChemComm},

  number       = 51,

  volume       = 54,

  place        = {United States},

  year         = {Mon Jun 04 00:00:00 EDT 2018},

  month        = {Mon Jun 04 00:00:00 EDT 2018}

}

Copy to clipboard

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https://doi.org/10.1039/c8cc02563k

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Cited by: 12 works

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Figures / Tables:

Fig. 1: Crystal structure of RE₃Bi₇ (RE = Nd, Sm). RE and Bi atoms are shown in orange and purple, respectively. The unit cell is outlined wish dashed lines.

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Works referencing / citing this record:

Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods
journal, January 2020

Ovchinnikov, Alexander; Bobev, Svilen
Frontiers in Chemistry, Vol. 7
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Title: Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

Abstract

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