Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure

Hu, Linhua; Johnson, Ian D.; Kim, Soojeong; Nolis, Gene M.; Freeland, John W.; Yoo, Hyun Deog; Fister, Timothy T.; McCafferty, Liam; Ashton, Thomas E.; Darr, Jawwad A.; Cabana, Jordi

doi:10.1039/c8nr08347a

Title: Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure

Abstract

Reversible Mg removal from MgCr ₂ O ₄ (a high-voltage Mg-intercalation cathode material) was improved by nanosizing and introducing significant structural defects.

Authors:

^[1];

^[2]; Kim, Soojeong ^[3]; Nolis, Gene M. ^[1]; Freeland, John W. ^[3];

^[4];

^[3];

^[2]; Ashton, Thomas E. ^[2];

^[2];

^[1]

Univ. of Illinois at Chicago, Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. College London, London (United Kingdom)
Argonne National Lab. (ANL), Argonne, IL (United States)
Pusan National Univ., Busan (Republic of Korea)

Publication Date:: 2018-12-03

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Engineering and Physical Sciences Research Council (EPSRC); Science and Technologies Facilities Council (STFC-UK)

OSTI Identifier:: 1504775

Alternate Identifier(s):: OSTI ID: 1488344

Grant/Contract Number:: AC02-06CH11357; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Nanoscale

Additional Journal Information:: Journal Volume: 11; Journal Issue: 2; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Hu, Linhua, Johnson, Ian D., Kim, Soojeong, Nolis, Gene M., Freeland, John W., Yoo, Hyun Deog, Fister, Timothy T., McCafferty, Liam, Ashton, Thomas E., Darr, Jawwad A., and Cabana, Jordi. Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure.  United States: N. p., 2018. 
Web.  doi:10.1039/c8nr08347a.

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                    Hu, Linhua, Johnson, Ian D., Kim, Soojeong, Nolis, Gene M., Freeland, John W., Yoo, Hyun Deog, Fister, Timothy T., McCafferty, Liam, Ashton, Thomas E., Darr, Jawwad A., & Cabana, Jordi. Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure.  United States.  https://doi.org/10.1039/c8nr08347a

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                    Hu, Linhua, Johnson, Ian D., Kim, Soojeong, Nolis, Gene M., Freeland, John W., Yoo, Hyun Deog, Fister, Timothy T., McCafferty, Liam, Ashton, Thomas E., Darr, Jawwad A., and Cabana, Jordi. Mon .  
"Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure".  United States.  https://doi.org/10.1039/c8nr08347a.  https://www.osti.gov/servlets/purl/1504775.

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@article{osti_1504775,

  title        = {Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure},

  author       = {Hu, Linhua and Johnson, Ian D. and Kim, Soojeong and Nolis, Gene M. and Freeland, John W. and Yoo, Hyun Deog and Fister, Timothy T. and McCafferty, Liam and Ashton, Thomas E. and Darr, Jawwad A. and Cabana, Jordi},

  abstractNote = {Reversible Mg removal from MgCr 2 O 4 (a high-voltage Mg-intercalation cathode material) was improved by nanosizing and introducing significant structural defects.},

  doi          = {10.1039/c8nr08347a},

  journal      = {Nanoscale},

  number       = 2,

  volume       = 11,

  place        = {United States},

  year         = {2018},

  month        = {12}

}

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Works referencing / citing this record:

Reversible High Capacity and Reaction Mechanism of Cr ₂ (NCN) ₃ Negative Electrodes for Li‐Ion Batteries
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Arayamparambil, Jeethu Jiju; Chen, Kaixuan; Iadecola, Antonella
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Reversible High Capacity and Reaction Mechanism of Cr 2 (NCN) 3 Negative Electrodes for Li-Ion Batteries
text, January 2020

Arayamparambil, Jeethu Jiju; Chen, Kaixuan; Iadecola, Antonella
RWTH Aachen University
DOI: 10.18154/rwth-2020-04806

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Title: Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure

Abstract

Citation Formats

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

Ionic-liquid materials for the electrochemical challenges of the future journal, July 2009

Electrochemical extraction of lithium from LiMn2O4 journal, February 1984

Electrochemistry of Magnesium Electrolytes in Ionic Liquids for Secondary Batteries journal, October 2014

Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges journal, February 2017

Continuous Hydrothermal Synthesis of Inorganic Nanoparticles: Applications and Future Directions journal, August 2017

The influence of coordination geometry and valency on the K-edge absorption near edge spectra of selected chromium compounds journal, May 2004

Nonaqueous magnesium electrochemistry and its application in secondary batteries journal, January 2003

Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations journal, January 2015

VO2 nano-sheet negative electrodes for lithium-ion batteries journal, March 2016

On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials † journal, February 2010

Kinetic mechanisms of the formations of MgCr2O4 and FeCr2O4 spinels from their metal oxides journal, December 1991

Influence of Inversion on Mg Mobility and Electrochemistry in Spinels journal, September 2017

High power Nb-doped LiFePO4 Li-ion battery cathodes; pilot-scale synthesis and electrochemical properties journal, September 2016

High Capacity Rechargeable Magnesium-Ion Batteries Based on a Microporous Molybdenum–Vanadium Oxide Cathode journal, June 2016

Single-layered V2O5 a promising cathode material for rechargeable Li and Mg ion batteries: an ab initio study journal, January 2013

Fraction of the theoretical specific energy achieved on pack level for hypothetical battery chemistries journal, December 2014

Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host journal, April 2015

Crystal structures and cation distributions in simple spinels from powder XRD structural refinements: MgCr2O4, ZnCr2O4, Fe3O4 and the temperature dependence of the cation distribution in ZnAl2O4 journal, May 1994

Highly pseudocapacitive Nb-doped TiO 2 high power anodes for lithium-ion batteries journal, January 2015

Prototype systems for rechargeable magnesium batteries journal, October 2000

Thermal, structural, and impedance analysis of nanocrystalline magnesium chromite spinel synthesized via hydrothermal process journal, December 2013

Electrochemical insertion of lithium, sodium, and magnesium in molybdenum(VI) oxide journal, April 1995

Mapping Structure-Composition-Property Relationships in V- and Fe-Doped LiMnPO 4 Cathodes for Lithium-Ion Batteries journal, October 2016

The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source conference, January 2010

The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use journal, June 2002

Correlations in the electronic structure of half-metallic ferromagnetic CrO 2 films: An x-ray absorption and resonant photoemission spectroscopy study journal, August 2005

Towards effective small scale microbial fuel cells for energy generation from urine journal, February 2016

Multivalent Electrochemistry of Spinel Mg x Mn 3– x O 4 Nanocrystals journal, February 2018

Synthesis and investigation of magnesium chromium spinel journal, February 2010

Scaling-up a Confined Jet Reactor for the Continuous Hydrothermal Manufacture of Nanomaterials journal, April 2013

Pilot-scale continuous synthesis of a vanadium-doped LiFePO4/C nanocomposite high-rate cathodes for lithium-ion batteries journal, January 2016

First-Principles Study of the Voltage Profile and Mobility of Mg Intercalation in a Chromium Oxide Spinel journal, December 2017

Influence of inversion on Mg mobility and electrochemistry in spinels text, January 2017

Reversible High Capacity and Reaction Mechanism of Cr 2 (NCN) 3 Negative Electrodes for Li‐Ion Batteries journal, December 2019

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Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
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The influence of coordination geometry and valency on the K-edge absorption near edge spectra of selected chromium compounds
journal, May 2004

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journal, January 2015

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journal, March 2016

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journal, February 2010

Kinetic mechanisms of the formations of MgCr2O4 and FeCr2O4 spinels from their metal oxides
journal, December 1991

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journal, September 2017

High power Nb-doped LiFePO4 Li-ion battery cathodes; pilot-scale synthesis and electrochemical properties
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Single-layered V2O5 a promising cathode material for rechargeable Li and Mg ion batteries: an ab initio study
journal, January 2013

Fraction of the theoretical specific energy achieved on pack level for hypothetical battery chemistries
journal, December 2014

Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host
journal, April 2015

Crystal structures and cation distributions in simple spinels from powder XRD structural refinements: MgCr2O4, ZnCr2O4, Fe3O4 and the temperature dependence of the cation distribution in ZnAl2O4
journal, May 1994

Highly pseudocapacitive Nb-doped TiO ₂ high power anodes for lithium-ion batteries
journal, January 2015

Prototype systems for rechargeable magnesium batteries
journal, October 2000

Thermal, structural, and impedance analysis of nanocrystalline magnesium chromite spinel synthesized via hydrothermal process
journal, December 2013

Electrochemical insertion of lithium, sodium, and magnesium in molybdenum(VI) oxide
journal, April 1995

Mapping Structure-Composition-Property Relationships in V- and Fe-Doped LiMnPO ₄ Cathodes for Lithium-Ion Batteries
journal, October 2016

The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source
conference, January 2010

The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use
journal, June 2002

Correlations in the electronic structure of half-metallic ferromagnetic ${CrO}_{2}$ films: An x-ray absorption and resonant photoemission spectroscopy study
journal, August 2005

Towards effective small scale microbial fuel cells for energy generation from urine
journal, February 2016

Multivalent Electrochemistry of Spinel Mg _x Mn _{3– x} O ₄ Nanocrystals
journal, February 2018

Synthesis and investigation of magnesium chromium spinel
journal, February 2010

Scaling-up a Confined Jet Reactor for the Continuous Hydrothermal Manufacture of Nanomaterials
journal, April 2013

Pilot-scale continuous synthesis of a vanadium-doped LiFePO4/C nanocomposite high-rate cathodes for lithium-ion batteries
journal, January 2016

First-Principles Study of the Voltage Profile and Mobility of Mg Intercalation in a Chromium Oxide Spinel
journal, December 2017

Influence of inversion on Mg mobility and electrochemistry in spinels
text, January 2017

Reversible High Capacity and Reaction Mechanism of Cr ₂ (NCN) ₃ Negative Electrodes for Li‐Ion Batteries
journal, December 2019

Rapid synthesis of MgCo ₂ O ₄ and Mg _2/3 Ni _4/3 O ₂ nanocrystals in supercritical fluid for Mg-ion batteries
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Cr-doped lithium titanate nanocrystals as Mg ion insertion materials for Mg batteries
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Reversible High Capacity and Reaction Mechanism of Cr 2 (NCN) 3 Negative Electrodes for Li-Ion Batteries
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