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Title: Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)

Abstract

Reaction of molecular O 2 with thorium alkyl complexes supported by amidinates and guanidinates generates thorium alkoxides via O 2 insertion into thorium-carbon bonds.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  2. Department of Chemistry, University of California, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1504515
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 17; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Settineri, Nicholas S., Shiau, Angela A., and Arnold, John. Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides). United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT00811J.
Settineri, Nicholas S., Shiau, Angela A., & Arnold, John. Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides). United Kingdom. doi:10.1039/C9DT00811J.
Settineri, Nicholas S., Shiau, Angela A., and Arnold, John. Tue . "Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)". United Kingdom. doi:10.1039/C9DT00811J.
@article{osti_1504515,
title = {Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)},
author = {Settineri, Nicholas S. and Shiau, Angela A. and Arnold, John},
abstractNote = {Reaction of molecular O 2 with thorium alkyl complexes supported by amidinates and guanidinates generates thorium alkoxides via O 2 insertion into thorium-carbon bonds.},
doi = {10.1039/C9DT00811J},
journal = {Dalton Transactions},
number = 17,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
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