A high-throughput energy-dispersive tender X-ray spectrometer for shot-to-shot sulfur measurements
Abstract
An X-ray emission spectrometer that can detect the sulfur Kα emission lines with large throughput and a high energy resolution is presented. The instrument is based on a large d-spacing perfect Bragg analyzer that diffracts the sulfur Kα emission at close to backscattering angles. This facilitates the application of efficient concepts routinely employed in hard X-ray spectrometers towards the tender X-ray regime. The instrument described in this work is based on an energy-dispersive von Hamos geometry that is well suited for photon-in photon-out spectroscopy at X-ray free-electron laser and synchrotron sources. Comparison of its performance with previously used instrumentation is presented through measurements using sulfur-containing species performed at the LCLS. It is shown that the overall signal intensity is increased by a factor of ∼15. Implementation of this approach in the design of a tender X-ray spectroscopy endstation for LCLS-II is also discussed.
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1504514
- Alternate Identifier(s):
- OSTI ID: 1527378; OSTI ID: 1528876
- Grant/Contract Number:
- AC02-76SF00515; AC02-05CH11231
- Resource Type:
- Published Article
- Journal Name:
- Journal of Synchrotron Radiation (Online)
- Additional Journal Information:
- Journal Name: Journal of Synchrotron Radiation (Online) Journal Volume: 26 Journal Issue: 3; Journal ID: ISSN 1600-5775
- Publisher:
- International Union of Crystallography
- Country of Publication:
- Denmark
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION; 36 MATERIALS SCIENCE; X-ray emission spectroscopy; tender X-rays; X-ray absorption spectroscopy; X-ray free-electron lasers; photon-in photon-out spectroscopy methods
Citation Formats
Abraham, Baxter, Nowak, Stanislaw, Weninger, Clemens, Armenta, Rebecca, Defever, Jim, Day, David, Carini, Gabriella, Nakahara, Kazutaka, Gallo, Alessandro, Nelson, Silke, Nordlund, Dennis, Kroll, Thomas, Hunter, Mark S., van Driel, Tim, Zhu, Diling, Weng, Tsu-Chien, Alonso-Mori, Roberto, and Sokaras, Dimosthenis. A high-throughput energy-dispersive tender X-ray spectrometer for shot-to-shot sulfur measurements. Denmark: N. p., 2019.
Web. doi:10.1107/S1600577519002431.
Abraham, Baxter, Nowak, Stanislaw, Weninger, Clemens, Armenta, Rebecca, Defever, Jim, Day, David, Carini, Gabriella, Nakahara, Kazutaka, Gallo, Alessandro, Nelson, Silke, Nordlund, Dennis, Kroll, Thomas, Hunter, Mark S., van Driel, Tim, Zhu, Diling, Weng, Tsu-Chien, Alonso-Mori, Roberto, & Sokaras, Dimosthenis. A high-throughput energy-dispersive tender X-ray spectrometer for shot-to-shot sulfur measurements. Denmark. https://doi.org/10.1107/S1600577519002431
Abraham, Baxter, Nowak, Stanislaw, Weninger, Clemens, Armenta, Rebecca, Defever, Jim, Day, David, Carini, Gabriella, Nakahara, Kazutaka, Gallo, Alessandro, Nelson, Silke, Nordlund, Dennis, Kroll, Thomas, Hunter, Mark S., van Driel, Tim, Zhu, Diling, Weng, Tsu-Chien, Alonso-Mori, Roberto, and Sokaras, Dimosthenis. Tue .
"A high-throughput energy-dispersive tender X-ray spectrometer for shot-to-shot sulfur measurements". Denmark. https://doi.org/10.1107/S1600577519002431.
@article{osti_1504514,
title = {A high-throughput energy-dispersive tender X-ray spectrometer for shot-to-shot sulfur measurements},
author = {Abraham, Baxter and Nowak, Stanislaw and Weninger, Clemens and Armenta, Rebecca and Defever, Jim and Day, David and Carini, Gabriella and Nakahara, Kazutaka and Gallo, Alessandro and Nelson, Silke and Nordlund, Dennis and Kroll, Thomas and Hunter, Mark S. and van Driel, Tim and Zhu, Diling and Weng, Tsu-Chien and Alonso-Mori, Roberto and Sokaras, Dimosthenis},
abstractNote = {An X-ray emission spectrometer that can detect the sulfur Kα emission lines with large throughput and a high energy resolution is presented. The instrument is based on a large d-spacing perfect Bragg analyzer that diffracts the sulfur Kα emission at close to backscattering angles. This facilitates the application of efficient concepts routinely employed in hard X-ray spectrometers towards the tender X-ray regime. The instrument described in this work is based on an energy-dispersive von Hamos geometry that is well suited for photon-in photon-out spectroscopy at X-ray free-electron laser and synchrotron sources. Comparison of its performance with previously used instrumentation is presented through measurements using sulfur-containing species performed at the LCLS. It is shown that the overall signal intensity is increased by a factor of ∼15. Implementation of this approach in the design of a tender X-ray spectroscopy endstation for LCLS-II is also discussed.},
doi = {10.1107/S1600577519002431},
journal = {Journal of Synchrotron Radiation (Online)},
number = 3,
volume = 26,
place = {Denmark},
year = {Tue Apr 02 00:00:00 EDT 2019},
month = {Tue Apr 02 00:00:00 EDT 2019}
}
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https://doi.org/10.1107/S1600577519002431
https://doi.org/10.1107/S1600577519002431
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Cited by: 11 works
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Figures / Tables:
Figure 1: LiNbO3(01$\bar{4}$) von Hamos and Si(111) Johansson spectrometers acquired experimental data simultaneously. The dual instrument experimental scheme is depicted. X-ray emission induced by LCLS pulses incident on the flowing sample is collected by both crystal analyzers and recorded shotto- shot by position-sensitive detectors. The off-Rowland circle sample leads tomore »
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