A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs
Abstract
The introduction of a symmetry- and size-matching pore-partitioning agent in the form of either a molecular ligand, such as 2,4,6-tri(4-pyridinyl)-1,3,5-triazine (tpt), or a metal-complex cluster, into the hexagonal channels of MIL-88/MOF-235-type (the acs net) to create pacs-type (partitioned acs) crystalline porous materials is an effective strategy to develop high-performance gas adsorbents. We have developed here an integrated COF–MOF coassembly strategy as a new method for pore-space partitioning through the coassembly of [(M3(OH)1-x(O)x(COO)6] MOF-type and [B3O3(py)3] COF-type trimers. With this strategy, the coordination-driven assembly of the acs framework occurred concurrently and synergistically with the COF-1-type condensation of pyridine-4-boronic acid into a C3-symmetric trimeric boroxine molecule. Furthermore, the resulting boroxine-based pacs materials exhibited dramatically enhanced gas-sorption properties as compared to nonpartitioned acs-type materials and are among the most efficient NH3-sorption materials
- Authors:
-
[1]
- Univ. of California, Riverside, CA (United States)
- California State Univ. (CalState), Long Beach, CA (United States)
- Univ. of California, Riverside, CA (United States); Taiyuan Univ. of Technology (China)
- Taiyuan Univ. of Technology (China)
- Publication Date:
- Research Org.:
- Univ. of California, Riverside, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1596459
- Alternate Identifier(s):
- OSTI ID: 1504511
- Grant/Contract Number:
- SC0010596
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 19; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; boronic acids; covalent organic frameworks; materials science; metal–organic frameworks; pore-space partitioning
Citation Formats
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, and Feng, Pingyun. A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs. United States: N. p., 2019.
Web. doi:10.1002/anie.201901343.
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, & Feng, Pingyun. A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs. United States. https://doi.org/10.1002/anie.201901343
Wang, Yanxiang, Zhao, Xiang, Yang, Huajun, Bu, Xianhui, Wang, Yong, Jia, Xiaoxia, Li, Jinping, and Feng, Pingyun. Tue .
"A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs". United States. https://doi.org/10.1002/anie.201901343. https://www.osti.gov/servlets/purl/1596459.
@article{osti_1596459,
title = {A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs},
author = {Wang, Yanxiang and Zhao, Xiang and Yang, Huajun and Bu, Xianhui and Wang, Yong and Jia, Xiaoxia and Li, Jinping and Feng, Pingyun},
abstractNote = {The introduction of a symmetry- and size-matching pore-partitioning agent in the form of either a molecular ligand, such as 2,4,6-tri(4-pyridinyl)-1,3,5-triazine (tpt), or a metal-complex cluster, into the hexagonal channels of MIL-88/MOF-235-type (the acs net) to create pacs-type (partitioned acs) crystalline porous materials is an effective strategy to develop high-performance gas adsorbents. We have developed here an integrated COF–MOF coassembly strategy as a new method for pore-space partitioning through the coassembly of [(M3(OH)1-x(O)x(COO)6] MOF-type and [B3O3(py)3] COF-type trimers. With this strategy, the coordination-driven assembly of the acs framework occurred concurrently and synergistically with the COF-1-type condensation of pyridine-4-boronic acid into a C3-symmetric trimeric boroxine molecule. Furthermore, the resulting boroxine-based pacs materials exhibited dramatically enhanced gas-sorption properties as compared to nonpartitioned acs-type materials and are among the most efficient NH3-sorption materials},
doi = {10.1002/anie.201901343},
journal = {Angewandte Chemie (International Edition)},
number = 19,
volume = 58,
place = {United States},
year = {Tue Apr 02 00:00:00 EDT 2019},
month = {Tue Apr 02 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 58 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Gas Storage in Nanoporous Materials
journal, June 2008
- Morris, Russell E.; Wheatley, Paul S.
- Angewandte Chemie International Edition, Vol. 47, Issue 27
Gasspeicherung in nanoporösen Materialien
journal, June 2008
- Morris, Russell E.; Wheatley, Paul S.
- Angewandte Chemie, Vol. 120, Issue 27
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Tuning MOF CO 2 Adsorption Properties via Cation Exchange
journal, April 2010
- An, Jihyun; Rosi, Nathaniel L.
- Journal of the American Chemical Society, Vol. 132, Issue 16
Protecting group and switchable pore-discriminating adsorption properties of a hydrophilic–hydrophobic metal–organic framework
journal, March 2011
- Mohideen, M. Infas H.; Xiao, Bo; Wheatley, Paul S.
- Nature Chemistry, Vol. 3, Issue 4
Bimetallic Metal–Organic Frameworks for Gas Storage and Separation
journal, March 2017
- Yang, Xinchun; Xu, Qiang
- Crystal Growth & Design, Vol. 17, Issue 4
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
journal, May 2016
- Cui, X.; Chen, K.; Xing, H.
- Science, Vol. 353, Issue 6295
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites
journal, October 2018
- Li, Libo; Lin, Rui-Biao; Krishna, Rajamani
- Science, Vol. 362, Issue 6413
In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes
journal, June 2015
- Denny, Michael S.; Cohen, Seth M.
- Angewandte Chemie International Edition, Vol. 54, Issue 31
In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes
journal, June 2015
- Denny, Michael S.; Cohen, Seth M.
- Angewandte Chemie, Vol. 127, Issue 31
Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation
journal, July 2014
- Peng, Yongwu; Gong, Tengfei; Zhang, Kang
- Nature Communications, Vol. 5, Issue 1
Liquid-phase epitaxial growth of a homochiral MOF thin film on poly( l -DOPA) functionalized substrate for improved enantiomer separation
journal, January 2016
- Gu, Zhi-Gang; Fu, Wen-Qiang; Wu, Xin
- Chemical Communications, Vol. 52, Issue 4
Water-Soluble and Ultrastable Ti 4 L 6 Tetrahedron with Coordination Assembly Function
journal, November 2017
- He, Yan-Ping; Yuan, Lv-Bing; Chen, Guang-Hui
- Journal of the American Chemical Society, Vol. 139, Issue 46
Metal-Organic Frameworks for Separation
journal, March 2018
- Zhao, Xiang; Wang, Yanxiang; Li, Dong-Sheng
- Advanced Materials, Vol. 30, Issue 37
Metal-Organic Frameworks as Platforms for Catalytic Applications
journal, November 2017
- Jiao, Long; Wang, Yang; Jiang, Hai-Long
- Advanced Materials, Vol. 30, Issue 37
Metalation of a Thiocatechol-Functionalized Zr(IV)-Based Metal–Organic Framework for Selective C–H Functionalization
journal, February 2015
- Fei, Honghan; Cohen, Seth M.
- Journal of the American Chemical Society, Vol. 137, Issue 6
A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017
- Wang, Le; Agnew, Douglas W.; Yu, Xiao
- Angewandte Chemie International Edition, Vol. 57, Issue 2
A Metal-Organic Framework with Exceptional Activity for C−H Bond Amination
journal, December 2017
- Wang, Le; Agnew, Douglas W.; Yu, Xiao
- Angewandte Chemie, Vol. 130, Issue 2
Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System
journal, May 2018
- Wang, Xiao-Li; Dong, Long-Zhang; Qiao, Man
- Angewandte Chemie International Edition, Vol. 57, Issue 31
Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System
journal, May 2018
- Wang, Xiao-Li; Dong, Long-Zhang; Qiao, Man
- Angewandte Chemie, Vol. 130, Issue 31
Creating Well-Defined Hexabenzocoronene in Zirconium Metal–Organic Framework by Postsynthetic Annulation
journal, January 2019
- Qin, Jun-Sheng; Yuan, Shuai; Zhang, Lei
- Journal of the American Chemical Society, Vol. 141, Issue 5
Photocatalytic Metal–Organic Frameworks for Selective 2,2,2-Trifluoroethylation of Styrenes
journal, September 2016
- Yu, Xiao; Cohen, Seth M.
- Journal of the American Chemical Society, Vol. 138, Issue 38
Rational Design of MOF/COF Hybrid Materials for Photocatalytic H 2 Evolution in the Presence of Sacrificial Electron Donors
journal, August 2018
- Zhang, Feng-Ming; Sheng, Jing-Li; Yang, Zhao-Di
- Angewandte Chemie International Edition, Vol. 57, Issue 37
Rational Design of MOF/COF Hybrid Materials for Photocatalytic H 2 Evolution in the Presence of Sacrificial Electron Donors
journal, August 2018
- Zhang, Feng-Ming; Sheng, Jing-Li; Yang, Zhao-Di
- Angewandte Chemie, Vol. 130, Issue 37
Acid and Base Resistant Zirconium Polyphenolate-Metalloporphyrin Scaffolds for Efficient CO 2 Photoreduction
journal, November 2017
- Chen, Er-Xia; Qiu, Mei; Zhang, Yong-Fan
- Advanced Materials, Vol. 30, Issue 2
Hierarchical Porous and High Surface Area Tubular Carbon as Dye Adsorbent and Capacitor Electrode
journal, May 2015
- Chen, Long; Ji, Tuo; Brisbin, Logan
- ACS Applied Materials & Interfaces, Vol. 7, Issue 22
Pore Space Partition in Metal–Organic Frameworks
journal, January 2017
- Zhai, Quan-Guo; Bu, Xianhui; Zhao, Xiang
- Accounts of Chemical Research, Vol. 50, Issue 2
An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials
journal, December 2016
- Zhai, Quan-Guo; Bu, Xianhui; Mao, Chengyu
- Nature Communications, Vol. 7, Issue 1
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units
journal, September 2004
- Serre, Christian; Millange, Franck; Surblé, Suzy
- Angewandte Chemie International Edition, Vol. 43, Issue 46
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units
journal, September 2004
- Serre, Christian; Millange, Franck; Surblé, Suzy
- Angewandte Chemie, Vol. 116, Issue 46
Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology
journal, May 2005
- Sudik, Andrea C.; Côté, Adrien P.; Yaghi, Omar M.
- Inorganic Chemistry, Vol. 44, Issue 9, p. 2998-3000
Entrapment of Metal Clusters in Metal–Organic Framework Channels by Extended Hooks Anchored at Open Metal Sites
journal, May 2013
- Zheng, Shou-Tian; Zhao, Xiang; Lau, Samuel
- Journal of the American Chemical Society, Vol. 135, Issue 28
Multivariable Modular Design of Pore Space Partition
journal, November 2016
- Zhao, Xiang; Bu, Xianhui; Nguyen, Edward T.
- Journal of the American Chemical Society, Vol. 138, Issue 46
Pore Space Partition by Symmetry-Matching Regulated Ligand Insertion and Dramatic Tuning on Carbon Dioxide Uptake
journal, January 2015
- Zhao, Xiang; Bu, Xianhui; Zhai, Quan-Guo
- Journal of the American Chemical Society, Vol. 137, Issue 4
Coordination templated [2+2+2] cyclotrimerization in a porous coordination framework
journal, September 2015
- Wei, Yong-Sheng; Zhang, Mei; Liao, Pei-Qin
- Nature Communications, Vol. 6, Issue 1
Chemistry of Covalent Organic Frameworks
journal, November 2015
- Waller, Peter J.; Gándara, Felipe; Yaghi, Omar M.
- Accounts of Chemical Research, Vol. 48, Issue 12
Recent progress in covalent organic framework thin films: fabrications, applications and perspectives
journal, January 2019
- Wang, Han; Zeng, Zhuotong; Xu, Piao
- Chemical Society Reviews, Vol. 48, Issue 2
Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005
- Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
- Science, Vol. 310, Issue 5751, p. 1166-1170
Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007
- Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
- Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007
- El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
- Science, Vol. 316, Issue 5822, p. 268-272
Targeted Synthesis of Porous Aromatic Frameworks and their Composites for Versatile, Facile, Efficacious, and Durable Antibacterial Polymer Coatings
journal, September 2013
- Yuan, Ye; Sun, Fuxing; Zhang, Feng
- Advanced Materials, Vol. 25, Issue 45
Boronic acid building blocks: tools for self assembly
journal, January 2011
- Nishiyabu, Ryuhei; Kubo, Yuji; James, Tony D.
- Chem. Commun., Vol. 47, Issue 4
Boroxine chemistry and applications: A perspective
journal, January 2010
- Korich, Andrew L.; Iovine, Peter M.
- Dalton Trans., Vol. 39, Issue 6
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009
- Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
- Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571
3D Microporous Base-Functionalized Covalent Organic Frameworks for Size-Selective Catalysis
journal, February 2014
- Fang, Qianrong; Gu, Shuang; Zheng, Jie
- Angewandte Chemie International Edition, Vol. 53, Issue 11
3D Microporous Base-Functionalized Covalent Organic Frameworks for Size-Selective Catalysis
journal, February 2014
- Fang, Qianrong; Gu, Shuang; Zheng, Jie
- Angewandte Chemie, Vol. 126, Issue 11
Construction of Crystalline 2D Covalent Organic Frameworks with Remarkable Chemical (Acid/Base) Stability via a Combined Reversible and Irreversible Route
journal, November 2012
- Kandambeth, Sharath; Mallick, Arijit; Lukose, Binit
- Journal of the American Chemical Society, Vol. 134, Issue 48
A hydrazone-based covalent organic framework for photocatalytic hydrogen production
journal, January 2014
- Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V.
- Chem. Sci., Vol. 5, Issue 7
Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis
journal, April 2008
- Kuhn, Pierre; Antonietti, Markus; Thomas, Arne
- Angewandte Chemie International Edition, Vol. 47, Issue 18
Ionothermalsynthese von porösen kovalenten Triazin- Polymernetzwerken
journal, April 2008
- Kuhn, Pierre; Antonietti, Markus; Thomas, Arne
- Angewandte Chemie, Vol. 120, Issue 18
An Azine-Linked Covalent Organic Framework
journal, November 2013
- Dalapati, Sasanka; Jin, Shangbin; Gao, Jia
- Journal of the American Chemical Society, Vol. 135, Issue 46
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
journal, November 2009
- Ben, Teng; Ren, Hao; Ma, Shengqian
- Angewandte Chemie International Edition, Vol. 48, Issue 50, p. 9457-9460
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
journal, November 2009
- Ben, Teng; Ren, Hao; Ma, Shengqian
- Angewandte Chemie, Vol. 121, Issue 50
Designed synthesis of large-pore crystalline polyimide covalent organic frameworks
journal, July 2014
- Fang, Qianrong; Zhuang, Zhongbin; Gu, Shuang
- Nature Communications, Vol. 5, Issue 1
Targeted synthesis of a porous borazine-linked covalent organic framework
journal, January 2012
- Jackson, Karl T.; Reich, Thomas E.; El-Kaderi, Hani M.
- Chemical Communications, Vol. 48, Issue 70
Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation
journal, February 2015
- Dutta, Ananya; Koh, Kyoungmoo; Wong-Foy, Antek G.
- Angewandte Chemie International Edition, Vol. 54, Issue 13
Porous Solids Arising from Synergistic and Competing Modes of Assembly: Combining Coordination Chemistry and Covalent Bond Formation
journal, February 2015
- Dutta, Ananya; Koh, Kyoungmoo; Wong-Foy, Antek G.
- Angewandte Chemie, Vol. 127, Issue 13
A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction
journal, January 2018
- Gai, Yanli; Chen, Xitong; Yang, Huajun
- Chemical Communications, Vol. 54, Issue 85
Porphyrinic coordination lattices with fluoropillars
journal, January 2017
- Lin, Qipu; Mao, Chengyu; Kong, Aiguo
- J. Mater. Chem. A, Vol. 5, Issue 40
Very Large Swelling in Hybrid Frameworks: A Combined Computational and Powder Diffraction Study
journal, November 2005
- Mellot-Draznieks, Caroline; Serre, Christian; Surblé, Suzy
- Journal of the American Chemical Society, Vol. 127, Issue 46
Site Partition: Turning One Site into Two for Adsorbing CO 2
journal, June 2016
- Tian, Ziqi; Dai, Sheng; Jiang, De-en
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework
journal, October 2018
- Godfrey, Harry G. W.; da Silva, Ivan; Briggs, Lydia
- Angewandte Chemie International Edition, Vol. 57, Issue 45
Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework
journal, October 2018
- Godfrey, Harry G. W.; da Silva, Ivan; Briggs, Lydia
- Angewandte Chemie, Vol. 130, Issue 45
Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption
journal, February 2018
- Rieth, Adam J.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 140, Issue 9
A Hydrazone-based Covalent Organic Framework for Photocatalytic Hydrogen Production
preprint, January 2014
- Stegbauer, Linus; Schwinghammer, Katharina; Lotsch, Bettina V.
- arXiv
Works referencing / citing this record:
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie International Edition, Vol. 59, Issue 15
Adjustment of the performance and stability of isostructural zeolitic tetrazolate-imidazolate frameworks
journal, January 2020
- Li, Hai-Zhen; Du, Dong-Ying; Sun, Yayong
- Dalton Transactions, Vol. 49, Issue 15
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie, Vol. 132, Issue 15