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Title: Synergy between phase transformation and domain switching in two morphotropic phase boundary ferroelectrics

Abstract

We present that many applications of ferroic materials take advantage of the microstructural redistribution under an external stimulus. Despite extensive studies on the microstructural evolution during both domain switching and phase transformations of high-performance ferroelectrics near morphotropic phase boundaries (MPBs), the synergetic interactions between both leading factors remain unclear. Herein, we have illustrated and discerned the correlative response of phase transformation and domain switching in an archetypical piezoceramic of PbTiO3-BiScO3 using a combination of in situ high-energy synchrotron x-ray diffraction and phase-field simulations. The direct structural evidence and domain development from simulations reveal a significant reversible orientation-dependent emerging phase transformation and enhanced domain switching. Increasingly populated polarization variants aligned with the applied electric field owing to this strong synergistic interaction play an important role in enhancing the piezoelectric performances of MPB ferroelectrics. Lastly, in addition to providing further insight into the microstructures of ferroelectrics, the present results have the potential to guide the design of high-performance materials.

Authors:
 [1];  [2];  [1];  [3];  [3];  [4];  [1];  [1]
  1. University of Science and Technology Beijing (China)
  2. Beijing Institute of Technology (China)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Pennsylvania State Univ., University Park, PA (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1504451
Alternate Identifier(s):
OSTI ID: 1482275
Grant/Contract Number:  
AC02-06CH11357; FG02-07ER46417
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 2; Journal Issue: 11; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE

Citation Formats

Liu, Hui, Huang, Houbing, Fan, Longlong, Ren, Yang, Zhou, Hua, Chen, Long-Qing, Chen, Jun, and Xing, Xianran. Synergy between phase transformation and domain switching in two morphotropic phase boundary ferroelectrics. United States: N. p., 2018. Web. doi:10.1103/PhysRevMaterials.2.111403.
Liu, Hui, Huang, Houbing, Fan, Longlong, Ren, Yang, Zhou, Hua, Chen, Long-Qing, Chen, Jun, & Xing, Xianran. Synergy between phase transformation and domain switching in two morphotropic phase boundary ferroelectrics. United States. doi:10.1103/PhysRevMaterials.2.111403.
Liu, Hui, Huang, Houbing, Fan, Longlong, Ren, Yang, Zhou, Hua, Chen, Long-Qing, Chen, Jun, and Xing, Xianran. Thu . "Synergy between phase transformation and domain switching in two morphotropic phase boundary ferroelectrics". United States. doi:10.1103/PhysRevMaterials.2.111403. https://www.osti.gov/servlets/purl/1504451.
@article{osti_1504451,
title = {Synergy between phase transformation and domain switching in two morphotropic phase boundary ferroelectrics},
author = {Liu, Hui and Huang, Houbing and Fan, Longlong and Ren, Yang and Zhou, Hua and Chen, Long-Qing and Chen, Jun and Xing, Xianran},
abstractNote = {We present that many applications of ferroic materials take advantage of the microstructural redistribution under an external stimulus. Despite extensive studies on the microstructural evolution during both domain switching and phase transformations of high-performance ferroelectrics near morphotropic phase boundaries (MPBs), the synergetic interactions between both leading factors remain unclear. Herein, we have illustrated and discerned the correlative response of phase transformation and domain switching in an archetypical piezoceramic of PbTiO3-BiScO3 using a combination of in situ high-energy synchrotron x-ray diffraction and phase-field simulations. The direct structural evidence and domain development from simulations reveal a significant reversible orientation-dependent emerging phase transformation and enhanced domain switching. Increasingly populated polarization variants aligned with the applied electric field owing to this strong synergistic interaction play an important role in enhancing the piezoelectric performances of MPB ferroelectrics. Lastly, in addition to providing further insight into the microstructures of ferroelectrics, the present results have the potential to guide the design of high-performance materials.},
doi = {10.1103/PhysRevMaterials.2.111403},
journal = {Physical Review Materials},
number = 11,
volume = 2,
place = {United States},
year = {2018},
month = {11}
}

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Works referenced in this record:

Bridging domain mechanism for phase coexistence in morphotropic phase boundary ferroelectrics
journal, April 2007

  • Rao, Wei-Feng; Wang, Yu U.
  • Applied Physics Letters, Vol. 90, Issue 18
  • DOI: 10.1063/1.2736276

A high energy synchrotron x-ray study of crystallographic texture and lattice strain in soft lead zirconate titanate ceramics
journal, October 2004

  • Hall, D. A.; Steuwer, A.; Cherdhirunkorn, B.
  • Journal of Applied Physics, Vol. 96, Issue 8
  • DOI: 10.1063/1.1787590

Structural contribution to the ferroelectric fatigue in lead zirconate titanate ceramics
journal, September 2014


Domain Wall Displacement is the Origin of Superior Permittivity and Piezoelectricity in BaTiO 3 at Intermediate Grain Sizes
journal, September 2013

  • Ghosh, Dipankar; Sakata, Akito; Carter, Jared
  • Advanced Functional Materials, Vol. 24, Issue 7
  • DOI: 10.1002/adfm.201301913

Domain texture distributions in tetragonal lead zirconate titanate by x-ray and neutron diffraction
journal, February 2005

  • Jones, Jacob L.; Slamovich, Elliott B.; Bowman, Keith J.
  • Journal of Applied Physics, Vol. 97, Issue 3
  • DOI: 10.1063/1.1849821

A Strain-Driven Morphotropic Phase Boundary in BiFeO3
journal, November 2009

  • Zeches, R. J.; Rossell, M. D.; Zhang, J. X.
  • Science, Vol. 326, Issue 5955, p. 977-980
  • DOI: 10.1126/science.1177046

Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics
journal, September 1998


Enhanced Piezoelectric Response due to Polarization Rotation in Cobalt-Substituted BiFeO 3 Epitaxial Thin Films
journal, August 2016

  • Shimizu, Keisuke; Hojo, Hajime; Ikuhara, Yuichi
  • Advanced Materials, Vol. 28, Issue 39
  • DOI: 10.1002/adma.201602450

Interplay of strain mechanisms in morphotropic piezoceramics
journal, August 2015


Domain Formation and Domain Wall Motions in Ferroelectric BaTi O 3 Single Crystals
journal, August 1954


Phase-Field Models for Microstructure Evolution
journal, August 2002


Anomalous reduction in domain wall displacement at the morphotropic phase boundary of the piezoelectric alloy system PbTi O 3 BiSc O 3
journal, March 2016


Structural Description of the Macroscopic Piezo- and Ferroelectric Properties of Lead Zirconate Titanate
journal, August 2011


Transferring lead-free piezoelectric ceramics into application
journal, June 2015


Electric-field-induced phase-change behavior in (Bi0.5Na0.5)TiO3–BaTiO3–(K0.5Na0.5)NbO3: A combinatorial investigation
journal, April 2010


Ultrahigh piezoelectricity in ferroelectric ceramics by design
journal, March 2018


Structural Evidence for Strong Coupling between Polarization Rotation and Lattice Strain in Monoclinic Relaxor Ferroelectrics
journal, July 2017


Thin-film ferroelectric materials and their applications
journal, November 2016


Ferroelectric Memories
journal, December 1989


Deaging and Asymmetric Energy Landscapes in Electrically Biased Ferroelectrics
journal, April 2012


Ferroic glasses
journal, October 2017


Collective dynamics underpins Rayleigh behavior in disordered polycrystalline ferroelectrics
journal, April 2010

  • Bintachitt, P.; Jesse, S.; Damjanovic, D.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 16
  • DOI: 10.1073/pnas.0913172107

Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals
journal, August 1997

  • Park, Seung-Eek; Shrout, Thomas R.
  • Journal of Applied Physics, Vol. 82, Issue 4
  • DOI: 10.1063/1.365983

Ferroelectric polarization reversal via successive ferroelastic transitions
journal, October 2014

  • Xu, Ruijuan; Liu, Shi; Grinberg, Ilya
  • Nature Materials, Vol. 14, Issue 1
  • DOI: 10.1038/nmat4119

Domain switching in polycrystalline ferroelectric ceramics
journal, September 2005

  • Li, J. Y.; Rogan, R. C.; Üstündag, E.
  • Nature Materials, Vol. 4, Issue 10
  • DOI: 10.1038/nmat1485

Enhanced extrinsic domain switching strain in core–shell structured BaTiO 3 –KNbO 3 ceramics
journal, October 2015


Phase Diagram of the Perovskite System (1−x)BiScO3-xPbTiO3
journal, September 2004

  • Eitel, R. E.; Zhang, S. J.; Shrout, T. R.
  • Journal of Applied Physics, Vol. 96, Issue 5
  • DOI: 10.1063/1.1777810

Phase-Field Method of Phase Transitions/Domain Structures in Ferroelectric Thin Films: A Review
journal, June 2008


Evolving morphotropic phase boundary in lead-free (Bi1/2Na1/2)TiO3–BaTiO3 piezoceramics
journal, January 2011

  • Jo, Wook; Daniels, John E.; Jones, Jacob L.
  • Journal of Applied Physics, Vol. 109, Issue 1
  • DOI: 10.1063/1.3530737

Piezoelectricity and rotostriction through polar and non-polar coupled instabilities in bismuth-based piezoceramics
journal, July 2016

  • Acosta, Matias; Schmitt, Ljubomira A.; Cazorla, Claudio
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep28742

Role of Reversible Phase Transformation for Strong Piezoelectric Performance at the Morphotropic Phase Boundary
journal, January 2018


Critical Role of Monoclinic Polarization Rotation in High-Performance Perovskite Piezoelectric Materials
journal, July 2017