Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol
Abstract
The synergistic interaction among different components in complex catalysts is one of the crucial factors in determining catalytic performance. Here we report the interactions among the three components in controlling the catalytic performance of Cu–ZnO–ZrO2 (CZZ) catalyst for CO2 hydrogenation to methanol. The in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) measurements under the activity test pressure (3 MPa) reveal that the CO2 hydrogenation to methanol on the CZZ catalysts follows the formate pathway. Density functional theory (DFT) calculations agree with the in situ DRIFTS measurements, showing that the ZnO–ZrO2 interfaces are the active sites for CO2 adsorption and conversion, while the presence of metallic Cu is also necessary to facilitate H2 dissociation and to provide hydrogen resource. The combined experiment and DFT results reveal that tuning the interaction between ZnO and ZrO2 can be considered as another important factor for designing high performance catalysts for methanol generation from CO2.
- Authors:
-
- Kunming Univ. of Science and Technology (China). State Key Lab. of Complex Nonferrous Metal Resources Clean Utilization Engineering. Faculty of Metallurgical and Energy Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Kunming Univ. of Science and Technology (China). State Key Lab. of Complex Nonferrous Metal Resources Clean Utilization Engineering; Columbia Univ., New York, NY (United States). Dept. of Earth and Environmental Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division; Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering
- Kunming Univ. of Science and Technology (China). State Key Lab. of Complex Nonferrous Metal Resources Clean Utilization Engineering; Dali Univ. (China). School of Pharmacy and Chemistry
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Kunming Univ. of Science and Technology (China)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC); National Key Technologies R & D Program of China; Candidate Talents Training Fund of Yunnan Province (China)
- OSTI Identifier:
- 1504379
- Report Number(s):
- BNL-211494-2019-JAAM
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- SC0012704; AC02-05CH11231; 51774159; 51304099; 51404122; 2011BAC01B03; 2014HB006
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalytic mechanisms; chemical engineering; heterogeneous catalysis
Citation Formats
Wang, Yuhao, Kattel, Shyam, Gao, Wengui, Li, Kongzhai, Liu, Ping, Chen, Jingguang G., and Wang, Hua. Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-09072-6.
Wang, Yuhao, Kattel, Shyam, Gao, Wengui, Li, Kongzhai, Liu, Ping, Chen, Jingguang G., & Wang, Hua. Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol. United States. https://doi.org/10.1038/s41467-019-09072-6
Wang, Yuhao, Kattel, Shyam, Gao, Wengui, Li, Kongzhai, Liu, Ping, Chen, Jingguang G., and Wang, Hua. Mon .
"Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol". United States. https://doi.org/10.1038/s41467-019-09072-6. https://www.osti.gov/servlets/purl/1504379.
@article{osti_1504379,
title = {Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol},
author = {Wang, Yuhao and Kattel, Shyam and Gao, Wengui and Li, Kongzhai and Liu, Ping and Chen, Jingguang G. and Wang, Hua},
abstractNote = {The synergistic interaction among different components in complex catalysts is one of the crucial factors in determining catalytic performance. Here we report the interactions among the three components in controlling the catalytic performance of Cu–ZnO–ZrO2 (CZZ) catalyst for CO2 hydrogenation to methanol. The in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) measurements under the activity test pressure (3 MPa) reveal that the CO2 hydrogenation to methanol on the CZZ catalysts follows the formate pathway. Density functional theory (DFT) calculations agree with the in situ DRIFTS measurements, showing that the ZnO–ZrO2 interfaces are the active sites for CO2 adsorption and conversion, while the presence of metallic Cu is also necessary to facilitate H2 dissociation and to provide hydrogen resource. The combined experiment and DFT results reveal that tuning the interaction between ZnO and ZrO2 can be considered as another important factor for designing high performance catalysts for methanol generation from CO2.},
doi = {10.1038/s41467-019-09072-6},
journal = {Nature Communications},
number = ,
volume = 10,
place = {United States},
year = {2019},
month = {3}
}
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Works referenced in this record:
Solid-state interactions, adsorption sites and functionality of Cu-ZnO/ZrO2 catalysts in the CO2 hydrogenation to CH3OH
journal, November 2008
- Arena, Francesco; Italiano, Giuseppe; Barbera, Katia
- Applied Catalysis A: General, Vol. 350, Issue 1
Mechanistic study of a new low-temperature methanol synthesis on Cu/MgO catalysts
journal, July 2005
- Yang, Ruiqin; Zhang, Yi; Iwama, Yuki
- Applied Catalysis A: General, Vol. 288, Issue 1-2
In situ IR studies on the mechanism of methanol synthesis over an ultrafine Cu/ZnO/Al2O3 catalyst
journal, July 1998
- Sun, Qi; Liu, Chong-Wei; Pan, Wei
- Applied Catalysis A: General, Vol. 171, Issue 2
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO 2 Hydrogenation Processes
journal, May 2017
- Álvarez, Andrea; Bansode, Atul; Urakawa, Atsushi
- Chemical Reviews, Vol. 117, Issue 14
From CO2 to Methanol by Hybrid QM/MM Embedding This work was supported by EU Esprit IV project 25047. S.A.F. is grateful to ICI and Synetix for funding. K. Waugh, L. Whitmore, S. Cristol, and P. Sushko are thanked for their helpful insights. QM/MM=quantum mechanics/molecular mechanics.
journal, December 2001
- French, Samuel A.; Sokol, Alexey A.; Bromley, Stefan T.
- Angewandte Chemie International Edition, Vol. 40, Issue 23
Highly selective hydrogenation of CO2 to methanol over CuO–ZnO–ZrO2 catalysts prepared by a surfactant-assisted co-precipitation method
journal, April 2015
- Li, Li; Mao, Dongsen; Yu, Jun
- Journal of Power Sources, Vol. 279
Mixing Copper Nanoparticles and ZnO Nanocrystals: A Route towards Understanding the Hydrogenation of CO2 to Methanol?
journal, March 2011
- Meunier, Frederic C.
- Angewandte Chemie International Edition, Vol. 50, Issue 18
Influence of Zr on the performance of Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol
journal, February 2013
- Gao, Peng; Li, Feng; Zhan, Haijuan
- Journal of Catalysis, Vol. 298
Au/3DOM Co3O4: highly active nanocatalysts for the oxidation of carbon monoxide and toluene
journal, January 2013
- Xie, Shaohua; Dai, Hongxing; Deng, Jiguang
- Nanoscale, Vol. 5, Issue 22
Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface
journal, July 2017
- Kattel, Shyam; Liu, Ping; Chen, Jingguang G.
- Journal of the American Chemical Society, Vol. 139, Issue 29
Adsorption of CO 2 at ZnO: A Surface Structure Effect from DFT+ U Calculations
journal, October 2013
- Tang, Qian-Lin; Luo, Qing-Hong
- The Journal of Physical Chemistry C, Vol. 117, Issue 44
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998
- Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
- Physical Review B, Vol. 57, Issue 3, p. 1505-1509
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
journal, May 2016
- Kuld, S.; Thorhauge, M.; Falsig, H.
- Science, Vol. 352, Issue 6288
Optimizing Binding Energies of Key Intermediates for CO 2 Hydrogenation to Methanol over Oxide-Supported Copper
journal, September 2016
- Kattel, Shyam; Yan, Binhang; Yang, Yixiong
- Journal of the American Chemical Society, Vol. 138, Issue 38
In-SituInfrared Study of Methanol Synthesis from H2/CO2over Cu/SiO2and Cu/ZrO2/SiO2
journal, November 1997
- Fisher, Ian A.; Bell, Alexis T.
- Journal of Catalysis, Vol. 172, Issue 1
Active Sites on Oxide Surfaces: ZnO-Catalyzed Synthesis of Methanol from CO and H 2
journal, April 2005
- Kurtz, Melanie; Strunk, Jennifer; Hinrichsen, Olaf
- Angewandte Chemie International Edition, Vol. 44, Issue 18
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
journal, March 2017
- Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G.
- Science, Vol. 355, Issue 6331
Reverse water-gas shift reaction at the Cu/ZnO interface: Influence of the Cu/Zn ratio on structure-activity correlations
journal, October 2016
- Álvarez Galván, Consuelo; Schumann, Julia; Behrens, Malte
- Applied Catalysis B: Environmental, Vol. 195
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method
journal, August 2016
- Dong, Xiaosu; Li, Feng; Zhao, Ning
- Applied Catalysis B: Environmental, Vol. 191
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000
- Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol
journal, July 2007
- Arena, F.; Barbera, K.; Italiano, G.
- Journal of Catalysis, Vol. 249, Issue 2
Structure–activity relationships of Cu–ZrO 2 catalysts for CO 2 hydrogenation to methanol: interaction effects and reaction mechanism
journal, January 2017
- Wang, Yu Hao; Gao, Wen Gui; Wang, Hua
- RSC Advances, Vol. 7, Issue 14
Theoretical Study of Methanol Synthesis from CO 2 Hydrogenation on Metal-Doped Cu(111) Surfaces
journal, December 2011
- Yang, Yixiong; White, Michael G.; Liu, Ping
- The Journal of Physical Chemistry C, Vol. 116, Issue 1
Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials’ Interface in Selective Hydrogenation of CO2 to CH3OH
journal, January 2011
- Liao, Fenglin; Huang, Yaqun; Ge, Junwei
- Angewandte Chemie, Vol. 123, Issue 9
Effects of oxide carriers on surface functionality and process performance of the Cu–ZnO system in the synthesis of methanol via CO2 hydrogenation
journal, April 2013
- Arena, Francesco; Mezzatesta, Giovanni; Zafarana, Giovanni
- Journal of Catalysis, Vol. 300
In Situ Investigations of Structural Changes in Cu/ZnO Catalysts
journal, September 2000
- Grunwaldt, J. -D; Molenbroek, A. M.; Topsøe, N. -Y
- Journal of Catalysis, Vol. 194, Issue 2
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie International Edition, Vol. 54, Issue 15
Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011
- Wang, Wei; Wang, Shengping; Ma, Xinbin
- Chemical Society Reviews, Vol. 40, Issue 7
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Effect of the ZrO2 phase on the structure and behavior of supported Cu catalysts for ethanol conversion
journal, November 2013
- Sato, A. G.; Volanti, D. P.; Meira, D. M.
- Journal of Catalysis, Vol. 307
Glycine–nitrate combustion synthesis of CuO–ZnO–ZrO2 catalysts for methanol synthesis from CO2 hydrogenation
journal, May 2010
- Guo, Xiaoming; Mao, Dongsen; Lu, Guanzhong
- Journal of Catalysis, Vol. 271, Issue 2
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
journal, December 2016
- Bu, Lingzheng; Zhang, Nan; Guo, Shaojun
- Science, Vol. 354, Issue 6318
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014
- Graciani, J.; Mudiyanselage, K.; Xu, F.
- Science, Vol. 345, Issue 6196
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Transient behavior of Cu/ZnO-based methanol synthesis catalysts
journal, February 2009
- Vesborg, Peter C. K.; Chorkendorff, Ib; Knudsen, Ida
- Journal of Catalysis, Vol. 262, Issue 1
Inhomogeneous Electron Gas
journal, November 1964
- Hohenberg, P.; Kohn, W.
- Physical Review, Vol. 136, Issue 3B, p. B864-B871
CO 2 hydrogenation to methanol over CuO–ZnO–ZrO 2 –SiO 2 catalysts: Effects of SiO 2 contents
journal, May 2017
- Phongamwong, Thanaree; Chantaprasertporn, Usanee; Witoon, Thongthai
- Chemical Engineering Journal, Vol. 316
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012
- Behrens, M.; Studt, F.; Kasatkin, I.
- Science, Vol. 336, Issue 6083, p. 893-897
Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992
- Perdew, John P.; Wang, Yue
- Physical Review B, Vol. 45, Issue 23, p. 13244-13249
The Influence of the Precipitation/Ageing Temperature on a Cu/ZnO/ZrO 2 Catalyst for Methanol Synthesis from H 2 and CO 2
journal, April 2014
- Frei, Elias; Schaadt, Achim; Ludwig, Thilo
- ChemCatChem, Vol. 6, Issue 6
Tuning of catalytic CO2 hydrogenation by changing composition of CuO–ZnO–ZrO2 catalysts
journal, June 2016
- Witoon, Thongthai; Kachaban, Nantana; Donphai, Waleeporn
- Energy Conversion and Management, Vol. 118
Reversible Hydrogenation of Carbon Dioxide to Formic Acid and Methanol: Lewis Acid Enhancement of Base Metal Catalysts
journal, February 2017
- Bernskoetter, Wesley H.; Hazari, Nilay
- Accounts of Chemical Research, Vol. 50, Issue 4
Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
journal, October 2016
- van den Berg, Roy; Prieto, Gonzalo; Korpershoek, Gerda
- Nature Communications, Vol. 7, Issue 1
The effects of zirconia morphology on methanol synthesis from CO and H2H2 over Cu/ZrO2Cu/ZrO2 catalystsPart I. Steady-state studies
journal, July 2005
- Rhodes, M.; Bell, A.
- Journal of Catalysis, Vol. 233, Issue 1
The effects of zirconia morphology on methanol synthesis from CO and H2 over Cu/ZrO2 catalystsPart II. Transient-response infrared studies
journal, July 2005
- Rhodes, M.; Pokrovski, K.; Bell, A.
- Journal of Catalysis, Vol. 233, Issue 1
Role of the Cu-ZrO 2 Interfacial Sites for Conversion of Ethanol to Ethyl Acetate and Synthesis of Methanol from CO 2 and H 2
journal, September 2016
- Ro, Insoo; Liu, Yifei; Ball, Madelyn R.
- ACS Catalysis, Vol. 6, Issue 10
Electronic Modulation of a Copper/Zinc Oxide Catalyst by a Heterojunction for Selective Hydrogenation of Carbon Dioxide to Methanol
journal, March 2012
- Liao, Fenglin; Zeng, Ziyan; Eley, Clive
- Angewandte Chemie International Edition, Vol. 51, Issue 24
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol
journal, June 2014
- Bonura, G.; Cordaro, M.; Cannilla, C.
- Applied Catalysis B: Environmental, Vol. 152-153
In Situ FTIR Spectroscopic Analysis of Carbonate Transformations during Adsorption and Desorption of CO 2 in K-Promoted HTlc
journal, June 2010
- Du, Hai; Williams, Christopher T.; Ebner, Armin D.
- Chemistry of Materials, Vol. 22, Issue 11
The Cu–ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures
journal, April 2015
- Le Valant, Anthony; Comminges, Clément; Tisseraud, Céline
- Journal of Catalysis, Vol. 324
A highly selective and stable ZnO-ZrO 2 solid solution catalyst for CO 2 hydrogenation to methanol
journal, October 2017
- Wang, Jijie; Li, Guanna; Li, Zelong
- Science Advances, Vol. 3, Issue 10
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie, Vol. 127, Issue 15
Inhomogeneous Electron Gas
journal, March 1973
- Rajagopal, A. K.; Callaway, J.
- Physical Review B, Vol. 7, Issue 5
Electronic Modulation of a Copper/Zinc Oxide Catalyst by a Heterojunction for Selective Hydrogenation of Carbon Dioxide to Methanol
journal, March 2012
- Liao, Fenglin; Zeng, Ziyan; Eley, Clive
- Angewandte Chemie, Vol. 124, Issue 24
Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials’ Interface in Selective Hydrogenation of CO2 to CH3OH
journal, January 2011
- Liao, Fenglin; Huang, Yaqun; Ge, Junwei
- Angewandte Chemie International Edition, Vol. 50, Issue 9
Voltage- and time-dependent valence state transition in cobalt oxide catalysts during the oxygen evolution reaction
journal, April 2020
- Zhou, Jing; Zhang, Linjuan; Huang, Yu-Cheng
- Nature Communications, Vol. 11, Issue 1
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials’ Interface in Selective Hydrogenation of CO2 to CH3OH
journal, January 2011
- Liao, Fenglin; Huang, Yaqun; Ge, Junwei
- Angewandte Chemie, Vol. 123, Issue 9
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015
- Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
- Angewandte Chemie, Vol. 127, Issue 15
Mixing Copper Nanoparticles and ZnO Nanocrystals: A Route towards Understanding the Hydrogenation of CO2 to Methanol?
journal, March 2011
- Meunier, Frederic C.
- Angewandte Chemie International Edition, Vol. 50, Issue 18
Electronic Modulation of a Copper/Zinc Oxide Catalyst by a Heterojunction for Selective Hydrogenation of Carbon Dioxide to Methanol
journal, March 2012
- Liao, Fenglin; Zeng, Ziyan; Eley, Clive
- Angewandte Chemie International Edition, Vol. 51, Issue 24
The Influence of the Precipitation/Ageing Temperature on a Cu/ZnO/ZrO 2 Catalyst for Methanol Synthesis from H 2 and CO 2
journal, April 2014
- Frei, Elias; Schaadt, Achim; Ludwig, Thilo
- ChemCatChem, Vol. 6, Issue 6
Mechanistic study of a new low-temperature methanol synthesis on Cu/MgO catalysts
journal, July 2005
- Yang, Ruiqin; Zhang, Yi; Iwama, Yuki
- Applied Catalysis A: General, Vol. 288, Issue 1-2
Solid-state interactions, adsorption sites and functionality of Cu-ZnO/ZrO2 catalysts in the CO2 hydrogenation to CH3OH
journal, November 2008
- Arena, Francesco; Italiano, Giuseppe; Barbera, Katia
- Applied Catalysis A: General, Vol. 350, Issue 1
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol
journal, June 2014
- Bonura, G.; Cordaro, M.; Cannilla, C.
- Applied Catalysis B: Environmental, Vol. 152-153
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method
journal, August 2016
- Dong, Xiaosu; Li, Feng; Zhao, Ning
- Applied Catalysis B: Environmental, Vol. 191
Reverse water-gas shift reaction at the Cu/ZnO interface: Influence of the Cu/Zn ratio on structure-activity correlations
journal, October 2016
- Álvarez Galván, Consuelo; Schumann, Julia; Behrens, Malte
- Applied Catalysis B: Environmental, Vol. 195
CO 2 hydrogenation to methanol over CuO–ZnO–ZrO 2 –SiO 2 catalysts: Effects of SiO 2 contents
journal, May 2017
- Phongamwong, Thanaree; Chantaprasertporn, Usanee; Witoon, Thongthai
- Chemical Engineering Journal, Vol. 316
The effects of zirconia morphology on methanol synthesis from CO and H2H2 over Cu/ZrO2Cu/ZrO2 catalystsPart I. Steady-state studies
journal, July 2005
- Rhodes, M.; Bell, A.
- Journal of Catalysis, Vol. 233, Issue 1
The effects of zirconia morphology on methanol synthesis from CO and H2 over Cu/ZrO2 catalystsPart II. Transient-response infrared studies
journal, July 2005
- Rhodes, M.; Pokrovski, K.; Bell, A.
- Journal of Catalysis, Vol. 233, Issue 1
Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol
journal, July 2007
- Arena, F.; Barbera, K.; Italiano, G.
- Journal of Catalysis, Vol. 249, Issue 2
Transient behavior of Cu/ZnO-based methanol synthesis catalysts
journal, February 2009
- Vesborg, Peter C. K.; Chorkendorff, Ib; Knudsen, Ida
- Journal of Catalysis, Vol. 262, Issue 1
Glycine–nitrate combustion synthesis of CuO–ZnO–ZrO2 catalysts for methanol synthesis from CO2 hydrogenation
journal, May 2010
- Guo, Xiaoming; Mao, Dongsen; Lu, Guanzhong
- Journal of Catalysis, Vol. 271, Issue 2
Effects of oxide carriers on surface functionality and process performance of the Cu–ZnO system in the synthesis of methanol via CO2 hydrogenation
journal, April 2013
- Arena, Francesco; Mezzatesta, Giovanni; Zafarana, Giovanni
- Journal of Catalysis, Vol. 300
Effect of the ZrO2 phase on the structure and behavior of supported Cu catalysts for ethanol conversion
journal, November 2013
- Sato, A. G.; Volanti, D. P.; Meira, D. M.
- Journal of Catalysis, Vol. 307
The Cu–ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures
journal, April 2015
- Le Valant, Anthony; Comminges, Clément; Tisseraud, Céline
- Journal of Catalysis, Vol. 324
Highly selective hydrogenation of CO2 to methanol over CuO–ZnO–ZrO2 catalysts prepared by a surfactant-assisted co-precipitation method
journal, April 2015
- Li, Li; Mao, Dongsen; Yu, Jun
- Journal of Power Sources, Vol. 279
Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO 2 Hydrogenation Processes
journal, May 2017
- Álvarez, Andrea; Bansode, Atul; Urakawa, Atsushi
- Chemical Reviews, Vol. 117, Issue 14
Role of the Cu-ZrO 2 Interfacial Sites for Conversion of Ethanol to Ethyl Acetate and Synthesis of Methanol from CO 2 and H 2
journal, September 2016
- Ro, Insoo; Liu, Yifei; Ball, Madelyn R.
- ACS Catalysis, Vol. 6, Issue 10
In Situ FTIR Spectroscopic Analysis of Carbonate Transformations during Adsorption and Desorption of CO 2 in K-Promoted HTlc
journal, June 2010
- Du, Hai; Williams, Christopher T.; Ebner, Armin D.
- Chemistry of Materials, Vol. 22, Issue 11
Optimizing Binding Energies of Key Intermediates for CO 2 Hydrogenation to Methanol over Oxide-Supported Copper
journal, September 2016
- Kattel, Shyam; Yan, Binhang; Yang, Yixiong
- Journal of the American Chemical Society, Vol. 138, Issue 38
Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface
journal, July 2017
- Kattel, Shyam; Liu, Ping; Chen, Jingguang G.
- Journal of the American Chemical Society, Vol. 139, Issue 29
Theoretical Study of Methanol Synthesis from CO 2 Hydrogenation on Metal-Doped Cu(111) Surfaces
journal, December 2011
- Yang, Yixiong; White, Michael G.; Liu, Ping
- The Journal of Physical Chemistry C, Vol. 116, Issue 1
Adsorption of CO 2 at ZnO: A Surface Structure Effect from DFT+ U Calculations
journal, October 2013
- Tang, Qian-Lin; Luo, Qing-Hong
- The Journal of Physical Chemistry C, Vol. 117, Issue 44
Structure sensitivity of Cu and CuZn catalysts relevant to industrial methanol synthesis
journal, October 2016
- van den Berg, Roy; Prieto, Gonzalo; Korpershoek, Gerda
- Nature Communications, Vol. 7, Issue 1
Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011
- Wang, Wei; Wang, Shengping; Ma, Xinbin
- Chemical Society Reviews, Vol. 40, Issue 7
Au/3DOM Co3O4: highly active nanocatalysts for the oxidation of carbon monoxide and toluene
journal, January 2013
- Xie, Shaohua; Dai, Hongxing; Deng, Jiguang
- Nanoscale, Vol. 5, Issue 22
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000
- Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012
- Behrens, M.; Studt, F.; Kasatkin, I.
- Science, Vol. 336, Issue 6083, p. 893-897
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
journal, May 2016
- Kuld, S.; Thorhauge, M.; Falsig, H.
- Science, Vol. 352, Issue 6288
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
journal, December 2016
- Bu, Lingzheng; Zhang, Nan; Guo, Shaojun
- Science, Vol. 354, Issue 6318
Works referencing / citing this record:
Rational Engineering of Multilayered Co 3 O 4 /ZnO Nanocatalysts through Chemical Transformations from Matryoshka‐Type ZIFs
journal, August 2019
- Huang, Zhongliang; Fan, Longlong; Zhao, Feigang
- Advanced Functional Materials, Vol. 29, Issue 42
CO2 hydrogenation to high-value products via heterogeneous catalysis
journal, December 2019
- Ye, Run-Ping; Ding, Jie; Gong, Weibo
- Nature Communications, Vol. 10, Issue 1
Selective hydrogenation of CO 2 over a Ce promoted Cu-based catalyst confined by SBA-15
journal, January 2019
- Hu, Xiaosong; Zhao, Chaoyue; Guan, Qingxin
- Inorganic Chemistry Frontiers, Vol. 6, Issue 7